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CARBON COMPOUNDS
Std. X
Science & Technology - I
IUPAC nomenclature system
International Union for Pure and Applied Chemistry
(IUPAC)
• An IUPAC name is given to a compound based on the
name of its parent alkane.
prefix - parent - suffix
• Step 1:
• Draw the structural formula of the straight chain compound
and count the number of carbon atoms in it.
• Write the name of this alkane.
• If the compound contains a double bond OR a triple bond
change the ending of the parent's name from ‘ane’ to ‘ene’ OR
from ‘ane’ to ‘yne’.
IUPAC nomenclature system
International Union for Pure and Applied Chemistry
(IUPAC)
• Step 2: If the structural formula contains a functional group
replaces the last letter ‘e’ from the parent's name with the
condensed name of the functional group as the suffix.
(Exception: The condensed name of the functional group
‘halogen’ is always attached as the prefix.)
• Step 3: Number the carbon atoms in the carbon chain from
one end to the other. Assign the number ‘1’ to carbon in the
functional group -CHO or -COOH, if present, Otherwise, the
chain can be numbered in two directions. Accept that
numbering which gives a smaller number to the carbon
carrying the functional group. In the final name, a digit
(number) and a character (letter) should be separated by a
small horizontal line
IUPAC nomenclature system
Important carbon compounds
• Ethanol:
• At room temperature colourless ethanol is a liquid
• its boiling points is 78 0C.
• Generally ethanol is called alcohol or spirit.
• Ethanol is soluble in water in all proportions.
• When aqueous solution of ethanol is tested with litmus paper it is found to be
neutral.
• Consumption of small quantities of dilute ethanol shows its effect, even though is
condemned still it has remained a socially widespread practice. Consumption of
alcohol harms health in a number of ways.
• It adversely affects the physiological processes and the central nervous system.
Consumption of even a small quantity of pure ethanol (called absolute alcohol) can
be lethal. Ethanol being a good solvent, it is used in medicines such as tincture iodine
(solution of iodine and ethanol), cough mixture, and also in many tonics.
Chemical properties of ethanol
• Reaction with sodium
2Na + 2CH3-CH2- OH  2 CH3-CH2-ONa+ H2
All the alcohols react with sodium metal to liberate hydrogen gas and form
sodium alkoxide salts. In the reaction of ethanol with sodium metal, hydrogen
gas and sodium ethaoxide are formed as products.
Chemical properties of ethanol
• Dehydration reaction: When ethanol is heated at the temperature
170 0C with an excess amount of concentrated sulphuric acid, one
molecule of water is removed from its molecule to form ethene, an
unsaturated compound.
CH3-CH2-OH  CH2=CH2 + H2O
• Here, concentrated sulphuric acid acts as a dehydrating agent.
Important carbon compounds
• Ethanoic acid:
• Ethanoic acid is a colourless liquid with boiling point1180C.
• Ethanoic acid is commonly known as acetic acid.
• Its aqueous solution is acidic and turns blue litmus red.
• Vineger, which is used as preservative in pickles, is a 5-8 % aqueous solution
of acetic acid.
• The melting point of pure ethanoic acid is 170 0C . Therefore, during winter in
cold countries ethanoic acid freezes at room temperature itself and looks like
ice. Therefore it is named ‘glacial acetic acid’.
Chemical properties of ethanoic acid
• Reaction with base
• A reaction with strong base
• Ethanoic acid gives neutralization reaction with a strong base sodium
hydroxide to form a salt and water.
CH3-COOH + NaOH  CH3-COO Na + H2O
• The IUPAC name of the salt formed here is sodium ethanoate while
it’s common name is sodium acetate.
Chemical properties of ethanoic acid
• Reaction with carbonate and bicarbonate
• Ethanoic acid reacts with the basic salt, namely, sodium carbonate, to form a
salt , named sodium ethanoate, water and carbon dioxide gas.
• The CO2 gas of the effervescence passes through the gas delivery tube and
reacts with the lime water in the small test tube. ‘Lime water turning milky’ is
the test of carbon dioxide gas. If sodium bicarbonate is used instead of
sodium carboanate in the above activity, similar observation are obtained.
CH3COOH + NaHCO3  CH3COONa+ H2O + CO2

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Carbon Compounds.pptx

  • 2. IUPAC nomenclature system International Union for Pure and Applied Chemistry (IUPAC) • An IUPAC name is given to a compound based on the name of its parent alkane. prefix - parent - suffix • Step 1: • Draw the structural formula of the straight chain compound and count the number of carbon atoms in it. • Write the name of this alkane. • If the compound contains a double bond OR a triple bond change the ending of the parent's name from ‘ane’ to ‘ene’ OR from ‘ane’ to ‘yne’.
  • 3. IUPAC nomenclature system International Union for Pure and Applied Chemistry (IUPAC) • Step 2: If the structural formula contains a functional group replaces the last letter ‘e’ from the parent's name with the condensed name of the functional group as the suffix. (Exception: The condensed name of the functional group ‘halogen’ is always attached as the prefix.) • Step 3: Number the carbon atoms in the carbon chain from one end to the other. Assign the number ‘1’ to carbon in the functional group -CHO or -COOH, if present, Otherwise, the chain can be numbered in two directions. Accept that numbering which gives a smaller number to the carbon carrying the functional group. In the final name, a digit (number) and a character (letter) should be separated by a small horizontal line
  • 5.
  • 6. Important carbon compounds • Ethanol: • At room temperature colourless ethanol is a liquid • its boiling points is 78 0C. • Generally ethanol is called alcohol or spirit. • Ethanol is soluble in water in all proportions. • When aqueous solution of ethanol is tested with litmus paper it is found to be neutral. • Consumption of small quantities of dilute ethanol shows its effect, even though is condemned still it has remained a socially widespread practice. Consumption of alcohol harms health in a number of ways. • It adversely affects the physiological processes and the central nervous system. Consumption of even a small quantity of pure ethanol (called absolute alcohol) can be lethal. Ethanol being a good solvent, it is used in medicines such as tincture iodine (solution of iodine and ethanol), cough mixture, and also in many tonics.
  • 7. Chemical properties of ethanol • Reaction with sodium 2Na + 2CH3-CH2- OH  2 CH3-CH2-ONa+ H2 All the alcohols react with sodium metal to liberate hydrogen gas and form sodium alkoxide salts. In the reaction of ethanol with sodium metal, hydrogen gas and sodium ethaoxide are formed as products.
  • 8. Chemical properties of ethanol • Dehydration reaction: When ethanol is heated at the temperature 170 0C with an excess amount of concentrated sulphuric acid, one molecule of water is removed from its molecule to form ethene, an unsaturated compound. CH3-CH2-OH  CH2=CH2 + H2O • Here, concentrated sulphuric acid acts as a dehydrating agent.
  • 9. Important carbon compounds • Ethanoic acid: • Ethanoic acid is a colourless liquid with boiling point1180C. • Ethanoic acid is commonly known as acetic acid. • Its aqueous solution is acidic and turns blue litmus red. • Vineger, which is used as preservative in pickles, is a 5-8 % aqueous solution of acetic acid. • The melting point of pure ethanoic acid is 170 0C . Therefore, during winter in cold countries ethanoic acid freezes at room temperature itself and looks like ice. Therefore it is named ‘glacial acetic acid’.
  • 10. Chemical properties of ethanoic acid • Reaction with base • A reaction with strong base • Ethanoic acid gives neutralization reaction with a strong base sodium hydroxide to form a salt and water. CH3-COOH + NaOH  CH3-COO Na + H2O • The IUPAC name of the salt formed here is sodium ethanoate while it’s common name is sodium acetate.
  • 11. Chemical properties of ethanoic acid • Reaction with carbonate and bicarbonate • Ethanoic acid reacts with the basic salt, namely, sodium carbonate, to form a salt , named sodium ethanoate, water and carbon dioxide gas. • The CO2 gas of the effervescence passes through the gas delivery tube and reacts with the lime water in the small test tube. ‘Lime water turning milky’ is the test of carbon dioxide gas. If sodium bicarbonate is used instead of sodium carboanate in the above activity, similar observation are obtained. CH3COOH + NaHCO3  CH3COONa+ H2O + CO2