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PHOTORESIST COATING ON
    SILICON WAFERS
            BY
          KARTIKEY GROVER
          LALIT AGGARWAL
WHAT IS MEMS
• It’s a technology of very small device.
• MEMS are made up of components between 1
  to 100 micrometres in size and generally range
  in size from 20 micrometres to a millimetre.
• The fabrication of MEMS evolved from the
  process technology in semiconductor device
  fabrication.
Patterning
• Patterning in MEMS is the transfer of a pattern
  into a material.
• In patterning we use lithography.
• Lithography is the transfer of a pattern into a
  photosensitive material by selective exposure
  to a radiation source such as light.
• In order to do it we need photoresist coating.
CATEOGORIES OF PHOTORESIST

• A positive resist is a type of photoresist in which the
  portion of the photoresist that is exposed to light
  becomes soluble to the photoresist developer. The
  portion of the photoresist that is unexposed remains
  insoluble to the photoresist developer.
• A negative resist is a type of photoresist in which the
  portion of the photoresist that is exposed to light
  becomes insoluble to the photoresist developer. The
  unexposed portion of the photoresist is dissolved by
  the photoresist developer.
GENERAL CHEMICAL COMPOSITION
         OF PHOTORESIST
• Different chemicals may be used for
  permanently giving the material the desired
  property variations:
• Poly(methyl methacrylate) (PMMA),
• Poly(methyl glutarimide) (PMGI)
• Phenol formaldehyde resin (DNQ/Novolac),
• SU-8.
THREE MAJOR PHOTORESIST COATING
          TECHNIQUES
• SPIN COATING
• SPRAY COATING
• ELECTRODEPOSITION OF PHOTORESIST
SPIN COATING
• It is the standard coating
  method for flat wafers in IC
  technology
• In short, an excess amount of a
  solution is placed on the
  substrate, which is then rotated
  at high speed in order to spread
  the fluid by centrifugal force.
Spin coating : Stages
SPIN COATING
• Solution viscosity and the spinning speed are
  the only parameters which influence the layer
  forming process
• The thickness approximately decreases with
  the (increasing) square-root of the spin speed
  (in rpm)
ADVANTAGES OF SPIN COATING
• Spin coating is a mature technique and uses
  commercially available equipment and resists.
• used at all stages of processing on all types of
  substrate layers.
• The high resist film thickness homogeneity as
  well as the short coating times makes spin-
  coating the most-applied coating technique at
  least in microelectronics.
• The process optimization focuses only on these
  two parameters.
DISADVANTAGES OF SPIN COATING
• The deeply etched features cause a physical
  obstruction to the solution flow, preventing
  complete coverage.
• Depends on the position of cavity.
• Sizes and shapes of the cavities also have
  influence on the resist uniformity
• The reproducibility of spin coating is very less.
1. The lowest uniformity
variation can be observed at
H/V = 2/3, 1, 3/2, which
indicates a better resist
uniformity in the square or
large rectangle cavities.
SPRAY COATING
SPRAY COATING
• It uses an Ultrasonic atomization technology that has unique
  advantage that is based on two features: its ability to generate
  very small droplets of an extremely narrow range diameter
  size, and its ability to apply these droplets gently on the
  substrate with minimum “bounce back” from the target
  surface.
• To get the proper droplet size distribution of photoresist, a
  resist solution with lower viscosity is necessary
• By optimizing the coating
process a good uniform
resist layer has been
deposited on wafer with
375μm-deep cavities.

• The uniformity of resist
layer obtained by this spray
coating technique is better
than with the spin coating
ADVANTAGES OF SPRAY COATING
• This technique uses much less resist than spin
  coating. The spray process requires no spin off
  photoresist so that it can effect up to 70% less resist
  consumption to spin process.
• The resist thickness is repeatable over all cavities
  with the same size, regardless the position of cavities
  on the wafer
• Spray coating has no thickness variation caused by
  directional effect of spinning
(a) Spin Coating (b) Spray Coating (c) spray coating with angle control
DISADVANTAGES OF SPRAY COATING
• variations in resist thickness are observed if cavities with a
  large difference in size are present on the same wafer. The
  resist thickness at the bottom of a small cavity is thicker that
  the one in a large cavity. If the difference in dimension of
  cavities is large, it will lead to a large variation in resist
  thickness between cavities.
• Photoresist spray coating has more variables than spin
  coating.
ELECTRODEPOSITION OF
                PHOTORESIST
• The process used in electroplating is called Electrodeposition.
• The process uses electrical current to reduce cations of a
  desired material from a solution and coat a conductive object
  with a thin layer of the material
• Wafer to be deposited is the cathode of the circuit.
• the anode is made of the metal to be plated on the part.
ADVANTAGES OF
          ELCECTRODEPOSITION
• The main advantage of this ED coating is the
  conformal resist layer independently of the
  geometry of the nonplanar features
• For that reason, ED coating is the most suited
  technique to pattern structures that run in and
  across cavities or when a smaller line width is
  required
DISADVANTAGE OF ED
• This technique always requires a conductive
  (metal) surface.
• The set up and process handling are more
  complicated than the other two coating
  techniques.
• The coating bath should be checked and
  maintained frequently in order to get a
  reproducible process.
COMPARISON
CONCLUSION
• Spin coating is a simple method but it does
  not give a good and reproducible result on
  deep cavities of different sizes and randomly
  distributed across the wafer
• Spray coating and ED deposition certainly
  bring better results but they need special
  equipment
• ED deposition is perfectly suited for patterning
  metal layer
THE END
THANK YOU

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Photoresist coating

  • 1. PHOTORESIST COATING ON SILICON WAFERS BY KARTIKEY GROVER LALIT AGGARWAL
  • 2. WHAT IS MEMS • It’s a technology of very small device. • MEMS are made up of components between 1 to 100 micrometres in size and generally range in size from 20 micrometres to a millimetre. • The fabrication of MEMS evolved from the process technology in semiconductor device fabrication.
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  • 4. Patterning • Patterning in MEMS is the transfer of a pattern into a material. • In patterning we use lithography. • Lithography is the transfer of a pattern into a photosensitive material by selective exposure to a radiation source such as light. • In order to do it we need photoresist coating.
  • 5. CATEOGORIES OF PHOTORESIST • A positive resist is a type of photoresist in which the portion of the photoresist that is exposed to light becomes soluble to the photoresist developer. The portion of the photoresist that is unexposed remains insoluble to the photoresist developer. • A negative resist is a type of photoresist in which the portion of the photoresist that is exposed to light becomes insoluble to the photoresist developer. The unexposed portion of the photoresist is dissolved by the photoresist developer.
  • 6. GENERAL CHEMICAL COMPOSITION OF PHOTORESIST • Different chemicals may be used for permanently giving the material the desired property variations: • Poly(methyl methacrylate) (PMMA), • Poly(methyl glutarimide) (PMGI) • Phenol formaldehyde resin (DNQ/Novolac), • SU-8.
  • 7. THREE MAJOR PHOTORESIST COATING TECHNIQUES • SPIN COATING • SPRAY COATING • ELECTRODEPOSITION OF PHOTORESIST
  • 8. SPIN COATING • It is the standard coating method for flat wafers in IC technology • In short, an excess amount of a solution is placed on the substrate, which is then rotated at high speed in order to spread the fluid by centrifugal force.
  • 9. Spin coating : Stages
  • 10. SPIN COATING • Solution viscosity and the spinning speed are the only parameters which influence the layer forming process • The thickness approximately decreases with the (increasing) square-root of the spin speed (in rpm)
  • 11. ADVANTAGES OF SPIN COATING • Spin coating is a mature technique and uses commercially available equipment and resists. • used at all stages of processing on all types of substrate layers. • The high resist film thickness homogeneity as well as the short coating times makes spin- coating the most-applied coating technique at least in microelectronics. • The process optimization focuses only on these two parameters.
  • 12. DISADVANTAGES OF SPIN COATING • The deeply etched features cause a physical obstruction to the solution flow, preventing complete coverage. • Depends on the position of cavity. • Sizes and shapes of the cavities also have influence on the resist uniformity • The reproducibility of spin coating is very less.
  • 13. 1. The lowest uniformity variation can be observed at H/V = 2/3, 1, 3/2, which indicates a better resist uniformity in the square or large rectangle cavities.
  • 15. SPRAY COATING • It uses an Ultrasonic atomization technology that has unique advantage that is based on two features: its ability to generate very small droplets of an extremely narrow range diameter size, and its ability to apply these droplets gently on the substrate with minimum “bounce back” from the target surface. • To get the proper droplet size distribution of photoresist, a resist solution with lower viscosity is necessary
  • 16. • By optimizing the coating process a good uniform resist layer has been deposited on wafer with 375μm-deep cavities. • The uniformity of resist layer obtained by this spray coating technique is better than with the spin coating
  • 17. ADVANTAGES OF SPRAY COATING • This technique uses much less resist than spin coating. The spray process requires no spin off photoresist so that it can effect up to 70% less resist consumption to spin process. • The resist thickness is repeatable over all cavities with the same size, regardless the position of cavities on the wafer • Spray coating has no thickness variation caused by directional effect of spinning
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  • 19. (a) Spin Coating (b) Spray Coating (c) spray coating with angle control
  • 20. DISADVANTAGES OF SPRAY COATING • variations in resist thickness are observed if cavities with a large difference in size are present on the same wafer. The resist thickness at the bottom of a small cavity is thicker that the one in a large cavity. If the difference in dimension of cavities is large, it will lead to a large variation in resist thickness between cavities. • Photoresist spray coating has more variables than spin coating.
  • 21. ELECTRODEPOSITION OF PHOTORESIST • The process used in electroplating is called Electrodeposition. • The process uses electrical current to reduce cations of a desired material from a solution and coat a conductive object with a thin layer of the material • Wafer to be deposited is the cathode of the circuit. • the anode is made of the metal to be plated on the part.
  • 22. ADVANTAGES OF ELCECTRODEPOSITION • The main advantage of this ED coating is the conformal resist layer independently of the geometry of the nonplanar features
  • 23. • For that reason, ED coating is the most suited technique to pattern structures that run in and across cavities or when a smaller line width is required
  • 24. DISADVANTAGE OF ED • This technique always requires a conductive (metal) surface. • The set up and process handling are more complicated than the other two coating techniques. • The coating bath should be checked and maintained frequently in order to get a reproducible process.
  • 26. CONCLUSION • Spin coating is a simple method but it does not give a good and reproducible result on deep cavities of different sizes and randomly distributed across the wafer • Spray coating and ED deposition certainly bring better results but they need special equipment • ED deposition is perfectly suited for patterning metal layer