Introduction, Properties &
Applications of 2D Materials
Assad Ur Rehman
Contents
 Introduction
 History
 Types
 Properties
 Synthesis
 Characterization
 Applications
Introduction
 Single or Multi layered materials having
negligible thickness (~atomic scale).
 For graphene, 1 to 10 layers are treated
as 2D Material.
 Multi layered materials are regarded as 3D
materials when they have considerable
thickness.
[1]. Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.
History
 Bordie in 1859 made a failed attempt to
exfoliate a single sheet from graphite.
 R.E. Peierls and L.D. Landau in 1937
suggested that strictly 2D material could
not exist.
 Hahns-Peter Bohm introduced the term
graphene in 1962.
 Geim and Novesolov got Nobel Prize in
2004 for exfoliation of stable graphene and
its characterization.
[1]. Brodie, B. C. Philosophical Transactions of the Royal Society of London 1859,149, 249.
[2]. Joensen, P.; Frindt, R. F.; Morrison, S. R. Mater. Res. Bull. 1986, 21, 457.
[3]. Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.
Different Types Of 2Ds
 Graphene: Single layer of Carbon.
 Germanene :Single layer of Germenium.
 Silicene: Single layer of Silicon.
 Phospherene: Single layer of phosphorus.
 Hexa Boron Nitride: Compund 2D material
with alternating Boron and Nitrogen atoms.
 Transition Metals Dichalcogenides:
Compund 2D materials of Transition
metals & Chalcogens.
1] Lee, Kangho; Kim, Hye-Young; Lotya, Mustafa; Coleman, Jonathan N.; Kim, Gyu-Tae; Duesberg, Georg S. (2011-09-22).
2] Wu, Haihua; Yang, Rong; Song, Baomin; Han, Qiusen; Li, Jingying; Zhang, Ying; Fang, Yan; Tenne, Reshef; Wang,
Chen. "Biocompatible Inorganic Fullerene-Like Molybdenum Disulfide Nanoparticles Produced by Pulsed Laser Ablation
in Water
Graphene
 2D carbon allotrope having atomic
dimensions with honeycomb structure.
 Monolayer of graphene has a thickness of
3.4𝐴.
 Nearly (97.7% per monolayer) transparent
to visible light.
 100 times stronger than steel (Strength
130 GPa).
Graphene
 Highest thermal and electrical conductivity
(mobility 2,00,000𝑐𝑚2
/𝑉𝑠)
 Semi Metal
Interesting, right?
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2d materials introductions

  • 1.
    Introduction, Properties & Applicationsof 2D Materials Assad Ur Rehman
  • 2.
    Contents  Introduction  History Types  Properties  Synthesis  Characterization  Applications
  • 3.
    Introduction  Single orMulti layered materials having negligible thickness (~atomic scale).  For graphene, 1 to 10 layers are treated as 2D Material.  Multi layered materials are regarded as 3D materials when they have considerable thickness. [1]. Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.
  • 4.
    History  Bordie in1859 made a failed attempt to exfoliate a single sheet from graphite.  R.E. Peierls and L.D. Landau in 1937 suggested that strictly 2D material could not exist.  Hahns-Peter Bohm introduced the term graphene in 1962.  Geim and Novesolov got Nobel Prize in 2004 for exfoliation of stable graphene and its characterization. [1]. Brodie, B. C. Philosophical Transactions of the Royal Society of London 1859,149, 249. [2]. Joensen, P.; Frindt, R. F.; Morrison, S. R. Mater. Res. Bull. 1986, 21, 457. [3]. Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.
  • 5.
    Different Types Of2Ds  Graphene: Single layer of Carbon.  Germanene :Single layer of Germenium.  Silicene: Single layer of Silicon.  Phospherene: Single layer of phosphorus.  Hexa Boron Nitride: Compund 2D material with alternating Boron and Nitrogen atoms.  Transition Metals Dichalcogenides: Compund 2D materials of Transition metals & Chalcogens. 1] Lee, Kangho; Kim, Hye-Young; Lotya, Mustafa; Coleman, Jonathan N.; Kim, Gyu-Tae; Duesberg, Georg S. (2011-09-22). 2] Wu, Haihua; Yang, Rong; Song, Baomin; Han, Qiusen; Li, Jingying; Zhang, Ying; Fang, Yan; Tenne, Reshef; Wang, Chen. "Biocompatible Inorganic Fullerene-Like Molybdenum Disulfide Nanoparticles Produced by Pulsed Laser Ablation in Water
  • 6.
    Graphene  2D carbonallotrope having atomic dimensions with honeycomb structure.  Monolayer of graphene has a thickness of 3.4𝐴.  Nearly (97.7% per monolayer) transparent to visible light.  100 times stronger than steel (Strength 130 GPa).
  • 7.
    Graphene  Highest thermaland electrical conductivity (mobility 2,00,000𝑐𝑚2 /𝑉𝑠)  Semi Metal
  • 8.
    Interesting, right? This isjust a sneak preview of the full presentation. We hope you like it! To see the rest of it, just click here to view it in full on PowerShow.com. Then, if you’d like, you can also log in to PowerShow.com to download the entire presentation for free.