TXSA 111
      CHEMISTRY
SEMESTER 1—JANUARY 2013
 BY: MR PS NKOSI
SYLLABUS
 BASIC CONCEPTS ABOUT MATTER.
 ATOMIC STRUCTURE AND PERIODIC TABLE.
 CHEMICAL BONDING AND INTERMOLECULAR FORCES.
 THE MOLE CONCEPT AND BALANCING CHEMICAL
  EQUATIONS.
 SOLUTION.
 ACIDS AND BASES.
 OXIDATION AND REDUCTION.
 INTRODUCTION TO ORGANIC CHEMISTRY.
 INTRODUCTION TO INORGANIC CHEMISTRY.
……....................................................................................................
             PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies       2
BASIC CONCEPTS ABOUT MATTER
 CHEMISTRY is the study of matter and the changes it
 undergoes.
   Structure
   Properties
 MATTER is all substances of the universe, living and
  non-living.
 It made up of molecules and atoms.
   It can be changed from one state to another by
       Adding or removing heat
       Pressurizing


        PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   3
Matter is usually classified into three classical states of matter,
with plasma sometimes added as a fourth state for scientific purposes.
From left to right: grains of refined sucrose (a solid), water (a liquid), depiction
of particles in a gas, and a plasma globe (plasma).




                       PS Nkosi, Durban University of Technology,
                       Department of Clothing and Textile Studies                      4
The properties of substance can
be used in a number of ways:
1. To identify an unknown substance, e.g in chemistry
   laboratories, crime labs and medical labs.
2. To distinguish between different substances, e.g.
   gold and fake gold.
3. To characterize a newly discovered substance- the
   substance is new if it has a unique set of properties.
4. Predicting the usefulness of a substance for specific
   applications, e.g carbon monoxide is not used as an
   atmosphere in space capsules

      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   5
PHYSICAL PROPERTIES
 This are characteristics of matter that can be observed
 or measured without altering the chemical
 composition and identity of the substance.
   E.g. State, colour, density, melting point, boiling point,
    volume, temperature, mass.




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   6
CHEMICAL PROPERTIES
 This are properties can be observed if a change in
 chemical composition and identity of a substance
 occurs.
   E.g. Charcoal burns, iron rusts




       PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   7
CLASSIFY EACH OF THE
FOLLOWING AS CHEMICAL OR
PHYSICAL
a) A substance is very hard.
b) A substance melts at 48 degrees.
c) A substance is flammable.
d) A substance is green in colour.
e) A substance does not react with chlorine.
f) A substance decomposes on hearting.



      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   8
Classify as : Physical or Chemical
properties.
a) Density
b) Ability to burn
c) Explosiveness
d) Solubility
e) Melting point
f) Corrosiveness




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   9
A PHYSICAL CHANGE
 This is a change which causes no change in
 composition.
   E.g. the melting of ice




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   10
A CHEMICAL CHANGE
 Is one which is accompanied by a change in
  composition.
 It involves the disappearance of one or more
  substances ( reactants) and the appearance of one or
  more new substance (product). These changes are
  referred to as CHEMICAL REACTIONS.




     PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   11
Classify as : Physical or chemical
changes.
a) Freezing water.                                  f) Digesting of food.
b) Rusting of Iron.                                 g) Absorption of a
c) Evaporation of dry                                  vitamin from the
   ice.                                                intestinal tract.
d) Explosion of gun                                 h) Detoxification of a
   powder.                                             drug in the liver.
e) Tearing of paper.                                i) Synthesis of
                                                       protein in muscle
                                                       tissue.
     PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   12
ENERGY
 Is the capacity to do work.
 It can not be destroyed.
 It can be converted from one form into another.
    Gravitational potential energy to kinetic energy.
    Electrical to kinetic.
    Electrical to thermal (heat).




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   13
A PURE SUBSTANCE
 This substance has a definite, invariable composition
 and cannot be separated into simpler substance by
 physical means.

 HOW IS IT TO DETERMINED WHETHER A
 SUBSTANCE IS PURE OR NOT ?




       PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   14
A MIXTURE
 Is a combination of two or more substances in which
 the substances retain their identities.
   i.e. there in no chemical reaction between their
    components.
       The components may be separated by physical means
         E.g. salt + water

       The components may be in any proportion
         E.g. concentrated or diluted orange juice.




        PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   15
A HETEROGENEOUS MIXTURE
 This mixture contain two or more phases.
e.g
   Sausage and cheese pizza
   Concrete
   Sand and water
   Oil and vinegar (salad dressing)
   Blood
   Milk of magnesia



      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   16
A HOMOGENEOUS MIXTURE
 This mixture contain only one phase
e.g.
    Sugar dissolve in water
    Air
    Metal alloys
    Gastric juice
    Spinal tap fluid




       PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   17
Are the following classification a
pure or as mixture?
a) Copper                                           f) Wine
b) Air                                              g) Sulphur
c) Milk                                             h) Sugar solution
d) Water                                            i) Blood
e) Concrete                                         j)      Urine




     PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   18
Are each of the following mixture
homogeneous or heterogeneous?
a) Salt and pepper
b) Alcohol and water
c) Sulphur and iron
d) Two different salts
e) Milk of magnesia suspension
f) 5% dextrose in water (used for injection)




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   19
A MOLECULE
 It made up of atoms which are chemically bonded
  together.
 It can be broken down into smaller units only if
  chemical changes are allowed to take place.




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   20
AN ATOM
 This represents the limits of chemical subdivision of a
 molecule.
   E.g. pure substance can be divided into two classes.




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   21
ELEMENTS
 Are pure substance composed of homoatomic
  molecules i.e atoms of one type.
e.g
   Oxygen (O2)
   Iron (Fe)
   Carbon (C)




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   22
COMPOUNDS
 Are pure substances composed of heteroatomic
 molecules i.e two or more kinds of atoms.
   Carbon dioxide ( CO2)
   Suphuric acid ( H2SO4)
   Sodium chloride (NaCl)




      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   23
Classify these classes as
heterogeneous mixture,
homogeneous mixture, pure
substance, compound, element.
a) In which of these classes must two or more substance
   present?
b) Which of these classes could not possibly contain
   heteroatomic molecules?
c) A variable composition is possible for which of these
   classes?

      PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   24
Classify the following as:
     elements, compounds or no such
     classification
a) Analysis with some elaborate instruments indicates
     that substance A contains only aluminium atoms.
b)   Substance B and substance C react to give a new
     substance D
c)   Substance E decomposes on heating to give substance
     F and substance G.
d)   Heating substance H to 800 degrees causes no change
     in it.
e)   Analysis shows that substance I contains sulphur and
     oxygen.
f)   Heating substance J to 620 degrees causes it to
     change from a solid to a liquid.
         PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   25
Indicate whether each of the following
statements is TRUE or FALSE. If it false,
change it to make it true.
a) Some pure substance may be decomposed into simpler
     substances by chemical change.
b)   The smallest characteristic unit of a pure substance is an
     atom.
c)   Molecules of pure substances are always heteroatomic.
d)   Heterogeneous mixtures can be separated into
     component substance by physical means.
e)   In order for matter to be heterogeneous at least two
     substances must be present.
f)   Pure substance can be variable composite.
g)   The limit of physical subdivision is a molecule.
h)   A compound contain only one type of molecule.

        PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   26
PROPERTIES OF METALS
 Solid (one liquid – mercury)
 Shiny
 Malleable – can be pounded into sheets.
 Ductile – can be drawn into wires.
 High electrical conductivity.
 High thermal conductivity
 Oxides, if soluble, form alkaline solutions in water.
 Tend to form positive ions


       PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   27
PROPERTIES OF NON-METALS
 Generally gases, some solids, one liquid
 Not shiny
 Not malleable nor ductile
 Poor conductors of heat or electricity
 Oxides, if soluble, form acidic solutions in water
 Tend to form negative ions.




       PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies   28
ATOMIC STRUCTURE AND
PERIODIC TABLE.




       PS Nkosi, Durban University of Technology,
       Department of Clothing and Textile Studies   29

Textile science - Chemistry

  • 1.
    TXSA 111 CHEMISTRY SEMESTER 1—JANUARY 2013 BY: MR PS NKOSI
  • 2.
    SYLLABUS  BASIC CONCEPTSABOUT MATTER.  ATOMIC STRUCTURE AND PERIODIC TABLE.  CHEMICAL BONDING AND INTERMOLECULAR FORCES.  THE MOLE CONCEPT AND BALANCING CHEMICAL EQUATIONS.  SOLUTION.  ACIDS AND BASES.  OXIDATION AND REDUCTION.  INTRODUCTION TO ORGANIC CHEMISTRY.  INTRODUCTION TO INORGANIC CHEMISTRY. …….................................................................................................... PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 2
  • 3.
    BASIC CONCEPTS ABOUTMATTER  CHEMISTRY is the study of matter and the changes it undergoes.  Structure  Properties  MATTER is all substances of the universe, living and non-living.  It made up of molecules and atoms.  It can be changed from one state to another by  Adding or removing heat  Pressurizing PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 3
  • 4.
    Matter is usuallyclassified into three classical states of matter, with plasma sometimes added as a fourth state for scientific purposes. From left to right: grains of refined sucrose (a solid), water (a liquid), depiction of particles in a gas, and a plasma globe (plasma). PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 4
  • 5.
    The properties ofsubstance can be used in a number of ways: 1. To identify an unknown substance, e.g in chemistry laboratories, crime labs and medical labs. 2. To distinguish between different substances, e.g. gold and fake gold. 3. To characterize a newly discovered substance- the substance is new if it has a unique set of properties. 4. Predicting the usefulness of a substance for specific applications, e.g carbon monoxide is not used as an atmosphere in space capsules PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 5
  • 6.
    PHYSICAL PROPERTIES  Thisare characteristics of matter that can be observed or measured without altering the chemical composition and identity of the substance.  E.g. State, colour, density, melting point, boiling point, volume, temperature, mass. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 6
  • 7.
    CHEMICAL PROPERTIES  Thisare properties can be observed if a change in chemical composition and identity of a substance occurs.  E.g. Charcoal burns, iron rusts PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 7
  • 8.
    CLASSIFY EACH OFTHE FOLLOWING AS CHEMICAL OR PHYSICAL a) A substance is very hard. b) A substance melts at 48 degrees. c) A substance is flammable. d) A substance is green in colour. e) A substance does not react with chlorine. f) A substance decomposes on hearting. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 8
  • 9.
    Classify as :Physical or Chemical properties. a) Density b) Ability to burn c) Explosiveness d) Solubility e) Melting point f) Corrosiveness PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 9
  • 10.
    A PHYSICAL CHANGE This is a change which causes no change in composition.  E.g. the melting of ice PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 10
  • 11.
    A CHEMICAL CHANGE Is one which is accompanied by a change in composition.  It involves the disappearance of one or more substances ( reactants) and the appearance of one or more new substance (product). These changes are referred to as CHEMICAL REACTIONS. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 11
  • 12.
    Classify as :Physical or chemical changes. a) Freezing water. f) Digesting of food. b) Rusting of Iron. g) Absorption of a c) Evaporation of dry vitamin from the ice. intestinal tract. d) Explosion of gun h) Detoxification of a powder. drug in the liver. e) Tearing of paper. i) Synthesis of protein in muscle tissue. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 12
  • 13.
    ENERGY  Is thecapacity to do work.  It can not be destroyed.  It can be converted from one form into another.  Gravitational potential energy to kinetic energy.  Electrical to kinetic.  Electrical to thermal (heat). PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 13
  • 14.
    A PURE SUBSTANCE This substance has a definite, invariable composition and cannot be separated into simpler substance by physical means.  HOW IS IT TO DETERMINED WHETHER A SUBSTANCE IS PURE OR NOT ? PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 14
  • 15.
    A MIXTURE  Isa combination of two or more substances in which the substances retain their identities.  i.e. there in no chemical reaction between their components.  The components may be separated by physical means  E.g. salt + water  The components may be in any proportion  E.g. concentrated or diluted orange juice. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 15
  • 16.
    A HETEROGENEOUS MIXTURE This mixture contain two or more phases. e.g  Sausage and cheese pizza  Concrete  Sand and water  Oil and vinegar (salad dressing)  Blood  Milk of magnesia PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 16
  • 17.
    A HOMOGENEOUS MIXTURE This mixture contain only one phase e.g.  Sugar dissolve in water  Air  Metal alloys  Gastric juice  Spinal tap fluid PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 17
  • 18.
    Are the followingclassification a pure or as mixture? a) Copper f) Wine b) Air g) Sulphur c) Milk h) Sugar solution d) Water i) Blood e) Concrete j) Urine PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 18
  • 19.
    Are each ofthe following mixture homogeneous or heterogeneous? a) Salt and pepper b) Alcohol and water c) Sulphur and iron d) Two different salts e) Milk of magnesia suspension f) 5% dextrose in water (used for injection) PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 19
  • 20.
    A MOLECULE  Itmade up of atoms which are chemically bonded together.  It can be broken down into smaller units only if chemical changes are allowed to take place. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 20
  • 21.
    AN ATOM  Thisrepresents the limits of chemical subdivision of a molecule.  E.g. pure substance can be divided into two classes. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 21
  • 22.
    ELEMENTS  Are puresubstance composed of homoatomic molecules i.e atoms of one type. e.g  Oxygen (O2)  Iron (Fe)  Carbon (C) PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 22
  • 23.
    COMPOUNDS  Are puresubstances composed of heteroatomic molecules i.e two or more kinds of atoms.  Carbon dioxide ( CO2)  Suphuric acid ( H2SO4)  Sodium chloride (NaCl) PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 23
  • 24.
    Classify these classesas heterogeneous mixture, homogeneous mixture, pure substance, compound, element. a) In which of these classes must two or more substance present? b) Which of these classes could not possibly contain heteroatomic molecules? c) A variable composition is possible for which of these classes? PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 24
  • 25.
    Classify the followingas: elements, compounds or no such classification a) Analysis with some elaborate instruments indicates that substance A contains only aluminium atoms. b) Substance B and substance C react to give a new substance D c) Substance E decomposes on heating to give substance F and substance G. d) Heating substance H to 800 degrees causes no change in it. e) Analysis shows that substance I contains sulphur and oxygen. f) Heating substance J to 620 degrees causes it to change from a solid to a liquid. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 25
  • 26.
    Indicate whether eachof the following statements is TRUE or FALSE. If it false, change it to make it true. a) Some pure substance may be decomposed into simpler substances by chemical change. b) The smallest characteristic unit of a pure substance is an atom. c) Molecules of pure substances are always heteroatomic. d) Heterogeneous mixtures can be separated into component substance by physical means. e) In order for matter to be heterogeneous at least two substances must be present. f) Pure substance can be variable composite. g) The limit of physical subdivision is a molecule. h) A compound contain only one type of molecule. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 26
  • 27.
    PROPERTIES OF METALS Solid (one liquid – mercury)  Shiny  Malleable – can be pounded into sheets.  Ductile – can be drawn into wires.  High electrical conductivity.  High thermal conductivity  Oxides, if soluble, form alkaline solutions in water.  Tend to form positive ions PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 27
  • 28.
    PROPERTIES OF NON-METALS Generally gases, some solids, one liquid  Not shiny  Not malleable nor ductile  Poor conductors of heat or electricity  Oxides, if soluble, form acidic solutions in water  Tend to form negative ions. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 28
  • 29.
    ATOMIC STRUCTURE AND PERIODICTABLE. PS Nkosi, Durban University of Technology, Department of Clothing and Textile Studies 29