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Dielectric Dilemma
Robert S. Eisenberg
Department of Applied Mathematics
Illinois Institute of Technology;
Department of Physiology and Biophysics
Rush University Medical Center
Chicago IL
Bob.Eisenberg@gmail.com
February 4, 2019
File name: Dielectric Dilemma February 3-2 header 2019.docx
Keywords
conservation of current, Maxwell equations,
electrodynamics, Kirchoff’s law
Abstract
A dielectric dilemma faces scientists because Maxwell's equations are poor
approximations as usually written, with a single dielectric constant. Maxwell's
equations are then not accurate enough to be useful in many applications. The
dilemma can be partially resolved by a rederivation of conservation of current, where
current is defined now to include the ‘polarization of the vacuum’ 𝜀0 𝜕𝐄 𝜕𝑡⁄ .
Conserveration of current becomes Kirchoff's current law with this definition, in the
one dimensional circuits of our electronic technology. With this definition, Kirchoff's
laws are valid whenever Maxwell's equations are valid, explaining why those laws
reliably describe circuits that switch in nanoseconds.
1
Dielectrics pose a dilemma for scientists. Dielectrics are not well described by the
classical equations of electrodynamics, as they are usually written.
The equations of Maxwell [1-5] seem perfectly general in a vacuum, but, in the
presence of dielectrics or matter, Maxwell’s equations are not general at all. They
describe polarization1
of matter with a severe approximation. They describe polarization
by single dielectric constant, a single real number ≥ 1. This description is nearly
universal in textbooks, and in the minds of students, but a single dielectric constant is
too approximate to be useful in a technological world where computer circuits switch
faster than 10−9
sec and in a biological world where electrical signals are controlled by
atomic movements < 10−10
m within proteins.
The significant variation of dielectric parameters with time/frequency and
conditions has been known a long time [6, 7]. Dielectric parameters have been studied
extensively since then [6-36] because polarization is a major determinant of the forces
between molecules [37, 38]. The experimental results are remarkably diverse. In solids,
dielectric properties depend on time/frequency in every material. In ionic solutions,
dielectric properties depend–‘without rhyme or reason’–on the type and concentrations
of ions [11, 12]. Ionic solutions are of particular importance because all of life occurs
in such solutions, as well as a great deal of chemistry. Amidst this diversity, there seems
only one uniformity: dielectric properties cannot be described by a single real dielectric
constant.
In much higher frequency ranges, of light, for example, dielectric properties
determine the refractive index, optical properties, and thus spectra of materials [37],
because the polarization of electron orbitals determines how atoms absorb and radiate
electromagnetic energy. Spectra are so varied that they are used as fingerprints to
identify molecules [37, 39-43]. Spectral properties are as diverse as molecules and
obviously cannot be described by a single constant refractive index.
Many interactions of light and materials cannot be described at all by dielectric
constants. Dielectric constants are useful only when field strengths are small enough so
polarization is a linear phenomenon, independent of field strength. Some of the most
interesting applications of electrodynamics involve nonlinear, field dependent
1
We use ‘polarization’ to mean any charge that depends on the local electric field, for example the charge in an
highly polarizable anion like bromide Br−
or the nonuniform charge distribution of H2O in the liquid state, with
its complex time dependent (and perhaps nonlinear) polarization response to the local electric field. The charge
or charge densities of alkali metal ions like Na+
and K+
are independent of the local electric field and so are not
examples of polarization, but rather can be called permanent or fixed charge.
2
polarization [44-50].
The dielectric dilemma is clear: nonlinearities, spectra, and diverse dielectric behavior
cannot be described by a single dielectric constant, but Maxwell’s equations use a single
dielectric constant, as they are usually written.
When a dielectric is complex, polarization and dielectric behavior need to be
described by a functional, and the very form of the Maxwell equations changes. The
detailed properties of polarization need to be known and described under the range of
conditions in which polarization has significant effects. Polarization is rarely known
that well experimentally. Theoretical models or simulations of that scope are also scarce.
Maxwell’s equations with a single dielectric constant remain of great importance,
however unrealistic the approximation, because that is how they have been taught
([1-5, 51, 52]; [50] is the exception) ever since the equations were formulated [53-56].
Students often remain unaware of the complex properties of the polarization of
matter until they become scientists trying to use electrodynamics in applications. As
scientists, they face a dielectric dilemma. Too little is often known of polarization to
make the Maxwell equations useful in applications demanding precise understanding.
Conservation of current. We show here, however, that one property of
electrodynamics is independent of polarization, namely conservation of current. That
property is in fact enough to ensure that current flow in the one dimensional systems of
our electronic technology can be described accurately by the simple, nearly algebraic
equations of Kirchoff’s current law, without dealing explicitly with field equations and
their complexities, including singularities. The accuracy and simplicity of Kirchoff’s
current law help designers construct robust circuits that switch reliably in 10−9
sec.
Singularities of field equations in three dimensions can increase sensitivity
dramatically, making circuits less robust or reliable.
When current 𝐉 𝒕𝒐𝒕𝒂𝒍 is defined to include the ‘polarization of the vacuum’
𝜀0 𝜕𝐄 𝜕𝑡,⁄ conservation of current is entirely independent of the polarization and
dielectric properties of matter. Lack of experimental knowledge of polarization is
unimportant, as far as conservation of current 𝐉 𝒕𝒐𝒕𝒂𝒍 is concerned.
The dielectric dilemma of the Maxwell equations is then partially resolved.
Maxwell’s equations can be used to analyze current flow in vacuum and matter, without
knowledge of polarization. 𝐉 𝒕𝒐𝒕𝒂𝒍 is conserved exactly, in vacuum and dielectrics, indeed
in matter in general.
The resolution of the dielectric dilemma is only partial because electrical forces are
not determined by currents alone. Forces depend on polarization even if current does
not. Where forces are important, Maxwell’s equations are useful only if polarization is
3
known in detail. Applications that depend on Kirchoff’s current law can take advantage
of conservation of current, without knowing anything about polarization or forces at all,
as previously mentioned.
Proof. Here is the proof of these assertions, following [10, 57-62]. We define
current as did Lorrain and Corson [1], p. 276 eq. 6-148.
𝐉 𝒕𝒐𝒕𝒂𝒍 = 𝐉 + 𝜀0
𝜕𝐄
𝜕𝑡
⏞
Vacuum
Displacement
Current
𝐄 describes the electric field, with electric constant (permittivity of vacuum) 𝜀0 .
𝐉 describes all the movement of charge that has mass.
𝐉 includes conduction currents (carried by electrons, holes, or ions, for example).
𝐉 includes all material polarization, no matter how transient and small are the
underlying atomic motions. Thus, 𝐉 includes the dielectric current in its classical
approximation ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ as well as all more complex material polarization
currents. Here, 𝜀 𝑟 is the relative dielectric coefficient of perfect dielectrics and classical
electrodynamics, a single real positive constant ≥ 1.
Polarization. Polarization of two types is important in our derivation. Polarization of
matter (‘material polarization’) arises from the motion of charge, typically from the tiny,
transient, reversible motion of electrons in insulators; or the movement of holes and
electrons in semiconductors; or the distortion of electron orbitals around atoms or
molecules in ionic solutions; or the rearrangement of molecules with asymmetrical
distributions of permanent and induced charge, and some organized structure, like
water.
Polarization of the vacuum 𝜀0 𝜕𝐄 𝜕𝑡⁄ is qualitatively different from material
polarization and is not a property of matter at all–although it exists in matter–since a
vacuum contains no matter. It is not surprising that material models of current in a
vacuum 𝜀0 𝜕𝐄 𝜕𝑡⁄ are difficult to construct [53-56].
Polarization of the vacuum produces currents 𝐉 𝒕𝒐𝒕𝒂𝒍 that allow electric and
magnetic fields to propagate between stars at the velocity of light 𝑐 = 1 √ 𝜀0 𝜇 𝑜⁄ ,
determined by the electrical and magnetic constants 𝜀0 , 𝜇 𝑜 and nothing else [1-5,
51, 52].
Polarization of the vacuum is a general property of ‘the universe’. It arises from
the properties of space-time as described by the theory of relativity [1-5, 51, 52]. The
term 𝜀0 𝜕𝐄 𝜕𝑡,⁄ arises from a special property of charge. Charge is independent of
(1)
4
velocity, even at velocities approaching the speed of light, because the Lorentz
transformation of charge creates the term 𝜀0 𝜕𝐄 𝜕𝑡⁄ (as described in [63]; [2], p. 553;
[1], p. 228, eq. 5-110). Mass, length and time all depend on velocity. It does not [2, 63].
Charge is special.
Maxwell’s equations include Ampere’s Law as Maxwell formulated it
1
𝜇 𝑜
𝐜𝐮𝐫𝐥 𝐁 = 𝐉𝒕𝒐𝒕𝒂𝒍 = 𝐉 + 𝜀0
𝜕𝐄
𝜕𝑡
⏞
Vacuum
Displacement
Current
𝐉 = ( 𝜀 𝑟 − 1) 𝜀0
𝜕𝐄
𝜕𝑡⏟
Material
Displacement
Current
+ 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆
𝐁 describes the magnetic field. The polarization of idealized dielectrics
( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ is isolated from other currents in eq. (2) only for convenience in
dealing with the literature. 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆 includes conduction currents (carried by
electrons, holes, or ions, for example). 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆 also includes all material
polarization, no matter how transient and small are the underlying atomic motions.
Thus, 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆 includes the dielectric current in its classical approximation
( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ as well as all the other properties of material polarization and
classical conduction.
Conservation of Current. The divergence of the curl is zero whenever Maxwell’s
equations can be used, so conservation of current is as general as Maxwell’s equations
themselves.
Conservation of Current 𝐝𝐢𝐯 ( 𝐉 + 𝜀0
𝜕𝐄
𝜕𝑡
⏞
𝑪𝒖𝒓𝒓𝒆𝒏𝒕
) = 0 (4)
This equation can be solved for 𝐄. The solution shows that the electric field assumes
the value needed to conserve current .
𝐄(𝑥, 𝑦, 𝑧|𝑡) = −
𝟏
𝜺 𝟎
∫ 𝐉(𝑥, 𝑦, 𝑧|𝜏) dτ
𝒕
𝟎
(5)
(2)
(3)
5
𝐄𝐥𝐞𝐜𝐭𝐫𝐢𝐜 𝐟𝐢𝐞𝐥𝐝 is an output. 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) is not assumed. It is an output of the analysis.
𝐄(𝑥, 𝑦, 𝑧|𝑡) is consistent because it is the result of the integration of the Maxwell
equation (2) and so depends on ‘everything’ in a system.
𝐄(𝑥, 𝑦, 𝑧|𝑡) produces the polarization of the vacuum 𝜀0 𝜕𝐄 𝜕𝑡⁄ needed to
conserve total current 𝐉 𝒕𝒐𝒕𝒂𝒍, no matter what are the motions of matter that produce 𝐉,
no matter what are the properties of the material displacement current, including its
classical approximation ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡.⁄
𝐄(𝑥, 𝑦, 𝑧|𝑡) moves charges. The charge movement is a current that combines
with 𝜀0 𝜕𝐄 𝜕𝑡⁄ so Maxwell’s equations are satisfied exactly. 𝐄(𝑥, 𝑦, 𝑧|𝑡) describes the
field that produces these charge movements. 𝐄(𝑥, 𝑦, 𝑧|𝑡) produces the forces and
the material currents needed to satisfy Maxwell’s equations exactly, when they
are combined with the material and vacuum displacement currents.
These words describe the mathematical fact that the Maxwell equations form
a consistent theory, in which all variables—including 𝐄(𝑥, 𝑦, 𝑧|𝑡) and every form
of current and flux—satisfy the equations and boundary conditions with one set
of unchanging parameters.
In networks of circuit components, 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) varies dramatically from component
to component. The variation is not determined just by the local microphysics of
conduction and material polarization but also by the global physics and structure of the
network. 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) depends on local microphysics, Maxwell equations, and boundary
conditions that specify the global properties of the electric field.
The electric field is both global and local. This reality is most vivid in one
dimensional networks where components are in series. Currents 𝐉𝒕𝒐𝒕𝒂𝒍 are equal in
every component of a series system, at all times and in all conditions. The current in
one component depends on the current in another. The microphysics of conduction in
one component does not in itself determine the current flow through that component,
despite our local intuition which might suggest otherwise.
Reference [58] discusses this property of series systems in detail, showing how the
physics of each component consists of both the local microphysics specific to that
component, and also the polarization of the vacuum, the displacement current
𝜀0 𝜕𝐄 𝜕𝑡⁄ . Fig. 3 of [58], and its discussion, show how 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) varies in wires,
resistors, capacitors, diodes, ionic solutions. 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) varies in every component but
𝐉𝒕𝒐𝒕𝒂𝒍 is always the same, because the components are in series. The currents are equal
in the components of the series circuit of Fig. 3 [58], at all times and in all conditions,
6
because the Maxwell equations produce the 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) field, the material currents and
fluxes, and the ‘vacuum’ displacement current 𝜀0 𝜕𝐄 𝜕𝑡⁄ needed to conserve current
𝐉𝒕𝒐𝒕𝒂𝒍, no matter what are the local microphysics of conduction or polarization
[10, 58-60], no matter what the dielectric current is in its classical approximation
( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ .
Classical Treatments of Conservation of Current. The usual derivations [1-5, 51, 52],
of conservation of current follow Maxwell [53-56] and use the composite field
𝐃 = 𝜀 𝑟ε0 𝐄. The 𝐃 field is a composite because it includes a constitutive property
describing the dielectric properties of matter. The 𝐃 field does not have a universal
description independent of the properties of matter, because no universal description of
the dielectric properties of matter seems possible.
Indeed, the 𝐃 field includes a severe approximation. It treats the dielectric constant
𝜀 𝑟 as a single real constant number, in contradiction to experimental measurements of
dielectric properties [6-36], spectra [39-43, 64], and nonlinear polarization [44-50].
When polarization has complex properties, the Maxwell equations as usually written
are inadequate. They must be reformulated to describe the polarization that actually
exists in the system of interest because that polarization significantly changes the
outputs of the equations. Reformulation using the 𝐃 field becomes awkward, if not
impossible in many cases, e.g., when polarization is time dependent or nonlinear. In
those cases the form of the Maxwell equations changes and, from a mathematical point
of view, they become a quite different set of partial differential equations, or integro-
differential equations.
General statements of conservation of current, like eq. (4), are not easily found in
the literature, probably because Maxwell formulated his equations in terms of the 𝐃
field, and others have followed in his footsteps, understandably enough.
The usual derivations of conservation of current describe dielectric properties
inaccurately, so conservation of current appears to be inaccurate. Conservation of
current appears to be a poor approximation that does not fit experimental data.
The appearance that conservation of current is an approximation is unfortunate
because scientists are then reluctant to use the general statement of eq. (4) to understand
electrical properties of matter with complex dielectric properties or polarization. Eq. (4)
is particularly useful in understanding the physics of current flow in series arrangements
like (semiconductor) diodes or ionic channels of biological membranes, where currents
are the same everywhere, although the microphysics of conduction of charges is not the
same at all.
7
Conservation of current is not an approximation, as we have just shown.
Conservation of current is in fact a general and exact property of the Maxwell equations
[10, 60, 62, 65], independent of any properties of matter, true under all conditions. Use
of the general principle of conservation of current should allow scientists to better
understand and control the flow of current in the circuit boards of our high speed digital
devices, or in the crowded confines of protein channels in biological membranes,
whether the channels conduct ions, electrons, or charged forms of water like
H+
or H3O+
.
Dielectric dilemma resolved. The dielectric dilemma posed by traditional formulations
of Maxwell’s equations is thus partially resolved. Current 𝐉𝒕𝒐𝒕𝒂𝒍 is conserved.
Applications that depend mostly on current conservation, like Kirchoff’s current law
for electrical networks, can use Maxwell’s equations even when dielectric properties
are unknown.
The dielectric dilemma is only partially resolved because forces depend on
polarization even if current does not. Where forces are important, Maxwell’s equations
are useful in detail only if polarization is known in detail.
Engineering Applications. Engineering applications work reliably in dielectric
environments that are rarely known in detail, over a remarkable range of times, starting
around 10−10
sec in the digital circuits of our phones and computers.
Engineering applications use one dimensional systems in which current can be
easily measured by (for example) measuring the potential drop across a one ohm (or
smaller) resistor placed in series in a branch. All the components in series with that one
ohm resistor will have the same current under all conditions and at all times [10, 57-
60], independent of the dielectric complexities or conduction mechanism of current in
the component. Currents in networks of branches are more complex but networks
conserve current as it flows. Conservation of current takes the simple form of the
algebraic equations called Kirchoff’s current law, if current is defined as 𝐉𝒕𝒐𝒕𝒂𝒍 [57].
Kirchoff’s current law then allows exact analysis of one dimensional systems from the
shortest times, because the current law is accurate whenever Maxwell’s equations are
valid.
It seems hardly a coincidence that so much of our technology uses one dimensional
circuits where current can be accurately defined, measured, and controlled, even in
nanoseconds. Significant efforts are made to keep the flow of current one dimensional
in our high speed technology, particularly in its grounding systems [66], p.787 of [67].
One can hope that current flow in the channels of biology can some day be
controlled and exploited (almost) as well as in our semiconductor technology today.
8
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Industry and Chemistry Posted on arXiv.org with paper ID arXiv:1502.07251 44 1-
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[59] Eisenberg B 2016 Conservation of Current and Conservation of Charge Available on
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[60] Eisenberg B 2016 Maxwell Matters Available on arXiv as
https://arxiv.org/pdf/1607.06691
[61] Benseny A, Albareda G, Sanz Á S, Mompart J and Oriols X 2014 Applied bohmian
mechanics The European Physical Journal D 68 286
[62] Albareda G, Traversa F L, Benali A and Oriols X 2012 Computation of Quantum
Electrical Currents through the Ramo-Shockley-Pellegrini Theorem with Trajectories
Fluctuation & Noise Letters 11 1-11
12
[63] Pauli W 2013 Theory of Relativity: Dover Publications)
[64] Parsegian V A 1969 Nature (London) 221 844
[65] Marian D, Colomes E and Oriols X 2015 Time-dependent exchange and tunneling:
detection at the same place of two electrons emitted simultaneously from different
sources J Phys Condens Matter 27 245302
[66] Joffe E B and Lock K-S 2010 Grounds for Grounding (NY: Wiley-IEEE Press)
[67] Paul C R 2006 Introduction to electromagnetic compatibility vol 184: John Wiley &
Sons)

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Dielectric Dilemma 1901.10805 v2 feb 4 2019

  • 1. seehttps://arxiv.org,article1901.10805 Dielectric Dilemma Robert S. Eisenberg Department of Applied Mathematics Illinois Institute of Technology; Department of Physiology and Biophysics Rush University Medical Center Chicago IL Bob.Eisenberg@gmail.com February 4, 2019 File name: Dielectric Dilemma February 3-2 header 2019.docx Keywords conservation of current, Maxwell equations, electrodynamics, Kirchoff’s law
  • 2. Abstract A dielectric dilemma faces scientists because Maxwell's equations are poor approximations as usually written, with a single dielectric constant. Maxwell's equations are then not accurate enough to be useful in many applications. The dilemma can be partially resolved by a rederivation of conservation of current, where current is defined now to include the ‘polarization of the vacuum’ 𝜀0 𝜕𝐄 𝜕𝑡⁄ . Conserveration of current becomes Kirchoff's current law with this definition, in the one dimensional circuits of our electronic technology. With this definition, Kirchoff's laws are valid whenever Maxwell's equations are valid, explaining why those laws reliably describe circuits that switch in nanoseconds.
  • 3. 1 Dielectrics pose a dilemma for scientists. Dielectrics are not well described by the classical equations of electrodynamics, as they are usually written. The equations of Maxwell [1-5] seem perfectly general in a vacuum, but, in the presence of dielectrics or matter, Maxwell’s equations are not general at all. They describe polarization1 of matter with a severe approximation. They describe polarization by single dielectric constant, a single real number ≥ 1. This description is nearly universal in textbooks, and in the minds of students, but a single dielectric constant is too approximate to be useful in a technological world where computer circuits switch faster than 10−9 sec and in a biological world where electrical signals are controlled by atomic movements < 10−10 m within proteins. The significant variation of dielectric parameters with time/frequency and conditions has been known a long time [6, 7]. Dielectric parameters have been studied extensively since then [6-36] because polarization is a major determinant of the forces between molecules [37, 38]. The experimental results are remarkably diverse. In solids, dielectric properties depend on time/frequency in every material. In ionic solutions, dielectric properties depend–‘without rhyme or reason’–on the type and concentrations of ions [11, 12]. Ionic solutions are of particular importance because all of life occurs in such solutions, as well as a great deal of chemistry. Amidst this diversity, there seems only one uniformity: dielectric properties cannot be described by a single real dielectric constant. In much higher frequency ranges, of light, for example, dielectric properties determine the refractive index, optical properties, and thus spectra of materials [37], because the polarization of electron orbitals determines how atoms absorb and radiate electromagnetic energy. Spectra are so varied that they are used as fingerprints to identify molecules [37, 39-43]. Spectral properties are as diverse as molecules and obviously cannot be described by a single constant refractive index. Many interactions of light and materials cannot be described at all by dielectric constants. Dielectric constants are useful only when field strengths are small enough so polarization is a linear phenomenon, independent of field strength. Some of the most interesting applications of electrodynamics involve nonlinear, field dependent 1 We use ‘polarization’ to mean any charge that depends on the local electric field, for example the charge in an highly polarizable anion like bromide Br− or the nonuniform charge distribution of H2O in the liquid state, with its complex time dependent (and perhaps nonlinear) polarization response to the local electric field. The charge or charge densities of alkali metal ions like Na+ and K+ are independent of the local electric field and so are not examples of polarization, but rather can be called permanent or fixed charge.
  • 4. 2 polarization [44-50]. The dielectric dilemma is clear: nonlinearities, spectra, and diverse dielectric behavior cannot be described by a single dielectric constant, but Maxwell’s equations use a single dielectric constant, as they are usually written. When a dielectric is complex, polarization and dielectric behavior need to be described by a functional, and the very form of the Maxwell equations changes. The detailed properties of polarization need to be known and described under the range of conditions in which polarization has significant effects. Polarization is rarely known that well experimentally. Theoretical models or simulations of that scope are also scarce. Maxwell’s equations with a single dielectric constant remain of great importance, however unrealistic the approximation, because that is how they have been taught ([1-5, 51, 52]; [50] is the exception) ever since the equations were formulated [53-56]. Students often remain unaware of the complex properties of the polarization of matter until they become scientists trying to use electrodynamics in applications. As scientists, they face a dielectric dilemma. Too little is often known of polarization to make the Maxwell equations useful in applications demanding precise understanding. Conservation of current. We show here, however, that one property of electrodynamics is independent of polarization, namely conservation of current. That property is in fact enough to ensure that current flow in the one dimensional systems of our electronic technology can be described accurately by the simple, nearly algebraic equations of Kirchoff’s current law, without dealing explicitly with field equations and their complexities, including singularities. The accuracy and simplicity of Kirchoff’s current law help designers construct robust circuits that switch reliably in 10−9 sec. Singularities of field equations in three dimensions can increase sensitivity dramatically, making circuits less robust or reliable. When current 𝐉 𝒕𝒐𝒕𝒂𝒍 is defined to include the ‘polarization of the vacuum’ 𝜀0 𝜕𝐄 𝜕𝑡,⁄ conservation of current is entirely independent of the polarization and dielectric properties of matter. Lack of experimental knowledge of polarization is unimportant, as far as conservation of current 𝐉 𝒕𝒐𝒕𝒂𝒍 is concerned. The dielectric dilemma of the Maxwell equations is then partially resolved. Maxwell’s equations can be used to analyze current flow in vacuum and matter, without knowledge of polarization. 𝐉 𝒕𝒐𝒕𝒂𝒍 is conserved exactly, in vacuum and dielectrics, indeed in matter in general. The resolution of the dielectric dilemma is only partial because electrical forces are not determined by currents alone. Forces depend on polarization even if current does not. Where forces are important, Maxwell’s equations are useful only if polarization is
  • 5. 3 known in detail. Applications that depend on Kirchoff’s current law can take advantage of conservation of current, without knowing anything about polarization or forces at all, as previously mentioned. Proof. Here is the proof of these assertions, following [10, 57-62]. We define current as did Lorrain and Corson [1], p. 276 eq. 6-148. 𝐉 𝒕𝒐𝒕𝒂𝒍 = 𝐉 + 𝜀0 𝜕𝐄 𝜕𝑡 ⏞ Vacuum Displacement Current 𝐄 describes the electric field, with electric constant (permittivity of vacuum) 𝜀0 . 𝐉 describes all the movement of charge that has mass. 𝐉 includes conduction currents (carried by electrons, holes, or ions, for example). 𝐉 includes all material polarization, no matter how transient and small are the underlying atomic motions. Thus, 𝐉 includes the dielectric current in its classical approximation ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ as well as all more complex material polarization currents. Here, 𝜀 𝑟 is the relative dielectric coefficient of perfect dielectrics and classical electrodynamics, a single real positive constant ≥ 1. Polarization. Polarization of two types is important in our derivation. Polarization of matter (‘material polarization’) arises from the motion of charge, typically from the tiny, transient, reversible motion of electrons in insulators; or the movement of holes and electrons in semiconductors; or the distortion of electron orbitals around atoms or molecules in ionic solutions; or the rearrangement of molecules with asymmetrical distributions of permanent and induced charge, and some organized structure, like water. Polarization of the vacuum 𝜀0 𝜕𝐄 𝜕𝑡⁄ is qualitatively different from material polarization and is not a property of matter at all–although it exists in matter–since a vacuum contains no matter. It is not surprising that material models of current in a vacuum 𝜀0 𝜕𝐄 𝜕𝑡⁄ are difficult to construct [53-56]. Polarization of the vacuum produces currents 𝐉 𝒕𝒐𝒕𝒂𝒍 that allow electric and magnetic fields to propagate between stars at the velocity of light 𝑐 = 1 √ 𝜀0 𝜇 𝑜⁄ , determined by the electrical and magnetic constants 𝜀0 , 𝜇 𝑜 and nothing else [1-5, 51, 52]. Polarization of the vacuum is a general property of ‘the universe’. It arises from the properties of space-time as described by the theory of relativity [1-5, 51, 52]. The term 𝜀0 𝜕𝐄 𝜕𝑡,⁄ arises from a special property of charge. Charge is independent of (1)
  • 6. 4 velocity, even at velocities approaching the speed of light, because the Lorentz transformation of charge creates the term 𝜀0 𝜕𝐄 𝜕𝑡⁄ (as described in [63]; [2], p. 553; [1], p. 228, eq. 5-110). Mass, length and time all depend on velocity. It does not [2, 63]. Charge is special. Maxwell’s equations include Ampere’s Law as Maxwell formulated it 1 𝜇 𝑜 𝐜𝐮𝐫𝐥 𝐁 = 𝐉𝒕𝒐𝒕𝒂𝒍 = 𝐉 + 𝜀0 𝜕𝐄 𝜕𝑡 ⏞ Vacuum Displacement Current 𝐉 = ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⏟ Material Displacement Current + 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆 𝐁 describes the magnetic field. The polarization of idealized dielectrics ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ is isolated from other currents in eq. (2) only for convenience in dealing with the literature. 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆 includes conduction currents (carried by electrons, holes, or ions, for example). 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆 also includes all material polarization, no matter how transient and small are the underlying atomic motions. Thus, 𝐉 𝒆𝒗𝒆𝒓𝒚𝒕𝒉𝒊𝒏𝒈 𝒆𝒍𝒔𝒆 includes the dielectric current in its classical approximation ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ as well as all the other properties of material polarization and classical conduction. Conservation of Current. The divergence of the curl is zero whenever Maxwell’s equations can be used, so conservation of current is as general as Maxwell’s equations themselves. Conservation of Current 𝐝𝐢𝐯 ( 𝐉 + 𝜀0 𝜕𝐄 𝜕𝑡 ⏞ 𝑪𝒖𝒓𝒓𝒆𝒏𝒕 ) = 0 (4) This equation can be solved for 𝐄. The solution shows that the electric field assumes the value needed to conserve current . 𝐄(𝑥, 𝑦, 𝑧|𝑡) = − 𝟏 𝜺 𝟎 ∫ 𝐉(𝑥, 𝑦, 𝑧|𝜏) dτ 𝒕 𝟎 (5) (2) (3)
  • 7. 5 𝐄𝐥𝐞𝐜𝐭𝐫𝐢𝐜 𝐟𝐢𝐞𝐥𝐝 is an output. 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) is not assumed. It is an output of the analysis. 𝐄(𝑥, 𝑦, 𝑧|𝑡) is consistent because it is the result of the integration of the Maxwell equation (2) and so depends on ‘everything’ in a system. 𝐄(𝑥, 𝑦, 𝑧|𝑡) produces the polarization of the vacuum 𝜀0 𝜕𝐄 𝜕𝑡⁄ needed to conserve total current 𝐉 𝒕𝒐𝒕𝒂𝒍, no matter what are the motions of matter that produce 𝐉, no matter what are the properties of the material displacement current, including its classical approximation ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡.⁄ 𝐄(𝑥, 𝑦, 𝑧|𝑡) moves charges. The charge movement is a current that combines with 𝜀0 𝜕𝐄 𝜕𝑡⁄ so Maxwell’s equations are satisfied exactly. 𝐄(𝑥, 𝑦, 𝑧|𝑡) describes the field that produces these charge movements. 𝐄(𝑥, 𝑦, 𝑧|𝑡) produces the forces and the material currents needed to satisfy Maxwell’s equations exactly, when they are combined with the material and vacuum displacement currents. These words describe the mathematical fact that the Maxwell equations form a consistent theory, in which all variables—including 𝐄(𝑥, 𝑦, 𝑧|𝑡) and every form of current and flux—satisfy the equations and boundary conditions with one set of unchanging parameters. In networks of circuit components, 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) varies dramatically from component to component. The variation is not determined just by the local microphysics of conduction and material polarization but also by the global physics and structure of the network. 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) depends on local microphysics, Maxwell equations, and boundary conditions that specify the global properties of the electric field. The electric field is both global and local. This reality is most vivid in one dimensional networks where components are in series. Currents 𝐉𝒕𝒐𝒕𝒂𝒍 are equal in every component of a series system, at all times and in all conditions. The current in one component depends on the current in another. The microphysics of conduction in one component does not in itself determine the current flow through that component, despite our local intuition which might suggest otherwise. Reference [58] discusses this property of series systems in detail, showing how the physics of each component consists of both the local microphysics specific to that component, and also the polarization of the vacuum, the displacement current 𝜀0 𝜕𝐄 𝜕𝑡⁄ . Fig. 3 of [58], and its discussion, show how 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) varies in wires, resistors, capacitors, diodes, ionic solutions. 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) varies in every component but 𝐉𝒕𝒐𝒕𝒂𝒍 is always the same, because the components are in series. The currents are equal in the components of the series circuit of Fig. 3 [58], at all times and in all conditions,
  • 8. 6 because the Maxwell equations produce the 𝐄( 𝑥, 𝑦, 𝑧| 𝑡) field, the material currents and fluxes, and the ‘vacuum’ displacement current 𝜀0 𝜕𝐄 𝜕𝑡⁄ needed to conserve current 𝐉𝒕𝒐𝒕𝒂𝒍, no matter what are the local microphysics of conduction or polarization [10, 58-60], no matter what the dielectric current is in its classical approximation ( 𝜀 𝑟 − 1) 𝜀0 𝜕𝐄 𝜕𝑡⁄ . Classical Treatments of Conservation of Current. The usual derivations [1-5, 51, 52], of conservation of current follow Maxwell [53-56] and use the composite field 𝐃 = 𝜀 𝑟ε0 𝐄. The 𝐃 field is a composite because it includes a constitutive property describing the dielectric properties of matter. The 𝐃 field does not have a universal description independent of the properties of matter, because no universal description of the dielectric properties of matter seems possible. Indeed, the 𝐃 field includes a severe approximation. It treats the dielectric constant 𝜀 𝑟 as a single real constant number, in contradiction to experimental measurements of dielectric properties [6-36], spectra [39-43, 64], and nonlinear polarization [44-50]. When polarization has complex properties, the Maxwell equations as usually written are inadequate. They must be reformulated to describe the polarization that actually exists in the system of interest because that polarization significantly changes the outputs of the equations. Reformulation using the 𝐃 field becomes awkward, if not impossible in many cases, e.g., when polarization is time dependent or nonlinear. In those cases the form of the Maxwell equations changes and, from a mathematical point of view, they become a quite different set of partial differential equations, or integro- differential equations. General statements of conservation of current, like eq. (4), are not easily found in the literature, probably because Maxwell formulated his equations in terms of the 𝐃 field, and others have followed in his footsteps, understandably enough. The usual derivations of conservation of current describe dielectric properties inaccurately, so conservation of current appears to be inaccurate. Conservation of current appears to be a poor approximation that does not fit experimental data. The appearance that conservation of current is an approximation is unfortunate because scientists are then reluctant to use the general statement of eq. (4) to understand electrical properties of matter with complex dielectric properties or polarization. Eq. (4) is particularly useful in understanding the physics of current flow in series arrangements like (semiconductor) diodes or ionic channels of biological membranes, where currents are the same everywhere, although the microphysics of conduction of charges is not the same at all.
  • 9. 7 Conservation of current is not an approximation, as we have just shown. Conservation of current is in fact a general and exact property of the Maxwell equations [10, 60, 62, 65], independent of any properties of matter, true under all conditions. Use of the general principle of conservation of current should allow scientists to better understand and control the flow of current in the circuit boards of our high speed digital devices, or in the crowded confines of protein channels in biological membranes, whether the channels conduct ions, electrons, or charged forms of water like H+ or H3O+ . Dielectric dilemma resolved. The dielectric dilemma posed by traditional formulations of Maxwell’s equations is thus partially resolved. Current 𝐉𝒕𝒐𝒕𝒂𝒍 is conserved. Applications that depend mostly on current conservation, like Kirchoff’s current law for electrical networks, can use Maxwell’s equations even when dielectric properties are unknown. The dielectric dilemma is only partially resolved because forces depend on polarization even if current does not. Where forces are important, Maxwell’s equations are useful in detail only if polarization is known in detail. Engineering Applications. Engineering applications work reliably in dielectric environments that are rarely known in detail, over a remarkable range of times, starting around 10−10 sec in the digital circuits of our phones and computers. Engineering applications use one dimensional systems in which current can be easily measured by (for example) measuring the potential drop across a one ohm (or smaller) resistor placed in series in a branch. All the components in series with that one ohm resistor will have the same current under all conditions and at all times [10, 57- 60], independent of the dielectric complexities or conduction mechanism of current in the component. Currents in networks of branches are more complex but networks conserve current as it flows. Conservation of current takes the simple form of the algebraic equations called Kirchoff’s current law, if current is defined as 𝐉𝒕𝒐𝒕𝒂𝒍 [57]. Kirchoff’s current law then allows exact analysis of one dimensional systems from the shortest times, because the current law is accurate whenever Maxwell’s equations are valid. It seems hardly a coincidence that so much of our technology uses one dimensional circuits where current can be accurately defined, measured, and controlled, even in nanoseconds. Significant efforts are made to keep the flow of current one dimensional in our high speed technology, particularly in its grounding systems [66], p.787 of [67]. One can hope that current flow in the channels of biology can some day be controlled and exploited (almost) as well as in our semiconductor technology today.
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