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WAJA F4 Chemistry 2010                                                      Chapter 2: The Structure of Atom

CHAPTER 2: THE STRUCTURE OF ATOM
A MATTER
 Learning Outcomes
 You should be able to:
       describe the particulate nature of matter,
       state the kinetic theory of matter,
       define atoms, molecules and ions,
       relate the change in the state of matter to the change in heat,
       relate the change in heat to the change in kinetic energy of particles,
       explain the inter-conversion of the states of matter in terms of kinetic theory of
       matter.

Activity 1

Fill in the blanks with suitable word(s) in the box given

 Ions         tiny                 molecules          discrete               smallest              take part
 positively-charged       in              released        atoms                gas                 chemically
 solid           absorbed           different arrangement                    movement                liquid


1. Matter is made up of ………………………. and …………………… particles.
2. The tiny particles may be atoms ……………….. and ……………………….
3. An atom is the ………………… particle of an element that can …………………….. in a chemical
   reaction.
4. A molecule is a group of two or more …………………… which are …………………… bonded
   together.
5. An ion is a …………………………………. or negatively – charged particle
6. Diffusion occurs when particles of a substance move ……………… between the particles of
   another substance.
7. Diffusion of matter occurs most rapidly in ………………… state, slower in ………………….. state
   and slowest in …………………….. state. This is due to the different ……………………… and
   ………………………. of particles in the three states of matter.
8. Matter consists of small particles that always collide among each other. The particles move faster
   when energy is         …………………… and the particles move slower when                             the energy is
   ….………………..….
Activity 2

1. Complete the table below.

   State of matter                  Solid                        Liquid                          Gas

 Draw the
 arrangement of
 particles



                                                        1
WAJA F4 Chemistry 2010                                                     Chapter 2: The Structure of Atom

                          The      particles      are The      particles        are The        particles      are
                          packed       …………….. packed ………………. …………….. apart from
 Arrangement         of
                          together        in       an together     but    not    in each       other    and    in
 particles
                          …………………………                   ….……..……………….                 ……………………………
                          manner                       ………………………….                   motion.
                          Particles      can      only Particles                can Particles                 can
 Movement of              …………………… and ………………………...,                                 ………………………….,
 particles                ………………….. about ….……… and…………                              ……………………… and
                          their fixed positions        throughout the liquid.        ……………. freely
 Attractive forces        Particles are attracted Particles         are     held The       attraction      forces
 between the              by very ……………..              together    by      strong between particles           are
 particles                ……………..          between forces but ……………..                ……………….… forces
                          the partcles                 than the forces in solid
                                                       (moderately)
 Energy content of
 particles                 ……………………..                  ……………………….                    ……………………………


2. Underline the correct word in the passage below.
   When heat energy is supplied to particles in matter, its kinetic energy (increases /decreases) and
   the particles in matter vibrate ( faster/ slower). When matter loses heat energy, the kinetic energy
   of the particles (increases/decreases) and they vibrate ( faster/ slower).

3. State the change of matter for each conversion in the spaces provided.




  A ……………………………                       B …………….……………….. C……………..……………..


   D……………………………. E …………………………….. F ……………………………




                                                        2
WAJA F4 Chemistry 2010                                                 Chapter 2: The Structure of Atom

4. Complete the passage below by using the words given below.
   (solid, gas, boiling point, melting point, solid, gas, liquid, intermolecular, released, absorbed,
   overcome )

   The temperature at which a ………………………………… completely changes to a liquid is called
   ……………………………… Boiling point is the temperature at which a …………………… changes
    into …………….. . During the boiling process, the temperature remains constant because the heat
    energy is …………………… by the particles and is used to …………………...………………… the
   …………………………… forces between particles.

5. The graph below shows the change in temperature with time when a matter in solid state was
   heated.

                         O
           Temperature/ C
                                                          D

                              B

                                                 C


                A

                                                                                Time/s

   Based on the graph above, complete the table below.

   Point       States of matter       Explanation in terms of energy change and movement of
                                                              particles

                                    Heating causes the particles to ……………………….. more

  A to B                            energy and vibrate ………………………..                   The temperature of
                                    the       substance        and        the        kinetic       energy
                                    …………………………………

                                    Continuous heating does not cause the temperature of the
                                    substance to increase. The energy absorbed is used to
  B to C
                                    ……………………………                  the forces of attraction between the
                                    ………………………. The constant temperature is called the
                                    …………………..…………………………………………..

                                    Continuous heating causes the temperature of the liquid to
  C to D
                                    …………………………… The particles move……………………
                                    because their kinetic energy ………………………………………..




                                                     3
WAJA F4 Chemistry 2010                                                    Chapter 2: The Structure of Atom

6. (a) The graph below shows the change in temperature with time when a matter in liquid state is left
       to cool.
     Temperature / OC


               P
                             Q
                                             R   B


                             Q   A
                                                 A




                                             A




                                                           S
                                                           D
                                                                     Time/s
                                                               A




      Based on the graph above, complete the table below.
    Point           State of matter                                   Explanation

                                           As cooling continues, particles lose their…………………………
 P to Q
                                           and move ………………………. . The temperature……………...

                                           The stronger bonds ……………………. during freezing release
 Q to R
                                           energy. This energy released is the same as the energy
                                           ………………. to the surroundings during cooling. Thus the
                                           temperature remains unchanged. This constant temperature is
                                           called …………………………..

                                           The ………………is cooled. The particles vibrate……………….
    R to S
                                           as the temperature ……………………….
(b) Complete the passage below by using the words given below.
       (solid, gas, liquid, exactly balanced, decreased, increased)

     Freezing point is the temperature at which a …………………… changes into ………………………
     During the freezing process, the temperature remains unchanged because the heat lost to the
     environment is …………………….….. by the heat released when the liquid particles rearrange
     themselves to become solid.
B        THE ATOMIC STRUCTURE
     Learning Outcomes
     You should be able to:
       describe the development of atomic model,
       state the main subatomic particles of an atom,
       compare and contrast the relative mass and the relative charge of the protons, electrons and neutrons,
       define proton number,
       define nucleon number,
       determine the proton number,
       determine the nucleon number,
       relate the proton number to the nucleon number,
       relate the proton number to the type of element,
       write the symbol of elements,
       determine the number of neutrons, protons and electrons from the proton number and the nucleon
       number and vice versa,
       construct the atomic structure.

                                                       4
WAJA F4 Chemistry 2010                                               Chapter 2: The Structure of Atom

Activity 3
1. Complete the table and draw the structure of each atomic model.

          Model                      Structure                              Characteristic
 Dalton’s atomic model
 proposed by                                                 The atom was imagined as a small
                                                             indivisible ball similar to a very tiny ball.
 ……………………
 in 1805
 Thomson’s     atomic
 model proposed by                                           J.J Thomson discovered ……………….., a
                                                             negatively-charged particle.
 ……………………..                                                  The atom was described as a sphere of
 in 1897                                                     positive charge embedded with electrons.

 Rutherford’s atomic
 model proposed by                                           Ernest Rutherford discovered …………….,
                                                             a positively-charged particle in an atom.
  …………………… in                                                The central region of atom has a very small
 1911                                                        positively-charged      …………………..…,
                                                             which contains almost all the mass of the
                                                             atom.

 Bohr’s atomic model
 proposed by                                                 The electrons in an atom move in
                                                             ………..……… around the nucleus which
  ……………………in                                                 contains protons.
 1913

                                                             Chadwick proved the existence of
 Chadwick’s atomic                                           ……………….., the neutral particle in the
 model                                                       nucleus.
 proposed by                                                 The nucleus of the atom contains protons &
 …………..…………. in                                              neutrons, and the nucleus is surrounded by
 1932                                                        electrons.


Activity 4

Fill in the blanks and complete the table.
1.    Atoms are made up of subatomic particles namely protons, …………… and …………..

2. ………………………and …………….. are found in the nucleus of an atom while electrons surround
     the nucleus.
3.
      Subatomic particle       Symbol        Relative mass        Relative electric charge

             Proton

             Neutron

             Electron


                                                   5
WAJA F4 Chemistry 2010                                                Chapter 2: The Structure of Atom

4.    The proton number of an element is the number of ………………… in its atom.

                   Proton Number, Z = Number Of Proton

5.    Protons and neutrons are collectively called nucleons.
      The nucleon number of an element is the total number of ………………….. and
        ……………….. in its atom.

                 Nucleon Number, A = Number Of Proton + Number Of Neutron

6.    The nucleon number is also known as the ……………………………..

                     ……………………… = Nucleon Number -- Proton Number
                               = A -- Z

7. The standard representation for an atom of any element shows the proton number and the
   nucleon number of the element. It can be written as follows:

                             A
                             Z    X
      #   A – Nucleon number
          Z – proton number
          X – symbol of element

 1                                       21              Proton number                       2
H                                        Sc            Nucleon number                       He
 1                                       45                                                  4
 3  4                                                             5    6    7    8     9    10
Li Be                                                            B    C    N    O     F     Ne
 7  9                                                            11   12   14   16    19    20
11 12                                                            13   14   15   16    17    18
Na Mg                                                            Al   Si   P    S     Cl    Ar
23 24                                                            27   28   31   32    35    40
19 20 21
K Ca Sc
39 40 45

By referring to part of the Periodic Table of Element above, complete the table below.

                             Proton      No. of        Nucleon      No. of            Standard
     Element        Symbol
                             number     neutrons       number     electrons        representation
     Scandium

     Aluminium

     Argon

     Beryllium

     Boron

     Calcium

                                                   6
WAJA F4 Chemistry 2010                                                Chapter 2: The Structure of Atom


    Carbon

    Chlorine

    Fluorine

    Helium

    Hydrogen

    Lithium

    Magnesium

    Neon

    Nitrogen

    Oxygen

    Phosphorus

    Potassium


C ISOTOPES AND THEIR IMPORTANCE

 Learning Outcomes
 You should be able to:
   state the meaning of isotope,
   list examples of elements with isotopes,
   determine the number of subatomic particles of isotopes,
   justify the uses of isotope in daily life.


Activity 5
Fill in the blanks.

1. Isotopes are atoms of the same element with the ………………………. of proton but

    ……………………………….. of neutron.

2. Complete the table below:

               Number of   Symbol of     Number of       Number of   Number of       Name of
 Element
                isotopes    isotopes      protons        electrons   neutrons        isotope
                               1
                               1   H         1
                                              1                                    Hydrogen-2
Hydrogen              3
                                              1                          2
                               16
                                8  O          8                          8          Oxygen-16
                                                              8          9
 Oxygen               3
                               18
                                8  O
                                              6                                     Carbon-12

                                                     7
WAJA F4 Chemistry 2010                                                 Chapter 2: The Structure of Atom

 Carbon           3                           6                           7
                               14
                                6   C                        6            8
                               35
                               17   Cl        17
Chlorine          2
                                              17                          20
                                              35                                    Bromine-80
Bromine           2
                                              35            35                      Bromine-81

3. For each of the isotope list below, state one of its uses.

     a) Gamma rays of Cobalt-60: ………………………………………………………………….

     b). Carbon-14: …………………………………………………………………………………..

     c). Phosphorus-32: ……………………………………………………………………………..

     d). Sodium- 24: …………………………………………………………………………………

     e). Iodine -131: ……………………………………………………………………………………


D     THE ELECTRONIC STRUCTURE OF AN ATOM

    Learning Outcomes
    You should be able to:
       describe electron arrangements of elements with proton numbers 1 to 20,
       draw electron arrangement of an atom in an element,
       state the meaning of valence electrons,
       determine the number of valence electrons from the electron arrangement of an atom.



Activity 6

1. Electrons are filled in specific shells, starting with the shell nearest to the nucleus of the atom.
    Every shell can be filled only with a certain number of electrons.


    The first shell can be filled with a maximum of ……………. electrons
    The second shell can be filled with a maximum of ……………. electrons
    The third shell can be filled with a maximum of …………….electrons



                                                             Use ‘x’ as symbol for
                                                             electrons. Draw the maximum
                                                             number of electrons in each
                                                             shell.




                                                     8
WAJA F4 Chemistry 2010                                            Chapter 2: The Structure of Atom

                                                           23
    2(a) Draw the electron arrangement of a sodium atom, 11 Na in the box and complete the table given.

                                                    Number of protons

                                                    Number of electrons

                                                    Number of neutrons

                                                    Proton number

                                                    Nucleon number

                                                    Electron arrangement



    (b) Draw the electron arrangement of a chlorine atom, Cl in the box and complete the table given.

                                                    Number of protons

                                                    Number of electrons

                                                    Number of neutrons

                                                    Proton number

                                                    Nucleon number

                                                    Electron arrangement



x
x
    3 Valence electrons are electrons in the ………………..………… shell of a neutral atom.

    4 Identify the number of valence electrons in these atoms according to its electron arrangement.

         Atom of Element          Electron Arrangement          Number of valence electrons

               Oxygen                       2.6

             Aluminium                     2.8.3

              Chlorine                     2.8.7

                Neon                        2.8

             Potassium                    2.8.8.1

             Magnesium                     2.8.2

               Carbon                       2.4

            Phosphorus                     2.8.5

               Helium                        2


                                                     9

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The Structure of the Atom

  • 1. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom CHAPTER 2: THE STRUCTURE OF ATOM A MATTER Learning Outcomes You should be able to: describe the particulate nature of matter, state the kinetic theory of matter, define atoms, molecules and ions, relate the change in the state of matter to the change in heat, relate the change in heat to the change in kinetic energy of particles, explain the inter-conversion of the states of matter in terms of kinetic theory of matter. Activity 1 Fill in the blanks with suitable word(s) in the box given Ions tiny molecules discrete smallest take part positively-charged in released atoms gas chemically solid absorbed different arrangement movement liquid 1. Matter is made up of ………………………. and …………………… particles. 2. The tiny particles may be atoms ……………….. and ………………………. 3. An atom is the ………………… particle of an element that can …………………….. in a chemical reaction. 4. A molecule is a group of two or more …………………… which are …………………… bonded together. 5. An ion is a …………………………………. or negatively – charged particle 6. Diffusion occurs when particles of a substance move ……………… between the particles of another substance. 7. Diffusion of matter occurs most rapidly in ………………… state, slower in ………………….. state and slowest in …………………….. state. This is due to the different ……………………… and ………………………. of particles in the three states of matter. 8. Matter consists of small particles that always collide among each other. The particles move faster when energy is …………………… and the particles move slower when the energy is ….………………..…. Activity 2 1. Complete the table below. State of matter Solid Liquid Gas Draw the arrangement of particles 1
  • 2. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom The particles are The particles are The particles are packed …………….. packed ………………. …………….. apart from Arrangement of together in an together but not in each other and in particles ………………………… ….……..………………. …………………………… manner …………………………. motion. Particles can only Particles can Particles can Movement of …………………… and ………………………..., …………………………., particles ………………….. about ….……… and………… ……………………… and their fixed positions throughout the liquid. ……………. freely Attractive forces Particles are attracted Particles are held The attraction forces between the by very …………….. together by strong between particles are particles …………….. between forces but …………….. ……………….… forces the partcles than the forces in solid (moderately) Energy content of particles …………………….. ………………………. …………………………… 2. Underline the correct word in the passage below. When heat energy is supplied to particles in matter, its kinetic energy (increases /decreases) and the particles in matter vibrate ( faster/ slower). When matter loses heat energy, the kinetic energy of the particles (increases/decreases) and they vibrate ( faster/ slower). 3. State the change of matter for each conversion in the spaces provided. A …………………………… B …………….……………….. C……………..…………….. D……………………………. E …………………………….. F …………………………… 2
  • 3. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom 4. Complete the passage below by using the words given below. (solid, gas, boiling point, melting point, solid, gas, liquid, intermolecular, released, absorbed, overcome ) The temperature at which a ………………………………… completely changes to a liquid is called ……………………………… Boiling point is the temperature at which a …………………… changes into …………….. . During the boiling process, the temperature remains constant because the heat energy is …………………… by the particles and is used to …………………...………………… the …………………………… forces between particles. 5. The graph below shows the change in temperature with time when a matter in solid state was heated. O Temperature/ C D B C A Time/s Based on the graph above, complete the table below. Point States of matter Explanation in terms of energy change and movement of particles Heating causes the particles to ……………………….. more A to B energy and vibrate ……………………….. The temperature of the substance and the kinetic energy ………………………………… Continuous heating does not cause the temperature of the substance to increase. The energy absorbed is used to B to C …………………………… the forces of attraction between the ………………………. The constant temperature is called the …………………..………………………………………….. Continuous heating causes the temperature of the liquid to C to D …………………………… The particles move…………………… because their kinetic energy ……………………………………….. 3
  • 4. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom 6. (a) The graph below shows the change in temperature with time when a matter in liquid state is left to cool. Temperature / OC P Q R B Q A A A S D Time/s A Based on the graph above, complete the table below. Point State of matter Explanation As cooling continues, particles lose their………………………… P to Q and move ………………………. . The temperature……………... The stronger bonds ……………………. during freezing release Q to R energy. This energy released is the same as the energy ………………. to the surroundings during cooling. Thus the temperature remains unchanged. This constant temperature is called ………………………….. The ………………is cooled. The particles vibrate………………. R to S as the temperature ………………………. (b) Complete the passage below by using the words given below. (solid, gas, liquid, exactly balanced, decreased, increased) Freezing point is the temperature at which a …………………… changes into ……………………… During the freezing process, the temperature remains unchanged because the heat lost to the environment is …………………….….. by the heat released when the liquid particles rearrange themselves to become solid. B THE ATOMIC STRUCTURE Learning Outcomes You should be able to: describe the development of atomic model, state the main subatomic particles of an atom, compare and contrast the relative mass and the relative charge of the protons, electrons and neutrons, define proton number, define nucleon number, determine the proton number, determine the nucleon number, relate the proton number to the nucleon number, relate the proton number to the type of element, write the symbol of elements, determine the number of neutrons, protons and electrons from the proton number and the nucleon number and vice versa, construct the atomic structure. 4
  • 5. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom Activity 3 1. Complete the table and draw the structure of each atomic model. Model Structure Characteristic Dalton’s atomic model proposed by The atom was imagined as a small indivisible ball similar to a very tiny ball. …………………… in 1805 Thomson’s atomic model proposed by J.J Thomson discovered ……………….., a negatively-charged particle. …………………….. The atom was described as a sphere of in 1897 positive charge embedded with electrons. Rutherford’s atomic model proposed by Ernest Rutherford discovered ……………., a positively-charged particle in an atom. …………………… in The central region of atom has a very small 1911 positively-charged …………………..…, which contains almost all the mass of the atom. Bohr’s atomic model proposed by The electrons in an atom move in ………..……… around the nucleus which ……………………in contains protons. 1913 Chadwick proved the existence of Chadwick’s atomic ……………….., the neutral particle in the model nucleus. proposed by The nucleus of the atom contains protons & …………..…………. in neutrons, and the nucleus is surrounded by 1932 electrons. Activity 4 Fill in the blanks and complete the table. 1. Atoms are made up of subatomic particles namely protons, …………… and ………….. 2. ………………………and …………….. are found in the nucleus of an atom while electrons surround the nucleus. 3. Subatomic particle Symbol Relative mass Relative electric charge Proton Neutron Electron 5
  • 6. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom 4. The proton number of an element is the number of ………………… in its atom. Proton Number, Z = Number Of Proton 5. Protons and neutrons are collectively called nucleons. The nucleon number of an element is the total number of ………………….. and ……………….. in its atom. Nucleon Number, A = Number Of Proton + Number Of Neutron 6. The nucleon number is also known as the …………………………….. ……………………… = Nucleon Number -- Proton Number = A -- Z 7. The standard representation for an atom of any element shows the proton number and the nucleon number of the element. It can be written as follows: A Z X # A – Nucleon number Z – proton number X – symbol of element 1 21 Proton number 2 H Sc Nucleon number He 1 45 4 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 7 9 11 12 14 16 19 20 11 12 13 14 15 16 17 18 Na Mg Al Si P S Cl Ar 23 24 27 28 31 32 35 40 19 20 21 K Ca Sc 39 40 45 By referring to part of the Periodic Table of Element above, complete the table below. Proton No. of Nucleon No. of Standard Element Symbol number neutrons number electrons representation Scandium Aluminium Argon Beryllium Boron Calcium 6
  • 7. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom Carbon Chlorine Fluorine Helium Hydrogen Lithium Magnesium Neon Nitrogen Oxygen Phosphorus Potassium C ISOTOPES AND THEIR IMPORTANCE Learning Outcomes You should be able to: state the meaning of isotope, list examples of elements with isotopes, determine the number of subatomic particles of isotopes, justify the uses of isotope in daily life. Activity 5 Fill in the blanks. 1. Isotopes are atoms of the same element with the ………………………. of proton but ……………………………….. of neutron. 2. Complete the table below: Number of Symbol of Number of Number of Number of Name of Element isotopes isotopes protons electrons neutrons isotope 1 1 H 1 1 Hydrogen-2 Hydrogen 3 1 2 16 8 O 8 8 Oxygen-16 8 9 Oxygen 3 18 8 O 6 Carbon-12 7
  • 8. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom Carbon 3 6 7 14 6 C 6 8 35 17 Cl 17 Chlorine 2 17 20 35 Bromine-80 Bromine 2 35 35 Bromine-81 3. For each of the isotope list below, state one of its uses. a) Gamma rays of Cobalt-60: …………………………………………………………………. b). Carbon-14: ………………………………………………………………………………….. c). Phosphorus-32: …………………………………………………………………………….. d). Sodium- 24: ………………………………………………………………………………… e). Iodine -131: …………………………………………………………………………………… D THE ELECTRONIC STRUCTURE OF AN ATOM Learning Outcomes You should be able to: describe electron arrangements of elements with proton numbers 1 to 20, draw electron arrangement of an atom in an element, state the meaning of valence electrons, determine the number of valence electrons from the electron arrangement of an atom. Activity 6 1. Electrons are filled in specific shells, starting with the shell nearest to the nucleus of the atom. Every shell can be filled only with a certain number of electrons. The first shell can be filled with a maximum of ……………. electrons The second shell can be filled with a maximum of ……………. electrons The third shell can be filled with a maximum of …………….electrons Use ‘x’ as symbol for electrons. Draw the maximum number of electrons in each shell. 8
  • 9. WAJA F4 Chemistry 2010 Chapter 2: The Structure of Atom 23 2(a) Draw the electron arrangement of a sodium atom, 11 Na in the box and complete the table given. Number of protons Number of electrons Number of neutrons Proton number Nucleon number Electron arrangement (b) Draw the electron arrangement of a chlorine atom, Cl in the box and complete the table given. Number of protons Number of electrons Number of neutrons Proton number Nucleon number Electron arrangement x x 3 Valence electrons are electrons in the ………………..………… shell of a neutral atom. 4 Identify the number of valence electrons in these atoms according to its electron arrangement. Atom of Element Electron Arrangement Number of valence electrons Oxygen 2.6 Aluminium 2.8.3 Chlorine 2.8.7 Neon 2.8 Potassium 2.8.8.1 Magnesium 2.8.2 Carbon 2.4 Phosphorus 2.8.5 Helium 2 9