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The  Chemistry of Life 2007-2008
Why are we studying chemistry? ,[object Object]
Proton Neutron Electron Hydrogen 1 proton 1 electron  Oxygen 8 protons 8 neutrons 8 electrons + 0 – ,[object Object],[object Object]
The World of Elements C Different kinds of atoms = elements H O N P S Na K Mg Ca
Life requires ~25 chemical elements ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],Bonding properties How does this  atom behave?
[object Object],[object Object],Bonding properties What’s the magic number?  How does this atom behave? How does this atom behave?
Elements & their valence shells Elements in the  same row  have the same  number of shells Moving from left to right, each element has a sequential addition of electrons (& protons)
Elements & their valence shells Elements in the same  column  have the  same valence  &  similar chemical properties Remember some food chains are built on   reducing O to H 2 O & some on  reducing S to H 2 S
Chemical reactivity ,[object Object],[object Object],[object Object],[object Object],This tendency drives chemical reactions… and creates bonds – – –
Bonds in Biology ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Covalent bond Hydrogen bond H 2 O H 2 O – – H 2  (hydrogen gas)
Covalent bonds ,[object Object],[object Object],[object Object],[object Object],[object Object],H 2  (hydrogen gas) H — H H 2 O (water) – – H H Oxygen H H O
Multiple covalent bonds ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],More is better !   H H–C–H H – –
Nonpolar covalent bond ,[object Object],[object Object],[object Object],balanced, stable, good building block
Polar covalent bonds ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],+ + – – – – H H Oxygen
Hydrogen bonding ,[object Object],[object Object],[object Object],[object Object],Let’s go to the  videotape !   H O H
Chemistry of Life Properties of Water   2007-2008
More about Water Why are we studying water? ,[object Object],[object Object]
Chemistry of water ,[object Object],[object Object],[object Object]
Elixir of Life ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Ice !   I could use  more ice !
1. Cohesion & Adhesion ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Try that   with flour… or sugar…
How does H 2 O get to top of trees? ,[object Object],Let’s go to the  videotape !
2. Water is the solvent of life ,[object Object],[object Object],[object Object]
What dissolves in water? ,[object Object],[object Object],[object Object]
What doesn’t dissolve in water? ,[object Object],[object Object],[object Object],fat (triglycerol) Oh, look hydrocarbons !
3. The special case of ice ,[object Object],[object Object],[object Object],[object Object],And this has made all the  difference !
Ice floats
Why is “ice floats” important? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
4. Specific heat ,[object Object],[object Object],[object Object],[object Object],[object Object]
Specific heat & climate
5. Heat of vaporization ,[object Object],Evaporative cooling
Ionization of water & pH ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],H 2 O    H +  + OH –
pH Scale tenfold change in H+ ions pH1    pH2 10 -1     10 -2 10 times less H + pH8    pH7 10 -8     10 -7 10 times more H + pH10    pH8 10 -10     10 -8 100 times more H + 10 –1   H +  Ion Concentration Examples of Solutions Stomach acid, Lemon juice 1 pH 10 0 Hydrochloric acid 0 10 –2   2 10 –3   Vinegar, cola, beer 3 10 –4   Tomatoes 4 10 –5   Black coffee, Rainwater 5 10 –6   Urine, Saliva 6 10 –7   Pure water, Blood 7 10 –8   Seawater 8 10 –9   Baking soda 9 10 –10   Great Salt Lake 10 10 –11   Household ammonia 11 10 –12   Household bleach 12 10 –13   Oven cleaner 13 10 –14   Sodium hydroxide 14
Buffers & cellular regulation ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],1 0 0 1 2 3 4 5 6 7 8 9 3 Amount of base added Buffering range 4 5 2 pH
2007-2008 He’s gonna earn a  Darwin Award ! Do one brave thing today…then run like hell! Any Questions?

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Ch 2 3 chemistry

  • 1. The Chemistry of Life 2007-2008
  • 2.
  • 3.
  • 4. The World of Elements C Different kinds of atoms = elements H O N P S Na K Mg Ca
  • 5.
  • 6.
  • 7.
  • 8. Elements & their valence shells Elements in the same row have the same number of shells Moving from left to right, each element has a sequential addition of electrons (& protons)
  • 9. Elements & their valence shells Elements in the same column have the same valence & similar chemical properties Remember some food chains are built on reducing O to H 2 O & some on reducing S to H 2 S
  • 10.
  • 11.
  • 12.
  • 13.
  • 14.
  • 15.
  • 16.
  • 17. Chemistry of Life Properties of Water 2007-2008
  • 18.
  • 19.
  • 20.
  • 21.
  • 22.
  • 23.
  • 24.
  • 25.
  • 26.
  • 28.
  • 29.
  • 30. Specific heat & climate
  • 31.
  • 32.
  • 33. pH Scale tenfold change in H+ ions pH1 ď‚® pH2 10 -1 ď‚® 10 -2 10 times less H + pH8 ď‚® pH7 10 -8 ď‚® 10 -7 10 times more H + pH10 ď‚® pH8 10 -10 ď‚® 10 -8 100 times more H + 10 –1 H + Ion Concentration Examples of Solutions Stomach acid, Lemon juice 1 pH 10 0 Hydrochloric acid 0 10 –2 2 10 –3 Vinegar, cola, beer 3 10 –4 Tomatoes 4 10 –5 Black coffee, Rainwater 5 10 –6 Urine, Saliva 6 10 –7 Pure water, Blood 7 10 –8 Seawater 8 10 –9 Baking soda 9 10 –10 Great Salt Lake 10 10 –11 Household ammonia 11 10 –12 Household bleach 12 10 –13 Oven cleaner 13 10 –14 Sodium hydroxide 14
  • 34.
  • 35. 2007-2008 He’s gonna earn a Darwin Award ! Do one brave thing today…then run like hell! Any Questions?

Editor's Notes

  1. Domains of Study Domain of BioMolecules Domain of Cells Domain of Organisms Domain of Populations Domain of Communities
  2. Sulfur on the LEFT Magnesium on the RIGHT
  3. Oxygen has medium electronegativity so doesn’t pull electrons all the way off hydrogen whereas chlorine would. So oxygen forms a polar covalent bond. Carbon has only a weak electronegativity so forms a nonpolar covalent bond
  4. APBio/TOPICS/Biochemistry/MoviesAP/03_02WaterStructure_A.swf
  5. APBio/TOPICS/Biochemistry/Movies AP/hydrogenbonds-Thinkwell.swf
  6. APBio/TOPICS/04Biochemistry/MoviesAP/03_03WaterTransport_A.swf
  7. What dissolves in water easily? polar or non-polar molecules? How about Oxygen? Does that dissolve in H 2 O?
  8. What dissolves in water easily? polar or non-polar molecules? How about Oxygen? Does that dissolve in H 2 O?
  9. What dissolves in water easily? polar or non-polar molecules? How about Oxygen? Does that dissolve in H 2 O?
  10. In pure water only 1 water molecule in every 554 million is dissociated
  11. Exercise = acidic in muscles CO 2 = carbonic acid lactic acid body uses buffers to counter act this