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                               CH,ll ', Ugr,,tQ &,rte&sry1_*                                                            e_!


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                         kihqF qur hrrct ta                P'1

       lte orger co.t/r errerXq^losses t.., g Bqere-rv1, S" looer ils e0-fiuen,rt
        RCuchc,is
                   fhe
                         co*e" '{rom L d|,l'Ferenf sc..*r.-eE:
        I ProcesS Lim ilahbns:
            tn*gl osses due lo practra.l eekus .:F c^n' energl +r*as Formr,Ston fcrcSS
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       D fundcrrneilf&l U rnifc-fionS'.
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                                     4 = (tool o, ZS = Zb.L                                     process                '1to1u'
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                   D=icpAu.                            .                             P=   Fv =(zfuN)ts"*ts) -gloor
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             Uacd'ar ots c-
             &rcfor d*-                                       rr'= otfumc rnqss          r   l,6Gx tt,^"   1<3

    Ex  l/.8iSpecd oF rrttr"gen w.'oec-u"eS
    -l.liFroqrurr.,es (ti2-).
                              tj 2o". ohc:]r r:s -h!- rms speedjl_ilgw$bcgtes oG__qlqgi
         (n="78^*]qb;lO.a?k3=T.2orL.l3V,*u=.F^@Vrr.ns:5(om/5
          y.,r= Ll,&sr.ro-11Jg 1-= z-g3 tq   - - -V L.Gb nlo'uus
-YGr.b
     C-ort g*b              11ner   n c,. Ene.c61
                     %                                             x   Therrnc- **t1       f s airac-l{.1
                 f1*.,= N'ko.,1 = t         tq'Ke'lf                       g roportr'c,ncr. Q Te{Ylpe,{cr$ure
              therrnal F6*X1 Jg c.^         icJec,. Xa,s oQ   N a.rhurng A6,.^ = * U:ku'AT

     , Tne E*. oF o. s ubskrncr- f s p ro porfr6,ra^J; t?, H,.e- humber oQ cr.irornS
        A gcrs r-o m6re c^*orns hcrS rnore- 6*h Hac.n o, tci*s a.ts S-ne-
        Sdn4 e- Te-r.perer-h:re- w I Fe.rre-. cttt>rrrs.

     2. A A in Ternpe-rzlfure- cr*u8es c:. cropor{i''c,inc--L                    c-,1c,-ng,L I   n   {"1 4*
           5 $V2EV<u cets Vllerrnc.l *15 .t A [arctr er tso,rvrporature                                  cVrcuu.r-
                                            ;,
           (rrr.r€e.s a l*tgr chc*n1e t n thcrmc.,{ areft1
     O,  t'
     I,(a1            c
to o c-r|,13 oF                 c.-tsrnosphere- pre-Ssrre- ancl 2Lo c-         c-ont-crjn: 2.5 * lott rnole<-tr;eg
81 ho.^t nnr-rc-[r 6[oe-S itsS $.l-rn..-l                  d'ea"rt- |{      r'{-s hq-+eol tzt %'c-?.
 AT-= lo      i<
                                                ^*1rt
                      AFr,.,
                              :i  (2.5 r to'')[t   .tr,tol,l*X   ror.)
                      A 6*t    =6, 5Z 5




 r        ena W"'r< o{e aimpy Z d,'FFcrerrf
     +e.Ak                                                                  rrrcr-L{-S   oF   {-ratrSf'.'etr rh3
     enen1l bb or {..o"^ a, €lgFenn x
'Therrnc- ey.r3t1 fs trci-ns$<r-rec.t b [,^r cr sqel-e-rrn crtrd ?l-!- €-v1vt ran *-,enl
  cLS cr C-oAseclue-rice o? a fer^np. ;1; p$<r<nce b l* Pt"-&1
   ''Whe*1 the fast - p,at-,e.c,ues in t4^e hoFler oblec-l- coicJ<- u,l lhe Src'ser
          n,Tcrecr-re-S   (n Vhe- r-aer     obierrt-
          NeJr   Resol|l fi.ri1                k*n hoHer --> Coole.r o61<c-f
                                         4rc-xr'tslerrq)
           [{ ecr is Vhe- aer% .1 trc.ns$<-J- d, i o- tl^errnc.l q Fer-i:.c-t-rc       1               rr
                                                  ^
1'la1
                                                                            Ffotn nrro'rr'nq
                                            n bqJrr'er Ore.vc-nks IerlrprnSbwts sbrl o-Pou5                                      P_e'r.61
                                                 Wem Sqsk-rn tD 2.
                                                   (               H^e.-rvr tu coicdg

                                                       stem.r
                                                             uz                   Tr tTi
                                                             fr-                 'AtsurvrS    in SqstelnL hc'ra o.--hiXh.e* kr'u3

                                                                                  Lr.,o     n€-.-             r's /as I r'n a* pere<c*11
                                              ,oJ"E                                 a o
                                                                                                   ^uI
                                                                                           qtr'c e-o l ti-s icrn)

                          F-z^sl-                              Slow
                      Oa                                        <-<)
                                                           Etc.s'Lr c
                                                           rolisioh
                          L-b.L6"6;s.{                     GrCrrnS      Enerqq
                                                           #'
                                                                                                                h'crnS6erre-ct Fro"t {-he
                                       -+                                         Therrrn.) e" e''rXLI s
                                                                                                            (
                            n€''l-     &-'q71 franS$e.r                          ; .$o-tt*- t^lov'^n c<-bpr-"-S 6n {-h. U)o-rrnq- E;lcj€
                                            (as         Hec^'r)                  .b ${-re, Sot-se-r-"fvrcrvr'rt3 o-tsornS o11 *he- asler St^c{e
)rZ Sqsferns pc^c-e.d
 in thermc" eonrferc-l
LDi   I Frc^yrs$er *fiernrc^l              I tr                                       Cotlt5;orn3 lrc.rtt&er eAe.tfqL,t Fr.or- l'[re u-Efmer
                                                                                                                      to-S
                                                                                        Sq're-/}1 +-?, H^-o- *-tu/         ,vno"e enetTe'li<
ene*tl      t.l-nlil $.dr               (k,)c.u3                   (l<.)"."1
                                                                                           o-L*S       osa Cn€rrCq tb eSS e-rrrerqeFl'q
 &^*t      ternperir*t^rcs                                                                 a*Fzr rnS . Th i s  .i4v trc'ns$er = [ 915-
         O{e
                                            Q,<o                                           q; tr-) qrhen =." i=' h.*l*$.u..d
                t{"0- Scrrn.Lf
                                                                                           ^*XrI                                         SpJ*
                                                                                                                                         5qe,+errl
                                                       Q   =(-) 6fierr enerXl iS hr-ounskrred
                                                           OUF ok c^ S.t6h€rn
F {ecr"t     S   Fra.ns€e-r'qg9
                                                                                           6carrs
 €co"n hoF to cokix
                                            T+ lTr                                                    u)1,e4 the Sqs+<-tvts hc-re H^0. -tc,!r.a
                                                                                           a-Ne-rcLc* tfc.n6lC--h^onc-l lcine,fi'c e1er1r1
                                                                                           o-y,d, f{r,.r.S Hne-      sc}rne 1-crnpera}-iZ
                                                   Qz --l-Q,            r                  llnd,   e-o(l,Srbns sh'll tra-nsFere/^e-rqq t-"* L
                                                                                            Srcte fr.r {-{^n- ofu, 6ra J-l,,e-re,k n" fr*r err."E1
                                                                                           lrc.n s$cr )
                                    themcJ k1vilibr,utt
      lJn"     ls* Lc.* oF thermodqncrFn'cs : [g*= VJ*Q
          lZt sqstcrnS f n ^rhrcl^ on1 {-he- Fhe."'..t €-nefil chc-n3es, lh" %ny,
                                                                                                                                                 ^
          in fherr c- e-ne--n1 iS eluc^, +15 F{^e er1"t1 trc-.ns$err<d I'ata ar ouf't
          YL-,e Sq6€i.n cLS tt)rk W ard/c,r herr-t- O

      'sqslerns lL,crt cren't fnovinS Cno 6r) , Fhcrl_gun"n'9 q-hcst, cernicolrl(ca'-4, bul-
         UhoSe. t€,,x pert'h-tre5 dcrn ohc{nx,e- -- the:rnaAlna-rnr'6
                      Wov( on                                           Wclr< bt{
                                                                          su st<rn'
                      Sqstern                                             f,r) <O
                          w>o                  Srlsherrr
                    6ner3t1   ln              AE+v,=W rCl               EnerXl out
                        Q>o                                                  Q   <c)
                      Hee* to                                               Hec.l- &ro.n
                        6r.1S€rn
                                                                             =c1arcrn
7
                                                                                                                    PG.B
            Conc-eo,.rc- Ex  lt,3'. CompreSsinc a q4s
            -|1pfrt" c( 3a-s is in a-n ins,rc.$eol conta,jner, so |l.rcr-t no hec.i enoty qJn escq.{>e.
              tF
                 t pistan is used 4o arnyress *t^-o- g*s, uJha+ happe,',t /" l1- '|enp. oF t-/^o fq ?
                "The pr'6fon cr"gg,eS s frrr.e f0 Frr.l- $s, r.',.td {'h€re ts o. d;Ebrnr.errt, ih,S
                rns4rls thc* ,"n i< ts cLrne on .|il. qc,S bq {de pitton [Vrl to). No thervrar <.{eJ(tu
               COn  be evciluna+d ill the Qnvironriient, theHninq Q=O. Sincr. ane-rqqrS lrr,rrd.rl.,
               inlo the.p,lt+r"^, h" tfu""""l qe"U? "P +4i-a- fas rnus*,'nr-ui^e. Th,s
               tTlgatts          t/v-'#tnf   rhusl ncrerts€           a-5" cae.//.

    &. Il.lct', Wortt ond hea-l in a 4 tde.a-l Gds
     -Sup7ose u conVcrlner hods 5.or lOtt r"roec,*r€s oF ar1 rclec,.,{ flqs, 5oT oF q:orK
     o.fe- done on &'1",e toS b'-1 o pislan fLwf @rnpreSses r'1. the. +<:vtp oF th" 9cia
     Cha-rr,7cs by 3o'c- clurin3 *his proc-aes . Ilac': rnvc-h het* r^S *rans{<.rred Fa c..,-
    $-."- t{.,e- '*uiron.-.-ri+7 AE*n=1 N'KB ar
            n
                                                                 Q=tr6+q -W
                AE+r-, =    ? (s.or. ro")(.38    r ro-'3   Y*)( 3o .)                            : 3tS- 5oT

                                                                     e.rwtcc)'fvrn€.rr1-
                                                                                           ,Yy,   l;;:*' ilffii*
                                                                                             in Lhis    procs*ss


              En    *J, - Tra.nsfrr Drrcrns
               'h*V,       Re-Ssrt o,'r-; c.-n a blec'V or a- 6tart aF the- envirarnmcrtrts so <,-r-1p
                    Hac--f ifs +emp. cl.oesn'f nohc-<.c.bt1 cJnc,nXe uhen hec^-|- ;s tra-ttSl<rr<d
                  bt^ lt" 61stsern c-nc, &he Y?ser14;v-
                (Tu) -+Dt Re.gervoirl A re-servofr cr-F a higher +-e{1p. +{"&-"1 Vhe sysFcrn
                (f") - CDd Re-Eervoir I A reserv6jr o-k c loc.rer hp. 1-{ru---n +{"- s,1s}-<-{v^r
                 .+[-{er-r.t e$eql is }ra-yrS$errect bl* q Eqsl-ern a*tcl a- reservo(r r'f
                    1+.e-1 hcve- dil(ere.n* *e-lrnp.eratrreS

                             0 * , o-rnoon! of he-c-+ t-rr-.r's&-rreci +o o( Som cr hot fe.s€rvoir
    -^fr#au'                 Q c : &wroun| of hec-! Frcrns$e,rrect ho o- etov^ ct c-olc feServoir
                                             ;s
                                    Hedr*
                           ()l   H lrc.nr         Qc-
                                                         c.gP$-s                         t'|oL
                                                                                        Q&voir
                                                                 reserlar'r
    HoF reservott
         .rr!                                            --Cotd a-I- -fc
                                                         -
      a-+       -----r Fre                        c-€
                                                                                                                   y^gclurYes
                                                                              51shewr                              QH=Qc
               .+o+ rese(/oir fs crtsc,.r-{s aF Fhe top               (k53'f
               '(Dd re,&rvo-ir cr,-rrarrs c.r.t Ts bo*owr
                '-lhe sqslem tgFT"') b* 2 reservorr5
               ' Res"vuor.s c^vld alsratr 6,911aecfid b,t h;N" +W                       co^d t//f//-
                                                                                          **otrt/7
                        -"'- J't " I Lrr,-sE4r         -*uf ,
    )t Spnlarrrus hranskrs go rn 1 direc-hbn ont.1( *'
                                                    bt+couF,_
                                                             fuuVr{-TrcrrrsW Dr'a6ro.rn
7
                                                                                                                             ?csr
         Cbncegfual 5, ll.'l Anut, t**tdku-< . ', r
                                    :                      l'lno 8"O,
             -)ldhy-in phlSr'cS &ercnS- r's i+ rylor<- tux;oj ort *he bou la ereretse tn "e*,/ hal
              w e+^+rer?
             Llor, fua1 cenhhuovsl7 c-ctnver*s Fohemo E*n, . E (q*r?r4zt"th a. cons'ic-n{r bocLq k-r,rtX"
         Tourboel{ musi urnh'nrrl.zl1 {rransfu hr<* t- t1.*- ertv{rdftfte({1. Thts is ecLE.l fn c<,.t
         tt'te-u.]-l*r : 'hrcol- ts Sponlclner*ts! t'rasrs|ered h tdt- €t-tvtn* , bu[- olkan l,l.a- o-t'.
        l*af i: h,Xt^rr |hclrl l1cr* b..{i ts€rnp ,L{N" b"t1 ec*nnaf aol idset? l'h,s cr6ll/
        rutd Muat ose olLt* rne.-hc"rlisrns *b fi-c.nsSe"r- this **Ajt Suc-h as fe.rspr'rrn5.
        Tl.,nSe rher)-lc,'-rt6zraS r eTur're a.ctcl,'han -t ener7 elqr<,,no ih.lf<.
                                                                                           7


                                                                6nerto{ f5 e-xhc{ckd
       ffiexq, s     f
           u'C,rwur,ua
                                                                  ht ru{ l-l.re S.*

       Woor    =aR _ec_                         5ysfer4                                            'ie-,--u. bq       f ru ""ST.-
    6e41au&      Evergl it'pul                                   Fr.cess heal-
                                                                erlertl rs +tc.1s$<rrei                        deterrnined br dte
         Hecrt ene{j1      is
                           Q r+
                                                              "6. into !he- cotd tpcrter                         Znd La-,^t eF 'n-d{ra&lc:
                                                                                                                           dha(
        trcsrs$erle'l €rorn the                                                                                      c     tZ

         ho,t- r.^rqtler                           e-^ Worr - Qrr-e.                             e^oo=          -T
                                                    a          Qu                               e.o reh'cc.l   ry"axl mum eFft C   erc.t
              " B lc er^c.x e I , ?. werr< done is                                            o( o- h-e.^f e-n3ine-
              o-u:crr{S e SS      Y"c^rr^ {-L.r,e     hec^}        i vr   p   t-,r"t
                           (wo.,*       .   Q ")
             So   !her.      b-^.uST        ba hec-t Qc exhc^.rs<.l +" f{.re cod                      Te.servoir
                                                              q No hec+ enqfre- er.n corwqr
                                                                 tci% o[- Lt-,y in&z rsefi]. r,oor-(

                                        z-,b-r+ rg l-''g
                                           enercM rs'usecJ
                                           "^Yg1 l:,yi,
                                        hloun d'#.i"f=ff-l                        'h"nl    flzr^ nac)a-r 7yr13;n tr4,o c.,(e ac e-
     Stinu                                           Worl<      Nou+
                                                                               uc-eqjr- rec-eh)r procluceS h^'Sh-PreSSt,re.
                                                                              Sl-ect-gh al- ZO-e-. +Fle-r ils use-cl FD spin c
       Cod /                                                                  'l-t,-rtine, ifts cr-nds6gqd ( usiS cc-,ar3 .^.oher
       ksenroir                                                               (-c.. cr.- irec,-rro1 rive-.) bc,ctc h: Urcther qi ZO"C--
        3.1h"                                                                 'l'trre
                 rernarninq enerqq                                                    e-tce5s hor.l-rs,cleEei/ed ,n l/* nnq.'{1,,t
              Qc'Q *l - Wori is ex'krrrrsd                                    oxr.ber iS H^{t1 refur.lel,C}rd +l."l. qde beginS off4'n
             h, ll,e. ccd reservoir cLS                                      hrhcL!3 lLe rncrx. ross i l"e 46tn^c*qi4,,s yb,n I ;,t)
              ui&Sl h4f^,k                                                    a  , zlo"e +?-13= 5 L3
                                                                                         , LNLV'T
                                                                                                       K A*      zot +z1B= Z1#n
                                                                                €rvrr"X= l-      /b63l<
                                                                               €rrro* =L182
7
                                                                                                                            16'0
                 t, J   I 1 eerts P. nnps
                      L>Ticrntf€{:s hec- i*ou !ro*              cotcl reservior fo o. hot resgvior
                                                             "^
                          (tt"e o3'pcsifs .F the"ri,^l.rtol cdrrecht -,
                      6r.: Kgh''gnr*Vr:#rcc.nsffers h"a^h Fro* the cokl cur ins{ae lhe refrinercrior tl fiine
                         W0rn^q otr in f{,,9 fo,lvn,
                                                                                    Qtt= Q-rWin
                                     '-fhu.       arnou.,nt oF   heo.t-        6nerq q ry'vusd-. b e conSerfccl
                                           e,xl.arusd *o $re hoL
                                                                               IFfecr.tu lep-si a-er-I in t-'Ls h"[ stde- rnr,si*
                                                                                .q"o- tt€ Surn o F k'Lve nec.*-
                                                  ,f lyrty ,thL,/, tQ
                                         r€SB.rcvoir                               t^e.rvro.rec   &ror*        $-{.q col._l -sioVg
                                        a,mo,.mf & h!-I- e,Xycrs-bed              CLr41   {-ha uoorl< inpr.lf-'
                                        g"o"n {4a cold roS?yvo(y

                                                       CoeE6'ql'*"0   oF pa-[.t.,rrnc{rc€- (Coe) eseA far aKrreJl.l
                                                         coP=    g =                                                     =_ 6;
                                                                                                                            Qe
                                                                 l*1 c,>er r1a'ceA la                ?e.fucrn {t,- $ran&r Wl'
                                                                                                                             tr
       &+tnol        eyv,<rs usel to
        femove   l,ta* harn    a-   alcl                C,op,".,.o   =+€       Theore-fi,..-{ r'ylcr.x          C-c.t? oS o.- he-,or+
                q-rd gxkr-us'l-
        fe,se.rvoir                   hae,,f                                   P
                                                                                   u't-?    Used    L. coaig
       t> c. ho- reservoir
                                                                             )t A cu3er CoP yneAnE cl
                 t.F llea* pump Is ussJ eor hecoh'n3',                            rr,tsre- e.Ffrcrerrf hec$
           COp = 3da 3 ener€q ardcled
                                             to t{'re k:h rescr voir e Qt*"
                    Pc.tl r,oc,rt ralur'rec| to per-$orr,, t+r4- hrctfss-r W,'.1
    -lhgore-hr:c*I
                   nrcs coP
    "1 "-i*^t  e,*p-'
    Oser.l Crr hecA'=
                           COp-* =              #*

    -'f(. tnsr'oliq aF qosc F"ra* is agrrav, Ooc-. t+e{+ S.o".., lhe- ineicle {E depositeaj rnto t-L(
    Cdr !. lour citsc-^.n , Lrhrch has c,. 't*p o( 2O'c-. UIE-+; phe n 1x co,lo( Vr, hdV".
         'iH = 2o.c- 2a3k Tc-:Zl3<. boP,-.,* - fr., : L13l<
                                                                          {tZ">
      cop o.i 3.(o rne(.{ls f4"$,i. uie- p(Jmp 13,Gil- Tv--- ffis-----
     ot- her! (or c.l.r eret.{ ce6{- o& tf


       " If.5 c,- hoh dA1,          c-.-l.rc   yoor c-ph, s rctf,-5r r^)cJ-c^. 1.,r.          r.E>6,,4   ftv--t-e-   so3get;;
7



              '{he #crlafer o$ he<rf firon^ hot h cod t8 qn rrerersibte process
                AlthorSh inlerachons o-.1- i-he rnolecr-rlcrr te.va a.re ratq6ible, the sho$s at- lc.rg,r_.
              hurnbers frtr'(e, i{- overu.rhernr'ng1 ikd1 tt^c}+ 4te sqslern U;itl s/ove-
               fou:cocl @utl,i'briam (it-s           |te     ,-ost prob,-be    sh.,Fe-       in whr,ch +o be)

         &1m"ru I me4e*Jr.s {-he c.mourrq. oF otsoraer (n e,, Eqale'nn
            ncrecrseS &s lcru (nove- Sto* a.n c:r:oleleA sqolern to c- fl'tcsre cl&c'rclereet st|t4rr-t

               '2 fherr'nc,r ineraclig stlslen"rs u-tl al;((, l-engwcrturS 6ve a lor.,.l enkopq
                    jrda<cl: hdkralorns   Gle on o{e Bioe <l$ Fhe Vaorrt{, lhe sLt-ue, e'.-}ornt .. lfu o//*
                 The rur.rsf rc"ndsn laossib)e drSlribu*bn oF enory1 (*l" ts.t'l- orde-*'er) st1s+e.m)
                 correEfruk +b r'thzn {he Z slslerr":s Afe l'n f{.rmrj quilibl'orn dlqr"rtl l-*,PS.
               Fhopq incvec,r,seS os lhe 2 tqslews w rn,hc,rt1 ollfferenl terngera,trxee n'byg
               luwo,rd l-{rerrrc" equi I ilorium
             zn"t L".,^ o9 Therrr,odqha-m'c-a'. Thet e.,*'rcy1c,f o.n @la-ta-J aqs       CVT
                clerrecrses. 1e. errhopcl gfher incxecrsc, u,r"tr t-lne aystun reazhzs epilibrlum,
               or, il +hu. sqs+ern b*Sl-. ln equiibritim, Starls I'he Sar e-.
                                                                             Satn

          nn   lsotc"ted sqsfern e.rloles sucj. thrrt:
               " 0rdey hrynS rnio dr6orcler a..nd nlurdorrvness
               ' ln4o.-c.ha:n is los+ fct-tlr.cr +^ftc.n q.tt,,ed
               ' fh,e- 6r1tb<.m *ru-rrg du^-:nu .f other ftv*S oF **qq qre ha$ssorrneol                         +.)
                     therp,16,.1
                                   "JrW1
        ' 1'fterrna           hHs enkogcl, oHner t'or*s oF enerX do nof
                          e-rnerql^
             Vtihen orroFher hovrvr ol a.rernl is converYe *o dterrnal *o(u|, fhe,re is
              incfecrSe in ut/ropy. The proc-€ss usill_ ndf sytr*aneaslq re/e-/se-
              (S^fi*'n= DVy conve-rsionS e6- e)"rwcr Fo..'.s t'" **.11 . t/v1a,crnc,1 <-r
                                            c& of{.sr cz)rrr'>    gnqttl T.. Yr'T Y^c' *'-11
                                                               "f
                    is   irre-ve-r-s   ble)
        *'        */il#//ru,"[[rinru.
             ff                               {s ci-clct€d
                                                                 t$, ?*ff , rF ffi"u,
                                                             tD t{,e- hec^} errgine

                                               E   ---L. fhe work oul- coik$ns no
                                                   No.r-    Qlrrtr4tt.The   on   ^rri{   H4Gl-
                                                             €xhoBg{sa$ l€qrve iS rrik
                                                             her.C,Sto.^: to lhe cor,d
         6+-f1                                               resejV(or
    Cod Pessvur:
       Tc                       ,///iv'         qoes ocrt o+ H^e hrea! ryrrrnq intu he
                                                b'r*tyl rs f€.rvrovecl S.z,-u pfie he-a.t- er€roe.
7
                                                                                                                      Pa,z
              Alkrnc^hve 6t-0,ernenk o$                fhe     Znd trr^o        d Xte,rwodqrv:rrrvrrcs
              ?h.*.rn.t*n*
                                                           . UJhen 2 eqokms ctt diffuent )evnpercdwex intcnrcf,            ha,rl
           Fec{i Tert..1 6pn}anecrsr1
           Flor,ot tr.nh hot to cod                       s€{r1 is hctrskrd S?* klneoun1            Som      " hotter io *h
                                                           eoder 6q8iern, Fevor trom lYe co6.. b the hdfer

      "   hnhogtl conetdera*h'ons imt t               " f ts nov ptaiot to wrcrke <r hecr- e-rrqine -h$ts
          fhe possibe etftciencg      oF   u          converK fhermo             enetl ino qn equivop-nF         o,nnowr
           hq^t    enXine                              ofr wciy<,

     '+ |o,kus ene,vtg lo rnove                      'Hk nr! potsibe to wnrke er hecrf pump thc^k nnnnel s,
     hel^f 0.u* c^ ci,ta objeci io                     ko"n cr coo obleci ts c,. hot- oe* ''^lo on oxt€i-rurl
     o. Vttcrfrn objes-l-                              tu.ntt         t   nguF

     'Ihe- <x1hrcpl of           crn                  '1he h'.. dire.han in rNric ?he *rna71
                                                                                                 "ttre Prr,t -lrot'    "[ on
     isocr-lecl €qsfern Wi ne.'rer                  iSalcr-lecl   16+€r0n ncrecr.SeS tS
     5ponhcrneou$    decrecrse
                      1




           'We can! C,rfualh/ rotn od*- ,:t enetXl (tn.tq c<lrr't                                  .r ol€st"ofd)
            hre Cnu ru"n ou# of htqh-9uei sttrrc-et .l!'eneratl (G"r-s {4rcd-co.n .oa,'U
                                                                             vr
             be conver|..I inb other fiit^* o!
                                                   -*tf)
                E*'.Oi+ cocrFc^aYr: c,!'.s.m"c€, ener"ll, h l&rc1). quqlh,l.l . Jf's c- ltc1uful,r5a rJ eoarll
                    kcrnSpodd cqld ec,eir1 f,*.n".t in c* liust oS d,e,n",ices b 3ener.te. L,*i
                       9tclrtci, ar           rnobron.
                    'Vrlhen we lcqrn oi, Wedon'l- useup ils eneql-Ne 6imgt1 eonueft                      il
                                                                                            ,lu ['{u,r-rncul e
                     As we do +hs, v,redecreose lLe orrrunt ofi hrqh-quoti C"r,"-',. rn ile hovlcl
                     O.nc incretrSQ t4re SUggll ol- 5rt Ll.ss use-fu I aiFh'c*,tl F., .onwrr b o{o"6rmS'

    t(Z*'t   Lcrw oF therrntctqno.rnrts ontq agplries                     lb
                                                               ltOr-nteU Scza+<ns (qsl.erns i-,tc^+
           dcin'f ercfrurql erne"qtl Ul Fhr-ir environrrrent)
      &,    )0,^, bocr1    it
                          nof e"n isokrted ssern
               'her .fou hu(e in chrxnico{ enerfltt r)n te- {oo.l .1u., @l"t, rl5 us..J f". er,e€t.{, r'nosfr al




    $
                 i! enos up os tsrrv.cA €-nerxu1 Fh.rt qo* e-xhc"$.sV qs heolr hho l-{'e. envlranrr:.rrf-
                 !X: ctvuctrl Fne uxrbrop Vk$ ncrrurcA TJrcce-sses in qour bd.1 c-r'erdas
                               _ Eyrerqq larve1 Uour bd ,{vo6q{
                                                                               N 'tb
                                                                              fh,S cocfrinr.re'rA exc.krlrqr- otAerl,
                                                                                                              otqero
                                         lec.tves
                                                  o.t"
                                 {t  HFq T*T,q
                                  toosE          :I$'R-enttoq
                                                  r*r ol
                                                     ujeli
                                                                      (oop1 .r.pon rol Fhe €nvirLnry*nt .H.c^t
                                                                     nnctlfes o)r ,e -o.ncl *t t,te- j,SsibP
PG, 
        CI+ [z',                                                        I'tcrer



-t) Gc^S: Q Sgslern in rihtoh eqdr lccrrhoe rnoves fted1 through :pace r.r.rrbi , dh
      6cccrs(on, il_ cordes tuiHr onoYher pcrrHcle or' the uq o$ ils c.on!c.'.r'oer

    Lvlud:      r.o   ecrk bcrnds pe.r..tiF rnotr'on,ovriq                 t-e.-eptn1 *h e- pcrrh^oes c-os(
)
            e*t"or
a) Sol'c,l: A rrqrcl-sad h<:s cr. cleGnife etscf9 ard ec^n te- .ornpressed e)r
        deh"t'"d on'l1 s,grt{1 ,. f c<.rns ss .S e,o'n3 conn e,c}€d  epril- Iitlo
        rnoe<.rr"c,,.rr   6o13.
                                                             Lrluiot: gcr-rt'tdeS hc.-ye- goc-c.J<- U"r.tcls !.l.cJ.i-
    CnoSt                                                                        'tsre c-ose- toXe.t+^ec fl-e
                   Po.rhLes &re rn fASclOrn                 t Akee,p
                   fnohon curd inferc.t-c.H.{
                                              "n
                                                                q;-,.::)            crrn side c^ro.:n. ec<J
                                                                           pcrrtr'cle.s
                                e€ts'rc   c-o i sicrns        -?     oter,so tte- q,,,id c<r-r'r Q.r.*r
                            .: Sat id : fe Pc.-rf'k-e-S a'<-e-
                            -) rffi     q-a ne'q-.ts€.4 b re-c.F't d1
                                           6h +'+ slrinS-  izsoncls

                                w
                               ffi
                                                               ( f* e."rrpg = l4xrb sn)
Airannt'c- N{e1s S r A t-ocnic- Hc!q> Nornlsrr
    .Atornf e nocrSS Nurnbe-c (p.) = * prohcns'+ nerrtr-orns (n= b t(c =tz)
      Lt                                                                         ('tC)
          -ri!t<rr cr$ c! ecrAin5 sobscrtlol c,h &f.e crJn5rnc 6qmral
           tnC,
                 fcrdioc,c!-ive tsoiole used 9zr. ccrrbon dofrnl , !rc.,,3 b prohong+8ne..,tnu.
     'Ato-i. mc^ss LrnftLly) = t.t t x lo tt .q
                                                     t
        LadeFerrnrned bl ,T--Zcr Cercrc-r-1) *t.")= 2vr
       ' !4h>rntc- nncrSeeS crre, Cd lefl hecr1 e1'.rcr.r fo .dr gvto.nniC nur^er LA)
               tt1*, ,"r;r'lt A- , is tn- l,bOlt..)
      * 6r t-hiS h6k, juSl USe A cr-S t{,."- vaue of U"- olrtirnts rnv-5
     -F{oe-<r,r"crr    t{c^q = 6urm of }-he- cr-tornrc- fn(.rtsses o$ te-              o.J-crns   forntfnl
             fhe      motecrlJle
                             ettl rn(O.) = 2*,('cf) = 32cr
              'A lln e)efnenfk, crf,crcnE nr..crgS nur"nbay is Netr t*re 6cr.nr,e crq s Cr'Vornre-
                 numoar " q!omts,, ttumbulSives t-ne- dementS positioct tn thre- 6ricdic k$t*)
                          ig !V,e CIr.irnber- ol locol-onS
7
                     De&     nihbn         oF   .eth.       t{oe                                                                             P6.z

                    1   rt*rt"     of
                                tshgfcrnce,a-bbrevfc,.tecl 1 rnol., r's G.ozxloz3 fa"rorc- pc,rhcle5
                    (1 rnde oF rncrf}et ,s ft" a*novnt= o$ et-lLstc*ne€ conlcuninl arS *"1 bcrsrc f^rhttes
                    os lh€re Gre in iz 3 o$ ''c)
                       '{'{onatorrrtc Cnc,-s'. (e-x'. tirr9, l-he- bcrstc- por-h+cle rs te he-tum c^borv
                           G.oZ rrfg he-it,..n c-rlurnS c,re. t r',o o$ he-iurn.
                       -Dic^tO".ric Gac.S', (e-6r Orql&rl, of bcrsic- pc'-rtr.c,e- = OL
                              rno cXqyn gcr"S ,'<irrrrr'ns G.O?-x(oz3 rnbecr.,rleg "l& O2 c^rrcJ Ytr'.r,S
                              2 (G.oazr lo"t) 'ox11rrr cr-torn6
                      AvoXctdros Nurnber !S^) : Thq * of hac^trc pclrhEes per mole- of subescrnc-€.
                                         Nn=G.OLx1OtS nnol-l
                                                     !-             l-turnbev- oQ moe,s (n) oQ cl. surbsY<rnc€ c.onkrr'nrinl
                                                  f= Nn            N bc.r.6rt- gc*r-r.c)eS

                        'Nt.:t"*.- rncrss         (Hr"ol) eb ae €, sobskn(c rs Hne- rnoas n €nrcrrns -S
                                I mo of aobsyunc-e           ttC
                                 O+, Hne mocr - wrusg o( €.     is                   Hrr.,",t   (ttC)   =   l2g/ rno
     [U oa"tot3 shr>rrrl
      oSN                  )                                                 fnoles at c^ sclbelrrncg in fervns oS ihS rrras5.

          Ex Z.t'. Deterrnintnl quc.-nHes o$ oxq?-
      -A 5,16ern c.r>rrtc^r'ns oo1 og *fy-rr. !b,^t mo{ rnoss                                     cAoeS     i$   cantt^r'n? t*o,*. Yncuy
              Ox11cn (O r)       H"i'-r = Zg/i'.al Ft'..* rvrdte. cavrtcJnS Na mote.cur.*,, =-l**W$tf?
                         n=!X{p_== 3.125 rno       d 1. n,UR = 3.lLS ,L.ozxto'3*;t = 1.1;pzq.,..recutes
                                v-     rv.o
       Vounne (r"t)
         t'l-hg     crrvrc,,-tr*     g$ sp.^ce    lhe     eqtbenn occqpir$
              I     rnt =   tou.-3               uiter = i ooo -*3, so  r",t= 03 L
                                               (^ mrllililer (mr_) iS lhe so.dne c6 .Lcml

      lZ. 2 i'Ihefmc^t &pc^-nsion
           nc-re-ereeS l+€- vo[urn& oF c.r) oQics-F                             c-LS fe.nnpeac.br.re- rtncres.se-5
                                                                                 'f hecr- Cs Frc.nr$erreA '-o on              6[ecl-,   tK fkfi.
              "AY</ltpu*t*xF;aH'?"'r"*10:;ilhk'
                              tt'''rfher c*'c^rt'
                                                  ard                                                            ttxher speeds              m.ve
                    / r, I )                            I           I    I       -B.trcS c^<-< "Gfrehc]rec' '. ncrec^ses l+re-
                lVoluincl                               I        L/
             Tennp. T;                             I Volttrne v+ I                o dtstc,.^c-e blto c,$orns , Eo bhe cu"ue
                                                 Te-rg. G                        lournet inerecrses t.l g
         Voume       'llecrrre{ 6rP"nqi.^          '

                    AV=(3ViAT fo.                       rnost 6rrbstunceE, AV=V+-V; ia inecs1 rc-c-tcct                      tD   v!.,<-
    co9tfide-r"vh   eG   -it
    lliro;"g*l*                          tt:rt;:i[t           o"r"rcJs oq the- ncrhr.e, of, rr"€- bonc]s. in cr r.r-*e-rio])
7
                              Linecr-r Th<-rrncrl Ftgccnsion                        I                                                              P(is-
                                         A L=3 Li ar                           A6 o, solrd's oltrme             'ncf,ecrs€S, ecrc-h o0   ifs ltnecrr
      A constroF:Ccie(f,i:r'enf                of Wt- erF:rfitlcr-l dirvrenSdors increcr8eS crS roel.
                  'The- ex?reaaions for lhermc.l elpan6fon crre onr{ c'-pfroyirncrh€ e+precci<rts, }-hcf
                  Apgll over c^ irni.lecl r"*r? 6$ |eryrpercrlweS.
                 "Ef.Pirt'ccr- Brrn,..,re^t: l-hrl're er So€l frt fu m"c.s.,red clc*cl, b.t| Fhel clonf
                                                                                                   g
                                                                "t tcurO L therc- crre, rncrfc.rrb! ts{'.<r} cJc'
                   fegfe8en| Crnq [rrterltlinX fr^r.tdotnent                                                      UOT
                  eoq      to.:--.q. ei+her         .jlc.Jhtc,r.S
                                                                         :ta^r*e t2.3,, coefGic-ierrs oF Line..--
                                 *(r<-r)               Btr.-l)
            sr.r.bsf<rnc€ L r.., ec^*-                V",^rn..                       otvrn€ -lhermal e+po-r'eion a'l-20'c
          ' Arrntnurn            Z3x O-u           (s 1 n to'6
          .6lc.ss                 lxl6*c               Zl x t0-b         *,
                                                                                                            e.iquid
        '   lron ot 3lee-         Lx10:L             3G xro-b         r3
        ' Gncrele                  tZxttfu             SGrtob I t,- ll    -dr
                                                                        l'aJ
         '      alct$o
            Efhql
        . rlqrter
                                                       llC0x tot
                                                                         2tO
                                                                               It.!
                                                                               x   ltf
                                                                                          l-
                                                                                          l€
                                                                                          l)     la
                                                                                                           rt"
                                                                                                           '/1/ri,
        ' Air(*.a oflner Gs,s.s)                                        3t{6rtdk          tE         .5'i
                                                                                               r-r
                                                                                                      -2        o       L       q   E9tar<1rz.s!!)
                                                                                                             1a569<rc*hsre-   ('Q
                                                                                          -Vcrriatr'1oq<]F-I{.,,e--v-oT
                                                                                            i.,.) til^'le,fnPe.fc&Y.r.ce

                            f'he €g*ce Nenakr ct steel .J1osq1r1cr$r'crr *orrrer th 6ec^|t.J</ is lt0rrrc-ters oncr
                   -The- hrr'gh+        ol
            O"c ,^rinVJ d.cq. !f6oo Yr,vcln Fc,tlter is rT on c-{- ho} Surnrner cicg{ toVrarnr t<rnp = 3O'c-J
              AT=          3o<AL="ILIAT                                 --
                                                       AL= Lz*to-cla-').trc-)CBor.) Au= o.O(eS r-, .L.L,
            r Spoce Needle is Q.S<-nn tc^lte- in l-e €clmher , taLE^. he.igVr- = 8O.bG5rn
      Con..fh.'",       l-]1t2.l I t,)h,f happens to !e hote ?
     -A      rr€.tal ptc,,te krrs er slrc.ulcrr holein i|. As the plcute ls he^rec, doe8 lhe hote get lcrrrtrr ocern<-rltr
       *"    lhe siee oF Fhe hok EXPAkT DS <-g the- gc'...e. e-x pc.nds
                                   n.re..gg


                      lffi*
                      l-.,-:-:;l   Temgwrtr.rre
                                                                         * Put thQ-ld of a 6k.ssjc-,.r order verl hcrh rp<^Fsr tt'er1
                                                                      both           bc-it the stee- 1id- <ird lhe 6ge,ninX ic. $.e- tid
                                                                           _e'lgand,
        F'qure- 2'5(c;):
                                                                     th6t $S over {he g<reS jc,!r-'e.npcrrrcls br.1 more Vhc^n hq
                                                                     Skrss .c{r. fhe      lor id uliil be- oqgr, c.rd con be- moce.
           J

                        AS |V.e     +e.,ciP.
            t8.o
                        necrrs      O'i.                             e*Sl[    ae-n v:vecl '
    o2                  'rrcrker bg3fnS
                        to e.y.p11d
     -o .)
            t'.ort       6tgYrF1               snce. th€.
     €J                                       q)crher iS coe.l        Sgecl'ot Properhes oS Nc^"tser crnC ee.
    Vl o) K.ti tt         /               /-64ow 1o< S,s"t+€f                                                                    r^rcr.|er
    .ttJ*-    .or-l
                                          ue<.ooL' n&st.r,tts inq      - A rettrF of, te cx.,."Oe ctigtribrh'on o-n H^e Woer.44.,g/
     "z
     o/
                                          trrreCrR "dn Vo,+me
                                                                        u.thtcrh ce,lerrn tnes hot^r neclrbl molecrileS intercrol o{ ect ot{"
     e.
     5
              .olb
    'o t.os                                                    -> As qrcrber c1pffoc11hs H"e keeeioX goin mc>e<.LLeS benin hr hrwr
                                                               ctusYers ll'rc*t alre rnore €hronqtq I'aonded, Hao mocgr.eS rSw.rsl
                                                               dlL-"rr^t s1l 6,Ioit g.itUrr-'a+erf+ 'i6 F'"ni eir-rr <-utie.rs,-vnerr4i6qv l
                         Temg<rer.fu,e('c)                      voturne-tnLrerraes,. Aeeet'rui' +he t+]eter nasrrlts tn <rrr €-rren
                                                               <irer.r-er i ncrer.xse- r'n veufteJ-> tc-e (sord) is l,oss de.ngc S'cr.n
                                                               Y^r   + .e.r (i c1u ro) o.nd $<rcd6
fq.q-


             '(ac^ses diP$er ho- gdltds or trlcluids in lhc^t lhe^1 c,re. t'hjht1 Cornpestible
                L> pt gqs ccrrt expond or conlrcrct not- ontl ro res?on€ io ie*igetof.r.e,fo,-rFc.,lto
                 lu Squeeanl the p.^rhqeS .1.rge.r logerher or 7'*ldng *harn f<,.rWr c{Pc'*.
          l(fnehc Theonl:           J
             The e-xpqnrion o$ ?rogectres at the                                              of
                                                 ffrS os cr ,JhcE fn lerrnS                      rcudornllmovinl paHcle

 Terngerctnr.re
          "Te-9q-rcditJre     o$ On {deo, Aa-a I'n ferrns oS Hne                 wroh'ovq   o$ tndivtduol ?""+c["S
           o{ F{^. 8o.s.
      '   6rqt    Hnough di[€<rgrluoecules hove diFerent sgeecls, we c-crn de$tne- c.rr o.vercrqA
                      "V'*s =J@.^u- u:he.e (v'h,r"1 is $he ovg                        o+            +;;$J.-#'d
                                                                             '.il^e
          o't fhc- rmlecrrietr velocih'es- (rrn$= Y66F- il,.cr.n - Sc{u.G tr-€.
                                                                                  "g ".4)
                 l ou* =lttntv =)rn,j.-.'
                 -,
          Tl,a Ay3 <Y.,ehb- e-necSy of the                    i.^s porhc-e3 in texms oF l{re- rrrs         seeecl

                 k ".,,q=* <*f          (au = l.SE'           to*7x
                                                            , is the Botemc.nrlg c.rat<,.nt
                 b €' direr-$1 gropochoncJ }o !Le. a-bsoui€ {ernperot^re. CT)
             'Te{np ercuhr,re rn<cr'Eu.res the qv€.c4tr- ki ne-c *re.01 aF tlne. pcrrht le.s
                 in o, StlSlern
            XTP-rrrp      K   tnhmcte1 eonnedred to l{.re rcrnr<Jom rnohons o$ the pc'.rhtles in
                                                                                     ,                                   hhe
                                                                                                                      TOSil

 Pre.ssr,lre                                                                                            nef furre   <rS
   The- Qr..e - h: - a-r€-c raho [E), i"a"penc]enF o$ 'l-he- EurQrce., ec, rsed b,1                   lhe collrr'ons
    o$ [he g".s gc.rhcls u ith {he u-:cr,lls ol c. contc^r'ner.
            ; F          "PreSSur€ is q. sccdcr quo$ti
             ['=[.       'Gos e*er*s o.. €occa -tr rre3ni]ude (p=p"A)
             ,| fre56ur" *urril         -or*ffit ::ffi":**"^,                      is rss,-* vn. ecs ere-rts
                 G Rrrcg on o. 6qcft>cc.
                          (ve.q   6rncr-, t^suc^,lr^a        pressures   fn <iopc^sc.-ts),     olhu-,^e 1Wc^= 0[0Pa
                      ,                                   fe
             -rh" &,1 PusccJ=
                                         tPa: t it'
                                                                rvrarl be luite lorrlt'   b"t   if Fe1 excu-l1
             b."ffil"t-n$."*t#
                 (r'tl" ol.l      €orc-e   ot t€- 6srftr<€ aS lour l'"d,{ d,.r.e trc l-lre press$re & il'*-
                cYrtncsgh€re- rs sver t{o,oco poundS,rbul i}s bc.Jqr,<.e-d b.{ *                               *1"d
                p re6srre- inSide our bodq pUhinq ouJk, J
          . Ne| ftrceS Are exerkd                  ft'lere3 cr. ?resau,re- dtf{er<no Ap,
                                       anttl
Fneh on a turgelcg/a F*t= F -F,
                                             ^tten
                                 *PrA -P,A=Atp"-p) = AAp
 oleo, oS A     J
7

                                                                                                                             lqs-
                   'DecreoBinq l-he nurnber cF rnolecules               in   e con[,ainer decrec^ses               Vhe
                    pres.^re Be.o.,o. lhere ore fe-we" eolisians W ilh the wolts.
                   .nA pe.r$e.| vqcr^u-rn (p=Ofa) rs (rngoee,rbe blc ccrrrno,l- rernoe eerl rrrilecde
                    koon c^- regiorn o9 Sg.*re..
                    VcrCtturrr : (n p.c*cbice) rS gn encjosecl 6Pc,ce in tlhtc, P a'Io.rFrn
                      (usin3 P= OPo is +fun e' good ogproximafnn)

         Mecrsu."ir.o P.ess,.^re
          ' *) pres-sure o$ Fhe c*lrnosphere (*osF irngcrrt<rnf pressure ftr ou" dai h*)
             lhe-                                                                                                             Vq,rr'es
            t.ith o.)lihrde ond $lte weother, tuF fhe gobc,, e^verc*qa presaute-ql.!6€cr ervelr
                     1 Slun"c-l'c) Atmcsghe,re = 1 er.hrn = IOl,EdSPcr = o,3 <P..
           'ln le U,S. to..-e is vnecrtr:red in Po.^ncS otncl o.recr, in slucxre- incjuS
                 Pressrrre fs o$ben poonds per f nz to. gsi) I c'.tr^ = L{,1 psi
           'Gc,rute ?re.ss.r.. (P3) ie Fh.,e- pressere- in e-xcess oS- 1 c*n1
                           PS= P- c,-trn (r.r,.rst cretd ! a.-tm=lol.3<Pc. ho lhe r€{d{nc5 oT.^-
                                                   preggsye gc^uge        ht fr'"€I the       c.hEoti^Fe greStr-rre'(p)
                                                   ne,ecled    b.     rnost q^crrJc^HonS)

                          the
          - Pcrh'ents tuFletio5 Cto"n de-cow,.gce-ss(on sic-ness c^rnl a!rr conc,i&ronS n"c*.{ bg
           lrec*tec la er- hl"gerh*rc<- or,{ffn ohcunber ft.a uf oxqX,crr o.h qrecrter thetrr ofmr:a-
    pherte pre€Er.ne. h qrhcria:J chcr.rrrl.er l,sir 8-t* ena qtctfes o$ dtosne-b<-r O.?S'n is fi'tfed
    WilL ol..{ko^ {u cgtdfP           pressr.e- a>f L-l   fPc..    r,dhcr.t's   }f,e   trne.,t-   on tr c,ltdefS -.1 3u!
         A=ntrE]            Z-le?c,.=ap
                                   Ap                       F=lqZt-.zN
     A=ir to.'rs*/z)' F        = A'Ap                   F      = Z<N
     A = o.H1zm'           F   = (0,1.{e*"X21,ero p.,")


    fror., Collistons b        Pressr.rre. or,cl Fhg   lcl€*t-Gs Lc.r*s
     ,   [ncreqBtnl the Temp le<rcB           toan ncrecrse in PreEure
          L> ?c*rtic,e
                         {yn-ve c*}r higher epeec}6, fh"hiV tlne- wcds ry.ro*.e                  oFeq.ll   msre- [orc9,
            So {-hq-re: trnore presv}re
     'Decrecr.tin lL. Voume- tec.cts b on Increr^Se in Pr.sture
        L" Fto.e H.ealuent <,oi8on *ll te- rOC,r.S d' lt* <ocr.riqcr, clnd &htrS
                                                                                                     fnore PresAuJe
     'ncnec^sinq Vhe Number 6$ Pcrch'oeS lec^cls io c*rr ncrer,.te in PreEsuce
         L" |.kf€-
                   "trrrttiluenf cothsr'ont uf l l-he r.rcilfs .f FLre conle.,.i.,-*-,errrd fhuS tnore. ?..sSwe


             +Cotltstons in on ioecrl gos                 e<t#tg6o no e^,""11 ts osl in tf'e- <oision
                                             1ire per$eoH1
             thvr,, lhe porhefe rebo,.^,njS g.*" to-,*ral u:l its veod **Zd       &o* V ta -V
" The F;3 erer-el d**1 c. <oteion o$ d,,,.rahon At is rec*!aA l"r k!.L
                                                             I
         parhuels cv'drqe in momennd* Of ttro.,S)r At'APx = m(Vr)+ - rn (vl.);
                hiit5    (V*);"=y e*ncl CV*)e :   -V, he L*3 o.' Fhe FclrFr<le i6',
                      (n*-.-,;axx=Yn[vx)+- h(vri = -i"r zu
                                               AI                    At
                    11lg Q:..e. oh {-he pe^r-h'cle is neXcrtive. blc- i] poinls to Fh<r tet+.
                    Ac<onCinl                 E d-l.1r,.l, $+€ wall erperienceS le eg,.l but ogposirc Force
                              ,lo Ne'^ltern's
       .Ii             *. n*k'pilT*u$rp1
             [-,'no                                  fhe %r." op 1 <orision   r]e ]ohr nunnhr N.o*
        o$ corslons lhe^t ocr.uf, du*rir,<a t|'e h'-e to+exvc.I At. t[ lLrere- <'re- N p*hq,,eS
       'lnor io1 ol s,g"od y in cr bo> oF vitu*e V, t-Vre- t+ o$ coisions i s',
                            t."ou = !$n.,a,t
            'ncregei.,g t t+gc.rt'aes).'r tVc- siae- oF lher,oq A u.ri ncsecrse ..lcorr
            'ncre-cr.Si",1 the-  oQ {lne- box to Decrecrse the- Nc,orr [sprcads tLr. gcrrhees ouF)

                                                                                                             N
   '-f't1e    Ne! 6rce                        :
                       on *-.he r,,aer"ll F.,e-r= N)co[ ttrworr)*s, =HV^"'ot)tH) - -V
                                                                                        rnutA
        reg<rce V b.l VrrnS ond tUtc lhere c're 3 dimensk-,n.) 7. bl 3 I 6'rU lha} llne (o..o- ercrted
       un tsh woft b.1 cl vc^st hurnbcr of cotrsicrns iS'.
                              Fne-r    =   *+mv._J.A
             SlvidioJ tr^.+ b.1 A I F','net1      hc.r"ve   qn elpre66tor. {or +Le prcssore- i n       t{^'c-   t."ti
                        f=   P    =
                                      5 Y*u.-"'=           e +tlnnl,,.r)
              ).nnv*at = c"v3 rine-ht- e,ngrtl per perrhue- fn                  q<-^. r Eo   )


                      ?= 3 Sk*
       *The prestLre ol-an idecr.l qcrs degencs                     on   jutt z tht,.q'.
         0lhe number o$ pc,r|''c-qs per g|rbrc rn.i"r (N/v)
         6 ftQ- o.ve-r"cr*c6r kinehc errex-X1 o$ the pc.rhrceS ( <c"q)
             - pV=NkeT :          dec^.^ g-s [-c.,.rrr Lve.roton t)                   Siondsrel Tgmperqlure qncl lr.ssur
                    tanis oS pV rs e11:ivaent +,r T t P"..m)                          (StP) = 1 e^Frn ?ress$re-
             'fl=    h JnkgT= n g.T I d,er^I-gc^S Lqr^r (vereion-z)                     crncl o'c
                        p,=xinrul tr,a',",r+= Gcrs crrrrsh-rrt                    '    (1 r''ol oT 8es e^'t- ETp r- z?'{LJ

             PV=nRT
     "p I Alotoule prees,.rre Lin vnr'h5 o$ Pc") ' R ', Gc"s Conelc,'lf ( in uni]s o& *.r.r)
    'Vl Voume oFthe6crniw, or c.nk+ineroSqqs Lin u',ils "t ..t) '1:fa^fercr,l-ure [in units.g                         k)
        'y1= Numt.- oF moles in rFhe scr.rype qe c.o6uiner o( tcrs
                                             ."$ c^ rnoq
--$B| .volvYn( ts oec*:gr'd b.{ 1 rnoc, o{ o-n tlecr, gc-S q* a# FreSture of lc,hn ord c lemg o$ o'c-l
                                                               q
    l.*to^ = 1"0L3 KPct          V= tn W)/p                                  V=0.022t{ rn3 (           to3 u)
  P=                                                                                           ^3'
 Tt O". = Z1g R                  v = (t.oo *or)tr. sr Y*d .Cf,zt a k)        V. ZZ.'{ L
 n=1      rnol                             ot,3   q 52*
Pq.l
    lZ.q     I cler,l-frc^s ?roc=esses
       L)Thg ideal -qF^S c,*^f Xro.rtcles cr connealrtrn blur {re gres8.rre, Volume-, crvrd tempercr}trre
       s$ g qas. A"inq 1 o$ t-luse vcrricrbeS ccl.rses L or boFh o$ the othets to ehcrn$-
                       tt|,rs
       " Prop*Jhes of          ?ro.ess'.

    ' thg Quorrti d qlra iS Sxed. No Gr ls c^dcted ho o. rernovec) &orn +he- *rre"
    ' -Il.er. c we-defir'uc nihcA Slrl.e. The inhc,. vcdr..r.eS <>Q press,*re, lourne,
       arrd ervrterqrre. crr-e deSigr.c*"te,4 pi, !'ir'IT
       The"e       c-,*   u:e-a*a$fnec ffna                Eh:,.,e   , vcrues desgrc'ted ?+,V{,G

  6r qoS.S in Secred conlqiners., ttte nuynlrer o$ moss (* oF moecr,rr.es) does llOT cJccrnl,t
  ln lhc,.t ca5i,ss, the idecrt-qes lcrur c<rJn be roriben.. +S
                                                                 =CI.R.: eonE$cqntT
   Xhc vcilueS oF $g vorobles in +te fnihc"l ond S'r,r*l sfcrles are l-herr r<*hecl                               br1',
  'Blc p cnd VcTp:f'- prVC.=S;Vi ,riha" anct Fca,. stEltes C,r, crr, idecrl q<..s
orr bc,t-h sicles o$tFfre {1fl-                     r r -
€cru<r$icJc r r.rle w6q1 qgg l{         ir cr se<-ed cootcs'ner-               r
                                 T
p-"tF*;t'*tf ffil[l**, levnsorc,rhrrs busr be- i"r ke-Nin
             pI   Dic^grc*rns
                         Ec.ch slate- oS cf      idec" <a<s5 ig ferpre.se-nteci -> kncr,-r'nq p qr'd V, ctnd crssumi,
                                               CrSePoinf <jf cA oV'dtC,tQfcMn gea1' 6 id k",o*ttl {tt- o.seo,te.d,
                                            ^ Lspe.cr'$es prcssside- crr.d, v&ucne-) <-onlc*i^e-c,
                                            t                                                      1ou coJn $r'ncr T-
                                                 I = lcxrt< T-= 3btX:k Ts= Goo l<
                                           A pr6c-e-ss +hc!r cVrcrrrqeS the- qq5 frorn one Skrie o
                                           Onb{+rer- is reprrraSerrH bq g $ic.ier-turq o? o pV c)'c.trc{.{/'y'
                                                           t          (<-x'. he-c.tr'^3 i* or d.oyyrPretsstni it)
                                                      V   t*r)     C-onBtrrr* - Vcrutne P"ocess
                   6v;     I
                                                                   (bnstcrnt* PregEr"rre   Proc-eSS


   C,onatcrnh - Voluumq froce.sse.S tv+ *  i)
      b {h* vc.we of V doesn'+ crr*ntrl , Shor*rn cr3 cr vertr'c-c^, ine- i-t$ 4on t{re- pV clie,Xrc.r
&, lZ.6'.Ccmpuhnc+ hre presrure on c. Llo+ b.^a
*Tt,re- pre.ssu're fn a ccrr hr<- is 3o.opei oy G^ c.o.d Vnorninq rr)c.n l-hc- a-ir Fcvnp is o'<.
AS[€r g^g dc.{ {"{rc.rrns ug o-rd oriXh} €trn ghrheS on !he- Iotcrc,l< *"a, Hnc- lcrnp o[ c.i. tnticle- 4^e,
h'ne r.r.dno-S 3O'e, t Jkrc,.tts llne h're, pressuye cF fnrs t.rt p ?
        Pilr    =+.;-Yi- ?i= 3o'0 Psi t l'l'Jpsi                     f+=P;4.r+
            Tr T               p; =lL{,lpsi                                   r;'rt sobK 
        I'   = 0'C = Z?3   (    Tt = 3o"c = 303 <                 P+ =[q't,1pti X zra rJ
                                                                    ft. L'l9,La pti - I.r.19oi
                                                                    pP =    3{.1gsi
Contlc*rrf -       ?res6ure ProceEeeS ( P+ = P; )                                                  Pq.   t
              L: ffso ccred c^n sobc-,rrc- proce.GS
               'HggecrrS crs a lrlorraonh^,l line on c. PV diaXrom
             -tThe gcrs pressure ls delermfned by i+e requirement lkrt the
                                                                                       3c.s mu$,|- suggorh bofl^
               fhe rnaES on hop oS the piston      (qp6t{it cr const<.rr-dorrnun-rcl fur.e tl3 on trq?iston) crncl
              fhe Air pres6inl inwclrcJ ( lt e erir erlso pr€sses dr:.^n on lhe pishn)
             x-flnis p..s*.,.e is lnclepencler* of the ternp o€ fle gcrs or {}'e heiXvh oF the f,*ton
               se if s{rrl1s eorrs*c,rrl crs on1 o-s l'{ iS trnchar,cttd tt
                                                                 nnc.rSs fnCuinkc^.t'os e^ Constcrnt
                                                         p..se'.r.re    in the c1incJer




Ex rz.                                     com     SA
-A qcs occuglioi 5o,C)cm" cl"l 60'e- is             c-ooled qlF c.onstqnt Pressure r,tnt-i le. {-e.rnp is (O'c-.
 Qhcril lhe Hn& vciume-?                                  .              t ?E3.K.-
          Ti=bdc=3z3b<                 V+= ,f.v; Tf      Vt   = Eo,o.r"t t s4I,.   j
         'llq= l0'c = ZE 3 <r                   T'y     V+ =   93.Kcrr.s

Const<^n - -le.rngeltr^rc- Pybceas (Ta 'T;)
 bAss c.*ed, c,."r. solherwc*l pr<rcess
    br.'.   n piEton is beirg    goshecl dor,'rn a comgress a tG, buF the qcrs a$ircle.r ts e,"rbr',e.rg-ed {n R
      lc.rctt       eonrrlnsr- oG qu;rJ helcl cr-t e<rnstcrntTeir?, l$ tt',e- pieYon is g.rshec aocll$, t{.4J
      hecl erver*, +nons6el: thn*th +he tr:c*s -S lhe u{linaet u:i ke€f 'lre- gas c-+ 1!.r- sc.rs
       lernp crs tlne q.rr.o.,ndin5 iqud Lsotnsrn*. cornpreesc.rn)
        ' S.r}6i.rrt c.. eXg^.5eoq : -Ihe- ravqfse. grae-tS, *sl the- ?ielbn gon-r:..1 guJed outs
    'Bon c^nd V q,hcrn(g in crn iso+herrnc-A proc€Gs. As lo5 es Tr"r"'or'ns Stxcl,
            ?
              ..t '5 = ft Bf =
                               qgls!g5,t-                  *oH"lrrn: The qr<ph oF ar, lso$u.rrnc,l ?rbceRs

         ;$,"                  il*"= o', Y^uur*" R€,c^h,o.*hip blw p a.cr V, +he Br..gh 6g en          botkrrnc./
                   !-'u   Pro@ss is    a
                                   perbocr
    v1         v;      soerrrg Eypev'rsion wouo rnove in lhe olgosile cJirech'on
                          Hn                                                                   o,on3 {-tne- hlpcrboc^-
            The occrHon oft the hlperboc,- de perrls on lhe vcc*€- of f
            O* o,rceat corltsi<rnrt {-ernp *(D=4t!hes+ cpnsbcrr*r te-nnj.


- A gnort     ek         deeg brect-rh el the s,ur&rcq, ftti* hts un6s rpiv.r H'Ou oF cri.. He-ttl
                     Fc^V.eg e.
dercqds to e de4Hn e'f S.owr , tDhere l^q pressure ts t.5 c!hn^, A tis de,? , uJhc^Fb the volurn. oS
cu'r tn lhp snorthr-s lunqs1 Vt= Vi'P; Vt-(.{,t,c)(ffi)
                                      P+    V+= 2.b1 L
,lorK                                                                                                       Pq.1
           'AS gc.s      evgc"ncK,          tf does worK on cl-n obe-ct, F3*       [s   drre.io tlte qqs ?resstJre
            'Jl rnaSniude-         ot^                                                                     -i?t
                                                                                                                Vee.p tlre o6ton
                                                              ^ gc's in on
                                                   done b'{                isobc'rrc'                      in o!:rce. a-rl exltrn€^l
                                 'xlv-
                          rlgos= p(vr -vi) = pnV                                                          6rl-a tn(er Ue. E,c.-
                                                                                                           g"t ory*i€ b qc,$
              Wg*=o,r€cr Wrder lhe gV qrc-ph blw Vi cr.nd V+




                                                                                           AS lhe pfs&on fnoveto distuoce d,
                                                                                         the gcrs 6,.3 g'.rork E-",d

                                                                                                                    - 11,e q.ts
                                                                                                                    olurv.{ cfnr,Xrg
                                                                                                                     bq AV'd.A

        'norcle. [.r" c*
                          $os to do wc.rr(, lhe- o[uvne lnLr,Et Clr"nxt.
          Thus fto hrorK is done in a cont!un-- volurr,e proceas                                                       r

                                                                      h've when o.;             *;;"tnu'o)
        b.,.t t)egc$irq (-"."i.3               wori. i dore oh t1'.e qc.O 6then lhe       gas (s compressec) (AV.cl)
          'hJgoS=PAV on$ c*ppies  to conskrnt-ptestwe Proces8ea, Er                            a-n.1 oFher [ct€a.,| -ga.s
           proceS, Yut cc"cucre the ar".^ under lhe p Xrcrph

       'To Gilct,.crFe         p'esEurernuStsbe tn ?o 656 yeL"r-rne in wl3. The procluci .,f
                                ,rtcrrK)
        Pc^   (?*,   co,d tnt is Joole ( +he- u^-,nr'ts of wort< anrcl **g..4)

       {g* it  wor( done Bi tL'e sqSlern, whie Fhe orK W +hcrr apyears in t-[,e- lo 1c..,. ef-
       Aurwodqrfrrnics is (-rlorK done OAJ H-re selsferrr . B,-,-f 4f =- Ug-t , So *& lsn Lo-r-'l
        Qrrr be Nri+ten'. AE+t= Q- Wg*
                                                                           "":St).,
                                                 1 o__                                         ..*J
                                                                                                       
& l2,t,.Fn"r,' the r^,",'k rtr-,e by o G".S                                     --I t ,
-0,0lGg rol d$ ninog4n Tolcr^l |'l'le iaec.l-gcrs pra.r-ss sh<r,sn be)o,o I i               1*
 ^q)
    hkl c,re lhe inihoJ enct fi'r'rc,rt tevngerafu,"s .f n"" qSE?                  I ,                       {
                                                                                                                        V(c-r')
li)tb* rnuch ur.r6 s done tuj Hre g,.s?
                            f                                                         k:o,&o -la>
                                                                                      k:o
   p; Vi= nRT                           b) nig..s= oLrecr encle-r pv S"oph
                                           (o.oo"Z .n3),*zoo,oooTa) !(o.o.rcz-).zo,oooeq
0 11 = (ttqr,oo.rp*Xo.ooor d)
           (o,olO0ro)(t.atY*o'r)
                                                                      '
                                                  NXe"s= ''lo,oT + ?o.oT
                                                  Wgat= bO .O f
 G=
         [o,or oO r"or)tt.ar Y"or.    r)
 T+=rlb K
Ad iqb",t'" ?ro"..ss.s                                                                   ?G. ro
                 Lt Rn iclecr-tos proeess in rqhteh no hec"t ehertl isfrc.ns$e-rrccl blur {de-
                                                                                                      nc8
                   qnd the Envrronmerrl tl'us Q=O,
                'L possible $c{s it- ccrn occ{^-rl
                )-U" €qstern is thermctlll tnsr-rc*tr<dz prevtrrH.a hec.b t--crr,eSe-r
               z)The Fro<-ess .rc.pge-ns foo quic-klt 6. c^ frc ns$er b occsr (ryroe| cotr.tt'.:o)
              ' Fl re.gid Corngression (Adiobcrhc csmgres6icn) dr ex?crrlqt.r, (odic^bc^h'L €x?crrsfon) oT .. tc^S
                 doesn'f ollour fime C*/fl"-t .|.                        .*ui.,                             ,/
                                                                                                            -t"
                      . Rqises tne l5*gerreture                         of g<*s                   Lowe*s          t*terc.{,ure o8 6c.$
              .l.I$es WorK, rg..er t"c'.n heatsr to Oncvtlr- l*re- sgecds                                        oS   t-he-    moe.cr.,r,Ie8,
                c*nc, Iurs ehc'nXl Hne- Tqrnpercr*trre
           '.Fdrcrbcrh'c* CornPressic>Y" Q=O r sc A6+11 = - N$*= -
                  J.tu clo .*:crr( On $he- qc's b carnprcss i],ao Hne- trsr< aone -b Fhe go"S
                   rs negcrfive (Wgc.s-o).Thtx fl.,L F+r,, oS le gcr-S nc-re-crses Cte+6t61
                  crncl +he -Ieynp. goes up


                        bh Gpc,.nsioo:        go-s. t-hqts does t^ror<* on a pitFon b1 e+gc..no,'5
                                                             r+                                                                            ad,'ab..hb"lt
                  (VrlX..s   >o)'q€Jbs coder ttrf) os its Tt'urrrr. enertl decrarses [AE1'o)
                                                                                            t?
                                                                                                                                  2
                                                                                                                             Pz
6    Conceptrrc" & lz.zl Adirbcrh'c eurves cn q p V d,'otrorn
          +FV at*{rc.rn Ot c^
                              ffrS trnckrqoi,.l * i5o+krrrc,r compressdon&om pirrrt pr
             Z. Rotlnhtl'ho.rl '.rlo,,td ilnegv J,5r.^- look i$ the ga$ uJere com?r€ts€d
          la poinf
dacm F"nt 1 +D +{E- Sqrre S'norl PresEu.l€ bl . ragid                                           vL    
                                                            9d,ctU"^lr'c- corngressrbn?
                                                            tt
    Pz           Jhe cwvg of the qdrkrbcrhe                    r.r.".o".= $q feYnp. o[ the gcla cs the uror<-
    ?z                       qorprEiaign rhoves
                                         from                         a-bver
                         ,ia;[.TJii.A- +o-.'[Bh;rH4.
                                           -----                                    dorre- on the qos it frc*ns$rmecl in|o €u.'. Corsequerrtl$, t
                             G5SE:rn
                                               -                                    A^rve cr.rbs creross ihe- i66 i-harrnK fd ad on o- h,$*-F.r-F
                                      fLgher       r                                rsaFLrrm u)ht{ Fhe qcrs Pretsqr€ re.rraru-s p.
                                                                  .   -lhe $i..r   vdurr€ k i* lf'ere$ore l*qN ldqn tfut for lle.
    P1                                , LowerT
                                      v
                                                                       isofurmcrj com?reaion.
            vz                  tr




         Spe.i&c      Heert Lsq,,.u.' rs .)
          Lrlhe cr.rvrcunt a$ hec$ t,,.r-.t rqi3e< lf.eTernp oS 1k3 oT sr.rbstcrnce- b1 1S
            tt Dqends on1on lhe m..'.te-tcl hovn sghidn at oe$ i€"^          trcrele
           the hecrt neectecl(o) to groclr-rce cr Ternp. c,hc^ncnL tAT) {t:r mc.ss [F) wi{r .r. age.rhc                                 hec-r.F   tc)
                      Q = H'c 'AT        ( = t tte6o
                                                        ff"E q") Q = - (t*-p qss Dor^rn)
           Bl"    t1i   %+C    I ll       tr^.t.eS hec.f entrttl to e-l.rc^rr1p +U,e- Te-rng. oF c^ sr.:oskrn<< rrr[ c. s^"caL
                                                       Yyy3y€,

                                  Specit-nt- l,u-ah 'tf^errc {c AT oF o. aulbetqr.rrc- ro[ c'. snnc^, spec-ih<- h<sit
7
                                                                                                                                    Fe,.U.
     6. lZ.?t6,'erttl f^. .,'n '. Fen".
    -A 1ox3 stucf<rrt ccrfc,hes *1.'e $l,e,crnd is hoal +€.r.? increcrteS $tom 31.Ooc(9t,G'F) fo 31.o'c-(1q12op'
     l{o.*l rruc1 e11eql is reluirecl }o vc^ise hrs boclults f"rng, f
            Spec-iSL het^r oS the bod" 3'oo|g*'L
             Q = H.c'ar                                       Q = '1-1b0OO 5
          Q = (ro <3)tsrcoT*u. r.zr<)                        a = tl,trlosT
       Phcr8e          Chc^nq<S
                           T:lonsk n{- c."S 'tVre 6qS}<-rn
         TC'c)              a.s iirom tcrjz. trqu,ct O             'lhe   T"mp,          Rxecl qb o"c{ot an exterrled pgid of }tmt
                                                                                  r€.ryrcLins
                                                                  '[htS
                                                                       iS fhe hrne intervcr.( durinX Ohrch llne- ice met16.
                                           Skrm     is            As ils rne5, |he ce Ttr,(P'=Ooc- Gnd the iclurd r.rxr.er Temp"o"c-
                                           trrerrninS
                                                                ' Euen though+he qsrcrn iS ber hec*erl, tl'€Ter"?.doesni- br1,o tt
                                                                  rise qfi+il ALL the tce hos rnelFstr,
                                       Time
                                                               'Erte.g1 b- o.IdeA tb tV€- sn<tern it being troecl b brec^K
                  fs                                            bonds H,l the- u>qr-!er- maes.r'es, Aiot the- Sorro oF +he-r*rc^.l<r
            worrhi
                                                                 Fro* sot ie -> Lilurct
         0T*rn^0. o..h tohrch cr                                              Pr' iF llne
             q €aid         =     ?sn+ or
                                    hn                       {-he @                      (b"th phc,.te cVK,rqA)
                       fruibriurnl ftn1 omount o[ sottd con Coex,S- *l anul ernounl- oF Lrqurd
                 .PhcrSe
                  0b0c"u.s t.lh.rn a sqshem iS ob fhe melhnt or fr"eA€ point
                     '@                  >lighHl , l-he €rrhre slgFem Soon becornes q Liquncl
                                      , Eiqhtq, L[ enhre sqshern becomeS a sottd
                 @ Bt,^l l-he Ltquic        tde GqS ?hc,se            qnl curncxints o9 Lq,.rid cc^r| @ckic* d(
                                      "."d cr.* Fhts Te.rnp.1 c*nc(
                   Gntl o.nnounF cF (naS
                   'As hec.$r ts aolded to lhe sqshern) +deRmg. skols fhe sctr''e. Added **11 raused f
                    brerot< brrts blu, the Uqu{d rvroecgt6, c-tb,,.rrh3 H^qrn [0 rnove iob Hre C6ri qtoSg.
                                                                                    -=
         @1*1.          e^| r,;,htg,h o Gc's becorneS e Liquio Cond<nso.hon Poinl oy
                 A   l.-ruid be.connes cr Gc.g (iF E+n is ncrerfeJ)' Boitrlng Point


    -S           houe    q   Narrn soda    th$ g.r^wrsh"+ocoo,          woold i.t- be fnoreef*ec-frV{-   ta' qclc, 5J oF i$io,ooher
         'qo"t
    al 0'C or 253 o urc$er rc€ qt                O'C?
     ' Fbe   Zt ol-qrr+er    ice. ctf o"c- luai, ha^t 6* t^ri|l be hanskrrecl {rom +he scdc lo *.,e ica +<: .e)! i
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Physics notes

  • 1. 7 CH,ll ', Ugr,,tQ &,rte&sry1_* e_! tlcu qel Ef{tl"n..{ ( e) = ulhul kihqF qur hrrct ta P'1 lte orger co.t/r errerXq^losses t.., g Bqere-rv1, S" looer ils e0-fiuen,rt RCuchc,is fhe co*e" '{rom L d|,l'Ferenf sc..*r.-eE: I ProcesS Lim ilahbns: tn*gl osses due lo practra.l eekus .:F c^n' energl +r*as Formr,Ston fcrcSS - D fundcrrneilf&l U rnifc-fionS'. 6^erq.a toSSeS ct-v^e-d.-r-e t?r ph.lstc-cJ lct-r-,--:s Fhcr,t c-c^-rvno4- be c;^c*,/ Tf.l-Sd result d,'F{-,tu"tq <>F hzrnqQ.irrrnis Q-ron--t FLe- l-f.,e-rrnqr- *e.1q r,nto ot'{.-q*- forrrr'S oF e-nertq, ' Wc,,<rn3 up c. 9i3rl+ o* sz.rrs, ,-tout f nc-ne.crSe qor,r.f bodrl's 13 bV o.lmt)l lf(nT ' Bo+ qi * u- tcoe1 crse.d a-.[rc{ts -1 2r)oX oF eu"r-r.{.1 Fo cinaf -FL.a. sk..j r 3 lnc-re.crs<- in ut - "b.-lr-,.-F q.r.^ oF' , -IzooJ our b" r.'a€.s= "&Jh"..h r4.ouharJtdu 4 = (tool o, ZS = Zb.L process '1to1u' eQQ'c-l'erc1 is TLool= -tLeu. e-|_Fr'c-ter.1 due lD ' 'I--rrrvrl'-1=*1'lrr-r= tr,it".l bI loioc,V.orntshcr,l of F"ocl diTtbn r hiome-cjnco-vri"-s o! ho* .tctu rvrove Nlol Cr. F.,ndcrnne-rrrFcr" Ltr*iF btc proc-e-ss c-oud r"q w.c-r-clq rv"r<;re- e-FQtc-,,e-nt- , vsed d..i5 rnuSts o<- %n*1"d tre.c.lrrrccr- e-rne.rX1 Fro""r olhet Sol-r.rc.e-g, tltucr-g cherntccr enerXtl G .r.^J or o{^q.r Cossi eues . E*r"n', Conve-rhe.d h 6*t to 1 butrnfnS , cta:v,), {-{"!- rr€utt5 Er-v, converte.cl {L 6a.-*v''"'- e-: # = 3 sr - rnxer.1 due- tu cr Rrndarnnenkr, Lirnikrhbrt Ea^ CcunOt be- h''rcrnsGrrr^-.- ha oH".e.-r €trrng O0 *""1t r^l [Oti'/- e-0hUeyrg.l k 35'/"e t's ctose ltr h'{"c{rrejn<.c- ntc>a.t'rnuvn 6.erqr4 Ef&'a'enc"t Probbms crS "urV**b L{...( ql-". this co.t<1 be- *ve- usek,., qeqq o-lFgu! oF c..rr', e-nXtne or procsSs or H^€- tlorl< +4^cttk clo"e- ,',. corhilole.-h'n1 < n'U"hc"+,,1ou PfO€. E('. U-)h!.n Llov Cimb c. Pl,'3nr .>& glcrirs, ?r-t'= AU3 .(A"Lunc* qc,u had tu eof " r^,:ill Eereru-lg be- the- stc^I e.ne-rg.{ t.?uts nc.edeel fo o* entrne, ta6, 0r prcceS8 . A. i ulkn i1c,r.n r*n your c,,.l'. condihi.rne-r- tAhoh qou F^ig" - e,ec-hricsl *.xxf fngrri Sovel )or,,. lmr{ ned h do cdrliNc,lrc,- ii.,tc-*^tr^l'c}ns -C-t)ffPUK Vc"uef iot t^fV,of t{y g^}" t "6hc.J-,r.!wpo-rd'' o B. sove- c,tl evrergt vr*tves - CoVnpUte e = a hc"l- vp, ?*/ril.* .t* pcud t$"U,r**,.
  • 2. 7 Pc-r--Z -A Cr+r-3 brc^ve-;5 cio..15 c^- e-rzel v^o<C e^Jr St€,€.*a!1 $S c.t (Offr* ?0%) ^ph t-'.jhc*. q"{qq frarrilforrrrrh'on cefcl bvz"rrs.$brs ar-e- fs$(i^a p c.r-e.-? Akr Ar,t1;A&h+ AE r.e"., = W tCL Conse.rvcuh'c,n o& E e1. ftr on open sqtRrn, fnctr.rcIE .CC!. mov1.n3@ cocSfsrrtsgeec, n,raKl olttlg"S oF 6 {rJhigh rn,'ghf q{pt^.,t ta l'{.0.-c-c*r '&rod tg ev<-, so no - F qrr iS rwrnr well,r i Se.nnp. r"r:ilt be c.ng1tl.{.b, no AE"." 6<l,.rn does chonctr<-, clerx-ecrinX aS &r.e. r's brrrnecl AG.r."r, = frl rcl U*q tD cl o u.ny!1 [t" oF Ctyir€ Go.co * *u d-rayuEftr E aS h4c.i- ,tz> F{^a- e.rwrnt r A c(L( an a- hc..t a d r""3 coegfitjenl oF 0,60 ', CLfet* of Hlr (fovrtr <ll t{o Cf,*r = [,trnz, WhCtts t/nin. pou/e;. doe-s thts cry neeel b yv'royg o c,gteadq spee.cl o4 3ofr/s on kvel ftround I 'Cc* coing work blc of droq , Fshiry afrncnpcre *i) F = in mcrtn ihrJe tu d.o.q h-c,e- b: .l-lnis is +.t 6.cu thcri's ao5 r-,..rortr on l4^g €lWrn* D=icpAu. . P= Fv =(zfuN)ts"*ts) -gloor b= L(o 3px.2*V*9(t.rr) [eo*ru; *2&os -Tko c-orve-re-. ho* Fxlt'l ft r<*+<o] a+ zs rni(-o.s/guJtan o? go-s a* hr^6h,n*.7 sFecc) fuhc.,fk fL" a Cav-va*<- clriw<,n 25 mite-s (ctctt<*.,) o,j- Sants? "*{blen'1 o? fa g.<ff6>n ,F tc.s cankr.,.r'ng 1."{xtor t aF c$sry1teel *ernq aE*,., = PA! = P(+) au7'/.trtotT =GroowXatrtr) lt.to* =' irrtT - -'t'& = o.ot 3 = 8. E"/, O^ t. 6Z oF l-{^.- c-l,unfe*.| e-n.t-17 Froy", {-i.c gas f s use-d lz evucafte dfclt. fl^-c- regt i6 ^'tc>sh-" crg h!c^-t- $" Y^R- qv;ran*qr{. in t1rnle--licrr,l Enery.r' ln.,-td*S lvc.r6e otly -t13 _ af*dxlde wcrler onc€- bn erqq frui 'ft:or) its =!rot- ne-lo'ods , Lte l"-"d.I -K i;I;;b..' v-4 tv('trlaurg Gd z-{, Lo,' (nt'+,o' JZ.ipTiljr 6f"lri*ft"--t 1t.:--= S::1.1",brerjftuc.l fn"i k=,, .cr'*b,'n<s o^Wx t-hcr-fS -1:t.jl,f^ {-r' prodvre " ' u f e1er9' eJts|l cc-rgor1 clr'oy,icle, uth;ch r'S e-yhoJ<d; t^:e,ler r-Jhic4 cr-q be uSe-c. ta1'l-he-_taa) *1 -.,,2' O s c,{aqy1iq^,, . uOxic.,tahbn oF ti oF ?" .- +l eferc4t4 t'S Use.gr bq^ . . 4:*+-q$Lgt,trtl + enen3Y fs useo 3[rrcoae-b. <rX ot{^r cc,rb . eff",rOq r.l.lit reecrse ctPProA ' 17 <T oC en.ertt r-- -,r.thr--rdR;;€du d- r^a 0.,*t.1" a...-.-., fzroal r--. -- c- ^ - ^ tt --.- - purnr'n3 L. -, 1-'-.ns6aq1f..{l-'-t -u L- fuut"t oF H.,e- TH"ffi;;"H* F*r*., lr> o.s Q$6,rk* J,.o-^*t E;{."t*. . Jill'un c<rn bq e'o*tt3 w-rerr+r'rreel cw * Q) E*..^ t tsucr.5 nnerrt,ur,recj r'h rn,:$ rt CalofreS(cg'f) Ik.,a*t.j,..,$$ q4 ^ ^r Cnwqq C{.)n€JI Oir tDoct S LrLrcr_t { i= tsr:lb .OO cs"on'e- a 11,11 outes ",t quoted in Cciories Ccaf) u-ll c. cr.pibr^l_"c iCc.u.ie (a-so "at..t o'"€r94 cr^ltt'ia")= IOOO sr 1kcc.J . lF a, ccrndq. bar ..i'l n";6s " 1?dCn.l . fl U,,rnn{ :l uLc-tulll p rr> d,, ce :c.rn#r-u'ns lSo C*t, i(-b -r nd, ;t f ;il4 nrr) - "".lo',es Z*,bCS cc-l (r,r 9&2KT) irl E*".^.-t
  • 3. 7 & ll.s; trt,erg{ tn Fxd _Pe.s - - ft Z aZ .o]^' o( sodcr cohta-u'1rg eqprax. '/oj (v;+Lss i-h6, 7r cr^p) "F 6ufr*, a simple cc,,rd>hyolr.,-c-.), Hot^t fvrvch C)t!.mtccJ <nerql in .lstrles cl.:eS fhrs Scr{f,rf conta,r'n( tb.- -"-nt cr^-lorr'e.S iS lhis ? t g o( sf3c.r = t-T l<T 1- cat * L{, 1 jo,oes u3 =68011T - &Eo,ooo1 = bzza c-c^l = GoCaJ in !* c-..--, -P socl,e.* 6""-fl Us-e o$ J-s4__ Reshhq pd!/er(Vi ()t'14c,..-n .._-<- oF 6g fi.i i",a.' 'bod'a ii a-[uc.qS Usinq (aeratL/ t ovex cr-h re.St- " Liv<--r- zQ btrlo!,rn1 F repc^-irih3 hr'ssJ.re, d,3ue(.t-t.'3 F...a, q-.-td jce-e-prn{ *.Lr"rr. il:", e.3/3-". c:,-,4 ipo-er (.n w-l-fs) 'Brc.a',^, I1 'Enet^n1 c'orwteS F-o'n-lt 6-^-"n tn gtaur L-olra't 6.!zre.St ' ' l'teay {- -l d,.rtd ",-i t-r-lh^rrao-fel q ccrnwe-rlr-aa <.i^H-eJj t+ l-i"A-fmc.l € 'htne^1s LL -h'c-h 13 i-rc<,nS{-t.d.4 cLS heaf- b H^e- e)1vi.oY1rvreo1- ? 'A Spirarne'l-er me,.svreg hoc', rnuch 0z -he- bod,1 lffiff' r1 S tcr<t..o rrD + lleo.SLrre-s khe tacrclq's 'l-ot-c^f tcx)U TakL d.tJoor.. En.,z1 Us. (fr"Frfr{1,),";[* to-r-,t ge-h $c:7 rw'rt n3 oc+-,'"t ! ) 'lf qnu elimb cL aet o€ 6{zdrs c,.l a c.on€fcrrrt specd AUq :-A E11' * A C-.1..o,, = o (no ake) '--.G Whc,f L16u X*', t*1 :. 3 A.t .J , bolh ;a.rgas5 (n) be.rn3 "sed t-) 1-. Ail3: t6t<3{9.tmls) 1z'.1"..) = itoc:.5- IAE = AUq o- A 6.n Chevnr'ccrl ^"..eme-t"q.1 Fr"rd yuu.r bc,dl iS ccrrrve-rted in'l-o^ po,l-ent,c;' eIeyt'({ 2. 1t1hc.t tqou hac) b pnl The ..E+- is li^e ( He,3hr,is increa5l'-) and lhurna) rle1(nc- 5 | l c-r €(-(a rEr I uI c4 { nJLf, I 1 I vrrekc.r.-)oo;c enetnl Fl,'o- b.,d| arsec{ i n enerbl Lbcx i s s{' gll"ttq ..-:c.r.r,.e-r) corngl-h"1 Flr.{ r..s k . t c1.,.^" x-fr,f W hf:" .o€ och'v;6pg congdered,h -For Y," fuf"tt:oaltciagt o-nA *f9c ere4 in o€ och'vitts, 5-,".,.1 '-1ZpoT cUyitq,el"o -'":z:zoor ] o,::-:F!:, ! flt. f Uu"1i3, Fr*[Z lat;?ffi'EH:,N,";'H'# ra4dp a( Zo- Sd z oW15'/" EW ends up us t'f.-qrrncrl ,rrrl lncr€crciecl t^l &.tlq, I*uw rnc^n1 H|flhrs - lF u1". c-r,nELrrvlec c! Zo a c.,-n oF sodc(r h.r^ **.1 *ttXt"t5 of sh^r'rS coud art C.tnno or' [,[i- 6-v.,.n" its c.onl-a^rhS3 f*ssuvv'te- .-. rvecrSS oF 6F {<} C-Lnc o. Fl,gtnt- tl Sfotrs hc.s q- vev h'cg- he.rqh* .t z.-Inr . I c-r^*-r sodo- = G86 lqS oV 6o^...., Sr'nsq flvtg = m't'Arl 'l. Ssurne- ?5'/. ls trc.rrrk,rrnecl h> Act= 4*a = 1,1'ttsT-- i,nrrpc.Serl t/,3 -tr,r,::ltq.t-r") ' *5 Aug = l Lts,esXf" trr r ros 6) A.{ = ryla A(g= [,]'l()sT 2,-1rn : 1-t FiXhts of sk rrs ' h"q.i used f;er *.^cz:nd runnt= proporhonc.r.I F6 lcrurr speeal u'funnt 2x o-s R^.ef takes ofet". Zx as muc-h [rcru:€r, brlF cllso te"V4S 1w Zx ct0Lf b"*Bq quu. ttse- bu run a- ecrkcrin chEkrncs.- doetn'l- depend on your apeeal)
  • 4. 7 Co En Gn w ht-1,'Fh^ Rt,-tl "A, we;XYrt-lrpl'er ,Pls q. 5o t.S bo.- P."..t lhe- Fo.rr lb a P"si}1a,n ov€1- h,S hce^d ctn), bccc1( ks H"1a FL,r6r- qtcq-n O X in Successran. At- U^i- e" rrl oF fi,s eaerc{,s€ lJhc(F .41-n1 {-ra-nsFurrnc-honf hcuvt h;u-r p ) c..c-c-? 4 6lc-rn I ute-tVht'liFW * b-.t Snvrninh c,tt.:e-S na QorR on k1^4- aLiSrca'v't A F.tot, "A C*r" = 4) ot /ot"etu'l , (LSSurr"ve- H^r- Hrn€- t'6 Shcrrh eni'rXl-r <'a-c-r' #'"Vr^e- ---Lre- bc,-a ;3 rot^s.) H". t- fio hr-cr.!r g5 r^e.r>s$c-rred Qr*, lht ^uSel'<-S t:se' E.t e-rr, . U (l-'r.-r.**-11, qJl at t{.c- s1;*--t t-a) 'H^-e- e.llvvaq+f, {'h;s e^erX"l rS FraagQ'lntec| f., 5,-+" B--r t'S re-brlrnecJ, +r> its s!c{-hr^ru3 Fosih<:n cl.rrc} iS rlod tuvtuial t So la<-re'S beet1- no cVrqn* in .r kg -A3 )e l*toSt e*eraiSeS in [-f{ t 1- ( 1;fhnt .-*th}, runnrh3 c)v1 a. frec^-Lvr,tl) invalo ot-t Fl"e hcprrsfurpys;h'on oF E"-t-at--, + Er+-, 'A a.4c,l6t pe.cJc.ls 20 rniq a-v 6. 5;pe-ceJ og 15 l<*',1h.. Hau-s nL.eh rnejaba/ic q1gg11 tS tor " , re7u4 'l8O W esecJ in c*1cl in3 c'-f o- apeed a? t$ k-rnf hr 2<> mrx (*{) lr2-ac> 5 = ffi be=?At AG= Llt'OW (r2oos) u- Ae -sKoff 6ner.?1 Sh,rc, q( 'Boc)",1 cit,tg 6t"*.Jn frcr"n &rod, iF {"rts e.l.e{t1 isn't wEed, iF u,i be shured 4r -A"-F : srvrcJl on-ertnf o( U"rvt/ ne-cded Qr. rmrnecl,'cr-te 0.6e -G tlco2zn I cs-d glucose: c-r.a^r o.rwrvr,,h ?Htflsil-6cecl ir, rmrtsole hrtaerlt'v<t 'Ha-lhhq actull rna.k 5d-ares * LlooT aF l-/.aae "r ec,rb'(a, h,#A rr-ro(e {-/T-1 cc:n$urwel ln 7 du1 -Tha bd stoFeS &bcx^n- YOOa .,F csrbolqa"^*a. Aggrax. hc-,r.^.r 0<*r- c-zruc.l u 68 t.3 run$€, }rc.rr{ on Fhts s{-orecl qo7l 7 t1 t.T pu oF c<^rr"ox.aa,"^re. (rlooor)(.{oo3) = Q.tr loo T I 5o W useJ i n runrricl c!t- l5<m[ l+r e .yrr o& ,- A8.r.."r.,=Pct At": A.6.,n'-.^/p :-boi_-: b'tt3.oq s = t.Gl Ftours Ax= VAt =(teKrn/*r)(t.t"U gt; Ax = L_1.ta <rn - 25lcrn usa 4"nrf 6 ua)k bl. ol merhano'o,/ ine-F&z-;et'tcr es t n oL,-r ?u<'f.- (tne-he €-ne,ri.1 'frrnott{1 t-raltSfu"w1aA intz: ffu+rna} *uffi t'rt qoutl n/ruseles r ShoeS 6dh-oecLr c.r-1 be- c)e-Si3ne.c[ +a r"'rinirniae lc,Ss oF e."er11 Lt A l{.e Scl€ ol {-he Shoe Ccu,r S-Dre polen'o- enert.{ ,uJhioh "p",nq rn CAi^l bd re-turnecl t-D <nerh'c, *."?Y dcr*-,n3 fL'-L MN+ stride. (Spr,hq maJc< {-l.e- calli;fon cu/ lhe X-t'attnd ,nc'}e e"las'ne) .J
  • 5. 7 P6.5 lc-_- a t " ce,si u s s -a/ 'tre.lnre-nhe.il tdeat 6crS L'".tr*S do nol_ inferccc-t tl[ othe-r te-x.epF 6r collisfans:ec.SHc,tro no er^c-l"r is ost) , {he sqst<rn, haS no Va+enh.J **X1 (U{ , anll Kineh'c "*rtt nh*"*t enerXl oF en ideo. gas = ir"J'hDki ki.,e-Vtc.-en"r11 *T?-r'e SoBl o[* {-he o=turns {+c,=l rrLctke op f-h€- qc"-g *,The ternperc"bure- oF cqf 'derd gcts. rg e.- rne-c+-€uy-€. o[- {tte avecctl- (ineh'c <rre-rfl r$ H"e a,lrorns t-hc,!- rna)ca uF ++',L qa-s. ! z kouS -- Z vrn.Vrrrs n c.tomtcmas" r-oot rrrecr-q SqUA*1.e. Spe-er) nurnbe-r o$ qhornS "15{Sf =2 N rnv.-*' b I grn E' Tlwrgero.ture on tl.,e. Ke vin 6c<re (T=T. " 21 C O K= Points o-h uJicj^ !L"a Ktne-hL ^uX1 crF aJzms i$ 'Ze;^o -'24 lernperc.h-:res on Hne- <e,vin S<.c--e o{e Lr) 1-e*.n9e-rc.:tute- c>FcJt rc1ec.I gcx in S<-rrvrS aF f{^{- _ .. Ka*r <g dr,)er^c'ar- ktne-htc- e'nenxrl per a-tztnn 3 ku (fjottanrc.nn's conshanf) : t.3E x tO-tt %. kc..r3 = 2 KeT Y L on l..r clerends on {he, lonl etv.lure, nots on fhe crC-om rncLrs | lncrerrsinq x lrr c^ Scrctur oF cl lncrerrsino Lr-r Scrclur 1,.rg-r^se-.d oF2- 1 "i - e-'c'btrs 3<e'T fi epeed is ProporFr'onc.l br> t'lne rn { o$ vhe Ternpe.rce}ure. I 1-nlT ,' *h,gher kmpesalare c<rrresponclS i b ftrsfer alrcrnla or mr:leclrkrr epeecls xA gc.s ,.ll l*th* cr.kornS r-r:i ho"ve- Qlster cr,hrrvrt, ChcrSin3 X c.fz.cJa,,'ot {+an On Crvercrsyq <>( tcrS tll hecrvfer c.-FornS C e-}atqts I b'{ 't C'IH) S,r+"c oQ- {Z Uacd'ar ots c- &rcfor d*- rr'= otfumc rnqss r l,6Gx tt,^" 1<3 Ex l/.8iSpecd oF rrttr"gen w.'oec-u"eS -l.liFroqrurr.,es (ti2-). tj 2o". ohc:]r r:s -h!- rms speedjl_ilgw$bcgtes oG__qlqgi (n="78^*]qb;lO.a?k3=T.2orL.l3V,*u=.F^@Vrr.ns:5(om/5 y.,r= Ll,&sr.ro-11Jg 1-= z-g3 tq - - -V L.Gb nlo'uus
  • 6. -YGr.b C-ort g*b 11ner n c,. Ene.c61 % x Therrnc- **t1 f s airac-l{.1 f1*.,= N'ko.,1 = t tq'Ke'lf g roportr'c,ncr. Q Te{Ylpe,{cr$ure therrnal F6*X1 Jg c.^ icJec,. Xa,s oQ N a.rhurng A6,.^ = * U:ku'AT , Tne E*. oF o. s ubskrncr- f s p ro porfr6,ra^J; t?, H,.e- humber oQ cr.irornS A gcrs r-o m6re c^*orns hcrS rnore- 6*h Hac.n o, tci*s a.ts S-ne- Sdn4 e- Te-r.perer-h:re- w I Fe.rre-. cttt>rrrs. 2. A A in Ternpe-rzlfure- cr*u8es c:. cropor{i''c,inc--L c-,1c,-ng,L I n {"1 4* 5 $V2EV<u cets Vllerrnc.l *15 .t A [arctr er tso,rvrporature cVrcuu.r- ;, (rrr.r€e.s a l*tgr chc*n1e t n thcrmc.,{ areft1 O, t' I,(a1 c to o c-r|,13 oF c.-tsrnosphere- pre-Ssrre- ancl 2Lo c- c-ont-crjn: 2.5 * lott rnole<-tr;eg 81 ho.^t nnr-rc-[r 6[oe-S itsS $.l-rn..-l d'ea"rt- |{ r'{-s hq-+eol tzt %'c-?. AT-= lo i< ^*1rt AFr,., :i (2.5 r to'')[t .tr,tol,l*X ror.) A 6*t =6, 5Z 5 r ena W"'r< o{e aimpy Z d,'FFcrerrf +e.Ak rrrcr-L{-S oF {-ratrSf'.'etr rh3 enen1l bb or {..o"^ a, €lgFenn x 'Therrnc- ey.r3t1 fs trci-ns$<r-rec.t b [,^r cr sqel-e-rrn crtrd ?l-!- €-v1vt ran *-,enl cLS cr C-oAseclue-rice o? a fer^np. ;1; p$<r<nce b l* Pt"-&1 ''Whe*1 the fast - p,at-,e.c,ues in t4^e hoFler oblec-l- coicJ<- u,l lhe Src'ser n,Tcrecr-re-S (n Vhe- r-aer obierrt- NeJr Resol|l fi.ri1 k*n hoHer --> Coole.r o61<c-f 4rc-xr'tslerrq) [{ ecr is Vhe- aer% .1 trc.ns$<-J- d, i o- tl^errnc.l q Fer-i:.c-t-rc 1 rr ^
  • 7. 1'la1 Ffotn nrro'rr'nq n bqJrr'er Ore.vc-nks IerlrprnSbwts sbrl o-Pou5 P_e'r.61 Wem Sqsk-rn tD 2. ( H^e.-rvr tu coicdg stem.r uz Tr tTi fr- 'AtsurvrS in SqstelnL hc'ra o.--hiXh.e* kr'u3 Lr.,o n€-.- r's /as I r'n a* pere<c*11 ,oJ"E a o ^uI qtr'c e-o l ti-s icrn) F-z^sl- Slow Oa <-<) Etc.s'Lr c rolisioh L-b.L6"6;s.{ GrCrrnS Enerqq #' h'crnS6erre-ct Fro"t {-he -+ Therrrn.) e" e''rXLI s ( n€''l- &-'q71 franS$e.r ; .$o-tt*- t^lov'^n c<-bpr-"-S 6n {-h. U)o-rrnq- E;lcj€ (as Hec^'r) .b ${-re, Sot-se-r-"fvrcrvr'rt3 o-tsornS o11 *he- asler St^c{e )rZ Sqsferns pc^c-e.d in thermc" eonrferc-l LDi I Frc^yrs$er *fiernrc^l I tr Cotlt5;orn3 lrc.rtt&er eAe.tfqL,t Fr.or- l'[re u-Efmer to-S Sq're-/}1 +-?, H^-o- *-tu/ ,vno"e enetTe'li< ene*tl t.l-nlil $.dr (k,)c.u3 (l<.)"."1 o-L*S osa Cn€rrCq tb eSS e-rrrerqeFl'q &^*t ternperir*t^rcs a*Fzr rnS . Th i s .i4v trc'ns$er = [ 915- O{e Q,<o q; tr-) qrhen =." i=' h.*l*$.u..d t{"0- Scrrn.Lf ^*XrI SpJ* 5qe,+errl Q =(-) 6fierr enerXl iS hr-ounskrred OUF ok c^ S.t6h€rn F {ecr"t S Fra.ns€e-r'qg9 6carrs €co"n hoF to cokix T+ lTr u)1,e4 the Sqs+<-tvts hc-re H^0. -tc,!r.a a-Ne-rcLc* tfc.n6lC--h^onc-l lcine,fi'c e1er1r1 o-y,d, f{r,.r.S Hne- sc}rne 1-crnpera}-iZ Qz --l-Q, r llnd, e-o(l,Srbns sh'll tra-nsFere/^e-rqq t-"* L Srcte fr.r {-{^n- ofu, 6ra J-l,,e-re,k n" fr*r err."E1 lrc.n s$cr ) themcJ k1vilibr,utt lJn" ls* Lc.* oF thermodqncrFn'cs : [g*= VJ*Q lZt sqstcrnS f n ^rhrcl^ on1 {-he- Fhe."'..t €-nefil chc-n3es, lh" %ny, ^ in fherr c- e-ne--n1 iS eluc^, +15 F{^e er1"t1 trc-.ns$err<d I'ata ar ouf't YL-,e Sq6€i.n cLS tt)rk W ard/c,r herr-t- O 'sqslerns lL,crt cren't fnovinS Cno 6r) , Fhcrl_gun"n'9 q-hcst, cernicolrl(ca'-4, bul- UhoSe. t€,,x pert'h-tre5 dcrn ohc{nx,e- -- the:rnaAlna-rnr'6 Wov( on Wclr< bt{ su st<rn' Sqstern f,r) <O w>o Srlsherrr 6ner3t1 ln AE+v,=W rCl EnerXl out Q>o Q <c) Hee* to Hec.l- &ro.n 6r.1S€rn =c1arcrn
  • 8. 7 PG.B Conc-eo,.rc- Ex lt,3'. CompreSsinc a q4s -|1pfrt" c( 3a-s is in a-n ins,rc.$eol conta,jner, so |l.rcr-t no hec.i enoty qJn escq.{>e. tF t pistan is used 4o arnyress *t^-o- g*s, uJha+ happe,',t /" l1- '|enp. oF t-/^o fq ? "The pr'6fon cr"gg,eS s frrr.e f0 Frr.l- $s, r.',.td {'h€re ts o. d;Ebrnr.errt, ih,S rns4rls thc* ,"n i< ts cLrne on .|il. qc,S bq {de pitton [Vrl to). No thervrar <.{eJ(tu COn be evciluna+d ill the Qnvironriient, theHninq Q=O. Sincr. ane-rqqrS lrr,rrd.rl., inlo the.p,lt+r"^, h" tfu""""l qe"U? "P +4i-a- fas rnus*,'nr-ui^e. Th,s tTlgatts t/v-'#tnf rhusl ncrerts€ a-5" cae.//. &. Il.lct', Wortt ond hea-l in a 4 tde.a-l Gds -Sup7ose u conVcrlner hods 5.or lOtt r"roec,*r€s oF ar1 rclec,.,{ flqs, 5oT oF q:orK o.fe- done on &'1",e toS b'-1 o pislan fLwf @rnpreSses r'1. the. +<:vtp oF th" 9cia Cha-rr,7cs by 3o'c- clurin3 *his proc-aes . Ilac': rnvc-h het* r^S *rans{<.rred Fa c..,- $-."- t{.,e- '*uiron.-.-ri+7 AE*n=1 N'KB ar n Q=tr6+q -W AE+r-, = ? (s.or. ro")(.38 r ro-'3 Y*)( 3o .) : 3tS- 5oT e.rwtcc)'fvrn€.rr1- ,Yy, l;;:*' ilffii* in Lhis procs*ss En *J, - Tra.nsfrr Drrcrns 'h*V, Re-Ssrt o,'r-; c.-n a blec'V or a- 6tart aF the- envirarnmcrtrts so <,-r-1p Hac--f ifs +emp. cl.oesn'f nohc-<.c.bt1 cJnc,nXe uhen hec^-|- ;s tra-ttSl<rr<d bt^ lt" 61stsern c-nc, &he Y?ser14;v- (Tu) -+Dt Re.gervoirl A re-servofr cr-F a higher +-e{1p. +{"&-"1 Vhe sysFcrn (f") - CDd Re-Eervoir I A reserv6jr o-k c loc.rer hp. 1-{ru---n +{"- s,1s}-<-{v^r .+[-{er-r.t e$eql is }ra-yrS$errect bl* q Eqsl-ern a*tcl a- reservo(r r'f 1+.e-1 hcve- dil(ere.n* *e-lrnp.eratrreS 0 * , o-rnoon! of he-c-+ t-rr-.r's&-rreci +o o( Som cr hot fe.s€rvoir -^fr#au' Q c : &wroun| of hec-! Frcrns$e,rrect ho o- etov^ ct c-olc feServoir ;s Hedr* ()l H lrc.nr Qc- c.gP$-s t'|oL Q&voir reserlar'r HoF reservott .rr! --Cotd a-I- -fc - a-+ -----r Fre c-€ y^gclurYes 51shewr QH=Qc .+o+ rese(/oir fs crtsc,.r-{s aF Fhe top (k53'f '(Dd re,&rvo-ir cr,-rrarrs c.r.t Ts bo*owr '-lhe sqslem tgFT"') b* 2 reservorr5 ' Res"vuor.s c^vld alsratr 6,911aecfid b,t h;N" +W co^d t//f//- **otrt/7 -"'- J't " I Lrr,-sE4r -*uf , )t Spnlarrrus hranskrs go rn 1 direc-hbn ont.1( *' bt+couF,_ fuuVr{-TrcrrrsW Dr'a6ro.rn
  • 9. 7 ?csr Cbncegfual 5, ll.'l Anut, t**tdku-< . ', r : l'lno 8"O, -)ldhy-in phlSr'cS &ercnS- r's i+ rylor<- tux;oj ort *he bou la ereretse tn "e*,/ hal w e+^+rer? Llor, fua1 cenhhuovsl7 c-ctnver*s Fohemo E*n, . E (q*r?r4zt"th a. cons'ic-n{r bocLq k-r,rtX" Tourboel{ musi urnh'nrrl.zl1 {rransfu hr<* t- t1.*- ertv{rdftfte({1. Thts is ecLE.l fn c<,.t tt'te-u.]-l*r : 'hrcol- ts Sponlclner*ts! t'rasrs|ered h tdt- €t-tvtn* , bu[- olkan l,l.a- o-t'. l*af i: h,Xt^rr |hclrl l1cr* b..{i ts€rnp ,L{N" b"t1 ec*nnaf aol idset? l'h,s cr6ll/ rutd Muat ose olLt* rne.-hc"rlisrns *b fi-c.nsSe"r- this **Ajt Suc-h as fe.rspr'rrn5. Tl.,nSe rher)-lc,'-rt6zraS r eTur're a.ctcl,'han -t ener7 elqr<,,no ih.lf<. 7 6nerto{ f5 e-xhc{ckd ffiexq, s f u'C,rwur,ua ht ru{ l-l.re S.* Woor =aR _ec_ 5ysfer4 'ie-,--u. bq f ru ""ST.- 6e41au& Evergl it'pul Fr.cess heal- erlertl rs +tc.1s$<rrei deterrnined br dte Hecrt ene{j1 is Q r+ "6. into !he- cotd tpcrter Znd La-,^t eF 'n-d{ra&lc: dha( trcsrs$erle'l €rorn the c tZ ho,t- r.^rqtler e-^ Worr - Qrr-e. e^oo= -T a Qu e.o reh'cc.l ry"axl mum eFft C erc.t " B lc er^c.x e I , ?. werr< done is o( o- h-e.^f e-n3ine- o-u:crr{S e SS Y"c^rr^ {-L.r,e hec^} i vr p t-,r"t (wo.,* . Q ") So !her. b-^.uST ba hec-t Qc exhc^.rs<.l +" f{.re cod Te.servoir q No hec+ enqfre- er.n corwqr tci% o[- Lt-,y in&z rsefi]. r,oor-( z-,b-r+ rg l-''g enercM rs'usecJ "^Yg1 l:,yi, hloun d'#.i"f=ff-l 'h"nl flzr^ nac)a-r 7yr13;n tr4,o c.,(e ac e- Stinu Worl< Nou+ uc-eqjr- rec-eh)r procluceS h^'Sh-PreSSt,re. Sl-ect-gh al- ZO-e-. +Fle-r ils use-cl FD spin c Cod / 'l-t,-rtine, ifts cr-nds6gqd ( usiS cc-,ar3 .^.oher ksenroir (-c.. cr.- irec,-rro1 rive-.) bc,ctc h: Urcther qi ZO"C-- 3.1h" 'l'trre rernarninq enerqq e-tce5s hor.l-rs,cleEei/ed ,n l/* nnq.'{1,,t Qc'Q *l - Wori is ex'krrrrsd oxr.ber iS H^{t1 refur.lel,C}rd +l."l. qde beginS off4'n h, ll,e. ccd reservoir cLS hrhcL!3 lLe rncrx. ross i l"e 46tn^c*qi4,,s yb,n I ;,t) ui&Sl h4f^,k a , zlo"e +?-13= 5 L3 , LNLV'T K A* zot +z1B= Z1#n €rvrr"X= l- /b63l< €rrro* =L182
  • 10. 7 16'0 t, J I 1 eerts P. nnps L>Ticrntf€{:s hec- i*ou !ro* cotcl reservior fo o. hot resgvior "^ (tt"e o3'pcsifs .F the"ri,^l.rtol cdrrecht -, 6r.: Kgh''gnr*Vr:#rcc.nsffers h"a^h Fro* the cokl cur ins{ae lhe refrinercrior tl fiine W0rn^q otr in f{,,9 fo,lvn, Qtt= Q-rWin '-fhu. arnou.,nt oF heo.t- 6nerq q ry'vusd-. b e conSerfccl e,xl.arusd *o $re hoL IFfecr.tu lep-si a-er-I in t-'Ls h"[ stde- rnr,si* .q"o- tt€ Surn o F k'Lve nec.*- ,f lyrty ,thL,/, tQ r€SB.rcvoir t^e.rvro.rec &ror* $-{.q col._l -sioVg a,mo,.mf & h!-I- e,Xycrs-bed CLr41 {-ha uoorl< inpr.lf-' g"o"n {4a cold roS?yvo(y CoeE6'ql'*"0 oF pa-[.t.,rrnc{rc€- (Coe) eseA far aKrreJl.l coP= g = =_ 6; Qe l*1 c,>er r1a'ceA la ?e.fucrn {t,- $ran&r Wl' tr &+tnol eyv,<rs usel to femove l,ta* harn a- alcl C,op,".,.o =+€ Theore-fi,..-{ r'ylcr.x C-c.t? oS o.- he-,or+ q-rd gxkr-us'l- fe,se.rvoir hae,,f P u't-? Used L. coaig t> c. ho- reservoir )t A cu3er CoP yneAnE cl t.F llea* pump Is ussJ eor hecoh'n3', rr,tsre- e.Ffrcrerrf hec$ COp = 3da 3 ener€q ardcled to t{'re k:h rescr voir e Qt*" Pc.tl r,oc,rt ralur'rec| to per-$orr,, t+r4- hrctfss-r W,'.1 -lhgore-hr:c*I nrcs coP "1 "-i*^t e,*p-' Oser.l Crr hecA'= COp-* = #* -'f(. tnsr'oliq aF qosc F"ra* is agrrav, Ooc-. t+e{+ S.o".., lhe- ineicle {E depositeaj rnto t-L( Cdr !. lour citsc-^.n , Lrhrch has c,. 't*p o( 2O'c-. UIE-+; phe n 1x co,lo( Vr, hdV". 'iH = 2o.c- 2a3k Tc-:Zl3<. boP,-.,* - fr., : L13l< {tZ"> cop o.i 3.(o rne(.{ls f4"$,i. uie- p(Jmp 13,Gil- Tv--- ffis----- ot- her! (or c.l.r eret.{ ce6{- o& tf " If.5 c,- hoh dA1, c-.-l.rc yoor c-ph, s rctf,-5r r^)cJ-c^. 1.,r. r.E>6,,4 ftv--t-e- so3get;;
  • 11. 7 '{he #crlafer o$ he<rf firon^ hot h cod t8 qn rrerersibte process AlthorSh inlerachons o-.1- i-he rnolecr-rlcrr te.va a.re ratq6ible, the sho$s at- lc.rg,r_. hurnbers frtr'(e, i{- overu.rhernr'ng1 ikd1 tt^c}+ 4te sqslern U;itl s/ove- fou:cocl @utl,i'briam (it-s |te ,-ost prob,-be sh.,Fe- in whr,ch +o be) &1m"ru I me4e*Jr.s {-he c.mourrq. oF otsoraer (n e,, Eqale'nn ncrecrseS &s lcru (nove- Sto* a.n c:r:oleleA sqolern to c- fl'tcsre cl&c'rclereet st|t4rr-t '2 fherr'nc,r ineraclig stlslen"rs u-tl al;((, l-engwcrturS 6ve a lor.,.l enkopq jrda<cl: hdkralorns Gle on o{e Bioe <l$ Fhe Vaorrt{, lhe sLt-ue, e'.-}ornt .. lfu o//* The rur.rsf rc"ndsn laossib)e drSlribu*bn oF enory1 (*l" ts.t'l- orde-*'er) st1s+e.m) correEfruk +b r'thzn {he Z slslerr":s Afe l'n f{.rmrj quilibl'orn dlqr"rtl l-*,PS. Fhopq incvec,r,seS os lhe 2 tqslews w rn,hc,rt1 ollfferenl terngera,trxee n'byg luwo,rd l-{rerrrc" equi I ilorium zn"t L".,^ o9 Therrr,odqha-m'c-a'. Thet e.,*'rcy1c,f o.n @la-ta-J aqs CVT clerrecrses. 1e. errhopcl gfher incxecrsc, u,r"tr t-lne aystun reazhzs epilibrlum, or, il +hu. sqs+ern b*Sl-. ln equiibritim, Starls I'he Sar e-. Satn nn lsotc"ted sqsfern e.rloles sucj. thrrt: " 0rdey hrynS rnio dr6orcler a..nd nlurdorrvness ' ln4o.-c.ha:n is los+ fct-tlr.cr +^ftc.n q.tt,,ed ' fh,e- 6r1tb<.m *ru-rrg du^-:nu .f other ftv*S oF **qq qre ha$ssorrneol +.) therp,16,.1 "JrW1 ' 1'fterrna hHs enkogcl, oHner t'or*s oF enerX do nof e-rnerql^ Vtihen orroFher hovrvr ol a.rernl is converYe *o dterrnal *o(u|, fhe,re is incfecrSe in ut/ropy. The proc-€ss usill_ ndf sytr*aneaslq re/e-/se- (S^fi*'n= DVy conve-rsionS e6- e)"rwcr Fo..'.s t'" **.11 . t/v1a,crnc,1 <-r c& of{.sr cz)rrr'> gnqttl T.. Yr'T Y^c' *'-11 "f is irre-ve-r-s ble) *' */il#//ru,"[[rinru. ff {s ci-clct€d t$, ?*ff , rF ffi"u, tD t{,e- hec^} errgine E ---L. fhe work oul- coik$ns no No.r- Qlrrtr4tt.The on ^rri{ H4Gl- €xhoBg{sa$ l€qrve iS rrik her.C,Sto.^: to lhe cor,d 6+-f1 resejV(or Cod Pessvur: Tc ,///iv' qoes ocrt o+ H^e hrea! ryrrrnq intu he b'r*tyl rs f€.rvrovecl S.z,-u pfie he-a.t- er€roe.
  • 12. 7 Pa,z Alkrnc^hve 6t-0,ernenk o$ fhe Znd trr^o d Xte,rwodqrv:rrrvrrcs ?h.*.rn.t*n* . UJhen 2 eqokms ctt diffuent )evnpercdwex intcnrcf, ha,rl Fec{i Tert..1 6pn}anecrsr1 Flor,ot tr.nh hot to cod s€{r1 is hctrskrd S?* klneoun1 Som " hotter io *h eoder 6q8iern, Fevor trom lYe co6.. b the hdfer " hnhogtl conetdera*h'ons imt t " f ts nov ptaiot to wrcrke <r hecr- e-rrqine -h$ts fhe possibe etftciencg oF u converK fhermo enetl ino qn equivop-nF o,nnowr hq^t enXine ofr wciy<, '+ |o,kus ene,vtg lo rnove 'Hk nr! potsibe to wnrke er hecrf pump thc^k nnnnel s, hel^f 0.u* c^ ci,ta objeci io ko"n cr coo obleci ts c,. hot- oe* ''^lo on oxt€i-rurl o. Vttcrfrn objes-l- tu.ntt t nguF 'Ihe- <x1hrcpl of crn '1he h'.. dire.han in rNric ?he *rna71 "ttre Prr,t -lrot' "[ on isocr-lecl €qsfern Wi ne.'rer iSalcr-lecl 16+€r0n ncrecr.SeS tS 5ponhcrneou$ decrecrse 1 'We can! C,rfualh/ rotn od*- ,:t enetXl (tn.tq c<lrr't .r ol€st"ofd) hre Cnu ru"n ou# of htqh-9uei sttrrc-et .l!'eneratl (G"r-s {4rcd-co.n .oa,'U vr be conver|..I inb other fiit^* o! -*tf) E*'.Oi+ cocrFc^aYr: c,!'.s.m"c€, ener"ll, h l&rc1). quqlh,l.l . Jf's c- ltc1uful,r5a rJ eoarll kcrnSpodd cqld ec,eir1 f,*.n".t in c* liust oS d,e,n",ices b 3ener.te. L,*i 9tclrtci, ar rnobron. 'Vrlhen we lcqrn oi, Wedon'l- useup ils eneql-Ne 6imgt1 eonueft il ,lu ['{u,r-rncul e As we do +hs, v,redecreose lLe orrrunt ofi hrqh-quoti C"r,"-',. rn ile hovlcl O.nc incretrSQ t4re SUggll ol- 5rt Ll.ss use-fu I aiFh'c*,tl F., .onwrr b o{o"6rmS' t(Z*'t Lcrw oF therrntctqno.rnrts ontq agplries lb ltOr-nteU Scza+<ns (qsl.erns i-,tc^+ dcin'f ercfrurql erne"qtl Ul Fhr-ir environrrrent) &, )0,^, bocr1 it nof e"n isokrted ssern 'her .fou hu(e in chrxnico{ enerfltt r)n te- {oo.l .1u., @l"t, rl5 us..J f". er,e€t.{, r'nosfr al $ i! enos up os tsrrv.cA €-nerxu1 Fh.rt qo* e-xhc"$.sV qs heolr hho l-{'e. envlranrr:.rrf- !X: ctvuctrl Fne uxrbrop Vk$ ncrrurcA TJrcce-sses in qour bd.1 c-r'erdas _ Eyrerqq larve1 Uour bd ,{vo6q{ N 'tb fh,S cocfrinr.re'rA exc.krlrqr- otAerl, otqero lec.tves o.t" {t HFq T*T,q toosE :I$'R-enttoq r*r ol ujeli (oop1 .r.pon rol Fhe €nvirLnry*nt .H.c^t nnctlfes o)r ,e -o.ncl *t t,te- j,SsibP
  • 13. PG, CI+ [z', I'tcrer -t) Gc^S: Q Sgslern in rihtoh eqdr lccrrhoe rnoves fted1 through :pace r.r.rrbi , dh 6cccrs(on, il_ cordes tuiHr onoYher pcrrHcle or' the uq o$ ils c.on!c.'.r'oer Lvlud: r.o ecrk bcrnds pe.r..tiF rnotr'on,ovriq t-e.-eptn1 *h e- pcrrh^oes c-os( ) e*t"or a) Sol'c,l: A rrqrcl-sad h<:s cr. cleGnife etscf9 ard ec^n te- .ornpressed e)r deh"t'"d on'l1 s,grt{1 ,. f c<.rns ss .S e,o'n3 conn e,c}€d epril- Iitlo rnoe<.rr"c,,.rr 6o13. Lrluiot: gcr-rt'tdeS hc.-ye- goc-c.J<- U"r.tcls !.l.cJ.i- CnoSt 'tsre c-ose- toXe.t+^ec fl-e Po.rhLes &re rn fASclOrn t Akee,p fnohon curd inferc.t-c.H.{ "n q;-,.::) crrn side c^ro.:n. ec<J pcrrtr'cle.s e€ts'rc c-o i sicrns -? oter,so tte- q,,,id c<r-r'r Q.r.*r .: Sat id : fe Pc.-rf'k-e-S a'<-e- -) rffi q-a ne'q-.ts€.4 b re-c.F't d1 6h +'+ slrinS- izsoncls w ffi ( f* e."rrpg = l4xrb sn) Airannt'c- N{e1s S r A t-ocnic- Hc!q> Nornlsrr .Atornf e nocrSS Nurnbe-c (p.) = * prohcns'+ nerrtr-orns (n= b t(c =tz) Lt ('tC) -ri!t<rr cr$ c! ecrAin5 sobscrtlol c,h &f.e crJn5rnc 6qmral tnC, fcrdioc,c!-ive tsoiole used 9zr. ccrrbon dofrnl , !rc.,,3 b prohong+8ne..,tnu. 'Ato-i. mc^ss LrnftLly) = t.t t x lo tt .q t LadeFerrnrned bl ,T--Zcr Cercrc-r-1) *t.")= 2vr ' !4h>rntc- nncrSeeS crre, Cd lefl hecr1 e1'.rcr.r fo .dr gvto.nniC nur^er LA) tt1*, ,"r;r'lt A- , is tn- l,bOlt..) * 6r t-hiS h6k, juSl USe A cr-S t{,."- vaue of U"- olrtirnts rnv-5 -F{oe-<r,r"crr t{c^q = 6urm of }-he- cr-tornrc- fn(.rtsses o$ te- o.J-crns forntfnl fhe motecrlJle ettl rn(O.) = 2*,('cf) = 32cr 'A lln e)efnenfk, crf,crcnE nr..crgS nur"nbay is Netr t*re 6cr.nr,e crq s Cr'Vornre- numoar " q!omts,, ttumbulSives t-ne- dementS positioct tn thre- 6ricdic k$t*) ig !V,e CIr.irnber- ol locol-onS
  • 14. 7 De& nihbn oF .eth. t{oe P6.z 1 rt*rt" of tshgfcrnce,a-bbrevfc,.tecl 1 rnol., r's G.ozxloz3 fa"rorc- pc,rhcle5 (1 rnde oF rncrf}et ,s ft" a*novnt= o$ et-lLstc*ne€ conlcuninl arS *"1 bcrsrc f^rhttes os lh€re Gre in iz 3 o$ ''c) '{'{onatorrrtc Cnc,-s'. (e-x'. tirr9, l-he- bcrstc- por-h+cle rs te he-tum c^borv G.oZ rrfg he-it,..n c-rlurnS c,re. t r',o o$ he-iurn. -Dic^tO".ric Gac.S', (e-6r Orql&rl, of bcrsic- pc'-rtr.c,e- = OL rno cXqyn gcr"S ,'<irrrrr'ns G.O?-x(oz3 rnbecr.,rleg "l& O2 c^rrcJ Ytr'.r,S 2 (G.oazr lo"t) 'ox11rrr cr-torn6 AvoXctdros Nurnber !S^) : Thq * of hac^trc pclrhEes per mole- of subescrnc-€. Nn=G.OLx1OtS nnol-l !- l-turnbev- oQ moe,s (n) oQ cl. surbsY<rnc€ c.onkrr'nrinl f= Nn N bc.r.6rt- gc*r-r.c)eS 'Nt.:t"*.- rncrss (Hr"ol) eb ae €, sobskn(c rs Hne- rnoas n €nrcrrns -S I mo of aobsyunc-e ttC O+, Hne mocr - wrusg o( €. is Hrr.,",t (ttC) = l2g/ rno [U oa"tot3 shr>rrrl oSN ) fnoles at c^ sclbelrrncg in fervns oS ihS rrras5. Ex Z.t'. Deterrnintnl quc.-nHes o$ oxq?- -A 5,16ern c.r>rrtc^r'ns oo1 og *fy-rr. !b,^t mo{ rnoss cAoeS i$ cantt^r'n? t*o,*. Yncuy Ox11cn (O r) H"i'-r = Zg/i'.al Ft'..* rvrdte. cavrtcJnS Na mote.cur.*,, =-l**W$tf? n=!X{p_== 3.125 rno d 1. n,UR = 3.lLS ,L.ozxto'3*;t = 1.1;pzq.,..recutes v- rv.o Vounne (r"t) t'l-hg crrvrc,,-tr* g$ sp.^ce lhe eqtbenn occqpir$ I rnt = tou.-3 uiter = i ooo -*3, so r",t= 03 L (^ mrllililer (mr_) iS lhe so.dne c6 .Lcml lZ. 2 i'Ihefmc^t &pc^-nsion nc-re-ereeS l+€- vo[urn& oF c.r) oQics-F c-LS fe.nnpeac.br.re- rtncres.se-5 'f hecr- Cs Frc.nr$erreA '-o on 6[ecl-, tK fkfi. "AY</ltpu*t*xF;aH'?"'r"*10:;ilhk' tt'''rfher c*'c^rt' ard ttxher speeds m.ve / r, I ) I I I -B.trcS c^<-< "Gfrehc]rec' '. ncrec^ses l+re- lVoluincl I L/ Tennp. T; I Volttrne v+ I o dtstc,.^c-e blto c,$orns , Eo bhe cu"ue Te-rg. G lournet inerecrses t.l g Voume 'llecrrre{ 6rP"nqi.^ ' AV=(3ViAT fo. rnost 6rrbstunceE, AV=V+-V; ia inecs1 rc-c-tcct tD v!.,<- co9tfide-r"vh eG -it lliro;"g*l* tt:rt;:i[t o"r"rcJs oq the- ncrhr.e, of, rr"€- bonc]s. in cr r.r-*e-rio])
  • 15. 7 Linecr-r Th<-rrncrl Ftgccnsion I P(is- A L=3 Li ar A6 o, solrd's oltrme 'ncf,ecrs€S, ecrc-h o0 ifs ltnecrr A constroF:Ccie(f,i:r'enf of Wt- erF:rfitlcr-l dirvrenSdors increcr8eS crS roel. 'The- ex?reaaions for lhermc.l elpan6fon crre onr{ c'-pfroyirncrh€ e+precci<rts, }-hcf Apgll over c^ irni.lecl r"*r? 6$ |eryrpercrlweS. "Ef.Pirt'ccr- Brrn,..,re^t: l-hrl're er So€l frt fu m"c.s.,red clc*cl, b.t| Fhel clonf g "t tcurO L therc- crre, rncrfc.rrb! ts{'.<r} cJc' fegfe8en| Crnq [rrterltlinX fr^r.tdotnent UOT eoq to.:--.q. ei+her .jlc.Jhtc,r.S :ta^r*e t2.3,, coefGic-ierrs oF Line..-- *(r<-r) Btr.-l) sr.r.bsf<rnc€ L r.., ec^*- V",^rn.. otvrn€ -lhermal e+po-r'eion a'l-20'c ' Arrntnurn Z3x O-u (s 1 n to'6 .6lc.ss lxl6*c Zl x t0-b *, e.iquid ' lron ot 3lee- Lx10:L 3G xro-b r3 ' Gncrele tZxttfu SGrtob I t,- ll -dr l'aJ ' alct$o Efhql . rlqrter llC0x tot 2tO It.! x ltf l- l€ l) la rt" '/1/ri, ' Air(*.a oflner Gs,s.s) 3t{6rtdk tE .5'i r-r -2 o L q E9tar<1rz.s!!) 1a569<rc*hsre- ('Q -Vcrriatr'1oq<]F-I{.,,e--v-oT i.,.) til^'le,fnPe.fc&Y.r.ce f'he €g*ce Nenakr ct steel .J1osq1r1cr$r'crr *orrrer th 6ec^|t.J</ is lt0rrrc-ters oncr -The- hrr'gh+ ol O"c ,^rinVJ d.cq. !f6oo Yr,vcln Fc,tlter is rT on c-{- ho} Surnrner cicg{ toVrarnr t<rnp = 3O'c-J AT= 3o<AL="ILIAT -- AL= Lz*to-cla-').trc-)CBor.) Au= o.O(eS r-, .L.L, r Spoce Needle is Q.S<-nn tc^lte- in l-e €clmher , taLE^. he.igVr- = 8O.bG5rn Con..fh.'", l-]1t2.l I t,)h,f happens to !e hote ? -A rr€.tal ptc,,te krrs er slrc.ulcrr holein i|. As the plcute ls he^rec, doe8 lhe hote get lcrrrtrr ocern<-rltr *" lhe siee oF Fhe hok EXPAkT DS <-g the- gc'...e. e-x pc.nds n.re..gg lffi* l-.,-:-:;l Temgwrtr.rre * Put thQ-ld of a 6k.ssjc-,.r order verl hcrh rp<^Fsr tt'er1 both bc-it the stee- 1id- <ird lhe 6ge,ninX ic. $.e- tid _e'lgand, F'qure- 2'5(c;): th6t $S over {he g<reS jc,!r-'e.npcrrrcls br.1 more Vhc^n hq Skrss .c{r. fhe lor id uliil be- oqgr, c.rd con be- moce. J AS |V.e +e.,ciP. t8.o necrrs O'i. e*Sl[ ae-n v:vecl ' o2 'rrcrker bg3fnS to e.y.p11d -o .) t'.ort 6tgYrF1 snce. th€. €J q)crher iS coe.l Sgecl'ot Properhes oS Nc^"tser crnC ee. Vl o) K.ti tt / /-64ow 1o< S,s"t+€f r^rcr.|er .ttJ*- .or-l ue<.ooL' n&st.r,tts inq - A rettrF of, te cx.,."Oe ctigtribrh'on o-n H^e Woer.44.,g/ "z o/ trrreCrR "dn Vo,+me u.thtcrh ce,lerrn tnes hot^r neclrbl molecrileS intercrol o{ ect ot{" e. 5 .olb 'o t.os -> As qrcrber c1pffoc11hs H"e keeeioX goin mc>e<.LLeS benin hr hrwr ctusYers ll'rc*t alre rnore €hronqtq I'aonded, Hao mocgr.eS rSw.rsl dlL-"rr^t s1l 6,Ioit g.itUrr-'a+erf+ 'i6 F'"ni eir-rr <-utie.rs,-vnerr4i6qv l Temg<rer.fu,e('c) voturne-tnLrerraes,. Aeeet'rui' +he t+]eter nasrrlts tn <rrr €-rren <irer.r-er i ncrer.xse- r'n veufteJ-> tc-e (sord) is l,oss de.ngc S'cr.n Y^r + .e.r (i c1u ro) o.nd $<rcd6
  • 16. fq.q- '(ac^ses diP$er ho- gdltds or trlcluids in lhc^t lhe^1 c,re. t'hjht1 Cornpestible L> pt gqs ccrrt expond or conlrcrct not- ontl ro res?on€ io ie*igetof.r.e,fo,-rFc.,lto lu Squeeanl the p.^rhqeS .1.rge.r logerher or 7'*ldng *harn f<,.rWr c{Pc'*. l(fnehc Theonl: J The e-xpqnrion o$ ?rogectres at the of ffrS os cr ,JhcE fn lerrnS rcudornllmovinl paHcle Terngerctnr.re "Te-9q-rcditJre o$ On {deo, Aa-a I'n ferrns oS Hne wroh'ovq o$ tndivtduol ?""+c["S o{ F{^. 8o.s. ' 6rqt Hnough di[€<rgrluoecules hove diFerent sgeecls, we c-crn de$tne- c.rr o.vercrqA "V'*s =J@.^u- u:he.e (v'h,r"1 is $he ovg o+ +;;$J.-#'d '.il^e o't fhc- rmlecrrietr velocih'es- (rrn$= Y66F- il,.cr.n - Sc{u.G tr-€. "g ".4) l ou* =lttntv =)rn,j.-.' -, Tl,a Ay3 <Y.,ehb- e-necSy of the i.^s porhc-e3 in texms oF l{re- rrrs seeecl k ".,,q=* <*f (au = l.SE' to*7x , is the Botemc.nrlg c.rat<,.nt b €' direr-$1 gropochoncJ }o !Le. a-bsoui€ {ernperot^re. CT) 'Te{np ercuhr,re rn<cr'Eu.res the qv€.c4tr- ki ne-c *re.01 aF tlne. pcrrht le.s in o, StlSlern XTP-rrrp K tnhmcte1 eonnedred to l{.re rcrnr<Jom rnohons o$ the pc'.rhtles in , hhe TOSil Pre.ssr,lre nef furre <rS The- Qr..e - h: - a-r€-c raho [E), i"a"penc]enF o$ 'l-he- EurQrce., ec, rsed b,1 lhe collrr'ons o$ [he g".s gc.rhcls u ith {he u-:cr,lls ol c. contc^r'ner. ; F "PreSSur€ is q. sccdcr quo$ti ['=[. 'Gos e*er*s o.. €occa -tr rre3ni]ude (p=p"A) ,| fre56ur" *urril -or*ffit ::ffi":**"^, is rss,-* vn. ecs ere-rts G Rrrcg on o. 6qcft>cc. (ve.q 6rncr-, t^suc^,lr^a pressures fn <iopc^sc.-ts), olhu-,^e 1Wc^= 0[0Pa , fe -rh" &,1 PusccJ= tPa: t it' rvrarl be luite lorrlt' b"t if Fe1 excu-l1 b."ffil"t-n$."*t# (r'tl" ol.l €orc-e ot t€- 6srftr<€ aS lour l'"d,{ d,.r.e trc l-lre press$re & il'*- cYrtncsgh€re- rs sver t{o,oco poundS,rbul i}s bc.Jqr,<.e-d b.{ * *1"d p re6srre- inSide our bodq pUhinq ouJk, J . Ne| ftrceS Are exerkd ft'lere3 cr. ?resau,re- dtf{er<no Ap, anttl Fneh on a turgelcg/a F*t= F -F, ^tten *PrA -P,A=Atp"-p) = AAp oleo, oS A J
  • 17. 7 lqs- 'DecreoBinq l-he nurnber cF rnolecules in e con[,ainer decrec^ses Vhe pres.^re Be.o.,o. lhere ore fe-we" eolisians W ilh the wolts. .nA pe.r$e.| vqcr^u-rn (p=Ofa) rs (rngoee,rbe blc ccrrrno,l- rernoe eerl rrrilecde koon c^- regiorn o9 Sg.*re.. VcrCtturrr : (n p.c*cbice) rS gn encjosecl 6Pc,ce in tlhtc, P a'Io.rFrn (usin3 P= OPo is +fun e' good ogproximafnn) Mecrsu."ir.o P.ess,.^re ' *) pres-sure o$ Fhe c*lrnosphere (*osF irngcrrt<rnf pressure ftr ou" dai h*) lhe- Vq,rr'es t.ith o.)lihrde ond $lte weother, tuF fhe gobc,, e^verc*qa presaute-ql.!6€cr ervelr 1 Slun"c-l'c) Atmcsghe,re = 1 er.hrn = IOl,EdSPcr = o,3 <P.. 'ln le U,S. to..-e is vnecrtr:red in Po.^ncS otncl o.recr, in slucxre- incjuS Pressrrre fs o$ben poonds per f nz to. gsi) I c'.tr^ = L{,1 psi 'Gc,rute ?re.ss.r.. (P3) ie Fh.,e- pressere- in e-xcess oS- 1 c*n1 PS= P- c,-trn (r.r,.rst cretd ! a.-tm=lol.3<Pc. ho lhe r€{d{nc5 oT.^- preggsye gc^uge ht fr'"€I the c.hEoti^Fe greStr-rre'(p) ne,ecled b. rnost q^crrJc^HonS) the - Pcrh'ents tuFletio5 Cto"n de-cow,.gce-ss(on sic-ness c^rnl a!rr conc,i&ronS n"c*.{ bg lrec*tec la er- hl"gerh*rc<- or,{ffn ohcunber ft.a uf oxqX,crr o.h qrecrter thetrr ofmr:a- pherte pre€Er.ne. h qrhcria:J chcr.rrrl.er l,sir 8-t* ena qtctfes o$ dtosne-b<-r O.?S'n is fi'tfed WilL ol..{ko^ {u cgtdfP pressr.e- a>f L-l fPc.. r,dhcr.t's }f,e trne.,t- on tr c,ltdefS -.1 3u! A=ntrE] Z-le?c,.=ap Ap F=lqZt-.zN A=ir to.'rs*/z)' F = A'Ap F = Z<N A = o.H1zm' F = (0,1.{e*"X21,ero p.,") fror., Collistons b Pressr.rre. or,cl Fhg lcl€*t-Gs Lc.r*s , [ncreqBtnl the Temp le<rcB toan ncrecrse in PreEure L> ?c*rtic,e {yn-ve c*}r higher epeec}6, fh"hiV tlne- wcds ry.ro*.e oFeq.ll msre- [orc9, So {-hq-re: trnore presv}re 'Decrecr.tin lL. Voume- tec.cts b on Increr^Se in Pr.sture L" Fto.e H.ealuent <,oi8on *ll te- rOC,r.S d' lt* <ocr.riqcr, clnd &htrS fnore PresAuJe 'ncnec^sinq Vhe Number 6$ Pcrch'oeS lec^cls io c*rr ncrer,.te in PreEsuce L" |.kf€- "trrrttiluenf cothsr'ont uf l l-he r.rcilfs .f FLre conle.,.i.,-*-,errrd fhuS tnore. ?..sSwe +Cotltstons in on ioecrl gos e<t#tg6o no e^,""11 ts osl in tf'e- <oision 1ire per$eoH1 thvr,, lhe porhefe rebo,.^,njS g.*" to-,*ral u:l its veod **Zd &o* V ta -V
  • 18. " The F;3 erer-el d**1 c. <oteion o$ d,,,.rahon At is rec*!aA l"r k!.L I parhuels cv'drqe in momennd* Of ttro.,S)r At'APx = m(Vr)+ - rn (vl.); hiit5 (V*);"=y e*ncl CV*)e : -V, he L*3 o.' Fhe FclrFr<le i6', (n*-.-,;axx=Yn[vx)+- h(vri = -i"r zu AI At 11lg Q:..e. oh {-he pe^r-h'cle is neXcrtive. blc- i] poinls to Fh<r tet+. Ac<onCinl E d-l.1r,.l, $+€ wall erperienceS le eg,.l but ogposirc Force ,lo Ne'^ltern's .Ii *. n*k'pilT*u$rp1 [-,'no fhe %r." op 1 <orision r]e ]ohr nunnhr N.o* o$ corslons lhe^t ocr.uf, du*rir,<a t|'e h'-e to+exvc.I At. t[ lLrere- <'re- N p*hq,,eS 'lnor io1 ol s,g"od y in cr bo> oF vitu*e V, t-Vre- t+ o$ coisions i s', t."ou = !$n.,a,t 'ncregei.,g t t+gc.rt'aes).'r tVc- siae- oF lher,oq A u.ri ncsecrse ..lcorr 'ncre-cr.Si",1 the- oQ {lne- box to Decrecrse the- Nc,orr [sprcads tLr. gcrrhees ouF) N '-f't1e Ne! 6rce : on *-.he r,,aer"ll F.,e-r= N)co[ ttrworr)*s, =HV^"'ot)tH) - -V rnutA reg<rce V b.l VrrnS ond tUtc lhere c're 3 dimensk-,n.) 7. bl 3 I 6'rU lha} llne (o..o- ercrted un tsh woft b.1 cl vc^st hurnbcr of cotrsicrns iS'. Fne-r = *+mv._J.A SlvidioJ tr^.+ b.1 A I F','net1 hc.r"ve qn elpre66tor. {or +Le prcssore- i n t{^'c- t."ti f= P = 5 Y*u.-"'= e +tlnnl,,.r) ).nnv*at = c"v3 rine-ht- e,ngrtl per perrhue- fn q<-^. r Eo ) ?= 3 Sk* *The prestLre ol-an idecr.l qcrs degencs on jutt z tht,.q'. 0lhe number o$ pc,r|''c-qs per g|rbrc rn.i"r (N/v) 6 ftQ- o.ve-r"cr*c6r kinehc errex-X1 o$ the pc.rhrceS ( <c"q) - pV=NkeT : dec^.^ g-s [-c.,.rrr Lve.roton t) Siondsrel Tgmperqlure qncl lr.ssur tanis oS pV rs e11:ivaent +,r T t P"..m) (StP) = 1 e^Frn ?ress$re- 'fl= h JnkgT= n g.T I d,er^I-gc^S Lqr^r (vereion-z) crncl o'c p,=xinrul tr,a',",r+= Gcrs crrrrsh-rrt ' (1 r''ol oT 8es e^'t- ETp r- z?'{LJ PV=nRT "p I Alotoule prees,.rre Lin vnr'h5 o$ Pc") ' R ', Gc"s Conelc,'lf ( in uni]s o& *.r.r) 'Vl Voume oFthe6crniw, or c.nk+ineroSqqs Lin u',ils "t ..t) '1:fa^fercr,l-ure [in units.g k) 'y1= Numt.- oF moles in rFhe scr.rype qe c.o6uiner o( tcrs ."$ c^ rnoq --$B| .volvYn( ts oec*:gr'd b.{ 1 rnoc, o{ o-n tlecr, gc-S q* a# FreSture of lc,hn ord c lemg o$ o'c-l q l.*to^ = 1"0L3 KPct V= tn W)/p V=0.022t{ rn3 ( to3 u) P= ^3' Tt O". = Z1g R v = (t.oo *or)tr. sr Y*d .Cf,zt a k) V. ZZ.'{ L n=1 rnol ot,3 q 52*
  • 19. Pq.l lZ.q I cler,l-frc^s ?roc=esses L)Thg ideal -qF^S c,*^f Xro.rtcles cr connealrtrn blur {re gres8.rre, Volume-, crvrd tempercr}trre s$ g qas. A"inq 1 o$ t-luse vcrricrbeS ccl.rses L or boFh o$ the othets to ehcrn$- tt|,rs " Prop*Jhes of ?ro.ess'. ' thg Quorrti d qlra iS Sxed. No Gr ls c^dcted ho o. rernovec) &orn +he- *rre" ' -Il.er. c we-defir'uc nihcA Slrl.e. The inhc,. vcdr..r.eS <>Q press,*re, lourne, arrd ervrterqrre. crr-e deSigr.c*"te,4 pi, !'ir'IT The"e c-,* u:e-a*a$fnec ffna Eh:,.,e , vcrues desgrc'ted ?+,V{,G 6r qoS.S in Secred conlqiners., ttte nuynlrer o$ moss (* oF moecr,rr.es) does llOT cJccrnl,t ln lhc,.t ca5i,ss, the idecrt-qes lcrur c<rJn be roriben.. +S =CI.R.: eonE$cqntT Xhc vcilueS oF $g vorobles in +te fnihc"l ond S'r,r*l sfcrles are l-herr r<*hecl br1', 'Blc p cnd VcTp:f'- prVC.=S;Vi ,riha" anct Fca,. stEltes C,r, crr, idecrl q<..s orr bc,t-h sicles o$tFfre {1fl- r r - €cru<r$icJc r r.rle w6q1 qgg l{ ir cr se<-ed cootcs'ner- r T p-"tF*;t'*tf ffil[l**, levnsorc,rhrrs busr be- i"r ke-Nin pI Dic^grc*rns Ec.ch slate- oS cf idec" <a<s5 ig ferpre.se-nteci -> kncr,-r'nq p qr'd V, ctnd crssumi, CrSePoinf <jf cA oV'dtC,tQfcMn gea1' 6 id k",o*ttl {tt- o.seo,te.d, ^ Lspe.cr'$es prcssside- crr.d, v&ucne-) <-onlc*i^e-c, t 1ou coJn $r'ncr T- I = lcxrt< T-= 3btX:k Ts= Goo l< A pr6c-e-ss +hc!r cVrcrrrqeS the- qq5 frorn one Skrie o Onb{+rer- is reprrraSerrH bq g $ic.ier-turq o? o pV c)'c.trc{.{/'y' t (<-x'. he-c.tr'^3 i* or d.oyyrPretsstni it) V t*r) C-onBtrrr* - Vcrutne P"ocess 6v; I (bnstcrnt* PregEr"rre Proc-eSS C,onatcrnh - Voluumq froce.sse.S tv+ * i) b {h* vc.we of V doesn'+ crr*ntrl , Shor*rn cr3 cr vertr'c-c^, ine- i-t$ 4on t{re- pV clie,Xrc.r &, lZ.6'.Ccmpuhnc+ hre presrure on c. Llo+ b.^a *Tt,re- pre.ssu're fn a ccrr hr<- is 3o.opei oy G^ c.o.d Vnorninq rr)c.n l-hc- a-ir Fcvnp is o'<. AS[€r g^g dc.{ {"{rc.rrns ug o-rd oriXh} €trn ghrheS on !he- Iotcrc,l< *"a, Hnc- lcrnp o[ c.i. tnticle- 4^e, h'ne r.r.dno-S 3O'e, t Jkrc,.tts llne h're, pressuye cF fnrs t.rt p ? Pilr =+.;-Yi- ?i= 3o'0 Psi t l'l'Jpsi f+=P;4.r+ Tr T p; =lL{,lpsi r;'rt sobK I' = 0'C = Z?3 ( Tt = 3o"c = 303 < P+ =[q't,1pti X zra rJ ft. L'l9,La pti - I.r.19oi pP = 3{.1gsi
  • 20. Contlc*rrf - ?res6ure ProceEeeS ( P+ = P; ) Pq. t L: ffso ccred c^n sobc-,rrc- proce.GS 'HggecrrS crs a lrlorraonh^,l line on c. PV diaXrom -tThe gcrs pressure ls delermfned by i+e requirement lkrt the 3c.s mu$,|- suggorh bofl^ fhe rnaES on hop oS the piston (qp6t{it cr const<.rr-dorrnun-rcl fur.e tl3 on trq?iston) crncl fhe Air pres6inl inwclrcJ ( lt e erir erlso pr€sses dr:.^n on lhe pishn) x-flnis p..s*.,.e is lnclepencler* of the ternp o€ fle gcrs or {}'e heiXvh oF the f,*ton se if s{rrl1s eorrs*c,rrl crs on1 o-s l'{ iS trnchar,cttd tt nnc.rSs fnCuinkc^.t'os e^ Constcrnt p..se'.r.re in the c1incJer Ex rz. com SA -A qcs occuglioi 5o,C)cm" cl"l 60'e- is c-ooled qlF c.onstqnt Pressure r,tnt-i le. {-e.rnp is (O'c-. Qhcril lhe Hn& vciume-? . t ?E3.K.- Ti=bdc=3z3b< V+= ,f.v; Tf Vt = Eo,o.r"t t s4I,. j 'llq= l0'c = ZE 3 <r T'y V+ = 93.Kcrr.s Const<^n - -le.rngeltr^rc- Pybceas (Ta 'T;) bAss c.*ed, c,."r. solherwc*l pr<rcess br.'. n piEton is beirg goshecl dor,'rn a comgress a tG, buF the qcrs a$ircle.r ts e,"rbr',e.rg-ed {n R lc.rctt eonrrlnsr- oG qu;rJ helcl cr-t e<rnstcrntTeir?, l$ tt',e- pieYon is g.rshec aocll$, t{.4J hecl erver*, +nons6el: thn*th +he tr:c*s -S lhe u{linaet u:i ke€f 'lre- gas c-+ 1!.r- sc.rs lernp crs tlne q.rr.o.,ndin5 iqud Lsotnsrn*. cornpreesc.rn) ' S.r}6i.rrt c.. eXg^.5eoq : -Ihe- ravqfse. grae-tS, *sl the- ?ielbn gon-r:..1 guJed outs 'Bon c^nd V q,hcrn(g in crn iso+herrnc-A proc€Gs. As lo5 es Tr"r"'or'ns Stxcl, ? ..t '5 = ft Bf = qgls!g5,t- *oH"lrrn: The qr<ph oF ar, lso$u.rrnc,l ?rbceRs ;$," il*"= o', Y^uur*" R€,c^h,o.*hip blw p a.cr V, +he Br..gh 6g en botkrrnc./ !-'u Pro@ss is a perbocr v1 v; soerrrg Eypev'rsion wouo rnove in lhe olgosile cJirech'on Hn o,on3 {-tne- hlpcrboc^- The occrHon oft the hlperboc,- de perrls on lhe vcc*€- of f O* o,rceat corltsi<rnrt {-ernp *(D=4t!hes+ cpnsbcrr*r te-nnj. - A gnort ek deeg brect-rh el the s,ur&rcq, ftti* hts un6s rpiv.r H'Ou oF cri.. He-ttl Fc^V.eg e. dercqds to e de4Hn e'f S.owr , tDhere l^q pressure ts t.5 c!hn^, A tis de,? , uJhc^Fb the volurn. oS cu'r tn lhp snorthr-s lunqs1 Vt= Vi'P; Vt-(.{,t,c)(ffi) P+ V+= 2.b1 L
  • 21. ,lorK Pq.1 'AS gc.s evgc"ncK, tf does worK on cl-n obe-ct, F3* [s drre.io tlte qqs ?resstJre 'Jl rnaSniude- ot^ -i?t Vee.p tlre o6ton ^ gc's in on done b'{ isobc'rrc' in o!:rce. a-rl exltrn€^l 'xlv- rlgos= p(vr -vi) = pnV 6rl-a tn(er Ue. E,c.- g"t ory*i€ b qc,$ Wg*=o,r€cr Wrder lhe gV qrc-ph blw Vi cr.nd V+ AS lhe pfs&on fnoveto distuoce d, the gcrs 6,.3 g'.rork E-",d - 11,e q.ts olurv.{ cfnr,Xrg bq AV'd.A 'norcle. [.r" c* $os to do wc.rr(, lhe- o[uvne lnLr,Et Clr"nxt. Thus fto hrorK is done in a cont!un-- volurr,e proceas r h've when o.; *;;"tnu'o) b.,.t t)egc$irq (-"."i.3 wori. i dore oh t1'.e qc.O 6then lhe gas (s compressec) (AV.cl) 'hJgoS=PAV on$ c*ppies to conskrnt-ptestwe Proces8ea, Er a-n.1 oFher [ct€a.,| -ga.s proceS, Yut cc"cucre the ar".^ under lhe p Xrcrph 'To Gilct,.crFe p'esEurernuStsbe tn ?o 656 yeL"r-rne in wl3. The procluci .,f ,rtcrrK) Pc^ (?*, co,d tnt is Joole ( +he- u^-,nr'ts of wort< anrcl **g..4) {g* it wor( done Bi tL'e sqSlern, whie Fhe orK W +hcrr apyears in t-[,e- lo 1c..,. ef- Aurwodqrfrrnics is (-rlorK done OAJ H-re selsferrr . B,-,-f 4f =- Ug-t , So *& lsn Lo-r-'l Qrrr be Nri+ten'. AE+t= Q- Wg* "":St)., 1 o__ ..*J & l2,t,.Fn"r,' the r^,",'k rtr-,e by o G".S --I t , -0,0lGg rol d$ ninog4n Tolcr^l |'l'le iaec.l-gcrs pra.r-ss sh<r,sn be)o,o I i 1* ^q) hkl c,re lhe inihoJ enct fi'r'rc,rt tevngerafu,"s .f n"" qSE? I , { V(c-r') li)tb* rnuch ur.r6 s done tuj Hre g,.s? f k:o,&o -la> k:o p; Vi= nRT b) nig..s= oLrecr encle-r pv S"oph (o.oo"Z .n3),*zoo,oooTa) !(o.o.rcz-).zo,oooeq 0 11 = (ttqr,oo.rp*Xo.ooor d) (o,olO0ro)(t.atY*o'r) ' NXe"s= ''lo,oT + ?o.oT Wgat= bO .O f G= [o,or oO r"or)tt.ar Y"or. r) T+=rlb K
  • 22. Ad iqb",t'" ?ro"..ss.s ?G. ro Lt Rn iclecr-tos proeess in rqhteh no hec"t ehertl isfrc.ns$e-rrccl blur {de- nc8 qnd the Envrronmerrl tl'us Q=O, 'L possible $c{s it- ccrn occ{^-rl )-U" €qstern is thermctlll tnsr-rc*tr<dz prevtrrH.a hec.b t--crr,eSe-r z)The Fro<-ess .rc.pge-ns foo quic-klt 6. c^ frc ns$er b occsr (ryroe| cotr.tt'.:o) ' Fl re.gid Corngression (Adiobcrhc csmgres6icn) dr ex?crrlqt.r, (odic^bc^h'L €x?crrsfon) oT .. tc^S doesn'f ollour fime C*/fl"-t .|. .*ui., ,/ -t" . Rqises tne l5*gerreture of g<*s Lowe*s t*terc.{,ure o8 6c.$ .l.I$es WorK, rg..er t"c'.n heatsr to Oncvtlr- l*re- sgecds oS t-he- moe.cr.,r,Ie8, c*nc, Iurs ehc'nXl Hne- Tqrnpercr*trre '.Fdrcrbcrh'c* CornPressic>Y" Q=O r sc A6+11 = - N$*= - J.tu clo .*:crr( On $he- qc's b carnprcss i],ao Hne- trsr< aone -b Fhe go"S rs negcrfive (Wgc.s-o).Thtx fl.,L F+r,, oS le gcr-S nc-re-crses Cte+6t61 crncl +he -Ieynp. goes up bh Gpc,.nsioo: go-s. t-hqts does t^ror<* on a pitFon b1 e+gc..no,'5 r+ ad,'ab..hb"lt (VrlX..s >o)'q€Jbs coder ttrf) os its Tt'urrrr. enertl decrarses [AE1'o) t? 2 Pz 6 Conceptrrc" & lz.zl Adirbcrh'c eurves cn q p V d,'otrorn +FV at*{rc.rn Ot c^ ffrS trnckrqoi,.l * i5o+krrrc,r compressdon&om pirrrt pr Z. Rotlnhtl'ho.rl '.rlo,,td ilnegv J,5r.^- look i$ the ga$ uJere com?r€ts€d la poinf dacm F"nt 1 +D +{E- Sqrre S'norl PresEu.l€ bl . ragid vL 9d,ctU"^lr'c- corngressrbn? tt Pz Jhe cwvg of the qdrkrbcrhe r.r.".o".= $q feYnp. o[ the gcla cs the uror<- ?z qorprEiaign rhoves from a-bver ,ia;[.TJii.A- +o-.'[Bh;rH4. ----- dorre- on the qos it frc*ns$rmecl in|o €u.'. Corsequerrtl$, t G5SE:rn - A^rve cr.rbs creross ihe- i66 i-harrnK fd ad on o- h,$*-F.r-F fLgher r rsaFLrrm u)ht{ Fhe qcrs Pretsqr€ re.rraru-s p. . -lhe $i..r vdurr€ k i* lf'ere$ore l*qN ldqn tfut for lle. P1 , LowerT v isofurmcrj com?reaion. vz tr Spe.i&c Heert Lsq,,.u.' rs .) Lrlhe cr.rvrcunt a$ hec$ t,,.r-.t rqi3e< lf.eTernp oS 1k3 oT sr.rbstcrnce- b1 1S tt Dqends on1on lhe m..'.te-tcl hovn sghidn at oe$ i€"^ trcrele the hecrt neectecl(o) to groclr-rce cr Ternp. c,hc^ncnL tAT) {t:r mc.ss [F) wi{r .r. age.rhc hec-r.F tc) Q = H'c 'AT ( = t tte6o ff"E q") Q = - (t*-p qss Dor^rn) Bl" t1i %+C I ll tr^.t.eS hec.f entrttl to e-l.rc^rr1p +U,e- Te-rng. oF c^ sr.:oskrn<< rrr[ c. s^"caL Yyy3y€, Specit-nt- l,u-ah 'tf^errc {c AT oF o. aulbetqr.rrc- ro[ c'. snnc^, spec-ih<- h<sit
  • 23. 7 Fe,.U. 6. lZ.?t6,'erttl f^. .,'n '. Fen". -A 1ox3 stucf<rrt ccrfc,hes *1.'e $l,e,crnd is hoal +€.r.? increcrteS $tom 31.Ooc(9t,G'F) fo 31.o'c-(1q12op' l{o.*l rruc1 e11eql is reluirecl }o vc^ise hrs boclults f"rng, f Spec-iSL het^r oS the bod" 3'oo|g*'L Q = H.c'ar Q = '1-1b0OO 5 Q = (ro <3)tsrcoT*u. r.zr<) a = tl,trlosT Phcr8e Chc^nq<S T:lonsk n{- c."S 'tVre 6qS}<-rn TC'c) a.s iirom tcrjz. trqu,ct O 'lhe T"mp, Rxecl qb o"c{ot an exterrled pgid of }tmt r€.ryrcLins '[htS iS fhe hrne intervcr.( durinX Ohrch llne- ice met16. Skrm is As ils rne5, |he ce Ttr,(P'=Ooc- Gnd the iclurd r.rxr.er Temp"o"c- trrerrninS ' Euen though+he qsrcrn iS ber hec*erl, tl'€Ter"?.doesni- br1,o tt rise qfi+il ALL the tce hos rnelFstr, Time 'Erte.g1 b- o.IdeA tb tV€- sn<tern it being troecl b brec^K fs bonds H,l the- u>qr-!er- maes.r'es, Aiot the- Sorro oF +he-r*rc^.l<r worrhi Fro* sot ie -> Lilurct 0T*rn^0. o..h tohrch cr Pr' iF llne q €aid = ?sn+ or hn {-he @ (b"th phc,.te cVK,rqA) fruibriurnl ftn1 omount o[ sottd con Coex,S- *l anul ernounl- oF Lrqurd .PhcrSe 0b0c"u.s t.lh.rn a sqshem iS ob fhe melhnt or fr"eA€ point '@ >lighHl , l-he €rrhre slgFem Soon becornes q Liquncl , Eiqhtq, L[ enhre sqshern becomeS a sottd @ Bt,^l l-he Ltquic tde GqS ?hc,se qnl curncxints o9 Lq,.rid cc^r| @ckic* d( "."d cr.* Fhts Te.rnp.1 c*nc( Gntl o.nnounF cF (naS 'As hec.$r ts aolded to lhe sqshern) +deRmg. skols fhe sctr''e. Added **11 raused f brerot< brrts blu, the Uqu{d rvroecgt6, c-tb,,.rrh3 H^qrn [0 rnove iob Hre C6ri qtoSg. -= @1*1. e^| r,;,htg,h o Gc's becorneS e Liquio Cond<nso.hon Poinl oy A l.-ruid be.connes cr Gc.g (iF E+n is ncrerfeJ)' Boitrlng Point -S houe q Narrn soda th$ g.r^wrsh"+ocoo, woold i.t- be fnoreef*ec-frV{- ta' qclc, 5J oF i$io,ooher 'qo"t al 0'C or 253 o urc$er rc€ qt O'C? ' Fbe Zt ol-qrr+er ice. ctf o"c- luai, ha^t 6* t^ri|l be hanskrrecl {rom +he scdc lo *.,e ica +<: .e)! i trans{orminS lhe0'c- tce +o Ooc t,'q",b} t.:o.,ter.^ Hec$ uoit lherr be hentkdred b the iq'ord acr,ber.to rc^it€ i k^p" Thrs ,no* f*-, ulitl be rernrree.l korn the soccr, $ui$ l q tryer finol Ternp, 'lf .1ot 6qJ{ ,iquid dh Ot l"cr,,[ uli orrll b0 trcssfrrred G,"rm $'E g,ocl€( [r t+1€- u:a,[cr1 ra,stt l+refe'vri oF t{rg ulqfer od b**"3 lhc.t d tl.e godfi, t.eSS E+q, (ernovd &rctn Pt-l. Uelqt hglrr G Gncepbuc.J R lz.qr Es+ o- st.r.^> Boi.? - tootre oooKinl pcrsfcr. gn FLr- SWelts ur€.ler iscrFcr tgour boi, UJi lne,pc'trr,, cod( rrrore elufc,k * luu tr^rn up lhe b*Xe. on tlne gtuve so tcrf lhe ,,,s.r<r [s of a. &.s,t b-i ? uhher boi[t ah D'o; no rncrrter how vlprax i] borig,lls-Ternp is k'torffi_ HLI|gprO*e $r^,#K that aeerrntneS Vuo 8S+ te crrokrq3 occ.q5i ACAir{ h{rte &stcr ror,hgdi"tl'dt?,w urltt nor a,'l--orvl **[ ^irg*u