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Effect of Boron Content on Steels and
Recommended Practice for Welding
27th September 2018 | By Sasanka Sinha
www.weldaustralia.com.au | info@weldaustralia.com.au | +61 (0)2 8748 0100
What Does Boron Do To Steels
• Boron is beneficial to steels in low concentrations
• Improve steel hardness and impact properties
• A minimum of 0.0005% B is recommended in carbon steels and 0.0012% in Q&T
steels
• In higher concentrations, boron can cause significant structural damage
• Can influence the formation of martensite
• Decreased fatigue life
• Increased carbon equivalence
• Decreases ductility and weldability within steels
• A maximum of 0.0008% B is recommended in carbon steels and 0.0030% in Q&T
steels
• Low fatigue life results in a shorter
functional lifespan of mining
equipment, excavators, structures,
etc.
• Increased costs for maintenance of
equipment
• Martensite formation may result in
sudden failure of structural supports
• Sudden failure can be catastrophic
to safety
Limitations of High Boron Steel in Mining
• ISO 4948 recommends separate
boron concentration ranges for
carbon steels and Q&T steels
• AS/NZS 1554.1 introduced a
maximum boron concentration for
prequalified steels in welding
• No Australian standard covers
welding of high boron steels
• This paper provides guidance for
the welding of high boron steels
Recommended
Boron Range for
Steels
Minimum Maximum
Carbon Steels 0.0005% 0.0008%
Quenched and
Tempered Steels
0.0012% 0.0030%
How Standards Regulate Boron Control
Parameters to Consider While Welding
• Concentration
• Boron Concentration
• Carbon Equivalence
• Measuring Boron
• Temperature
• Preheat Temperature
• Interpass Temperature
• Post Weld Heat Treatment
• A high boron concentration can
dramatically increase the carbon
equivalence in steels
• This can cause martensite to form
more readily
• Multiple formulas have been
developed to calculate the carbon
equivalency (CE)
Concentration
• Recommended practice is to
calculate the carbon equivalent
value
• Manufacturers should check for
boron compliance on the mill
certificate
Concentration
• Measuring boron can be done using
the following techniques:
• Energy Dispersive X-ray Spectroscopy
(EDX)
• Inductively Coupled Plasma Atomic
Emission Spectroscopy (ICP)
• X-ray Fluorescence Spectrometry (XRF)
• Optical Emission Spectroscopy (OES)
Concentration
EDX
• Highest Sensitivity
• Requires Electron Microscope
ICP
• High Accuracy
• Reliable Results
XRF
• Portable
• Low Accuracy
OES
• Readily Available
• Low Accuracy
• Martensite forms when the cooling
rate in steels are too high
• To restrict grain transformation of
martensite, the cooling rate must be
slowed and/or monitored
• Time temperature graphs can
indicate which cooling rates will not
form martensite
Temperature
• The best practice would be to
develop a weld procedure
specification (WPS)
• The WPS should note the preheat
temperature, interpass
temperature, and post weld heat
treatment for the weld
• Welders using a WPS should be
qualified to follow the instructions
of the WPS
Temperature
Case Study
Case Study
• Without best practice, quality
management cannot be achieved
• Safety can only be guaranteed with
quality management
• The implementation of procedures
and practices laid out by Standards
and work instructions ensure both
quality and safety
• Implementation is key!
“When selecting the appropriate weld quality
management requirements, the application
requirements determine the design code or
standard, which sets materials, fabrication and
inspection specifics to economically and safely
deliver the required technology or product.”
- Louise Petrick,
Weld Australia
Quality is Safety
For a repair on a mining excavator, a
repair strategy was developed. This
included:
• Inspection of the excavator
• Design of a repair strategy
• Preparation for the repair
• Implementation of a weld
procedure
Case Study: Weld Repair on an Excavator
• To understand the weld repair
required, a visual inspection was
conducted
• A visual inspection is a very
powerful tool for failure analysis
• Allows us to determine the root cause
of failure
• Useful to determine the extent of
damage
• Assists in the development of repair
strategy
Inspection of the Excavator
Checklists for Repair Strategy
Failure Details
• Crack initiation
point
• Load conditions
on cracked area
• Nature of crack
Repair Information
• Information
available
• Accessibility of
welding
• Availability of
welding
equipment
• Results of
gouging
Personnel
Involvement
• Authorisation of
weld repair
• Ability of welders
• Qualifications
within welding
personnel
Details of
Excavator
• Is it a repeat
repair?
• Machine purpose
and use
• Hours of
excavator
operation
Repair Strategies Are Unique
• The machine being repaired may exist under special environmental
conditions (e.g. windy environments restrict the use of gas shielding)
• The location of repair may be difficult to access (e.g. the track frame of the
excavator may restrict access to the repair)
• The size of the repair may affect the repair process
Preparation
Checking
Cracks
Check Size &
Position of
Cracks
Cause of
Problems
Study of Repair
Methods
Gouging and
Grinding
Fit-Up of Part
for Welding
Repair
Issue Weld
Procedure
Weld to Given
Procedure
Visual
Inspection,
UT/RT
Weld Profile
Improvement
Painting
Reassembly &
Final Check
Typical Repair Strategy
• Visual inspection revealed worn out
edges
• Fractured weld surface revealed lack
of fusion at the weld
• Serious manufacturing deficiency
• Grinding and magnetic particle
testing was done on track frame
• Weld build-up was carried out on
the edges
Case Study – Excavator Preparation
Case Study – Excavator Preparation
The edges on the ring were ground to 35 degree chamfers on both sides and a 3 mm gap was added between the two parts.
Welding Parameters
Type of
Pass
Welding
Position
Wire Size
(Diameter)
Voltage
(V)
Current
(A)
Root
Pass
Flat 1.2 mm 26 – 28 230 – 260
Filler
Pass
Flat 1.2 mm 28 – 30 240 – 280
Capping
Pass
Flat 1.2 mm 30 - 32 240 – 260
Case Study – Excavator Repair
Inside Swing Circle Mounting Seat Outside Swing Circle Mounting Seat
Case Study – Outcome of Repair
Case Study – Outcome of Repair
The outcomes of this excavation repair include:
• Ultrasonic testing of all critical joints
• Periodic in service inspection
• Improvement in weld profiling
• Training and certification of welders
• More effective control on shop floor and inspection stages
Case Study – Outcome of Repair
By implementing these outcomes, the following was achieved:
• Better practice in welding and general repairs
• Routine inspections to ensure safe operation of excavator
• Reduction in downtime and repair costs
• Improved safety and availability of the excavator
• The best practice in welding
operations is to adopt quality
management and process control
throughout the process
• Quality MUST be built into welds
• AS/NZS ISO 3834 outlines the
requirements for effective process
control
• Process control is critical for
ensuring safe operation within
industry
Ensuring Quality in Operations
Conclusion
• The concentration of boron in steels must be identified through the mill
certificate
• High boron steels must maintain a steady and slow cooling rate while
welding
• The use of a repair strategy results in good practice within several industries
• The best and safest practice comes with the implementation of a process
and production control system
Thank you!
Any questions?

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Effect of boron content on steels and recommended practice for welding Sasanka Sinha

  • 1. Effect of Boron Content on Steels and Recommended Practice for Welding 27th September 2018 | By Sasanka Sinha www.weldaustralia.com.au | info@weldaustralia.com.au | +61 (0)2 8748 0100
  • 2. What Does Boron Do To Steels • Boron is beneficial to steels in low concentrations • Improve steel hardness and impact properties • A minimum of 0.0005% B is recommended in carbon steels and 0.0012% in Q&T steels • In higher concentrations, boron can cause significant structural damage • Can influence the formation of martensite • Decreased fatigue life • Increased carbon equivalence • Decreases ductility and weldability within steels • A maximum of 0.0008% B is recommended in carbon steels and 0.0030% in Q&T steels
  • 3. • Low fatigue life results in a shorter functional lifespan of mining equipment, excavators, structures, etc. • Increased costs for maintenance of equipment • Martensite formation may result in sudden failure of structural supports • Sudden failure can be catastrophic to safety Limitations of High Boron Steel in Mining
  • 4. • ISO 4948 recommends separate boron concentration ranges for carbon steels and Q&T steels • AS/NZS 1554.1 introduced a maximum boron concentration for prequalified steels in welding • No Australian standard covers welding of high boron steels • This paper provides guidance for the welding of high boron steels Recommended Boron Range for Steels Minimum Maximum Carbon Steels 0.0005% 0.0008% Quenched and Tempered Steels 0.0012% 0.0030% How Standards Regulate Boron Control
  • 5. Parameters to Consider While Welding • Concentration • Boron Concentration • Carbon Equivalence • Measuring Boron • Temperature • Preheat Temperature • Interpass Temperature • Post Weld Heat Treatment
  • 6. • A high boron concentration can dramatically increase the carbon equivalence in steels • This can cause martensite to form more readily • Multiple formulas have been developed to calculate the carbon equivalency (CE) Concentration
  • 7. • Recommended practice is to calculate the carbon equivalent value • Manufacturers should check for boron compliance on the mill certificate Concentration
  • 8. • Measuring boron can be done using the following techniques: • Energy Dispersive X-ray Spectroscopy (EDX) • Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP) • X-ray Fluorescence Spectrometry (XRF) • Optical Emission Spectroscopy (OES) Concentration EDX • Highest Sensitivity • Requires Electron Microscope ICP • High Accuracy • Reliable Results XRF • Portable • Low Accuracy OES • Readily Available • Low Accuracy
  • 9. • Martensite forms when the cooling rate in steels are too high • To restrict grain transformation of martensite, the cooling rate must be slowed and/or monitored • Time temperature graphs can indicate which cooling rates will not form martensite Temperature
  • 10. • The best practice would be to develop a weld procedure specification (WPS) • The WPS should note the preheat temperature, interpass temperature, and post weld heat treatment for the weld • Welders using a WPS should be qualified to follow the instructions of the WPS Temperature
  • 13. • Without best practice, quality management cannot be achieved • Safety can only be guaranteed with quality management • The implementation of procedures and practices laid out by Standards and work instructions ensure both quality and safety • Implementation is key! “When selecting the appropriate weld quality management requirements, the application requirements determine the design code or standard, which sets materials, fabrication and inspection specifics to economically and safely deliver the required technology or product.” - Louise Petrick, Weld Australia Quality is Safety
  • 14. For a repair on a mining excavator, a repair strategy was developed. This included: • Inspection of the excavator • Design of a repair strategy • Preparation for the repair • Implementation of a weld procedure Case Study: Weld Repair on an Excavator
  • 15. • To understand the weld repair required, a visual inspection was conducted • A visual inspection is a very powerful tool for failure analysis • Allows us to determine the root cause of failure • Useful to determine the extent of damage • Assists in the development of repair strategy Inspection of the Excavator
  • 16. Checklists for Repair Strategy Failure Details • Crack initiation point • Load conditions on cracked area • Nature of crack Repair Information • Information available • Accessibility of welding • Availability of welding equipment • Results of gouging Personnel Involvement • Authorisation of weld repair • Ability of welders • Qualifications within welding personnel Details of Excavator • Is it a repeat repair? • Machine purpose and use • Hours of excavator operation
  • 17. Repair Strategies Are Unique • The machine being repaired may exist under special environmental conditions (e.g. windy environments restrict the use of gas shielding) • The location of repair may be difficult to access (e.g. the track frame of the excavator may restrict access to the repair) • The size of the repair may affect the repair process
  • 18. Preparation Checking Cracks Check Size & Position of Cracks Cause of Problems Study of Repair Methods Gouging and Grinding Fit-Up of Part for Welding Repair Issue Weld Procedure Weld to Given Procedure Visual Inspection, UT/RT Weld Profile Improvement Painting Reassembly & Final Check Typical Repair Strategy
  • 19. • Visual inspection revealed worn out edges • Fractured weld surface revealed lack of fusion at the weld • Serious manufacturing deficiency • Grinding and magnetic particle testing was done on track frame • Weld build-up was carried out on the edges Case Study – Excavator Preparation
  • 20. Case Study – Excavator Preparation The edges on the ring were ground to 35 degree chamfers on both sides and a 3 mm gap was added between the two parts.
  • 21. Welding Parameters Type of Pass Welding Position Wire Size (Diameter) Voltage (V) Current (A) Root Pass Flat 1.2 mm 26 – 28 230 – 260 Filler Pass Flat 1.2 mm 28 – 30 240 – 280 Capping Pass Flat 1.2 mm 30 - 32 240 – 260 Case Study – Excavator Repair
  • 22. Inside Swing Circle Mounting Seat Outside Swing Circle Mounting Seat Case Study – Outcome of Repair
  • 23. Case Study – Outcome of Repair The outcomes of this excavation repair include: • Ultrasonic testing of all critical joints • Periodic in service inspection • Improvement in weld profiling • Training and certification of welders • More effective control on shop floor and inspection stages
  • 24. Case Study – Outcome of Repair By implementing these outcomes, the following was achieved: • Better practice in welding and general repairs • Routine inspections to ensure safe operation of excavator • Reduction in downtime and repair costs • Improved safety and availability of the excavator
  • 25. • The best practice in welding operations is to adopt quality management and process control throughout the process • Quality MUST be built into welds • AS/NZS ISO 3834 outlines the requirements for effective process control • Process control is critical for ensuring safe operation within industry Ensuring Quality in Operations
  • 26. Conclusion • The concentration of boron in steels must be identified through the mill certificate • High boron steels must maintain a steady and slow cooling rate while welding • The use of a repair strategy results in good practice within several industries • The best and safest practice comes with the implementation of a process and production control system