This paper presents a novel approach using cellular automata to model the durability analysis of concrete structures exposed to aggressive environmental agents. The diffusion of these agents is modeled using cellular automata, which represent physical systems with discrete space, time, and state values. Mechanical damage from diffusion is evaluated using degradation laws. The interaction of diffusion and structural behavior is captured by modeling stochastic effects in mass transfer. Nonlinear structural analyses over time are performed using a deteriorating concrete beam element within a finite element framework. The approach is demonstrated on applications including a concrete box girder, T-beam, and arch bridge to identify critical members.