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Covalent Bonding Unit 11
Covalent Bonds Involve sharing outer energy level electrons.
How Are They Different Than Ionic? Ionic bonds work by electromagnetic attraction. A positively charged ion is attracted to a negative ion. Covalent bonds work by sharing electrons. They do not have charges, but are hard to separate due to this sharing.
Cl Cl How will two chlorine atoms react?
Cl Cl Each chlorine atom wants to  gain one electron to achieve an octet
Cl Cl
Cl Cl
Cl Cl
Cl Cl octet
Cl Cl octet circle the electrons for each atom that completes their octets
Cl Cl The octet is achieved by each atom sharing the electron pair in the middle circle the electrons for each atom that completes their octets
Cl Cl The octet is achieved by each atom sharing the electron pair in the middle circle the electrons for each atom that completes their octets
Cl Cl This is the bonding pair circle the electrons for each atom that completes their octets
Cl Cl Single bonds are abbreviated with a dash circle the electrons for each atom that completes their octets
Cl Cl This is the chlorine molecule, Cl2 circle the electrons for each atom that completes their octets
Covalent Bonds Each oxygen has 6 valence electrons and wants two more to have a full octet. 6 electrons 6 electrons
Covalent Bonds If one oxygen shares two electrons with the other, the other has a full octet. 8 electrons – happy! 4 electrons left
Covalent Bonds But, then the other oxygen is short, so it pulls them back. Now the other oxygen shares 2 electrons 4 electrons left 8 electrons – happy!
Covalent Bonds Thus, by each of them sharing two electrons back and forth, they both are at the full octet simultaneously. 8 electrons 8 electrons
O O
O O
O O
O O
O O Both electron pairs are shared.
O O Both electron pairs are shared.
So Who Covalently Bonds? Alkaline or Alkali Earth Metals do not form covalent bonds! Also Halogens are rarely covalently bonded. Mostly it is non-metals in groups 3,4,5, and 6
Electron Distribution . . .  C . Valence Electrons:		    4 Electrons occur in 4 fours separated as far apart as possible
Electron Distribution . . . . .  N  C . . Valence Electrons:		    4		       5 Electrons occur in 4 fours separated as far apart as possible
Electron Distribution . . . . .  N  C . . O . . Valence Electrons:		    4		       5		        6 Electrons occur in 4 fours separated as far apart as possible
Electron Distribution . . . . .  N  C . . O . . Valence Electrons:		    4		       5		        6 Electrons occur in 4 fours separated as far apart as possible Secret Question: Why do electrons first fill orbitals one at a time before pairing up?
Electron Distribution . . . . .  N  C . . O . . Valence Electrons:		    4		       5		        6 Electrons occur in 4 fours separated as far apart as possible Secret Question: Why do electrons first fill orbitals one at a time before pairing up? It is because electrons repel each other and want to be as far apart as possible.
Exception to Octet Rule Boron only has 3 valence electrons, so it is impossible to get to eight via covalent bonding Without 4 valence electrons, the shape of the molecule flattens out. BH3 B . . .
Single Bond Ethane is C2H6
Double Bond Ethene is C2H4
Triple Bond Acetylene is C2H2
Quadruple Bond??? Can not occur, because the last bond can not bend all the way around. Too far to bend Too far to bend Especially since triple bonds are so rigid
Possible Covalent Bonds Only where single electrons are located, can covalent bonds be made. Carbon has 4 single electrons, thus it can make 4 bonds. Nitrogen has 3 single electrons, thus it can make 3 bonds. Oxygen has 2 single electrons, thus it can make 2 bonds.
Double Bonds Revisited Since Oxygen can make two bonds, and Carbon can make four, it makes for some interesting combinations.
Why Carbon is the Key to Life It is precisely because carbon can make 4 bonds, as well as, double and triple bonds, that makes it so critical to life. Carbon chains can form virtually every formation possible.
DNA and the building blocks for life Carbon, plus two other flexible elements, oxygen and nitrogen form the backbone of DNA DNA contains the genetic code for the building of life out of the largest of all molecules, proteins.
Proteins are the largest molecules known

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Unit 11 Power Point

  • 2. Covalent Bonds Involve sharing outer energy level electrons.
  • 3. How Are They Different Than Ionic? Ionic bonds work by electromagnetic attraction. A positively charged ion is attracted to a negative ion. Covalent bonds work by sharing electrons. They do not have charges, but are hard to separate due to this sharing.
  • 4. Cl Cl How will two chlorine atoms react?
  • 5. Cl Cl Each chlorine atom wants to gain one electron to achieve an octet
  • 10. Cl Cl octet circle the electrons for each atom that completes their octets
  • 11. Cl Cl The octet is achieved by each atom sharing the electron pair in the middle circle the electrons for each atom that completes their octets
  • 12. Cl Cl The octet is achieved by each atom sharing the electron pair in the middle circle the electrons for each atom that completes their octets
  • 13. Cl Cl This is the bonding pair circle the electrons for each atom that completes their octets
  • 14. Cl Cl Single bonds are abbreviated with a dash circle the electrons for each atom that completes their octets
  • 15. Cl Cl This is the chlorine molecule, Cl2 circle the electrons for each atom that completes their octets
  • 16. Covalent Bonds Each oxygen has 6 valence electrons and wants two more to have a full octet. 6 electrons 6 electrons
  • 17. Covalent Bonds If one oxygen shares two electrons with the other, the other has a full octet. 8 electrons – happy! 4 electrons left
  • 18. Covalent Bonds But, then the other oxygen is short, so it pulls them back. Now the other oxygen shares 2 electrons 4 electrons left 8 electrons – happy!
  • 19. Covalent Bonds Thus, by each of them sharing two electrons back and forth, they both are at the full octet simultaneously. 8 electrons 8 electrons
  • 20. O O
  • 21. O O
  • 22. O O
  • 23. O O
  • 24. O O Both electron pairs are shared.
  • 25. O O Both electron pairs are shared.
  • 26. So Who Covalently Bonds? Alkaline or Alkali Earth Metals do not form covalent bonds! Also Halogens are rarely covalently bonded. Mostly it is non-metals in groups 3,4,5, and 6
  • 27. Electron Distribution . . . C . Valence Electrons: 4 Electrons occur in 4 fours separated as far apart as possible
  • 28. Electron Distribution . . . . . N C . . Valence Electrons: 4 5 Electrons occur in 4 fours separated as far apart as possible
  • 29. Electron Distribution . . . . . N C . . O . . Valence Electrons: 4 5 6 Electrons occur in 4 fours separated as far apart as possible
  • 30. Electron Distribution . . . . . N C . . O . . Valence Electrons: 4 5 6 Electrons occur in 4 fours separated as far apart as possible Secret Question: Why do electrons first fill orbitals one at a time before pairing up?
  • 31. Electron Distribution . . . . . N C . . O . . Valence Electrons: 4 5 6 Electrons occur in 4 fours separated as far apart as possible Secret Question: Why do electrons first fill orbitals one at a time before pairing up? It is because electrons repel each other and want to be as far apart as possible.
  • 32. Exception to Octet Rule Boron only has 3 valence electrons, so it is impossible to get to eight via covalent bonding Without 4 valence electrons, the shape of the molecule flattens out. BH3 B . . .
  • 36. Quadruple Bond??? Can not occur, because the last bond can not bend all the way around. Too far to bend Too far to bend Especially since triple bonds are so rigid
  • 37. Possible Covalent Bonds Only where single electrons are located, can covalent bonds be made. Carbon has 4 single electrons, thus it can make 4 bonds. Nitrogen has 3 single electrons, thus it can make 3 bonds. Oxygen has 2 single electrons, thus it can make 2 bonds.
  • 38. Double Bonds Revisited Since Oxygen can make two bonds, and Carbon can make four, it makes for some interesting combinations.
  • 39. Why Carbon is the Key to Life It is precisely because carbon can make 4 bonds, as well as, double and triple bonds, that makes it so critical to life. Carbon chains can form virtually every formation possible.
  • 40. DNA and the building blocks for life Carbon, plus two other flexible elements, oxygen and nitrogen form the backbone of DNA DNA contains the genetic code for the building of life out of the largest of all molecules, proteins.
  • 41. Proteins are the largest molecules known