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THE STRUCTURE OF
    THE ATOM
    Chapter 2
In this chapter, you will learn to:

                     Analyse matter
             Synthesise the atomic structure
         Understanding isotopes and their uses
    Understanding the electronic structure of an atom
  Appreciate the orderliness and uniqueness of the atomic
                          structure.
2.1 ANALYSING MATTER
          Describe the particulate nature of matter
              Define atoms, molecules and ions
              State the kinetic theory of matter
Relate the change in the state of matter to the change in heat.
 Relate the change in heat to the change in kinetic energy of
                             particles.
Explain the inter-conversion of the states of matter in terms of
                     kinetic theory of matter.
A) Particulate Nature of Matter
Matter refers to any substance which has mass and occupies
 space.
Continue…
According to the particulate theory of matter, matter is made
 up of tiny and discrete particles.
Continue…
Matter is composed of particles which consist of atoms,
 molecules or ions.
Matter can exist in three different phases. These phase
 include solid, liquid and gas.
B) Atoms, Molecules and Ions
Atoms
An atom is the smallest neutral particle in an element and it
 can exist by itself or take part in a chemical reaction.
Example:
   Copper, Cu, atom is a neutral particle.
   The smallest particle in oxygen gas is the oxygen, O, atom.
   Copper can exist by itself as copper atoms making up copper
    metal or combine with oxygen atoms to form copper(II) oxide,
    CuO, through a chemical reaction.                             Oxygen
                                          Oxygen           Copper
                                          atom          atom        atom




    Copper atoms             Oxygen gas          copper(II) oxide
Molecules
Molecules are neutral particles, made up of two or more
 atoms of the same element or different elements.
Example:
   Oxygen gas comprises oxygen molecules, O2. each molecules is
    made up of 2 oxygen atoms.
   Copper(II) oxide, CuO, consist of two different atoms, Cu and O.

               Oxygen
                                          Copper      Oxygen
                atom
                                           atom        atom




       Oxygen gas                  Copper(II) oxide
Others Molecules




H2      H2O    NH3      CH4
Ions
Ions are particles which are positively or negatively charged.
They are produced when atoms or a group of atoms receive or
 donate electrons.
Positively-charged ions are called cation, while negatively-
 charged particles are called anions.




                     The ionic compound NaCl
Continue…
cation – ion with a positive charge
          If a neutral atom loses one or more electrons
          it becomes a cation.




           Na            11 protons                             11 protons
                                                          Na+
                         11 electrons                           10 electrons

anion – ion with a negative charge
          If a neutral atom gains one or more electrons
          it becomes an anion.



            Cl           17 protons                             17 protons
                                                          Cl-
                         17 electrons                           18 electrons
C) The Kinetic Theory of Matter
The kinetic theory of matter state that matter consists of tiny
 and discrete particles that are constantly moving.
This theory has three basic assumptions:
   Matter is composed of small particles. These molecules move in
    random motion and collide with one another.
   There are attractive forces between the molecules when they are
    close together.
   Movements of the particles is affected by heat.
D) Change in the state of matter

    STATE                      SOLID                         LIQUID                     GAS
                                                     Not compact. Loosely
                                                     arranged with larger     Particles not arranged
                 Compact and orderly with small
Arrangement                                          spaces between           in order. Very far apart
                 empty spaces between
of particles                                         particles which are in   with large empty
                 particles.
                                                     contact with one         spaces.
                                                     another.
                                                     Vibrate, rotate and
                                                                              Vibrate, rotate and
                 Vibrate and rotate at their fixed   move from one point
Movement of                                                                   move very freely and at
                 positions. Cannot be                to another more freely
particles                                                                     random. Compressed
                 compressed.                         than solid particles.
                                                                              very easily.
                                                     Cannot be compressed.
Forces of
                                                     Fairly strong but
attraction
                 Very strong                         weaker than solid        Very weak
among
                                                     particles.
particles
                                                     Higher energy content    Highest energy content
                 Low energy content as
Energy content                                       as particles can move    as movement is at
                 movement is restricted.
                                                     easily.                  random
Continue…
 When a substances is
  heated or cooled its physical
  state alters with a
  corresponding change in
  energy:
   During melting,
    evaporation/boiling and
    sublimation, heat is
    absorbed by substances. In
    all these physical process,
    temperature rises.
   During freezing,
    condensation and
    sublimation, heat energy is
    released and temperature
    drops.
Heating graphs of substance
          Temperature/ oC




Boiling
point




Melting
point
Temperature/ oC




Boiling
point


Freezing
point
E) Diffusion
• Is the movement of particles at random from a highly
  concentrated area to less concentrated area.

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The structure of the atom

  • 1. THE STRUCTURE OF THE ATOM Chapter 2
  • 2. In this chapter, you will learn to: Analyse matter Synthesise the atomic structure Understanding isotopes and their uses Understanding the electronic structure of an atom Appreciate the orderliness and uniqueness of the atomic structure.
  • 3. 2.1 ANALYSING MATTER Describe the particulate nature of matter Define atoms, molecules and ions State the kinetic theory of matter Relate the change in the state of matter to the change in heat. Relate the change in heat to the change in kinetic energy of particles. Explain the inter-conversion of the states of matter in terms of kinetic theory of matter.
  • 4. A) Particulate Nature of Matter Matter refers to any substance which has mass and occupies space.
  • 5. Continue… According to the particulate theory of matter, matter is made up of tiny and discrete particles.
  • 6. Continue… Matter is composed of particles which consist of atoms, molecules or ions. Matter can exist in three different phases. These phase include solid, liquid and gas.
  • 8. Atoms An atom is the smallest neutral particle in an element and it can exist by itself or take part in a chemical reaction. Example:  Copper, Cu, atom is a neutral particle.  The smallest particle in oxygen gas is the oxygen, O, atom.  Copper can exist by itself as copper atoms making up copper metal or combine with oxygen atoms to form copper(II) oxide, CuO, through a chemical reaction. Oxygen Oxygen Copper atom atom atom Copper atoms Oxygen gas copper(II) oxide
  • 9. Molecules Molecules are neutral particles, made up of two or more atoms of the same element or different elements. Example:  Oxygen gas comprises oxygen molecules, O2. each molecules is made up of 2 oxygen atoms.  Copper(II) oxide, CuO, consist of two different atoms, Cu and O. Oxygen Copper Oxygen atom atom atom Oxygen gas Copper(II) oxide
  • 10. Others Molecules H2 H2O NH3 CH4
  • 11. Ions Ions are particles which are positively or negatively charged. They are produced when atoms or a group of atoms receive or donate electrons. Positively-charged ions are called cation, while negatively- charged particles are called anions. The ionic compound NaCl
  • 12. Continue… cation – ion with a positive charge If a neutral atom loses one or more electrons it becomes a cation. Na 11 protons 11 protons Na+ 11 electrons 10 electrons anion – ion with a negative charge If a neutral atom gains one or more electrons it becomes an anion. Cl 17 protons 17 protons Cl- 17 electrons 18 electrons
  • 13. C) The Kinetic Theory of Matter The kinetic theory of matter state that matter consists of tiny and discrete particles that are constantly moving. This theory has three basic assumptions:  Matter is composed of small particles. These molecules move in random motion and collide with one another.  There are attractive forces between the molecules when they are close together.  Movements of the particles is affected by heat.
  • 14. D) Change in the state of matter STATE SOLID LIQUID GAS Not compact. Loosely arranged with larger Particles not arranged Compact and orderly with small Arrangement spaces between in order. Very far apart empty spaces between of particles particles which are in with large empty particles. contact with one spaces. another. Vibrate, rotate and Vibrate, rotate and Vibrate and rotate at their fixed move from one point Movement of move very freely and at positions. Cannot be to another more freely particles random. Compressed compressed. than solid particles. very easily. Cannot be compressed. Forces of Fairly strong but attraction Very strong weaker than solid Very weak among particles. particles Higher energy content Highest energy content Low energy content as Energy content as particles can move as movement is at movement is restricted. easily. random
  • 15. Continue…  When a substances is heated or cooled its physical state alters with a corresponding change in energy:  During melting, evaporation/boiling and sublimation, heat is absorbed by substances. In all these physical process, temperature rises.  During freezing, condensation and sublimation, heat energy is released and temperature drops.
  • 16. Heating graphs of substance Temperature/ oC Boiling point Melting point
  • 18. E) Diffusion • Is the movement of particles at random from a highly concentrated area to less concentrated area.