The 2nd Law of Thermodynamics states that entropy, a measure of the number of microscopic arrangements of a system, always increases over time. Entropy is often misunderstood but can be calculated and measured. It is directly related to the number of possible macrostates a system can have for a given microstate and represents the system's degrees of freedom. While reversibility is theoretically possible, natural processes are irreversible and always lead to an increase in entropy. Rudolf Clausius originated the concept of entropy and demonstrated that heat transfer between objects always results in an overall rise in entropy across systems.