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UNIT TEST
Unit 1 Stoichiometry – Teacher Marked
Questions
Q25
C H O
Mol 40.00/12.01 = 3.331 Mol 6.73 / 1.01 = 6.663 Mol 53.27 / 16.00 = 3.330
(1 mark)
RatioC: H: O = 1:2:1
(1 mark)
Empirical formula=CH2O
(1 mark)
Mr CH2O = 30
(1 mark)
Molecularformula= 90 / 30 = 3 = (CH2O)3 = C3H6O3
(1 mark)
Q26
Mol KCl = 15.62 / [39.10 + 35.45] = 0.2095 mol
(1 mark)
Mol H2SO4 = (3/4) × 0.2095 = 0.1571 mol
(1 mark)
Mass H2SO4 = 0.1571 × [(1.01 × 2) + 32.07 + (16.00 × 4)] = 15.41g
(1 mark)
RatioKCl : CrO2Cl2 = 4:2 = 2:1
(1 mark)
Mol CrO2Cl2 = 0.2095 / 2 = 0.1048 mol
(1 mark)
Mass CrO2Cl2 =0.1048 × [52.00 + (16.00 × 2) + (35.45 × 2)] = 16.23g
(1 mark)
Q27
Mol KCl = 0.8114 / (39.10 + 35.45) = 0.01088 mol
(1 mark)
Mol K2Cr2O7 =0.2471 / [(39.10 × 2) + (52.00 × 2) + (16.00 × 7)] = 0.0008399 mol
(1 mark)
RatioKCl : K2Cr2O7 = 4:1
0.01088 mol KCl wouldneed 0.00272 mol K2Cr2O7 so K2Cr2O7 = limitingreagent(getsusedup)
(1 mark)
Mol CrO2Cl2 =0.0008399 × 2 = 0.0016798 mol
Mass CrO2Cl2 = 0.0016798 × [52.00 + (16.00 × 2) + (35.45 × 2)] = 0.2602g
(1 mark)
Mol K2SO4 = 0.0008399 × 3 = 0.0025197 mol
Mass K2SO4 = 0.0025197 × [(39.10 × 2) + 32.07 + (16.00 × 4)] = 0.4391g
(1 mark)
MolesH2O = 0.0008399 × 3 = 0.0025197 mol
Mass H2O = 0.0025197 × [(1.01 × 2) + 16.00] = 0.0454g
(1 mark)
Q29
Mol NaOH = 0.8442 × (12.85 / 1000) = 0.01085 mol
(1 mark)
RatioNaOH : CHCl3 = 7:2
Mol CHCl3 = 0.01085 × (2/7) = 0.0031 mol
(1 mark)
Concentration=0.0031 / (18.45/1000) = 0.1680 mol dm-3
(1 mark)
Q30
Mol Cl2 = 1068 / (35.45 × 2) = 15.06 mol
(1 mark)
Volume Cl2 =nRT / P = 15.06 × 8.31 × [273+25] / 89589 = 0.4163 m3
(1 mark)
RatioCl2:O2 = 10:5 = 2:1
Volume O2 = 0.4163 / 2 = 0.2081 m3
(1 mark)
[Total: 50 marks]

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Ch u1l18 unit_test_answers

  • 1. UNIT TEST Unit 1 Stoichiometry – Teacher Marked Questions Q25 C H O Mol 40.00/12.01 = 3.331 Mol 6.73 / 1.01 = 6.663 Mol 53.27 / 16.00 = 3.330 (1 mark) RatioC: H: O = 1:2:1 (1 mark) Empirical formula=CH2O (1 mark) Mr CH2O = 30 (1 mark) Molecularformula= 90 / 30 = 3 = (CH2O)3 = C3H6O3 (1 mark) Q26 Mol KCl = 15.62 / [39.10 + 35.45] = 0.2095 mol (1 mark) Mol H2SO4 = (3/4) × 0.2095 = 0.1571 mol (1 mark) Mass H2SO4 = 0.1571 × [(1.01 × 2) + 32.07 + (16.00 × 4)] = 15.41g (1 mark) RatioKCl : CrO2Cl2 = 4:2 = 2:1 (1 mark) Mol CrO2Cl2 = 0.2095 / 2 = 0.1048 mol (1 mark) Mass CrO2Cl2 =0.1048 × [52.00 + (16.00 × 2) + (35.45 × 2)] = 16.23g (1 mark)
  • 2. Q27 Mol KCl = 0.8114 / (39.10 + 35.45) = 0.01088 mol (1 mark) Mol K2Cr2O7 =0.2471 / [(39.10 × 2) + (52.00 × 2) + (16.00 × 7)] = 0.0008399 mol (1 mark) RatioKCl : K2Cr2O7 = 4:1 0.01088 mol KCl wouldneed 0.00272 mol K2Cr2O7 so K2Cr2O7 = limitingreagent(getsusedup) (1 mark) Mol CrO2Cl2 =0.0008399 × 2 = 0.0016798 mol Mass CrO2Cl2 = 0.0016798 × [52.00 + (16.00 × 2) + (35.45 × 2)] = 0.2602g (1 mark) Mol K2SO4 = 0.0008399 × 3 = 0.0025197 mol Mass K2SO4 = 0.0025197 × [(39.10 × 2) + 32.07 + (16.00 × 4)] = 0.4391g (1 mark) MolesH2O = 0.0008399 × 3 = 0.0025197 mol Mass H2O = 0.0025197 × [(1.01 × 2) + 16.00] = 0.0454g (1 mark) Q29 Mol NaOH = 0.8442 × (12.85 / 1000) = 0.01085 mol (1 mark) RatioNaOH : CHCl3 = 7:2 Mol CHCl3 = 0.01085 × (2/7) = 0.0031 mol (1 mark) Concentration=0.0031 / (18.45/1000) = 0.1680 mol dm-3 (1 mark) Q30 Mol Cl2 = 1068 / (35.45 × 2) = 15.06 mol (1 mark)
  • 3. Volume Cl2 =nRT / P = 15.06 × 8.31 × [273+25] / 89589 = 0.4163 m3 (1 mark) RatioCl2:O2 = 10:5 = 2:1 Volume O2 = 0.4163 / 2 = 0.2081 m3 (1 mark) [Total: 50 marks]