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IOSR Journal of Applied Geology and Geophysics (IOSR-JAGG)
e-ISSN: 2321–0990, p-ISSN: 2321–0982.Volume 3, Issue 4 Ver. I (Jul - Aug. 2015), PP 52-59
www.iosrjournals.org
DOI: 10.9790/0990-03415259 www.iosrjournals.org 52 | Page
A new method of assessment and equations on Carbon footprint
Sameer Sawant*1,2
and Basavraj Babaleshwar1,2
1
CEFA group, Talegaon Dabhade, Pune, India
2
Sir Parshurambhau College, Pune, India
Abstract: Carbon footprint or green terminology has become famous over a few decades in many countries
including India. Several industrial development schemes and policies are developed and are developing which
broadly focuses on green terminology [1, 2]. Although the terms such as carbon footprint, ecological footprint
and green terminology are much popular, there exists no standard ideology or a theory accepted so far which
would be used worldwide and thereby ends this long lasting debate. This article focuses on a new theory
developed in order to minimize the problems, uncertainties and errors related to the previous studies and to
attain precise completeness to the assessment with the help of equations which would also lead further research
and development in the field.
Keywords: Carbon footprint, ecological footprint, green terminology, emission factor, carbon intensity, work
done.
I. Introduction
Carbon dioxide (CO2) is one of the prominent Greenhouse-gases (GHGs) responsible for global
warming. Along with CO2 there are other GHGs like CH4, N2O, HFCs, PFCs and SF6 [4, 6] which are enlisted
in the Kyoto protocol [6] which add to greenhouse effects and global warming. GHGs are emitted through
various natural processes and human activities. Natural processes include volcanic eruptions, forest fires,
earthquakes, etc. Human activities include excessive usage of fuel, improper methods of waste disposal, rapid
growth in industrialization and urbanization, improper sewage practices, etc. Emission of GHGs in the
atmosphere leads to increase in the rate of global warming. The consequences of global warming are harsh.
Floods, climate changes, draughts, untimely rains, forest fires etc. all are the consequences of global warming
which affect human life directly or indirectly and also may lead to death. Though emission of GHGs through
natural processes cannot be controlled, the emission through human activities can be evaluated and corrective
measures can be implemented in order to control the rate of GHG emissions. Although it's presumed that global
warming can't be stopped, but the rate at which it occurs can be controlled. There is necessity of proper method
based upon precise and exclusive definitions and equations for understanding and evaluating carbon footprint
more precisely and scientifically which would help further practical research and development.
This article focuses on precise methodology for evaluation of carbon footprint and conveys new
definitions, thus resulting new equations for corrective data analysis. It also includes a case study of Sir
Parshurambhau College, Pune, India (the campus area is 25 acres) for verification and clarity of the proposed
methodology.
II. Brief Review
The concept of carbon footprint derives from the concept of ecological footprint raised by Wackernagel
and Rees in 1996 [17]. As one part of Ecological Footprint, the land area needed to sequester CO2 emitted from
burning fossil fuel is measured to estimate the land requirement for energy use [17]. There exist several
definitions on carbon footprint in wider literature. Yet no academic definition has been provided which would
be widely accepted.
A definition with practical solution is said to be proposed by Wiedmann and Minx: "The carbon
footprint is a measure of the exclusive total amount of carbon dioxide emissions that is directly or indirectly
caused by an activity or is accumulated over the life stages of a product." According to this definition,
exclusively only CO2 emissions must be included in order to account carbon footprint; presuming the fact that it
is difficult to quantify other substances with green house warming potential. In contradiction, DEFRA has
successfully evaluated emission factors of other substances (CH4 and N2O) for various inventories and
furthermore expressed emission factors in carbon dioxide equivalents (CO2e). The definition also refrains from
expressing carbon footprint as area based indicator [3,8] in order to avoid conversions to an area unit (ha, m2
,
km2
, etc). Along with methodological issues, it also involves carbon footprint comparison (between various
functional units) issue and errors since it is expressed in mere mass units (kg, t, etc). While righteously, the
authors hold to inclusion of indirect emissions in the evaluation of carbon footprint. It has been demonstrated by
some case studies that indirect emissions constitute the majority of carbon footprint of a functional unit [16].
A new method of assessment and equations on Carbon footprint
DOI: 10.9790/0990-03415259 www.iosrjournals.org 53 | Page
An organizational definition of carbon footprint is provided by Tao Gao, Qing Liu and Jianping Wang:
"An organizational carbon footprint measures the GHG emissions from all activities across the organization
including energy used in buildings, industrial processes and company vehicles." In this definition, other
substances or GHGs including CO2 are included for rightful carbon footprint assessment. A terminal
consumption analysis method based on the IO analysis is used as a method for evaluating organizational carbon
footprint [14]. But, similar to the definition provided by Wiedmann and Minx this definition too lacks the
element for comparison between different scale functional units.
For calculation of carbon footprint of a mega structure such as city or a municipality the following
definition is proposed by Larsen and Hertwich: "Carbon footprint is the life-cycle GHG emissions caused by the
production of goods and services consumed by a geographically-defined population or activity, independent of
whether the GHG emissions occur inside or outside the geographical borders of the population or activity of
interest." [15] According to this definition carbon footprint refers to GHG emissions based on the consumption
of a defined population, therefore calculation of the carbon footprint of a city or municipality should not be
limited to its geopolitical boundaries [16]. It provides an element for comparison between cities by promoting
evaluation of carbon footprint as GHG emissions per-capita. But population in a geopolitical area or a city is
variable or can be said to be constantly increasing and therefore this may introduce uncertainties and fatal errors
in setting GHG mitigation goals and comparing its own yearly carbon footprints.
All the above definitions involve methodological issues, evaluation and comparison errors or
incompleteness. For precise evaluation and exhaustive study of carbon footprint patterns, spatial and temporal
boundaries are necessary to be set and must be included in an ideal definition of carbon footprint. Such a
definition has been proposed by Glen Peters: "The 'carbon footprint' of a functional unit is the climate impact
under a specified metric that considers all relevant emission sources, sinks, and storage in both consumption and
production within the specified spatial and temporal system boundary." Following the definition of a carbon
footprint is the notion of 'embodied carbon', 'carbon flows', 'embedded carbon', 'virtual carbon', and similar
terms. Historically, the emissions that occur along the supply chain of a functional unit have been said to be
'emissions embodied' in the functional unit. The emissions are not a physical part of the functional unit, but are
associated with the functional unit via the production network [13]. Although the definition seems to be of a
wider and open perspective, it involves other necessary and prominent terms such as sinks and storage which
couldn't be ignored. Inclusion of spatial and temporal boundaries adds preciseness to the evaluation of carbon
footprint and to the further study. The method to determine carbon footprint is not included in the definition
which adds methodological issue.
III. New Theory
We propose the following definition, eliminating methodological confusions and minimizing errors and
uncertainties.
A carbon footprint of a functional unit is a measure of 'work done' (expressed in kWyear) by the GHG
emissions (expressed as CO2e) considering all relevant sources, sinks and storage in both consumption
and production within specified spatial and temporal system boundary.
This definition we proposed is similar to that proposed by Peters. As said above, the definition of
Peters is precise and ideal, except there is no method of determination of carbon footprint provided. We
included evaluation of work done by the GHG emissions in the definition, making it more precise. Work done is
expressed in joules and it provides more scientific information about GHG emissions. The evaluation of work
done is necessary and the equations required for this are discussed further including an example of a case study.
The very first stage of carbon footprint assessment is data collection. The four stages of data collection we used
are
a) Dividing the institute into discrete departments
b) Finding and listing the sources of emissions from every department
c) Preparing exhaustive questionnaire for every department separately
d) Data gathering and data extrapolation wherever inadequate data are available
Once the data are available, we need to evaluate the mass of carbon dioxide equivalents (tCO2e) as activity data
(AD) times the standard emission factor (EF) (emission factors as shown in table 1)
AD x EF = tCO2e
A new method of assessment and equations on Carbon footprint
DOI: 10.9790/0990-03415259 www.iosrjournals.org 54 | Page
It's presumed that evaluation of mass of CO2e will introduce some uncertainties because of data extrapolation.
Also, the use of standard emission factors may introduce some error on the data because it's known that the
emission rates may vary according to the region and locality. As far as possible authentic data must be gathered
avoiding extrapolation [19] and if possible, the correct emission factors for the region or locality must be found
to avoid errors.
Table 1: Emission factors for conversion (The emission factors are standard and taken from - Carbon gas
conversion factor respiratory- DEFRA [7])
Sr. No. Inventories Emission Factors Units
1 Human 1.1 kgCO2e/24hr
2 Petrol 2.1914 kgCO2e/l
3 Diesel 2.6024 kgCO2e/l
4 Water supply 0.0014 kgCO2e/l
5 Paper 0.928 kgCO2e/kg
6 Solid waste 0.021 kgCO2e/kg
7 LPG 0.214 kgCO2e/kWh
8 Electricity 0.856 kgCO2e/kWh
9 Plastic 2.154 kgCO2e/kg
10 Food and drinks 3.59 kgCO2e/kg
We evaluate kgCO2e from all inventories responsible for GHG emissions using the above standard
conversion factors [7, 11] as shown in Table 2 below. Although some extrapolation has been accounted
(wherever utmost necessary), most of the data are authentic and provided by the valid authorities of the
respective departments. For example, non-hostel (other) students are presumed to spend six hours in the campus.
Diesel vehicles are presumed to travel 4.7 km/l [12], whereas petrol vehicles are presumed to travel 18.8 km/l.
Table 2: Found emission sources for Sir Parshurambhau College and their evaluation in kgCO2e
Sr. No. Inventories Activity data Kg CO2e
1 Student Hostel 400 students 118800
Other 5040 students 374220
2 Travel 11505 km 4451.62
3 Tours 38292 km 8585.18
4 Water Kitchen 720000 liters 4735.76
Laboratory and other 2662682.5 liters
5 Paper 9631.54 kg 8938.07
6 Solid waste 17386.48 kg 365.12
7 LPG Kitchen 62341.5 kWh 15996.5
Other 12408.5 kWh
8 Electricity 144504 kWh 123695.4
9 Kitchen waste 11000 kg 39490
Total 699277.6
A new method of assessment and equations on Carbon footprint
DOI: 10.9790/0990-03415259 www.iosrjournals.org 55 | Page
Figure 1: Percent contribution from each source
It's found that students contribute almost 70% of the GHG emissions. This is obvious for a college and
also student source (or human source) do not need any mitigation presuming the fact that schools and colleges
are building blocks of nation building and hence this emission source must not be taken into consideration for
assessment (see Fig. 2). Either way, it's not possible to mitigate GHG emissions through human body.
Figure 2: Percent contribution from each source excluding human factor.
Further, the emissions must be separated into mandatory emissions (M) and waste emissions (W).
Separation of emissions is necessary because often unnecessary on site emission sources like garbage waste
which includes plastic, papers, etc. which are not responsible are also included in the emissions responsible for
the product or services of the functional unit. This adds errors and uncertainties in the evaluation of carbon
footprint. It makes the mitigation difficult and the functional unit never knows where to put effort on. But
bifurcation and further explained process of evaluation makes the unit aware about where it needs to set
mitigation goal and act? Therefore, the separation is very important.
A new method of assessment and equations on Carbon footprint
DOI: 10.9790/0990-03415259 www.iosrjournals.org 56 | Page
5.1 Waste emissions
Emissions of GHGs which are not related to any special purpose (production or services) of a
functional unit are known as waste emissions. For simplicity, they can be called as unnecessary emissions.
Solid waste, kitchen waste, water and LPG used for kitchen are the sources responsible for waste emissions;
precisely, they are not necessary for the special purpose of the college. It's found that waste emissions mostly
are ready to grave or in the last stage of the lifecycle. This is the reason for all the responsible emissions related
to kitchen are expressed separately in Table 2. Waste emissions sum to have 54204.197 kgCO2e emissions
which constitute to be approximately 12.9% of the total GHG emissions.
For waste emissions, emission density must be evaluated. Emission density is defined as areal density (dW), i.e.
the exclusive total waste emissions (W) expressed in mass of CO2e per area (A) of the premise.
Knowing the emission density, a functional unit can try to decrease its unnecessary emissions every
year. Relation to area gives advantage to compare the emission density to that of other functional units. The
waste emission density for Sir Parshurambhau College is evaluated to be approximately 0.5kgCO2e/m2
. Kitchen
waste and solid waste are chosen as waste emission sources because neither of the two is necessary for the
special purpose of the college.
5.2 Mandatory emissions
Emissions of GHGs adding to the carbon footprint which are compulsory or required for the special
purpose (production or services) of a functional unit are known as mandatory emissions.
For example; carbon emission by machines while manufacturing products, use of exam papers by a
university, official papers, usage of water for the special purpose, etc. Carbon emission by human body is
neither mandatory nor waste; it's a source we can't keep control on. Usage of water is unavoidable cause of
certain and obvious reasons. Even most of the industrial machines require high amount of water and hence it is
treated as mandatory for applicable sources. Mandatory emissions for the college are evaluated to be
152053.4285 kgCO2e emissions (see Table 3) which constitute to be approximately 22% of the GHG emissions.
Electricity accounts to be major contributor for mandatory GHG emissions and has 81% contribution.
Since electricity and LPG come under scope 2 [10, 4] emissions, we don't have enough control over them.
Proper usage of such sources would help minor decrease in the emissions. Small decrement too has equal
importance when it comes to GHG mitigation. The sources we can have enough control on are transportation,
water and paper.
Work done must be evaluated for GHG emissions from mandatory inventories (because mandatory
emissions are the only GHG emissions responsible for a product or a service). Work done is necessary to be
evaluated because during the evaluation process it gives the graphical relation between emission intensity VS
emission power of the production or service which is important for understanding carbon footprint to the depth.
We must therefore evaluate emission intensity and areal contribution for each of the individual inventories
further to obtain emission power.
Emission intensity is a measure of total CO2e from mandatory inventories (mandatory emissions) per 'n'
number of products (or some measure of input or output applicable [9, 18]).
A new method of assessment and equations on Carbon footprint
DOI: 10.9790/0990-03415259 www.iosrjournals.org 57 | Page
Figure 3: Percent contribution from each source for mandatory emissions
'M' is mass of GHG emissions from mandatory inventories and 'n' is total number of products or some other
output quantity (in this case, students are considered to be products).
The total emission intensity is calculated to be 27.9 W/m2
approximately. For a college or a university,
students can be treated as products. Therefore, we have chosen 'n' to be number of students in the college. If a
functional unit produces multiple products, the intensities of individual products must be evaluated and then
summated to find the total intensity. Taking the intensity as a whole for multiple products adds errors to the
calculation. This is because two groups of different products in a same functional unit may have different
emission rates.
Areal contribution (AC) is ratio of mass of CO2e from the inventory over total mass of mandatory emissions
times area of the premise. 'A' stands for the total area of the premise.
The total area of the premise is 101201.6 m2
.
Emission intensity and areal contribution for each of the inventories must be evaluated individually (see Table
3).
Furthermore, emission power must be evaluated (as shown in Table 3) to get the graphical relation between
emission intensity and emission power.
Table 3: Evaluation of total work done
Emission Mandatory Areal Emission Emission Work done
inventories emissions contribution intensity power
kgCO2e m2
W/m2
J/year kWyear
Transport 13036.774 8676.831 2.396 20793.72 20.79
Water 3727.755 2481.066 0.685 1700.14 1.7
Paper 8938.06 5948.867 1.643 9774.142 9.774
LPG 2655.419 1767.35 0.488 862.696 0.862
Electricity 123695.42 82327.446 22.738 1871972.066 1871.972
Total 152053.428 101201.568 27.951 1905102.784 1905.102
Emission power is defined as emission intensity times corresponding area for each inventory in mandatory
emissions. It's derived from the inverse square law which states, 'intensity is inversely proportional to area and
directly proportional to the power'.
A new method of assessment and equations on Carbon footprint
DOI: 10.9790/0990-03415259 www.iosrjournals.org 58 | Page
The emission power from mandatory emissions is found to be 1905102.784 J/year for the college. It is
recommended to use year as unit of time because carbon footprint is usually carried out over a period of year.
One can evaluate that for several years and represent average emission power or average work done per year.
The graphical relation between emission intensity and emission power is given in Fig. 4 below. The
regression error is found to be 1 which means there is no error for the plots to match the power series curve. The
equation of the curve obtained, y = 3620.677x2
is parabolic. The general equation for the curve can be written as
y = ax2
, this is valid for any assessment data. The coefficient 'a' could be found by dividing AC by IE.
From the emission power, work done can be evaluated.
Work done is defined as emission power of the mandatory emissions times the total time period (t) chosen for
an assessment of carbon footprint.
Figure 4: Emission Power VS emission intensity graphical relation
W = PE x t
Work done must be treated as the carbon footprint of any functional unit because it gives more
scientific information in joules (converted into kWyear) and involves spatial and temporal system boundaries in
itself; thus quantifying the carbon footprint. Also it gives graphical relation between emission intensity and
emission power along with the equation of the parabolic curve using the coefficient 'a'. The work done is
calculated to be 1905.10 kWyear for the college. This methodology provides various entities for comparison of
carbon footprint between different functional units. Although a wider consent is necessary to set a large
mitigation goal, institutes, organizations and industries may practice the presented methodology to extract
necessary information regarding their carbon footprint.
A new method of assessment and equations on Carbon footprint
DOI: 10.9790/0990-03415259 www.iosrjournals.org 59 | Page
IV. Conclusions
The presented research work provides a broad perspective on further bifurcation of inventories into
mandatory emissions and waste emissions. This promotes a more rational idea about how and where a
functional unit needs to put effort on in order to reduce its GHG emissions. The equations so derived provide a
more rational perspective and give information like emission density, emission intensity, emission power and
work done which can be derived from the collected database of the carbon footprint of a functional unit. Work
done must be treated as the real carbon footprint. Because each term involved in the evaluation of work done
provides important and necessary information for mitigating GHGs and understanding the carbon footprint
patterns. Any functional unit can use the presented equations to evaluate carbon footprint and find the
parameters to focus on. This makes assessing and offsetting or eliminating GHG emissions easier and also
overcomes most of the uncertainties and errors. The work done by the GHG emissions is found to be 1905.10
kWyear and the equation of power VS intensity curve is found to be y = 3620x2
for S P College. The
methodology, if followed by interrelated functional units, automatically generates a supply chain [5]. There
exists no need for considering supply chain tables and having a look at the process, because the methodology
itself eliminates double counting of the emissions. This process for evaluation of carbon footprint can be
practiced at all scales of functional units. For example, city, industry, organization, institute, local residence etc.
A wider perspective is initiated by the methodology along with its preciseness and completeness. Thus, it can be
practiced widely to know accurate carbon footprint and set a rightful and scientific mitigation goal. This would
help reduce GHG emissions in a rational way.
Acknowledgements
We especially thank Dr. Dilip N Sheth, principal of S P College, Pune for their cooperation and
permitting us to evaluate the carbon footprint of the college. Also, we thank Dr. Sunil Kulkarni for their
valuable coordination.
References
1. Government of India. Ministry of Commerce Industry Department of Industrial Policy Promotion (Manufacturing Policy Section).
PRESS NOTE NO. 2 (2011 SERIES)
2. MSME schemes, Government of India. National Institute for Micro, Small and Medium Enterprises (nimsme) (An organisation of
the Ministry of MSME, Govt. of India) Yousufguda, Hyderabad 500 045
3. Thomas Wiedmann and Jan Minx. A definition of Carbon Footprint. Ecological Economic Research Trends. Nova science
publishers .inc. 2007.
4. Dr. Thomas Wiedmann and John Barrett. A Greenhouse Gas Footprint Analysis of UK Central Government, 1990-2008
http://randd.defra.gov.uk/Default.aspx? Menu=Menu&Module=More&Location=None&Completed=0&ProjectID=17486
5. Carbon footprint estimation for a sustainable improvement of supply chains: state of the art, Pilar Cordero. Universitat Politecnica
de Valencia (Spain) http://www.jiem. org/index.php/jiem/article/view/570/491
6. United Nations Framework Convention on Climate Change (UNFCCC)- Kyoto protocol.
http://unfccc.int/kyoto_protocol/items/3145.php
7. Carbon gas conversion factor respiratory- DEFRA
8. Thomas Wiedmann and Jan Minx- A definition of carbon footprint. ISAUK Research Consulting, Durham, DH7 7FB, UK
(www.isa-research.co.uk); Stockholm Environment Institute, University of York, Heslington, York, YO10 5DD, UK
9. Denny Ellerman and Ian Sue Wing. Absolute vs. Intensity-Based Emission Caps. Joint Program on the Science and Policy of Global
Change MIT E40-428. E-mail: glob-alchange@mit.edu
10. Hillary Benn, Ed Milliband. Guidance on how to measure and report your green house gas emissions. Department for Environment,
Food and Rural A airs Nobel House.
11. Peter Thatcher, Lancaster. How much does breathing contribute to climate change? Science World
12. Shaleen Agarwal. Final Report Market Survey for Fuel Consumption norms for Diesel Trucks Buses in India. Petroleum
conservation research association(PCRA)
13. Glen P Peters. Carbon footprints and embodied carbon at multiple scales. Center for International Climate and Environmental
Research Oslo (CICERO), PB 1129 Blindern, Oslo, Norway
14. Tao Gao*, Qing Liu and Jianping Wang. A comparative study of carbon footprint and assessment standards. International journal of
low carbon technologies. http: //ijlct.oxfordjournals.org/content/early/2013/06/24/ijlct.ctt041.full
15. Hogne N. Larsen and Edgar G. Hertwich. Implementing Carbon-Footprint-Based Calculation Tools in Municipal Greenhouse Gas
Inventories, The Case of Norway. Journal of industrial ecology
16. Weiling Wu. Carbon Footprint a Case Study on the Municipality of Haninge. KTH, Uppsala University, and Swedish University of
Agricultural Sciences.
17. Wackernagel and Rees. Our ecological footprint, 1996.
18. Rui Zhao, Pauline Deutz, Gareth Neighbour and Michael McGuire. Carbon emissions intensity ratio: an indicator for an improved
carbon labeling scheme. IOP science.
19. Aida Sefic Williams. Life Cycle Analysis: A Step by Step Approach. ISTC Reports. Illinois Sustainable Technology Center.

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A new method of assessment and equations on Carbon footprint

  • 1. IOSR Journal of Applied Geology and Geophysics (IOSR-JAGG) e-ISSN: 2321–0990, p-ISSN: 2321–0982.Volume 3, Issue 4 Ver. I (Jul - Aug. 2015), PP 52-59 www.iosrjournals.org DOI: 10.9790/0990-03415259 www.iosrjournals.org 52 | Page A new method of assessment and equations on Carbon footprint Sameer Sawant*1,2 and Basavraj Babaleshwar1,2 1 CEFA group, Talegaon Dabhade, Pune, India 2 Sir Parshurambhau College, Pune, India Abstract: Carbon footprint or green terminology has become famous over a few decades in many countries including India. Several industrial development schemes and policies are developed and are developing which broadly focuses on green terminology [1, 2]. Although the terms such as carbon footprint, ecological footprint and green terminology are much popular, there exists no standard ideology or a theory accepted so far which would be used worldwide and thereby ends this long lasting debate. This article focuses on a new theory developed in order to minimize the problems, uncertainties and errors related to the previous studies and to attain precise completeness to the assessment with the help of equations which would also lead further research and development in the field. Keywords: Carbon footprint, ecological footprint, green terminology, emission factor, carbon intensity, work done. I. Introduction Carbon dioxide (CO2) is one of the prominent Greenhouse-gases (GHGs) responsible for global warming. Along with CO2 there are other GHGs like CH4, N2O, HFCs, PFCs and SF6 [4, 6] which are enlisted in the Kyoto protocol [6] which add to greenhouse effects and global warming. GHGs are emitted through various natural processes and human activities. Natural processes include volcanic eruptions, forest fires, earthquakes, etc. Human activities include excessive usage of fuel, improper methods of waste disposal, rapid growth in industrialization and urbanization, improper sewage practices, etc. Emission of GHGs in the atmosphere leads to increase in the rate of global warming. The consequences of global warming are harsh. Floods, climate changes, draughts, untimely rains, forest fires etc. all are the consequences of global warming which affect human life directly or indirectly and also may lead to death. Though emission of GHGs through natural processes cannot be controlled, the emission through human activities can be evaluated and corrective measures can be implemented in order to control the rate of GHG emissions. Although it's presumed that global warming can't be stopped, but the rate at which it occurs can be controlled. There is necessity of proper method based upon precise and exclusive definitions and equations for understanding and evaluating carbon footprint more precisely and scientifically which would help further practical research and development. This article focuses on precise methodology for evaluation of carbon footprint and conveys new definitions, thus resulting new equations for corrective data analysis. It also includes a case study of Sir Parshurambhau College, Pune, India (the campus area is 25 acres) for verification and clarity of the proposed methodology. II. Brief Review The concept of carbon footprint derives from the concept of ecological footprint raised by Wackernagel and Rees in 1996 [17]. As one part of Ecological Footprint, the land area needed to sequester CO2 emitted from burning fossil fuel is measured to estimate the land requirement for energy use [17]. There exist several definitions on carbon footprint in wider literature. Yet no academic definition has been provided which would be widely accepted. A definition with practical solution is said to be proposed by Wiedmann and Minx: "The carbon footprint is a measure of the exclusive total amount of carbon dioxide emissions that is directly or indirectly caused by an activity or is accumulated over the life stages of a product." According to this definition, exclusively only CO2 emissions must be included in order to account carbon footprint; presuming the fact that it is difficult to quantify other substances with green house warming potential. In contradiction, DEFRA has successfully evaluated emission factors of other substances (CH4 and N2O) for various inventories and furthermore expressed emission factors in carbon dioxide equivalents (CO2e). The definition also refrains from expressing carbon footprint as area based indicator [3,8] in order to avoid conversions to an area unit (ha, m2 , km2 , etc). Along with methodological issues, it also involves carbon footprint comparison (between various functional units) issue and errors since it is expressed in mere mass units (kg, t, etc). While righteously, the authors hold to inclusion of indirect emissions in the evaluation of carbon footprint. It has been demonstrated by some case studies that indirect emissions constitute the majority of carbon footprint of a functional unit [16].
  • 2. A new method of assessment and equations on Carbon footprint DOI: 10.9790/0990-03415259 www.iosrjournals.org 53 | Page An organizational definition of carbon footprint is provided by Tao Gao, Qing Liu and Jianping Wang: "An organizational carbon footprint measures the GHG emissions from all activities across the organization including energy used in buildings, industrial processes and company vehicles." In this definition, other substances or GHGs including CO2 are included for rightful carbon footprint assessment. A terminal consumption analysis method based on the IO analysis is used as a method for evaluating organizational carbon footprint [14]. But, similar to the definition provided by Wiedmann and Minx this definition too lacks the element for comparison between different scale functional units. For calculation of carbon footprint of a mega structure such as city or a municipality the following definition is proposed by Larsen and Hertwich: "Carbon footprint is the life-cycle GHG emissions caused by the production of goods and services consumed by a geographically-defined population or activity, independent of whether the GHG emissions occur inside or outside the geographical borders of the population or activity of interest." [15] According to this definition carbon footprint refers to GHG emissions based on the consumption of a defined population, therefore calculation of the carbon footprint of a city or municipality should not be limited to its geopolitical boundaries [16]. It provides an element for comparison between cities by promoting evaluation of carbon footprint as GHG emissions per-capita. But population in a geopolitical area or a city is variable or can be said to be constantly increasing and therefore this may introduce uncertainties and fatal errors in setting GHG mitigation goals and comparing its own yearly carbon footprints. All the above definitions involve methodological issues, evaluation and comparison errors or incompleteness. For precise evaluation and exhaustive study of carbon footprint patterns, spatial and temporal boundaries are necessary to be set and must be included in an ideal definition of carbon footprint. Such a definition has been proposed by Glen Peters: "The 'carbon footprint' of a functional unit is the climate impact under a specified metric that considers all relevant emission sources, sinks, and storage in both consumption and production within the specified spatial and temporal system boundary." Following the definition of a carbon footprint is the notion of 'embodied carbon', 'carbon flows', 'embedded carbon', 'virtual carbon', and similar terms. Historically, the emissions that occur along the supply chain of a functional unit have been said to be 'emissions embodied' in the functional unit. The emissions are not a physical part of the functional unit, but are associated with the functional unit via the production network [13]. Although the definition seems to be of a wider and open perspective, it involves other necessary and prominent terms such as sinks and storage which couldn't be ignored. Inclusion of spatial and temporal boundaries adds preciseness to the evaluation of carbon footprint and to the further study. The method to determine carbon footprint is not included in the definition which adds methodological issue. III. New Theory We propose the following definition, eliminating methodological confusions and minimizing errors and uncertainties. A carbon footprint of a functional unit is a measure of 'work done' (expressed in kWyear) by the GHG emissions (expressed as CO2e) considering all relevant sources, sinks and storage in both consumption and production within specified spatial and temporal system boundary. This definition we proposed is similar to that proposed by Peters. As said above, the definition of Peters is precise and ideal, except there is no method of determination of carbon footprint provided. We included evaluation of work done by the GHG emissions in the definition, making it more precise. Work done is expressed in joules and it provides more scientific information about GHG emissions. The evaluation of work done is necessary and the equations required for this are discussed further including an example of a case study. The very first stage of carbon footprint assessment is data collection. The four stages of data collection we used are a) Dividing the institute into discrete departments b) Finding and listing the sources of emissions from every department c) Preparing exhaustive questionnaire for every department separately d) Data gathering and data extrapolation wherever inadequate data are available Once the data are available, we need to evaluate the mass of carbon dioxide equivalents (tCO2e) as activity data (AD) times the standard emission factor (EF) (emission factors as shown in table 1) AD x EF = tCO2e
  • 3. A new method of assessment and equations on Carbon footprint DOI: 10.9790/0990-03415259 www.iosrjournals.org 54 | Page It's presumed that evaluation of mass of CO2e will introduce some uncertainties because of data extrapolation. Also, the use of standard emission factors may introduce some error on the data because it's known that the emission rates may vary according to the region and locality. As far as possible authentic data must be gathered avoiding extrapolation [19] and if possible, the correct emission factors for the region or locality must be found to avoid errors. Table 1: Emission factors for conversion (The emission factors are standard and taken from - Carbon gas conversion factor respiratory- DEFRA [7]) Sr. No. Inventories Emission Factors Units 1 Human 1.1 kgCO2e/24hr 2 Petrol 2.1914 kgCO2e/l 3 Diesel 2.6024 kgCO2e/l 4 Water supply 0.0014 kgCO2e/l 5 Paper 0.928 kgCO2e/kg 6 Solid waste 0.021 kgCO2e/kg 7 LPG 0.214 kgCO2e/kWh 8 Electricity 0.856 kgCO2e/kWh 9 Plastic 2.154 kgCO2e/kg 10 Food and drinks 3.59 kgCO2e/kg We evaluate kgCO2e from all inventories responsible for GHG emissions using the above standard conversion factors [7, 11] as shown in Table 2 below. Although some extrapolation has been accounted (wherever utmost necessary), most of the data are authentic and provided by the valid authorities of the respective departments. For example, non-hostel (other) students are presumed to spend six hours in the campus. Diesel vehicles are presumed to travel 4.7 km/l [12], whereas petrol vehicles are presumed to travel 18.8 km/l. Table 2: Found emission sources for Sir Parshurambhau College and their evaluation in kgCO2e Sr. No. Inventories Activity data Kg CO2e 1 Student Hostel 400 students 118800 Other 5040 students 374220 2 Travel 11505 km 4451.62 3 Tours 38292 km 8585.18 4 Water Kitchen 720000 liters 4735.76 Laboratory and other 2662682.5 liters 5 Paper 9631.54 kg 8938.07 6 Solid waste 17386.48 kg 365.12 7 LPG Kitchen 62341.5 kWh 15996.5 Other 12408.5 kWh 8 Electricity 144504 kWh 123695.4 9 Kitchen waste 11000 kg 39490 Total 699277.6
  • 4. A new method of assessment and equations on Carbon footprint DOI: 10.9790/0990-03415259 www.iosrjournals.org 55 | Page Figure 1: Percent contribution from each source It's found that students contribute almost 70% of the GHG emissions. This is obvious for a college and also student source (or human source) do not need any mitigation presuming the fact that schools and colleges are building blocks of nation building and hence this emission source must not be taken into consideration for assessment (see Fig. 2). Either way, it's not possible to mitigate GHG emissions through human body. Figure 2: Percent contribution from each source excluding human factor. Further, the emissions must be separated into mandatory emissions (M) and waste emissions (W). Separation of emissions is necessary because often unnecessary on site emission sources like garbage waste which includes plastic, papers, etc. which are not responsible are also included in the emissions responsible for the product or services of the functional unit. This adds errors and uncertainties in the evaluation of carbon footprint. It makes the mitigation difficult and the functional unit never knows where to put effort on. But bifurcation and further explained process of evaluation makes the unit aware about where it needs to set mitigation goal and act? Therefore, the separation is very important.
  • 5. A new method of assessment and equations on Carbon footprint DOI: 10.9790/0990-03415259 www.iosrjournals.org 56 | Page 5.1 Waste emissions Emissions of GHGs which are not related to any special purpose (production or services) of a functional unit are known as waste emissions. For simplicity, they can be called as unnecessary emissions. Solid waste, kitchen waste, water and LPG used for kitchen are the sources responsible for waste emissions; precisely, they are not necessary for the special purpose of the college. It's found that waste emissions mostly are ready to grave or in the last stage of the lifecycle. This is the reason for all the responsible emissions related to kitchen are expressed separately in Table 2. Waste emissions sum to have 54204.197 kgCO2e emissions which constitute to be approximately 12.9% of the total GHG emissions. For waste emissions, emission density must be evaluated. Emission density is defined as areal density (dW), i.e. the exclusive total waste emissions (W) expressed in mass of CO2e per area (A) of the premise. Knowing the emission density, a functional unit can try to decrease its unnecessary emissions every year. Relation to area gives advantage to compare the emission density to that of other functional units. The waste emission density for Sir Parshurambhau College is evaluated to be approximately 0.5kgCO2e/m2 . Kitchen waste and solid waste are chosen as waste emission sources because neither of the two is necessary for the special purpose of the college. 5.2 Mandatory emissions Emissions of GHGs adding to the carbon footprint which are compulsory or required for the special purpose (production or services) of a functional unit are known as mandatory emissions. For example; carbon emission by machines while manufacturing products, use of exam papers by a university, official papers, usage of water for the special purpose, etc. Carbon emission by human body is neither mandatory nor waste; it's a source we can't keep control on. Usage of water is unavoidable cause of certain and obvious reasons. Even most of the industrial machines require high amount of water and hence it is treated as mandatory for applicable sources. Mandatory emissions for the college are evaluated to be 152053.4285 kgCO2e emissions (see Table 3) which constitute to be approximately 22% of the GHG emissions. Electricity accounts to be major contributor for mandatory GHG emissions and has 81% contribution. Since electricity and LPG come under scope 2 [10, 4] emissions, we don't have enough control over them. Proper usage of such sources would help minor decrease in the emissions. Small decrement too has equal importance when it comes to GHG mitigation. The sources we can have enough control on are transportation, water and paper. Work done must be evaluated for GHG emissions from mandatory inventories (because mandatory emissions are the only GHG emissions responsible for a product or a service). Work done is necessary to be evaluated because during the evaluation process it gives the graphical relation between emission intensity VS emission power of the production or service which is important for understanding carbon footprint to the depth. We must therefore evaluate emission intensity and areal contribution for each of the individual inventories further to obtain emission power. Emission intensity is a measure of total CO2e from mandatory inventories (mandatory emissions) per 'n' number of products (or some measure of input or output applicable [9, 18]).
  • 6. A new method of assessment and equations on Carbon footprint DOI: 10.9790/0990-03415259 www.iosrjournals.org 57 | Page Figure 3: Percent contribution from each source for mandatory emissions 'M' is mass of GHG emissions from mandatory inventories and 'n' is total number of products or some other output quantity (in this case, students are considered to be products). The total emission intensity is calculated to be 27.9 W/m2 approximately. For a college or a university, students can be treated as products. Therefore, we have chosen 'n' to be number of students in the college. If a functional unit produces multiple products, the intensities of individual products must be evaluated and then summated to find the total intensity. Taking the intensity as a whole for multiple products adds errors to the calculation. This is because two groups of different products in a same functional unit may have different emission rates. Areal contribution (AC) is ratio of mass of CO2e from the inventory over total mass of mandatory emissions times area of the premise. 'A' stands for the total area of the premise. The total area of the premise is 101201.6 m2 . Emission intensity and areal contribution for each of the inventories must be evaluated individually (see Table 3). Furthermore, emission power must be evaluated (as shown in Table 3) to get the graphical relation between emission intensity and emission power. Table 3: Evaluation of total work done Emission Mandatory Areal Emission Emission Work done inventories emissions contribution intensity power kgCO2e m2 W/m2 J/year kWyear Transport 13036.774 8676.831 2.396 20793.72 20.79 Water 3727.755 2481.066 0.685 1700.14 1.7 Paper 8938.06 5948.867 1.643 9774.142 9.774 LPG 2655.419 1767.35 0.488 862.696 0.862 Electricity 123695.42 82327.446 22.738 1871972.066 1871.972 Total 152053.428 101201.568 27.951 1905102.784 1905.102 Emission power is defined as emission intensity times corresponding area for each inventory in mandatory emissions. It's derived from the inverse square law which states, 'intensity is inversely proportional to area and directly proportional to the power'.
  • 7. A new method of assessment and equations on Carbon footprint DOI: 10.9790/0990-03415259 www.iosrjournals.org 58 | Page The emission power from mandatory emissions is found to be 1905102.784 J/year for the college. It is recommended to use year as unit of time because carbon footprint is usually carried out over a period of year. One can evaluate that for several years and represent average emission power or average work done per year. The graphical relation between emission intensity and emission power is given in Fig. 4 below. The regression error is found to be 1 which means there is no error for the plots to match the power series curve. The equation of the curve obtained, y = 3620.677x2 is parabolic. The general equation for the curve can be written as y = ax2 , this is valid for any assessment data. The coefficient 'a' could be found by dividing AC by IE. From the emission power, work done can be evaluated. Work done is defined as emission power of the mandatory emissions times the total time period (t) chosen for an assessment of carbon footprint. Figure 4: Emission Power VS emission intensity graphical relation W = PE x t Work done must be treated as the carbon footprint of any functional unit because it gives more scientific information in joules (converted into kWyear) and involves spatial and temporal system boundaries in itself; thus quantifying the carbon footprint. Also it gives graphical relation between emission intensity and emission power along with the equation of the parabolic curve using the coefficient 'a'. The work done is calculated to be 1905.10 kWyear for the college. This methodology provides various entities for comparison of carbon footprint between different functional units. Although a wider consent is necessary to set a large mitigation goal, institutes, organizations and industries may practice the presented methodology to extract necessary information regarding their carbon footprint.
  • 8. A new method of assessment and equations on Carbon footprint DOI: 10.9790/0990-03415259 www.iosrjournals.org 59 | Page IV. Conclusions The presented research work provides a broad perspective on further bifurcation of inventories into mandatory emissions and waste emissions. This promotes a more rational idea about how and where a functional unit needs to put effort on in order to reduce its GHG emissions. The equations so derived provide a more rational perspective and give information like emission density, emission intensity, emission power and work done which can be derived from the collected database of the carbon footprint of a functional unit. Work done must be treated as the real carbon footprint. Because each term involved in the evaluation of work done provides important and necessary information for mitigating GHGs and understanding the carbon footprint patterns. Any functional unit can use the presented equations to evaluate carbon footprint and find the parameters to focus on. This makes assessing and offsetting or eliminating GHG emissions easier and also overcomes most of the uncertainties and errors. The work done by the GHG emissions is found to be 1905.10 kWyear and the equation of power VS intensity curve is found to be y = 3620x2 for S P College. The methodology, if followed by interrelated functional units, automatically generates a supply chain [5]. There exists no need for considering supply chain tables and having a look at the process, because the methodology itself eliminates double counting of the emissions. This process for evaluation of carbon footprint can be practiced at all scales of functional units. For example, city, industry, organization, institute, local residence etc. A wider perspective is initiated by the methodology along with its preciseness and completeness. Thus, it can be practiced widely to know accurate carbon footprint and set a rightful and scientific mitigation goal. This would help reduce GHG emissions in a rational way. Acknowledgements We especially thank Dr. Dilip N Sheth, principal of S P College, Pune for their cooperation and permitting us to evaluate the carbon footprint of the college. Also, we thank Dr. Sunil Kulkarni for their valuable coordination. References 1. Government of India. Ministry of Commerce Industry Department of Industrial Policy Promotion (Manufacturing Policy Section). PRESS NOTE NO. 2 (2011 SERIES) 2. MSME schemes, Government of India. National Institute for Micro, Small and Medium Enterprises (nimsme) (An organisation of the Ministry of MSME, Govt. of India) Yousufguda, Hyderabad 500 045 3. Thomas Wiedmann and Jan Minx. A definition of Carbon Footprint. Ecological Economic Research Trends. Nova science publishers .inc. 2007. 4. Dr. Thomas Wiedmann and John Barrett. A Greenhouse Gas Footprint Analysis of UK Central Government, 1990-2008 http://randd.defra.gov.uk/Default.aspx? Menu=Menu&Module=More&Location=None&Completed=0&ProjectID=17486 5. Carbon footprint estimation for a sustainable improvement of supply chains: state of the art, Pilar Cordero. Universitat Politecnica de Valencia (Spain) http://www.jiem. org/index.php/jiem/article/view/570/491 6. United Nations Framework Convention on Climate Change (UNFCCC)- Kyoto protocol. http://unfccc.int/kyoto_protocol/items/3145.php 7. Carbon gas conversion factor respiratory- DEFRA 8. Thomas Wiedmann and Jan Minx- A definition of carbon footprint. ISAUK Research Consulting, Durham, DH7 7FB, UK (www.isa-research.co.uk); Stockholm Environment Institute, University of York, Heslington, York, YO10 5DD, UK 9. Denny Ellerman and Ian Sue Wing. Absolute vs. Intensity-Based Emission Caps. Joint Program on the Science and Policy of Global Change MIT E40-428. E-mail: glob-alchange@mit.edu 10. Hillary Benn, Ed Milliband. Guidance on how to measure and report your green house gas emissions. Department for Environment, Food and Rural A airs Nobel House. 11. Peter Thatcher, Lancaster. How much does breathing contribute to climate change? Science World 12. Shaleen Agarwal. Final Report Market Survey for Fuel Consumption norms for Diesel Trucks Buses in India. Petroleum conservation research association(PCRA) 13. Glen P Peters. Carbon footprints and embodied carbon at multiple scales. Center for International Climate and Environmental Research Oslo (CICERO), PB 1129 Blindern, Oslo, Norway 14. Tao Gao*, Qing Liu and Jianping Wang. A comparative study of carbon footprint and assessment standards. International journal of low carbon technologies. http: //ijlct.oxfordjournals.org/content/early/2013/06/24/ijlct.ctt041.full 15. Hogne N. Larsen and Edgar G. Hertwich. Implementing Carbon-Footprint-Based Calculation Tools in Municipal Greenhouse Gas Inventories, The Case of Norway. Journal of industrial ecology 16. Weiling Wu. Carbon Footprint a Case Study on the Municipality of Haninge. KTH, Uppsala University, and Swedish University of Agricultural Sciences. 17. Wackernagel and Rees. Our ecological footprint, 1996. 18. Rui Zhao, Pauline Deutz, Gareth Neighbour and Michael McGuire. Carbon emissions intensity ratio: an indicator for an improved carbon labeling scheme. IOP science. 19. Aida Sefic Williams. Life Cycle Analysis: A Step by Step Approach. ISTC Reports. Illinois Sustainable Technology Center.