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Characterization on Microstructure
/XXX Property of the XXX Material
(Focous on a specific material)
NPU
2023.06.02.
Name:MUBEEN Malik Ahmed
Student ID:2022180008
Outline
1. The introduction of 1D/2D/3D(choose one of them)-dimensional
XXX materials
2. Characterization on structure/processing/performace of the
XXX materials
3.Analysis on relationship between performace and
microstructure/processing of the XXX materials
Introduction to 2D Grephene structure
The excellent performances of graphene are derived
from its unique 2D crystal structure. The horizontal
dimension of graphene can be sufficiently extended,
while the thickness is only in atomic scale. Thus, the
structural characterizations of graphene need to take
into account horizontal macroscopic scale as well as
atomic level analysis.
Structure of grephene
Characterization Of Grephene
Graphene’s characterization is an important aspect of
the study and research of graphene. Characterizations
involve the investigation of graphene morphology,
properties, defects, and layers based on spectroscopic
and microscopic measurements. Raman Spectroscopy,
Scanning electron microscope (SEM), Transmission
electron microscope (TEM), X-ray diffraction (XRD),
ultraviolet–visible spectroscopy (UV–Vis), and
atomic force microscopy (AFM) are used
characterization techniques.
By Raman Spectroscopy Graphene layers and the
structural quality can be studied by Raman
spectroscopy. Monochromatic radiation of Raman
spectroscopy interacts with the molecular vibration of
graphene resulting in a shift in radiation due to
scattering. Three main peaks are observed in graphene
and include; D, G and 2D peaks. D peak is observed
at 1350 cm−1 indicating a disorder in sp2
hybridization. G peak is located at 1580 cm−1
representing lattice vibration and 2D is located at
2700 cm−1 originating from Raman scattering second
order at Dirac point.
An increase in graphene disorder increases the ratio
ID/IG because of the elastic scattering due to the
higher defect intensity. However, when the carbon
structure becomes more amorphous, the ID/IG ratio
decreases. Jorio et al. conducted a Raman study on the
ion-induced defects in N-layer graphene. Raman
spectrum of graphene also known as the G band,
exhibits G mode due to the stretching of the C–C
bond. It is marked by a strong peaks at 1580 cm−1
which is the first-order of the Raman spectrum-
allowed feature originating from the zone centre
(Photon wave vector q = 0).
Applications
 Energy storage
Water filtration technology
Transistors
Solar cells
Biomedicine
References
[1] S. Bharech, R.J.J.M.S.M.E. Kumar, A review on the
properties and applications of graphene. 2015. 2(10): p. 70.
[2] K. Spyrou, P.J.F.o.g. Rudolf, An introduction to graphene.
2014: p. 1-20.
[3] Z.U. Khan, et al., A review of graphene oxide, graphene
buckypaper, and polymer/graphene composites: Properties and
fabrication techniques. 2016. 32 (4): p. 336-379.
[4] M. Skoda, et al., Graphene: one material, many possibilities—
application difficulties in biological systems, J. Nanomater. 2014
(2014), 890246.
[5] Y. Seekaew, et al., Synthesis, characterization, and
applications of graphene and derivatives, in: Carbon-Based
Nanofillers and their Rubber Nanocomposites, Elsevier, 2019, pp.
259–283.
[6] H. Shinohara, A. Tiwari, Graphene: an introduction to the
fundamentals and industrial applications. 2015: John Wiley &
Sons.
[7] M.J. Allen, V.C. Tung, R.B.J.C.r. Kaner, Honeycomb carbon:
a review of graphene. 2010. 110(1): p. 132-145.
[8] S.S. Shams, R. Zhang, J.J.M.S.-P. Zhu, Graphene synthesis: a
Review. 2015. 33(3): p. 566-578.
[9] T. Mathew et al., Graphene-based functional nanomaterials
for biomedical and bioanalysis applications. 2020. 23: p. 100184.
[10] T.P.D. Shareena et al., A review on graphene-based
nanomaterials in biomedical applications and risks in
environment and health. 2018. 10(3): p. 1-34.

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formate.pptx

  • 1. Characterization on Microstructure /XXX Property of the XXX Material (Focous on a specific material) NPU 2023.06.02. Name:MUBEEN Malik Ahmed Student ID:2022180008
  • 2. Outline 1. The introduction of 1D/2D/3D(choose one of them)-dimensional XXX materials 2. Characterization on structure/processing/performace of the XXX materials 3.Analysis on relationship between performace and microstructure/processing of the XXX materials
  • 3. Introduction to 2D Grephene structure The excellent performances of graphene are derived from its unique 2D crystal structure. The horizontal dimension of graphene can be sufficiently extended, while the thickness is only in atomic scale. Thus, the structural characterizations of graphene need to take into account horizontal macroscopic scale as well as atomic level analysis.
  • 5. Characterization Of Grephene Graphene’s characterization is an important aspect of the study and research of graphene. Characterizations involve the investigation of graphene morphology, properties, defects, and layers based on spectroscopic and microscopic measurements. Raman Spectroscopy, Scanning electron microscope (SEM), Transmission electron microscope (TEM), X-ray diffraction (XRD), ultraviolet–visible spectroscopy (UV–Vis), and atomic force microscopy (AFM) are used characterization techniques.
  • 6. By Raman Spectroscopy Graphene layers and the structural quality can be studied by Raman spectroscopy. Monochromatic radiation of Raman spectroscopy interacts with the molecular vibration of graphene resulting in a shift in radiation due to scattering. Three main peaks are observed in graphene and include; D, G and 2D peaks. D peak is observed at 1350 cm−1 indicating a disorder in sp2 hybridization. G peak is located at 1580 cm−1 representing lattice vibration and 2D is located at 2700 cm−1 originating from Raman scattering second order at Dirac point.
  • 7. An increase in graphene disorder increases the ratio ID/IG because of the elastic scattering due to the higher defect intensity. However, when the carbon structure becomes more amorphous, the ID/IG ratio decreases. Jorio et al. conducted a Raman study on the ion-induced defects in N-layer graphene. Raman spectrum of graphene also known as the G band, exhibits G mode due to the stretching of the C–C bond. It is marked by a strong peaks at 1580 cm−1 which is the first-order of the Raman spectrum- allowed feature originating from the zone centre (Photon wave vector q = 0).
  • 8.
  • 9. Applications  Energy storage Water filtration technology Transistors Solar cells Biomedicine
  • 10. References [1] S. Bharech, R.J.J.M.S.M.E. Kumar, A review on the properties and applications of graphene. 2015. 2(10): p. 70. [2] K. Spyrou, P.J.F.o.g. Rudolf, An introduction to graphene. 2014: p. 1-20. [3] Z.U. Khan, et al., A review of graphene oxide, graphene buckypaper, and polymer/graphene composites: Properties and fabrication techniques. 2016. 32 (4): p. 336-379. [4] M. Skoda, et al., Graphene: one material, many possibilities— application difficulties in biological systems, J. Nanomater. 2014 (2014), 890246. [5] Y. Seekaew, et al., Synthesis, characterization, and applications of graphene and derivatives, in: Carbon-Based Nanofillers and their Rubber Nanocomposites, Elsevier, 2019, pp. 259–283.
  • 11. [6] H. Shinohara, A. Tiwari, Graphene: an introduction to the fundamentals and industrial applications. 2015: John Wiley & Sons. [7] M.J. Allen, V.C. Tung, R.B.J.C.r. Kaner, Honeycomb carbon: a review of graphene. 2010. 110(1): p. 132-145. [8] S.S. Shams, R. Zhang, J.J.M.S.-P. Zhu, Graphene synthesis: a Review. 2015. 33(3): p. 566-578. [9] T. Mathew et al., Graphene-based functional nanomaterials for biomedical and bioanalysis applications. 2020. 23: p. 100184. [10] T.P.D. Shareena et al., A review on graphene-based nanomaterials in biomedical applications and risks in environment and health. 2018. 10(3): p. 1-34.