At Bell Laboratories, Brattain and Bardeen worked to develop electronic replacements for vacuum tubes. They experimented with using copper and copper oxide to regulate devices through rectification, but these devices did not work. They made a breakthrough when exploring the behavior of silicon samples exposed to light, discovering an "internal barrier" effect. After further experimenting and refining silicon samples, they were able to amplify power and voltage at a high frequency, inventing the first transistor. Kelly then clamped down secrecy at Bell Labs to protect their patentable discovery.