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Chapter 13, Section 2: the ozone shield
Standards: SEV4f
ATMOSPHERE &
CLIMATE CHANGE
• An area in the
stratosphere
where ozone is
highly
concentrated.
• Ozone (O3) absorbs
most of the UV
light that comes
from the sun.
WHAT IS THE OZONE LAYER?
Chlorofluorcarbons (CFCs)
• When first invented, were valued
because they are
• Nonpoisonous
• Nonflammable
• Do not corrode
• Were used for decades as
• Coolants in refrigerators & air
conditioners
• Component of Sytrofoam
• Propellant in hair spray,
deodorant, insecticides & paint
• In 1970’s it was discovered they may
be damaging the ozone layer.
WHAT CHEMICAL IS ATTRIBUTED WITH
CAUSING OZONE DEPLETION?
• At ground level, CFCs are
stable & do not cause
problems.
• When air currents carry them
to the stratosphere they can
deplete the ozone.
• Takes 10-20 years for the CFC’s to make
it to the stratosphere and they get
recycled while they are up there so they
are persistent for 60-120 years
• UV light from sun breaks CFC which
releases a chlorine atom.
• The chlorine atom breaks a molecule of
ozone (O3) into an O2 molecule and an
oxygen atom (O) which the chlorine
attaches to and creates chlorine
monoxide (ClO)
• Chlorine monoxide (ClO) hits another
ozone and the chlorine breaks off again
and attacks another ozone molecule.
• 1 chlorine from CFC can destroy
100,000 ozone molecules.
HOW DO CFC’S DEPLETE THE OZONE?
Ultraviolet light hits a chlorofluorocarbon
(CFC) molecule, such as CFCl3, breaking
off a chlorine atom and leaving
CFCl2.
UV radiation
Sun
Once free, the chlorine atom is off
to attack another ozone molecule
and begin the cycle again.
A free oxygen atom pulls
the oxygen atom off
the chlorine monoxide
molecule to form O2.
The chlorine
atom and the
oxygen atom join
to form a chlorine
monoxide molecule (ClO)
The chlorine atom attacks
an ozone (O3) molecule,
pulling an oxygen atom
off it and leaving
an oxygen
molecule (O2).
Cl
Cl
Cl
C
F
Cl
Cl
O
O
Cl
O
O
O
Cl
O
O
O
Cl
O
O
1980’s scientists
working in Antarctica
noticed a thinning of the
ozone by 50-98% that
was occurring each
spring.
WHAT IS “THE OZONE HOLE”?
 During the dark winter
months, VERY cold
strong winds called
polar vortex winds trap
CFC’s and convert them
to molecular Cl2
 In the spring, UV rays
split Cl2 and the
individual Cl atoms
break ozone down
rapidly.
 The thinning lasts for
several months.
HOW DOES THE OZONE HOLE FORM?
Ozone at ground
level is highly
reactive and reacts
with other molecules
of air pollution
before it can even
enter the
stratosphere.
WHY CAN’T OZONE CREATED AT GROUND
LEVEL (AKA- BAD OZONE) HELP HEAL THE
OZONE THINNING?
UV light can
Damage DNA
Premature aging
Weakened immune
system
Increase chance of
developing cataracts
Increase susceptibility
to skin cancer
WHAT ARE THE EFFECTS OF OZONE
THINNING ON HUMANS?
 Oceans
 Kills phytoplankton which is
the bottom of the marine food
chain.
 Disrupts food chains
 Phytoplankton removes CO2 so
if they die, CO2 levels would go
up in atmosphere (global
climate change)
 Freshwater
 Kill amphibian eggs
 Survivors suffer birth defects
 Populations decline
 Land Plants
 Interferes with photosynthesis
 Reduces crop yield
WHAT ARE THE EFFECTS OF OZONE
THINNING ON ANIMALS & PLANTS?
Montreal Protocol
(1987)
 Meeting of several nations
calling for reduction or
elimination of CFCs in
products.
 Many manufacturers are
switching to non-CFC
propellants in aerosol
cans.
 You can help by:
 Not buying Styrofoam
products
 If air conditioner leaks, fix it
to prevent release to air.
HOW CAN WE PROTECT THE OZONE
LAYER?
 Describe the process by which chlorofluorcarbons destroy
ozone molecules in the stratosphere.
 Describe the process by which the ozone hole forms over
Antarctica in the spring.
 List five harmful effects that UV radiation could have on
plants or animals as a result of ozone thinning.
 Explain why it will take years for the ozone layer to recover,
even though the use of CFCs has declined significantly.
YOU SHOULD BE ABLE TO…

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Unit 5 b ch 13 s2 the ozone shield

  • 1. Chapter 13, Section 2: the ozone shield Standards: SEV4f ATMOSPHERE & CLIMATE CHANGE
  • 2. • An area in the stratosphere where ozone is highly concentrated. • Ozone (O3) absorbs most of the UV light that comes from the sun. WHAT IS THE OZONE LAYER?
  • 3. Chlorofluorcarbons (CFCs) • When first invented, were valued because they are • Nonpoisonous • Nonflammable • Do not corrode • Were used for decades as • Coolants in refrigerators & air conditioners • Component of Sytrofoam • Propellant in hair spray, deodorant, insecticides & paint • In 1970’s it was discovered they may be damaging the ozone layer. WHAT CHEMICAL IS ATTRIBUTED WITH CAUSING OZONE DEPLETION?
  • 4. • At ground level, CFCs are stable & do not cause problems. • When air currents carry them to the stratosphere they can deplete the ozone. • Takes 10-20 years for the CFC’s to make it to the stratosphere and they get recycled while they are up there so they are persistent for 60-120 years • UV light from sun breaks CFC which releases a chlorine atom. • The chlorine atom breaks a molecule of ozone (O3) into an O2 molecule and an oxygen atom (O) which the chlorine attaches to and creates chlorine monoxide (ClO) • Chlorine monoxide (ClO) hits another ozone and the chlorine breaks off again and attacks another ozone molecule. • 1 chlorine from CFC can destroy 100,000 ozone molecules. HOW DO CFC’S DEPLETE THE OZONE?
  • 5. Ultraviolet light hits a chlorofluorocarbon (CFC) molecule, such as CFCl3, breaking off a chlorine atom and leaving CFCl2. UV radiation Sun Once free, the chlorine atom is off to attack another ozone molecule and begin the cycle again. A free oxygen atom pulls the oxygen atom off the chlorine monoxide molecule to form O2. The chlorine atom and the oxygen atom join to form a chlorine monoxide molecule (ClO) The chlorine atom attacks an ozone (O3) molecule, pulling an oxygen atom off it and leaving an oxygen molecule (O2). Cl Cl Cl C F Cl Cl O O Cl O O O Cl O O O Cl O O
  • 6. 1980’s scientists working in Antarctica noticed a thinning of the ozone by 50-98% that was occurring each spring. WHAT IS “THE OZONE HOLE”?
  • 7.  During the dark winter months, VERY cold strong winds called polar vortex winds trap CFC’s and convert them to molecular Cl2  In the spring, UV rays split Cl2 and the individual Cl atoms break ozone down rapidly.  The thinning lasts for several months. HOW DOES THE OZONE HOLE FORM?
  • 8. Ozone at ground level is highly reactive and reacts with other molecules of air pollution before it can even enter the stratosphere. WHY CAN’T OZONE CREATED AT GROUND LEVEL (AKA- BAD OZONE) HELP HEAL THE OZONE THINNING?
  • 9. UV light can Damage DNA Premature aging Weakened immune system Increase chance of developing cataracts Increase susceptibility to skin cancer WHAT ARE THE EFFECTS OF OZONE THINNING ON HUMANS?
  • 10.  Oceans  Kills phytoplankton which is the bottom of the marine food chain.  Disrupts food chains  Phytoplankton removes CO2 so if they die, CO2 levels would go up in atmosphere (global climate change)  Freshwater  Kill amphibian eggs  Survivors suffer birth defects  Populations decline  Land Plants  Interferes with photosynthesis  Reduces crop yield WHAT ARE THE EFFECTS OF OZONE THINNING ON ANIMALS & PLANTS?
  • 11. Montreal Protocol (1987)  Meeting of several nations calling for reduction or elimination of CFCs in products.  Many manufacturers are switching to non-CFC propellants in aerosol cans.  You can help by:  Not buying Styrofoam products  If air conditioner leaks, fix it to prevent release to air. HOW CAN WE PROTECT THE OZONE LAYER?
  • 12.  Describe the process by which chlorofluorcarbons destroy ozone molecules in the stratosphere.  Describe the process by which the ozone hole forms over Antarctica in the spring.  List five harmful effects that UV radiation could have on plants or animals as a result of ozone thinning.  Explain why it will take years for the ozone layer to recover, even though the use of CFCs has declined significantly. YOU SHOULD BE ABLE TO…