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APPLIED CHEMISTRY BS 4th
smester
Miss Rukhsar Latif
Sugar Industry
Introduction
 The industry employs more than 100,000 labour force while more than 9 million
people of rural population are involved in the production of sugarcane. Sugar
Industry is an agro-based industry, which provides employment to the landless
rural population and has a great impact on the economy of the country. The three
principal bye-products of a sugar industry are bagasses, molasses and press cake
which along constitute about 40 per cent of the weight of the total cane crushed.
Proper and economic utilization of these bye-products can reduce the cost of
production of sugar to some extent.
 Bagasse is a source of energy fuel for sugar industry which is
used to fire boilers for juice heating. Bagasse is also being used for making Medium
Density Fibre Board (MDFB) at some industries which is a substitute for natural
wood.
 In Pakistan, utilization of sugar bye-products has not received much attention as
compared to other countries of the world. Average yield of sugarcane in the world is
around 60 tons per hectare while in Pakistan, it has been worked out to 43.86 tons per
hectare. India with almost similar soil and climatic conditions had achieved about
61% higher yield for the year 1996-97.
• Pakistan is producing high quality sugar of international standards but it is costlier
due to various factors. International prices of sugar had declined due to higher
output over the demand. It was $225 per ton at the start of 1998 while it had come
down to $ 188 per ton on 12.9.1999.
• World output of 136 million tons of sugar had been forecasted for the
• season 1999-2000. Molasses may be utilized for production of power alcohol,
industrial alcohol and portable spirits. Press cake of sulphitation factories are used as
manure and that of carbonation factories are usually burnt. Sugar is commonly used
as a sweetener.
• It is one of the worlds valuable nutritious foods and is the main source of
carbohydrates and provides inexpensive calories for human body. Molasses may be
utilized for production of power alcohol, industrial alcohol and portable spirits.
Press cake of sulphitation factories are used as manure and that of carbonation
factories are usually burnt. Sugar is commonly used as a sweetener. It is one of the
worlds valuable nutritious foods and is the main source of carbohydrates and
provides inexpensive calories for human body.
.
• Sugarcane is the fourth largest cash crop grown in Pakistan which
contributes to the agriculture economy the crop value of Rs. 48,292
million. A 78 per cent of thissugar cane was utilized and crushed
by 73 sugar mills for the season 1998-99, producing 3.531 million
tons of refined sugar which was capable to contribute substantial
amount to the federal government revenue towards sales tax and
road access for Provincial government revenue. The industry
employs more than 100,000 labour force while more than 9 million
people of rural population are involved in the production of
sugarcane. • Sugar can be produce from beet or from sugar cane.
• In India sugarcanes are used, Europe –beet is used.
• The mills are typically operated for 4 to 8 months after the
harvesting of sugar cane.
• In Pakistan normally season starts in November and ends in April while in
Zambia it starts in April and finishes in Decembe.The sugar industry, which is
the second largest in the country after textiles, has a potential of great economic
significance for the country.
• In Sudan a north African country yield per hectare is 78 tons while it is 115 tons
per hectare in South African country - Zambia.
• Manufacturing process
The basic process
• Sugar cane must be crushed to extract the juice. The crushing process must break up
the hard nodes of the cane and flatten the stems. The juice is collected, filtered and
sometimes treated and then boiled to drive off the excess water. The dried cane residue
(bagasse) is often used as fuel for this process. The remaining liquid is allowed to set
into a solid mass known as jaggery, gur, chancaca or panela.
• Terminology
The following terminology is used in this technical brief:
• Bagasse The fibrous residue of sugar cane which remains after the crushing operation.
Boiling, The evaporation of moisture from the juice at temperatures of between 90 and
116ºC.
• Brix, The term 'degrees Brix' (or more usually ºBrix) is the sugar 'technologists'
measure of the concentration of dissolved solids in solution.
Clarification Removal of impurities from the juice.
• Extraction, The removal of juice from the cane by crushing.
Factory, This term is used throughout to indicate a sugar processing plant regardless of
its type, processing capacity or physical size.
• Invert sugar High temperatures and acid conditions can cause chemical decomposition
of the sucrose resulting in simpler sugars such as glucose and fructose forming.These
sugars are known as invert sugars and are not desirable in the final product.
• Massecuite, The concentrated cane juice obtained after boiling, also known as rab or final
syrup. Molasses A syrup by-product from the manufacture of sugar, containing sucrose,
invert sugars, moisture, ash and other insoluble matter.
• Open Pan (OP) Describes sugar produced by boiling juice in open pans at atmospheric
pressure. OPS Open Pan Sulphitation (OPS) is a method for production of white granular
sugar, developed in India.
• Recovery ,The proportion of sugar produced by weight of cane processed, usually expressed
as a percentage. For example, 10% recovery means that for every 100kg of cane processed
10kg of sugar is produced. Strike The removal of massecuite from the boiling operation at the
required concentration.
• Sucrose An organic chemical of the carbohydrate family, found in the sap of most green
plants.
• Ordinary white crystal sugar is almost (99.9%) pure sucrose while some of the non-crystalline
sugars may contain less; for example syrup and jaggery which contain as little as 50 and 80%
sucrose respectively
• TCD, Tonnes of Cane per Day refers to the amount of cane a processing plant crushes
each day and not the amount of sugar produced. Most sugar processing plants
are sized according to this figure which is based on a 24 hour day. However,
many small-scale factories, and some large ones, only operate for part of a day
and in some cases for only part of the year.
• Vacuum Pan Vacuum (VP) pan describes a particular type of technology used to boil or
evaporate the sugar cane juice.
Extraction
Small-scale extraction is done using small two or three-roll mills driven either
by draught animals or small engines. The larger small-scale and the medium-
scale factory will use a single motorised three-roll mill. Typically roll mills used
in the small-scale sector are either two or threeroll configuration set vertically
or horizontally. The rolls, usually made from cast iron or steel, are located in
wooden, steel or cast iron frames.Some of the smaller crushers, with capacities
of between 200 and 500kg cane per hour, have vertically set rolls and are
animal powered but can be modified to use small engines or electric
motors.
 Juice treatment Juice should be filtered through a cloth before boiling in order to remove
any solids such as dirt or particles of cane. Large-scale sugar processors add lime to the juice
in order to coagulate impurities which then settle out. (This is rarely done at the artisanal
level.) The juice is then neutralised with sulphur dioxide. Small-scale producers add a variety
of clarificants to the juice including wood ash. Many producers also add 'hydros' (sodium
hydrogen sulphate) at the final stages of boiling. This releases sulphur dioxide into the juice
and lightens the colour of the final product. (Note that a high sulphur content often remains in
the final product.)
 Filtration and Clarification
The amount of non-sugars such as bagasse and other particulates in the juice will affect its
purity, resulting in discoloration and reduced sweetness. Therefore filtration is essential and
if done with care can remove up to 60% of non-sugars from the juice.
A filter press, if available, will give the best results but can be expensive for small-scale
operations. However, reasonable levels of filtration can be achieved by allowing the juice to
stand for a few hours to allow particulates to precipitate out. The tanks should be fitted with a
fine mesh lid, through which the juice is poured to filter out large particles of bagasse and
other foreign bodies. The mesh will also prevent infestation from insects and help prevent
contamination by small animals and birds.
After settling the juice should be drawn from the tank ensuring that particulates settled at the
bottom of the tank are not disturbed. The juice can then be poured into the boiling pan
through a coarse cotton cloth to filter out fine particles that may remain in suspension.
• Clarification, if undertaken, is carried out during the boiling process by adding a small
amount of vegetable or chemical matter to the juice. The clarificants do not react with the
juice but coagulate during the heating process, trapping particles and contaminants and
bringing them to the surface during boiling. This appears on the surface as a scum which
can be removed using ong handled fine-mesh ladles or by passing a fine cotton cloth
through the juice.
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx
APPLIED CHEMISTRY BS 4th smester (1).pptx

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APPLIED CHEMISTRY BS 4th smester (1).pptx

  • 1. APPLIED CHEMISTRY BS 4th smester Miss Rukhsar Latif
  • 3.
  • 4.
  • 5.
  • 6. Introduction  The industry employs more than 100,000 labour force while more than 9 million people of rural population are involved in the production of sugarcane. Sugar Industry is an agro-based industry, which provides employment to the landless rural population and has a great impact on the economy of the country. The three principal bye-products of a sugar industry are bagasses, molasses and press cake which along constitute about 40 per cent of the weight of the total cane crushed. Proper and economic utilization of these bye-products can reduce the cost of production of sugar to some extent.  Bagasse is a source of energy fuel for sugar industry which is used to fire boilers for juice heating. Bagasse is also being used for making Medium Density Fibre Board (MDFB) at some industries which is a substitute for natural wood.  In Pakistan, utilization of sugar bye-products has not received much attention as compared to other countries of the world. Average yield of sugarcane in the world is around 60 tons per hectare while in Pakistan, it has been worked out to 43.86 tons per hectare. India with almost similar soil and climatic conditions had achieved about 61% higher yield for the year 1996-97.
  • 7. • Pakistan is producing high quality sugar of international standards but it is costlier due to various factors. International prices of sugar had declined due to higher output over the demand. It was $225 per ton at the start of 1998 while it had come down to $ 188 per ton on 12.9.1999. • World output of 136 million tons of sugar had been forecasted for the • season 1999-2000. Molasses may be utilized for production of power alcohol, industrial alcohol and portable spirits. Press cake of sulphitation factories are used as manure and that of carbonation factories are usually burnt. Sugar is commonly used as a sweetener. • It is one of the worlds valuable nutritious foods and is the main source of carbohydrates and provides inexpensive calories for human body. Molasses may be utilized for production of power alcohol, industrial alcohol and portable spirits. Press cake of sulphitation factories are used as manure and that of carbonation factories are usually burnt. Sugar is commonly used as a sweetener. It is one of the worlds valuable nutritious foods and is the main source of carbohydrates and provides inexpensive calories for human body. .
  • 8. • Sugarcane is the fourth largest cash crop grown in Pakistan which contributes to the agriculture economy the crop value of Rs. 48,292 million. A 78 per cent of thissugar cane was utilized and crushed by 73 sugar mills for the season 1998-99, producing 3.531 million tons of refined sugar which was capable to contribute substantial amount to the federal government revenue towards sales tax and road access for Provincial government revenue. The industry employs more than 100,000 labour force while more than 9 million people of rural population are involved in the production of sugarcane. • Sugar can be produce from beet or from sugar cane. • In India sugarcanes are used, Europe –beet is used. • The mills are typically operated for 4 to 8 months after the harvesting of sugar cane. • In Pakistan normally season starts in November and ends in April while in Zambia it starts in April and finishes in Decembe.The sugar industry, which is the second largest in the country after textiles, has a potential of great economic significance for the country. • In Sudan a north African country yield per hectare is 78 tons while it is 115 tons per hectare in South African country - Zambia.
  • 9. • Manufacturing process The basic process • Sugar cane must be crushed to extract the juice. The crushing process must break up the hard nodes of the cane and flatten the stems. The juice is collected, filtered and sometimes treated and then boiled to drive off the excess water. The dried cane residue (bagasse) is often used as fuel for this process. The remaining liquid is allowed to set into a solid mass known as jaggery, gur, chancaca or panela. • Terminology The following terminology is used in this technical brief: • Bagasse The fibrous residue of sugar cane which remains after the crushing operation. Boiling, The evaporation of moisture from the juice at temperatures of between 90 and 116ºC. • Brix, The term 'degrees Brix' (or more usually ºBrix) is the sugar 'technologists' measure of the concentration of dissolved solids in solution. Clarification Removal of impurities from the juice. • Extraction, The removal of juice from the cane by crushing. Factory, This term is used throughout to indicate a sugar processing plant regardless of its type, processing capacity or physical size. • Invert sugar High temperatures and acid conditions can cause chemical decomposition of the sucrose resulting in simpler sugars such as glucose and fructose forming.These sugars are known as invert sugars and are not desirable in the final product.
  • 10. • Massecuite, The concentrated cane juice obtained after boiling, also known as rab or final syrup. Molasses A syrup by-product from the manufacture of sugar, containing sucrose, invert sugars, moisture, ash and other insoluble matter. • Open Pan (OP) Describes sugar produced by boiling juice in open pans at atmospheric pressure. OPS Open Pan Sulphitation (OPS) is a method for production of white granular sugar, developed in India. • Recovery ,The proportion of sugar produced by weight of cane processed, usually expressed as a percentage. For example, 10% recovery means that for every 100kg of cane processed 10kg of sugar is produced. Strike The removal of massecuite from the boiling operation at the required concentration. • Sucrose An organic chemical of the carbohydrate family, found in the sap of most green plants. • Ordinary white crystal sugar is almost (99.9%) pure sucrose while some of the non-crystalline sugars may contain less; for example syrup and jaggery which contain as little as 50 and 80% sucrose respectively • TCD, Tonnes of Cane per Day refers to the amount of cane a processing plant crushes each day and not the amount of sugar produced. Most sugar processing plants are sized according to this figure which is based on a 24 hour day. However, many small-scale factories, and some large ones, only operate for part of a day and in some cases for only part of the year. • Vacuum Pan Vacuum (VP) pan describes a particular type of technology used to boil or evaporate the sugar cane juice.
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  • 15. Extraction Small-scale extraction is done using small two or three-roll mills driven either by draught animals or small engines. The larger small-scale and the medium- scale factory will use a single motorised three-roll mill. Typically roll mills used in the small-scale sector are either two or threeroll configuration set vertically or horizontally. The rolls, usually made from cast iron or steel, are located in wooden, steel or cast iron frames.Some of the smaller crushers, with capacities of between 200 and 500kg cane per hour, have vertically set rolls and are animal powered but can be modified to use small engines or electric motors.
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  • 17.  Juice treatment Juice should be filtered through a cloth before boiling in order to remove any solids such as dirt or particles of cane. Large-scale sugar processors add lime to the juice in order to coagulate impurities which then settle out. (This is rarely done at the artisanal level.) The juice is then neutralised with sulphur dioxide. Small-scale producers add a variety of clarificants to the juice including wood ash. Many producers also add 'hydros' (sodium hydrogen sulphate) at the final stages of boiling. This releases sulphur dioxide into the juice and lightens the colour of the final product. (Note that a high sulphur content often remains in the final product.)
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  • 19.  Filtration and Clarification The amount of non-sugars such as bagasse and other particulates in the juice will affect its purity, resulting in discoloration and reduced sweetness. Therefore filtration is essential and if done with care can remove up to 60% of non-sugars from the juice. A filter press, if available, will give the best results but can be expensive for small-scale operations. However, reasonable levels of filtration can be achieved by allowing the juice to stand for a few hours to allow particulates to precipitate out. The tanks should be fitted with a fine mesh lid, through which the juice is poured to filter out large particles of bagasse and other foreign bodies. The mesh will also prevent infestation from insects and help prevent contamination by small animals and birds. After settling the juice should be drawn from the tank ensuring that particulates settled at the bottom of the tank are not disturbed. The juice can then be poured into the boiling pan through a coarse cotton cloth to filter out fine particles that may remain in suspension. • Clarification, if undertaken, is carried out during the boiling process by adding a small amount of vegetable or chemical matter to the juice. The clarificants do not react with the juice but coagulate during the heating process, trapping particles and contaminants and bringing them to the surface during boiling. This appears on the surface as a scum which can be removed using ong handled fine-mesh ladles or by passing a fine cotton cloth through the juice.