Thin films of cadmium sulphide have been prepared using home built spray pyrolysis unit on glass
substrate at 400 C. Aqueous solutions of cadmium chloride and thiourea were used for the cadmium
sulphide (CdS) films and different proportions by weight/volume of mercury II chloride was used for
doping Hg onto cadmium sulphide (Cd1-xHgxS) films. The films obtained are having continuous, smooth
surface with good transmittance. The thickness of all films is of the order of 320 nm. Determination of the
crystalline nature has been done using XRD pattern. The effect of Hg on the surface morphology of CdS
film has been studied by Scanning Electron Microscopy. The optical band gap has been calculated using
the data from transmission spectra. Resistance before and after doping with Hg is also presented in the
paper.
International Journal of Engineering and Science Invention (IJESI)inventionjournals
International Journal of Engineering and Science Invention (IJESI) is an international journal intended for professionals and researchers in all fields of computer science and electronics. IJESI publishes research articles and reviews within the whole field Engineering Science and Technology, new teaching methods, assessment, validation and the impact of new technologies and it will continue to provide information on the latest trends and developments in this ever-expanding subject. The publications of papers are selected through double peer reviewed to ensure originality, relevance, and readability. The articles published in our journal can be accessed online.
Crystal Growth and Studies of Dihydrogen Phosphates of Potassium and Ammonium...IJERA Editor
A nonlinear optical (NLO) material Potassium dihydrogen phosphates (KDP) and Ammonium dihydrogen
phosphates (ADP) are grown by slow evaporation solution growth technique. The FTIR studies confirm the
presence of the functional group in the grown crystal. The optical transmittance studies show that the crystal has
transparence in the entire visible and IR region. The thermal stability of the materials was assessed by TG/DTA
analysis. The mechanical stability of the grown crystals was analyzed by Vicker’s microhardness test. The
dielectric behavior of the crystals was tested by dielectric analysis. The second harmonic generation (SHG) of
KDP is confirmed by Kurtz and Perry powder technique using Nd: YAG laser.
International Journal of Engineering and Science Invention (IJESI)inventionjournals
International Journal of Engineering and Science Invention (IJESI) is an international journal intended for professionals and researchers in all fields of computer science and electronics. IJESI publishes research articles and reviews within the whole field Engineering Science and Technology, new teaching methods, assessment, validation and the impact of new technologies and it will continue to provide information on the latest trends and developments in this ever-expanding subject. The publications of papers are selected through double peer reviewed to ensure originality, relevance, and readability. The articles published in our journal can be accessed online.
Crystal Growth and Studies of Dihydrogen Phosphates of Potassium and Ammonium...IJERA Editor
A nonlinear optical (NLO) material Potassium dihydrogen phosphates (KDP) and Ammonium dihydrogen
phosphates (ADP) are grown by slow evaporation solution growth technique. The FTIR studies confirm the
presence of the functional group in the grown crystal. The optical transmittance studies show that the crystal has
transparence in the entire visible and IR region. The thermal stability of the materials was assessed by TG/DTA
analysis. The mechanical stability of the grown crystals was analyzed by Vicker’s microhardness test. The
dielectric behavior of the crystals was tested by dielectric analysis. The second harmonic generation (SHG) of
KDP is confirmed by Kurtz and Perry powder technique using Nd: YAG laser.
Mechanical Properties of Concrete with Marine Sand as Partial Replacement of ...IJERA Editor
The process of depleting sources of natural aggregates challenges the production of technically and
environmentally adequate concrete. Alternative material from marine sources is good enough for the
replacement of fine aggregate in the concrete. The material was stockpiled in the open air and no washing,
drying or decontamination process was carried out. Physical and chemical properties of DMS material were
determined. All the materials used in the concrete were selected and tested as per the standard procedures of the
Indian standards. A unique design mix will be done based on the entire material test results. Different mixtures
were produced using DMS in different proportions from 15% to 100% as per the finalized trial of the design
mix. The concrete were submitted to compressive strength testsafter 7, 28 and 90 days of moist curing, as well
as flexure and splitting tensile strength tests for M-25 grade.
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology
Influence of Field Assisted Chemical Spray Pyrolysis Deposition Technique on the Structural and Optical Properties of CdS Thin Films
Original Research Article
Journal of Chemistry and Materials Research Vol. 1 (2), 2014, 23–27
U.U. Iwok*, J.A. Bwamba, N.O. Alu, K.K. Adama, Z. Abdullahi, A.C. Egba, A.A. Oberafo, B.O. Akogwu
Thin films of cadmium sulphide have been
successfully deposited by chemical bath deposition (CBD)
technique using a mixed aqueous solution of cadmium
sulphate, thiourea, and triethylamine. The films were
characterized using a variety of techniques. Powder X-ray
diffraction analysis shows that the as-deposited thin film has
the hexagonal (wurtzite) structure. Scanning electron
microscope (SEM) micrographs show the film surface consists
of clusters with a globular surface morphology. Energy
dispersive X-ray diffraction (EDAX) analysis confirmed the
film to be consistent with the formation of cadmium sulphide
on silica glass slide. The band gap, determined from optical
absorption spectroscopy, was 2.42 eV which is consistent with
other published results.
Synthesis and structural characterization of cd s nanocrystals added with pb2+eSAT Journals
Abstract
For the past few years, the prepration and characterization of nanocrystals of materials have become an interesting area in the
research activity. CdS (Cadmium Sulphide) is a well known semi conducting material which finds applications in optical devices.
In the present study, we have made an attempt to investigate the effect of Pb2+ as impurity on the properties of CdS nanocrystals.
The samples were prepared by using simple domestic microwave assisted solvothermal method with ethylene glycol as solvant.
The samples prepared were annealed to have good ordering. X-ray diffraction measurements were carried out for all the smples.
The grain size, lattice parameter and yield were determined. The colour before and after annealing was noted. EDX and SEM
analyses were also done. The prepared samples were electrically characterized by making dielectric measurements on the
prepared pellets. The present study indicates that the polarization mechanism in the nano crystals considered is mainly
contributed by the space charge polarization.
Keywords: Semiconducting II –IV materieals, Cadmium sulphide, XRD patterns, solvothermal method, electrical
measurements
An Investigation of SILAR Grown Cobalt Selenide Thin Films IIJSRJournal
Nowadays, several deposition techniques have been used to produce thin film materials. The obtained films were characterized by using different tools. These semiconductor materials could be employed in solar cell, laser devices and opto-electronic devices. The main objective of this work is to produce cobalt selenide thin films through successive ionic layer adsorption and reaction method. Advantages of this method include simple procedures, inexpensive equipment, it does not need expensive vacuum system and high quality substrate. During the deposition process, the films were deposited onto soda lime glass under various anionic bath immersion times. The properties of the films were studied for the first time via field emission scanning electron microscopy (FESEM) and UV-visible spectrophotometer. Based on the FESEM analysis, uniform morphology could be observed for the sample produced for 30 seconds (anionic immersion time). The band gap was about 2.6 eV and the optical transmission increased in the visible region could be detected for these samples.
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...IJARIIT
The structure and ion conductivity of Nd2Mo2O9powders were synthesized by using Nd(NO2)3, MoO3, and aspartic acid (fuel) in assisted combustion method with heating at 550˚C for 6 hours. The thermal decomposition, phase identification, morphology, ionic conductivity of the samples were studied by TGA/DTA, XRD and SEM four probe D.C. method respectively. The formation of Nd2Mo2O9 was confirmed by FTIR studies. The synthesis and crystallization were followed by thermochemical techniques (TGA/DTA) studies. The synthesized materials showed reasonable ionic conductivity. These results indicate that assisted combustion method is a promising method to prepare nanocrystalline Nd2Mo2O9 for solid oxide fuel cell.
Synthesis and Characterization of Mn, Ce Co-Doped CDS Nanoparticles Synthesiz...IJMER
Mn, Ce co-doped CdS nanoparticles were prepared by chemical co-precipitation method at room temperature. The prepared samples were characterized by X- ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis of X-rays (EDAX), photoluminescence (PL) and
high resolution Raman spectroscopic techniques. X-ray diffraction studies showed that the diameter of the particles was around 10-12 nm. Broadened XRD peaks revealed the formation of nanoparticles with wurtzite structure. The Raman spectra of undoped and Mn, Ce ions co-doped CdS nanoparticles showed longitudinal optical mode. Compared with the 1LO and 2LO Raman modes (296 and 590 cm-1
) of undoped CdS nanoparticles, the Raman modes of Mn, Ce co- doped CdS nanoparticles were slightly shifted towards lower frequency. PL spectra of the samples showed remarkable enhancement in the intensity upon doping
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...EROMOR
In this work, (Sn, Cr) co-doped In2O3 polycrystalline films were grown at room temperature by sputtering method using a base pressure of ∼5×10−2mbar (a low vacuum condition) in order to improve the oxidation process and reduce the time of films production.
OPTICAL BEHAVIOUR OF SYNTHESIZED ZNO NANOTABLETS AND ITS TRANSFORMED NANORODS...antjjournal
We are reporting the preparation of ZnO nanotablets at relatively low temperature (1500C) using zinc acetate [Zn(Ac)2], NaOH, cetyltrimethylammonium bromide (CTAB) by solvothermal method. By adjusting
the molar ratio of the reactants we obtained nanorods and we also obtained the variation of the dimension
of the nanorods using hydrazine hydrate as capping reagent. The prepared samples were morphologically
recognized as well crystallized. The average diameter of the ZnO nanotablets were ranging from 500 to 600 nm and the average thickness of the nanotablets were ranging from 85 to 90 nm. The length of ZnO nanorods were ranging from 300 to several micrometers and breadth of the ZnO nanorods were ranging from 80 to 160 nm. The optical properties of the prepared materials have also been studied with the exhibition of its interesting behavior.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
LGS crystal which melts congruently at 1470⁰C has been grown by Czochralski method. The langasite
crystal of length about 1cm grown along its Z-axis was cut in X and Y directions , polished and
subjected to various characterization studies. Phase and structure of the grown crystal was confirmed by
Powder XRD measurement. FTIR spectrum was carried out to confirm the functional groups present in
the grown crystals. The optical behavior was studied by UV–vis-NIR analysis. Electrical properties such as Dielectric constant, Resistivity, Conductivity and Piezoelectric coefficient have also been studied.
Pure and Al substituted Langanite
(La3Ga5.5Nb0.5O14) ceramics have been synthesized
by solid state sintering method and studied their
structural, dielectric and electrical properties. The
crystalline nature was confirmed by powder XRD
studies. The ac conductivity and dielectric
properties of La3Ga5.5-xAlxNb0.5O14 samples were
examined by using complex impedance technique.
Surface morphology and elemental composition
were studied by energy-dispersive x-ray
spectroscopy and scanning electron microscopy.
The frequency dependence of dielectric constant,
dielectric loss and AC conductivity were studied in
the frequency range of 100 KHz to 3 MHz at
different temperatures. The activation energy was
calculated using Arrhenius plot. The lattice
parameter, grain size, dielectric constant and AC
conductivity of pure LGN ceramics were deeply
affected by Al substitution in pure LGN.
Aluminum doped cadmium selenide tin films of different compositions, (0.1-1.0 mol %) deposited by dip
coating method on cleaned glass substrates at room temperature. All the films are polycrystalline nature
having hexagonal structure. For all the films the preferred orientation is (100). Some other orientations like
(101), (110), (112) (202) (203) are also observed in the films. The values of interplanar distance, dislocation
density, microstrain, lattice parameters, volume of unit cell, number of crystallites per unit area and particle
size of the aluminum doped thin films were calculated and their variation with dopant concentration was
studied. Interplanar distance, intensity, lattice parameters, volume of unit cell and particle size increases up
to 0.25mol % of aluminum. Microstrain, dislocation density and number of crystallite per unit area decreases
up to 0.25mol % aluminum concentration
Morphological and Optical Study of Sol-Gel SpinCoated Nanostructured CdSThin ...iosrjce
Nanostructured CdS thin films of different thicknesses were deposited on a cleaned glass substrate
using sol-gel spin coating technique. CdS thin films were prepared using cadmium acetate as cadmium source
and thiourea as sulfur source. The Morphological, chemical composition, and optical properties of the spin- coated
CdS thin film were studied using field emission- scanning electron microscopy (FE-SEM), Energy dispersive X –ray
(EDX) spectroscopy, and a UV-Vis-NIR spectrophotometer.The morphological results revealed that the films consist
of agglomerated spherical CdS nanoparticles with diameter < 20 nm, which distributed uniformly on the substrate
surface.The films show high transmittance > 90% and very strong absorption edge at 295 nm.The absorption edge
shifts towards longer wavelength as the film thickness increased.
Mechanical Properties of Concrete with Marine Sand as Partial Replacement of ...IJERA Editor
The process of depleting sources of natural aggregates challenges the production of technically and
environmentally adequate concrete. Alternative material from marine sources is good enough for the
replacement of fine aggregate in the concrete. The material was stockpiled in the open air and no washing,
drying or decontamination process was carried out. Physical and chemical properties of DMS material were
determined. All the materials used in the concrete were selected and tested as per the standard procedures of the
Indian standards. A unique design mix will be done based on the entire material test results. Different mixtures
were produced using DMS in different proportions from 15% to 100% as per the finalized trial of the design
mix. The concrete were submitted to compressive strength testsafter 7, 28 and 90 days of moist curing, as well
as flexure and splitting tensile strength tests for M-25 grade.
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology
Influence of Field Assisted Chemical Spray Pyrolysis Deposition Technique on the Structural and Optical Properties of CdS Thin Films
Original Research Article
Journal of Chemistry and Materials Research Vol. 1 (2), 2014, 23–27
U.U. Iwok*, J.A. Bwamba, N.O. Alu, K.K. Adama, Z. Abdullahi, A.C. Egba, A.A. Oberafo, B.O. Akogwu
Thin films of cadmium sulphide have been
successfully deposited by chemical bath deposition (CBD)
technique using a mixed aqueous solution of cadmium
sulphate, thiourea, and triethylamine. The films were
characterized using a variety of techniques. Powder X-ray
diffraction analysis shows that the as-deposited thin film has
the hexagonal (wurtzite) structure. Scanning electron
microscope (SEM) micrographs show the film surface consists
of clusters with a globular surface morphology. Energy
dispersive X-ray diffraction (EDAX) analysis confirmed the
film to be consistent with the formation of cadmium sulphide
on silica glass slide. The band gap, determined from optical
absorption spectroscopy, was 2.42 eV which is consistent with
other published results.
Synthesis and structural characterization of cd s nanocrystals added with pb2+eSAT Journals
Abstract
For the past few years, the prepration and characterization of nanocrystals of materials have become an interesting area in the
research activity. CdS (Cadmium Sulphide) is a well known semi conducting material which finds applications in optical devices.
In the present study, we have made an attempt to investigate the effect of Pb2+ as impurity on the properties of CdS nanocrystals.
The samples were prepared by using simple domestic microwave assisted solvothermal method with ethylene glycol as solvant.
The samples prepared were annealed to have good ordering. X-ray diffraction measurements were carried out for all the smples.
The grain size, lattice parameter and yield were determined. The colour before and after annealing was noted. EDX and SEM
analyses were also done. The prepared samples were electrically characterized by making dielectric measurements on the
prepared pellets. The present study indicates that the polarization mechanism in the nano crystals considered is mainly
contributed by the space charge polarization.
Keywords: Semiconducting II –IV materieals, Cadmium sulphide, XRD patterns, solvothermal method, electrical
measurements
An Investigation of SILAR Grown Cobalt Selenide Thin Films IIJSRJournal
Nowadays, several deposition techniques have been used to produce thin film materials. The obtained films were characterized by using different tools. These semiconductor materials could be employed in solar cell, laser devices and opto-electronic devices. The main objective of this work is to produce cobalt selenide thin films through successive ionic layer adsorption and reaction method. Advantages of this method include simple procedures, inexpensive equipment, it does not need expensive vacuum system and high quality substrate. During the deposition process, the films were deposited onto soda lime glass under various anionic bath immersion times. The properties of the films were studied for the first time via field emission scanning electron microscopy (FESEM) and UV-visible spectrophotometer. Based on the FESEM analysis, uniform morphology could be observed for the sample produced for 30 seconds (anionic immersion time). The band gap was about 2.6 eV and the optical transmission increased in the visible region could be detected for these samples.
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...IJARIIT
The structure and ion conductivity of Nd2Mo2O9powders were synthesized by using Nd(NO2)3, MoO3, and aspartic acid (fuel) in assisted combustion method with heating at 550˚C for 6 hours. The thermal decomposition, phase identification, morphology, ionic conductivity of the samples were studied by TGA/DTA, XRD and SEM four probe D.C. method respectively. The formation of Nd2Mo2O9 was confirmed by FTIR studies. The synthesis and crystallization were followed by thermochemical techniques (TGA/DTA) studies. The synthesized materials showed reasonable ionic conductivity. These results indicate that assisted combustion method is a promising method to prepare nanocrystalline Nd2Mo2O9 for solid oxide fuel cell.
Synthesis and Characterization of Mn, Ce Co-Doped CDS Nanoparticles Synthesiz...IJMER
Mn, Ce co-doped CdS nanoparticles were prepared by chemical co-precipitation method at room temperature. The prepared samples were characterized by X- ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis of X-rays (EDAX), photoluminescence (PL) and
high resolution Raman spectroscopic techniques. X-ray diffraction studies showed that the diameter of the particles was around 10-12 nm. Broadened XRD peaks revealed the formation of nanoparticles with wurtzite structure. The Raman spectra of undoped and Mn, Ce ions co-doped CdS nanoparticles showed longitudinal optical mode. Compared with the 1LO and 2LO Raman modes (296 and 590 cm-1
) of undoped CdS nanoparticles, the Raman modes of Mn, Ce co- doped CdS nanoparticles were slightly shifted towards lower frequency. PL spectra of the samples showed remarkable enhancement in the intensity upon doping
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...EROMOR
In this work, (Sn, Cr) co-doped In2O3 polycrystalline films were grown at room temperature by sputtering method using a base pressure of ∼5×10−2mbar (a low vacuum condition) in order to improve the oxidation process and reduce the time of films production.
OPTICAL BEHAVIOUR OF SYNTHESIZED ZNO NANOTABLETS AND ITS TRANSFORMED NANORODS...antjjournal
We are reporting the preparation of ZnO nanotablets at relatively low temperature (1500C) using zinc acetate [Zn(Ac)2], NaOH, cetyltrimethylammonium bromide (CTAB) by solvothermal method. By adjusting
the molar ratio of the reactants we obtained nanorods and we also obtained the variation of the dimension
of the nanorods using hydrazine hydrate as capping reagent. The prepared samples were morphologically
recognized as well crystallized. The average diameter of the ZnO nanotablets were ranging from 500 to 600 nm and the average thickness of the nanotablets were ranging from 85 to 90 nm. The length of ZnO nanorods were ranging from 300 to several micrometers and breadth of the ZnO nanorods were ranging from 80 to 160 nm. The optical properties of the prepared materials have also been studied with the exhibition of its interesting behavior.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
LGS crystal which melts congruently at 1470⁰C has been grown by Czochralski method. The langasite
crystal of length about 1cm grown along its Z-axis was cut in X and Y directions , polished and
subjected to various characterization studies. Phase and structure of the grown crystal was confirmed by
Powder XRD measurement. FTIR spectrum was carried out to confirm the functional groups present in
the grown crystals. The optical behavior was studied by UV–vis-NIR analysis. Electrical properties such as Dielectric constant, Resistivity, Conductivity and Piezoelectric coefficient have also been studied.
Pure and Al substituted Langanite
(La3Ga5.5Nb0.5O14) ceramics have been synthesized
by solid state sintering method and studied their
structural, dielectric and electrical properties. The
crystalline nature was confirmed by powder XRD
studies. The ac conductivity and dielectric
properties of La3Ga5.5-xAlxNb0.5O14 samples were
examined by using complex impedance technique.
Surface morphology and elemental composition
were studied by energy-dispersive x-ray
spectroscopy and scanning electron microscopy.
The frequency dependence of dielectric constant,
dielectric loss and AC conductivity were studied in
the frequency range of 100 KHz to 3 MHz at
different temperatures. The activation energy was
calculated using Arrhenius plot. The lattice
parameter, grain size, dielectric constant and AC
conductivity of pure LGN ceramics were deeply
affected by Al substitution in pure LGN.
Aluminum doped cadmium selenide tin films of different compositions, (0.1-1.0 mol %) deposited by dip
coating method on cleaned glass substrates at room temperature. All the films are polycrystalline nature
having hexagonal structure. For all the films the preferred orientation is (100). Some other orientations like
(101), (110), (112) (202) (203) are also observed in the films. The values of interplanar distance, dislocation
density, microstrain, lattice parameters, volume of unit cell, number of crystallites per unit area and particle
size of the aluminum doped thin films were calculated and their variation with dopant concentration was
studied. Interplanar distance, intensity, lattice parameters, volume of unit cell and particle size increases up
to 0.25mol % of aluminum. Microstrain, dislocation density and number of crystallite per unit area decreases
up to 0.25mol % aluminum concentration
Morphological and Optical Study of Sol-Gel SpinCoated Nanostructured CdSThin ...iosrjce
Nanostructured CdS thin films of different thicknesses were deposited on a cleaned glass substrate
using sol-gel spin coating technique. CdS thin films were prepared using cadmium acetate as cadmium source
and thiourea as sulfur source. The Morphological, chemical composition, and optical properties of the spin- coated
CdS thin film were studied using field emission- scanning electron microscopy (FE-SEM), Energy dispersive X –ray
(EDX) spectroscopy, and a UV-Vis-NIR spectrophotometer.The morphological results revealed that the films consist
of agglomerated spherical CdS nanoparticles with diameter < 20 nm, which distributed uniformly on the substrate
surface.The films show high transmittance > 90% and very strong absorption edge at 295 nm.The absorption edge
shifts towards longer wavelength as the film thickness increased.
Equivalent Dielectric property of hydrogenated carbon nitride film in CH4/N2 ...inventionjournals
International Journal of Engineering and Science Invention (IJESI) is an international journal intended for professionals and researchers in all fields of computer science and electronics. IJESI publishes research articles and reviews within the whole field Engineering Science and Technology, new teaching methods, assessment, validation and the impact of new technologies and it will continue to provide information on the latest trends and developments in this ever-expanding subject. The publications of papers are selected through double peer reviewed to ensure originality, relevance, and readability. The articles published in our journal can be accessed online.
Study Of Structural, Morphological And Optical Properties Of Pure CdO And Ag:...IOSRJAP
Pure and Ag doped CdO thin films were prepared by sol-gel technique with spin coating method on glass substrates, Ag:CdO doped with relatively high concentration Ag (2.5%, 5%, 10% and 15%) to obtain changes in structural, Optical And Morphological properties of Ag:CdO doped thin films at fixed annealing temperature (300◦ C), the results Shows changes in structural properties at (111) plane due to fixed annealing temperature, and decreasing in direct energy gap, and show changes in roughness average.
Influence of Synthesizing Temperatures on the Crystallinity, Morphology and B...AI Publications
CdSe thin films were deposited using Chemical Bath Deposition (CBD) by maintaining the bath at 20 °C, 40 °C, 60 °C and 80 °C temperatures. The thin films were deposited on ordinary glass substrates then characterized for their crystallinity, morphological and optical properties. From the X-ray Diffraction (XRD) analysis; it was revealed that there was a significant difference in crystallinity and the UV-vis spectroscopy enhanced the study of the energy band gaps which showed a drastic shifting. The study performed on the surface morphologies of the CdSe thin films exhibited a double layer of deposition; but did not show considerable difference from each other for different temperatures. The EDS pattern helped in determining the stoichiometric ratio.
Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...IJLT EMAS
In this article, different substrates for deposition of
CdS material have been discussed. Till date glass, mica, quartz,
ceramic, etc. are commonly employed substrates in thin film
growth. In the present work, CdS is deposited on Teflon
substrate by chemical bath deposition (CBD) method. Also the
films were deposited on different substrates like glass, copper
and zinc and compared with those prepared on Teflon substrate.
The films prepared on Teflon substrate were uniform, stable and
also showed good radiating property. These films were further
characterized by UV-VIS absorption spectral studies, SEM and
EDS studies.
Synthesis and application of natural dye sensitizd cds thin films as photoano...eSAT Journals
Abstract
Natural dyes obtained from plants, vegetables and fruits are widely studied and tested as low cost sensitizer for dye sensitized solar cell ( DSSC) in order to replace the rare and expensive inorganic and organic sensitizers. Although, many works have been done using TiO2, ZrO2, ZnO etc. as the nanoporous semiconductor, little importance was given to the use of CdS thin film as a cost effective alternative. In the present study CdS thin films were synthesized by chemical bath deposition (CBD) technique and its optical, structural and morphological properties were investigated by XRD, SEM and UV-Vis absorption spectroscopy. The as synthesized films were found to be nanoporous in nature and are favorable for adsorbing the dyes on to its surface. Two natural dyes extracted from locally available plant leaves namely lawsonia inermis linn and caesalpinia pulcherrima were then adsorbed on the as synthesized CdS thin films for the formation of the working electrode for application in DSSC. The interaction between the nanoporous CdS thin films and the natural dyes were investigated through UV-Vis absorption spectroscopy with an aim to fabricate working electrode for application in DSSC.
Keywords: DSSC, thin film, CdS, natural dyes
Properties of CdS Chemically Deposited thin films on the Effect of Ammonia Co...IOSR Journals
The effect of ammonia concentration on electrical properties, optical properties and structural properties of chemical bath deposited (CBD) Cadmium sulphide (CdS) thin films has been revealed. The films were prepared by using cadmium acetate as cadmium ion (Cd2+) source, thiourea as sulphur ion (S2-) source and ammonia as the complexing agent. Ammonia concentration was changed from 0.1 M – 3.0 M. Ammonia concentration at 2.0 M uniform, dense and continuously coated films were obtained. Not only typical cadmium-pure but also unusual sulphur deficiency phenomena were observed for CBD CdS thin films. In the present investigation, the carrier concentration varied form 1.831X106cm-3 to 1.026X106cm-3 when ammonia concentration is changed from 0.5M to 2.5 M. The direct band gap energy at 0.5M is 1.92eV while at 2.5M is 2.65eV. The surface morphology of as deposited thin films is almost smooth and no grains were observed clearly at low molar concentration and predominant grains at the concentration of ammonia is 2.0M. By estimated Cd:S ratio value is found to be 1.04 by using EDAX. The thin film deposited at 2.0M concentration shows the highest degree crystallinity. The formation mechanism of the films with various ammonia concentrations is discussed.
5 ijaems jun-2015-19-x-ray diffraction of multilayer cd s-polyaniline thin filmsINFOGAIN PUBLICATION
In the present investigation, the films of Cadmium Sulphide and Polyaniline have been prepared by vacuum Evaporation Technique. The growth and characterization of single layer and multilayer films have been done. In this paper, the study of X-Ray diffraction of multilayer CdS/Polyaniline thin films has been done.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
Crystal Growth and Studies of Dihydrogen Phosphates of Potassium and Ammonium...IJERA Editor
A nonlinear optical (NLO) material Potassium dihydrogen phosphates (KDP) and Ammonium dihydrogen
phosphates (ADP) are grown by slow evaporation solution growth technique. The FTIR studies confirm the
presence of the functional group in the grown crystal. The optical transmittance studies show that the crystal has
transparence in the entire visible and IR region. The thermal stability of the materials was assessed by TG/DTA
analysis. The mechanical stability of the grown crystals was analyzed by Vicker’s microhardness test. The
dielectric behavior of the crystals was tested by dielectric analysis. The second harmonic generation (SHG) of
KDP is confirmed by Kurtz and Perry powder technique using Nd: YAG laser.
Comparative Analysis of Optical Properties of Cdo Annealed thin Film deposite...AI Publications
Cadmium oxide transparent thin film is deposited by spray pyrolysis technique on glass subtract at 4000C and annealed at a temperature of 100 °C for one hour. The band gap was found depend on varius parameters is studied. It is noted that the shift in band gap i.e. decrease with the increasing film thickness in the range 2.15 eV to 2.40 eV. The optical constants such as, band gap, refractive index, extinction coefficient as a function of photon energy for all prepared films were calculated. also studied The XRD revealed of thin film of CdO shows polycrystalline in nature
A Front Surface Optimization Study for Photovoltaic ApplicationTELKOMNIKA JOURNAL
In this paper, we presented a possible front surface optical enhancement of Si solar cell by
optimizing the Antireflection (AR) and light trapping (LT) schemes. Conventional plasma enhanced
chemical vapor deposition (PECVD) and in house hot wire chemical vapor deposition (HWCVD) tool was
used to deposit Silicon Nitride (SiNX) layer and optimized at 668nm wavelength. This was followed by
surface texturing of random pyramids to further enhance the broadband reflectance of the front surface.
Broadband reflectance measurement using integrating sphere method showed achieved weighted average
reflectance (WAR) value of as low as 1.8% and 1.5%, when 85nm SiNX was deposited on top of random
pyramids structure using HWCVD and PECVD methods, respectively.
Detecting of NH3, CO2 polluted gases by using ZnO- In2O3 thin filmsijceronline
International Journal of Computational Engineering Research (IJCER) is dedicated to protecting personal information and will make every reasonable effort to handle collected information appropriately. All information collected, as well as related requests, will be handled as carefully and efficiently as possible in accordance with IJCER standards for integrity and objectivity.
Similar to STRUCTURAL, OPTICAL AND ELECTRICAL STUDIES ON SPRAY DEPOSITED MERCURY DOPED CADMIUM SULPHIDE THIN FILMS (20)
On the Unification of Physic and the Elimination of Unbound Quantitiesijrap
This paper supports Descartes' idea of a constant quantity of motion, modernized by Leibniz. Unlike Leibniz, the paper emphasizes that the idea is not realized by forms of energy, but by energy itself. It remains constant regardless of the form, type, or speed of motion, even that of light. Through force, energy is only transformed. Here it is proved that force is its derivative. It exists even at rest, representing the object's minimal energy state. With speed, we achieve its multiplication up to the maximum energy state, from which a maximum force is derived from the object. From this point, corresponding to Planck's Length, we find the value of the force wherever we want. Achieving this removes the differences between various natural forces. The new idea eliminates infinite magnitudes. The process allows the laws to transition from simple to complex forms and vice versa, through differentiation-integration. For this paper, this means achieving the Unification Theory.
Gravity Also Redshifts Light – the Missing Phenomenon That Could Resolve Most...ijrap
In this paper I discover that gravity also redshifts light like the velocity of its source does. When light travels towards a supermassive object, its waves (or photons) undergo continuous stretching, thereby shifting towards lower frequencies. Gravity redshifts light irrespective of whether its source is in motion or static with respect to its observer. An equation is derived for gravitational redshift, and a formula for combined redshift is presented by considering both the velocity, and gravity redshifts. Also explained is how frequencies of electromagnetic spectrum continuously downgrade as a light beam of mix frequencies passes towards a black hole. Further, a clear methodology is provided to figure out whether expansion of the universe is accelerating or decelerating, or alternatively, the universe is contracting.
In this paper I present a new theory that explains as to when and how dark energy is created as mass is destroyed. The theory extends Einstein’s mass energy equation to a more generic form in order to make it work even in high gravity conditions. It also explains why dark energy is created. Further, it is proved Einstein’s mass energy equation holds good only when the destroyed mass has no supermassive object in its close vicinity. The relationship between dark energy and dark matter is unveiled. An extended mathematical form of Einstein’s mass energy equation is derived, based on which the conditions leading to dark energy creation are explained. Three new physical parameters called dark energy discriminant, dark energy radius and dark energy boundary are introduced to facilitate easy understanding of the theory. It is explained in detail that an extremely superdense object has two dark energy boundaries, outer and inner. Mass destroyed only between these two boundaries creates dark energy. Dark energy space, the space between the two aforementioned boundaries, shrouds visible matter in obscurity from optical and electromagnetic telescopes. This theory identifies Gargantuan as a superdense black hole currently creating fresh dark energy, which could be the subject of interest for the astronomical research community having access to sophisticated telescopes, and working on dark energy. It also upholds dark energy and denies the existence of dark matter. Dark matter is nothing but the well-known visible matter positioned in dark energy space. An important relationship is derived between a photon’s frequency and its distance from a black hole to demonstrate the effect of gravity on light. Another important fact revealed by this theory is gravity stretches out light, thereby causing redshift, which is unaccounted in the computation of velocities of outer galaxies. Whether the universe is undergoing accelerated or decelerated expansion, or accelerated contraction can precisely be determined only after accounting for the redshift caused by gravity
International Journal on Soft Computing, Artificial Intelligence and Applicat...ijrap
International Journal on Soft Computing, Artificial Intelligence and Applications (IJSCAI)
is an open access peer-reviewed journal that provides an excellent international forum for sharing
knowledge and results in theory, methodology and applications of Artificial Intelligence, Soft
Computing. The Journal looks for significant contributions to all major fields of the Artificial
Intelligence, Soft Computing in theoretical and practical aspects. The aim of the Journal is to
provide a platform to the researchers and practitioners from both academia as well as industry to
meet and share cutting-edge development in the field.
Authors are solicited to contribute to the journal by submitting articles that illustrate research
results, projects, surveying works and industrial experiences that describe significant advances in
the areas of Database management systems.
SOME THEORETICAL ASPECTS OF HYDROGEN DIFFUSION IN BCC METALS AT LOW TEMPERATURESijrap
Purpose of the work is to discuss some theoretical aspects of the diffusion of hydrogen atoms in the crystal
lattice of BCC metals at low temperatures using the methods of statistical thermodynamics. The values of
the statistical model calculations of H diffusion coefficients in α-Fe, V, Ta, Nb, K are in good agreement
with the experimental data. The statistical model can also explain deviations from the Arrhenius equation
at temperatures 300-100 K in α-Fe, V, Nb and K. It was suggested that thermally activated fast tunnelling
transition of hydrogen atoms through the potential barrier at a temperature below 300 K provides an
almost free movement of H atoms in the α-Fe and V lattice at these temperatures. The results show that
quantum-statistical effects play a decisive role in the H diffusion in BCC metals at low temperatures. Using
the statistical model allows for the prediction of the diffusion coefficient for H in BCC metals at low
temperatures, where it’s necessary to consider quantum effects.
MASSIVE PHOTON HYPOTHESIS OPENS DOORS TO NEW FIELDS OF RESEARCHijrap
Mass, an inherent property of matter, is calculated directly for the photon particle from the very classical
principles of the kinetic theory of gases. It is not an end result with no perspective nor other outcome.
Quite the opposite, a single ponderable tiny photon frees the mind of old ways of thinking and opens up
new paths to a broad field of investigation where the very large can then be described and explained by the
very small. This reality of a non-zero mass suddenly shows up in the interpretation of many experiments
which become clear and simple to comprehend. Besides, that same key particle has the potential to unlock
and solve some long lasting major observational issues or enigmas. All this converges upon its
acknowledgement and acceptance.
PHENOMENOLOGICAL METHOD REGARDING A THIRD THEORY OF PHYSICS “THE EVENT:THE TH...ijrap
The quest for a third theory uniting macro-cosmos (relativity) and micro-cosmos (quantum mechanics) has coexisted with the denial of feminine/subjective polarity to masculine/objective. The dismissal of electromagnetism as the tension of opposites in quest of inner/outer unity is sourced in the denial of the feminine qualia -- the negative force field attributed to dark energy/dark matter. However, a conversion philosophy sourced in the hieros gamos and signified by the Mobius strip has formulated an integral consciousness methodology producing quantum objects by means of embracing the shadow haunting contemporary physics. This Self-reflecting process integrating subject/object comprises an ontology of kairos as the “quantum leap.” An interdisciplinary quest to create a phenomenological narrative is disclosed via a holistic apparatus of hermeneutics manifesting image/text of a contemporary grail journey. Reflected in this Third space is the sacred reality of autonomous number unifying polarities of feminine/subjective (quality) and objective/masculine (quantity) as new measurement apparatus for the quantum wave collapse.
3rd International Conference on Integrating Technology in Education (ITE 2022)ijrap
3rd International Conference on Integrating Technology in Education (ITE 2022) This forum also aims to provide a platform for exchanging ideas in new emerging trends that needs more focus and exposure and will attempt to publish proposals that strengthen our goals.
A SPECIAL RELATIONSHIP BETWEEN MATTER, ENERGY, INFORMATION, AND CONSCIOUSNESSijrap
This paper discusses the advantages of describing the universe, or nature, in terms of information and consciousness. Some problems encountered by theoretical physicists in the quest for the theory of everything stem from the limitations of trying to understand everything in terms of matter and energy only. However, if everything, including matter, energy, life, and mental processes, is described in terms of information and consciousness, much progress can be made in the search for the ultimate theory of the universe. As brilliant and successful as physics and chemistry have been over the last two centuries, it is important that nature is not viewed solely in terms of matter and energy. Two additional components are needed to unlock her secrets. While extensive writing exists that describes the connection between matter and energy and their physical basis, little work has been done to learn the special relationship between matter, energy, information, and consciousness.
This paper discusses the advantages of describing the universe, or nature, in terms of information and consciousness. Some problems encountered by theoretical physicists in the quest for the theory of everything stem from the limitations of trying to understand everything in terms of matter and energy only. However, if everything, including matter, energy, life, and mental processes, is described in terms of information and consciousness, much progress can be made in the search for the ultimate theory of the universe. As brilliant and successful as physics and chemistry have been over the last two centuries, it is important that nature is not viewed solely in terms of matter and energy. Two additional components are needed to unlock her secrets. While extensive writing exists that describes the connection between matter and energy and their physical basis, little work has been done to learn the special relationship between matter, energy, information, and
consciousness.
THE CONCEPT OF SPACE AND TIME: AN AFRICAN PERSPECTIVEijrap
Understanding the concept of space and time is critical, essential, and fundamental in searching for theall-encompassing theory or the theory of everything (ToE). Some physicists argue that time exists, whileothers posit that time is only a social or mental construct. The author presents an African thought systemon space and time conception, focusing on the African (Bantu) view of space and time. The author arguesthat before the advent of the Western linear view of space and time, Africans had their own visionregarding these two concepts. Their conception of time appears to be holistic, highly philosophical, non-linear, and thought-provoking. The author hopes that exploring these two concepts from an African perspective will provide a new and more in-depth insight into reality's nature. A scientific investigation of space and time from an African-centered perspective is a worthy and necessary endeavor in the quest forthe ToE
Learning to Pronounce as Measuring Cross Lingual Joint Orthography Phonology ...ijrap
Machine learning models allow us to compare languages by showing how hard a task in each language might be to learn and perform well on. Following this line of investigation, we explore what makes a language “hard to pronounce” by modelling the task of grapheme-to-phoneme (g2p) transliteration. By training a character-level transformer model on this task across 22 languages and measuring the model’s proficiency against its grapheme and phoneme inventories, we show that certain characteristics emerge that separate easier and harder languages with respect to learning to pronounce. Namely the complexity of a language's pronunciation from its orthography is due to the expressive or simplicity of its grapheme-to phoneme mapping. Further discussion illustrates how future studies should consider relative data sparsity per language to design fairer cross-lingual comparison tasks.
THE CONCEPT OF SPACE AND TIME: AN AFRICAN PERSPECTIVEijrap
Understanding the concept of space and time is critical, essential, and fundamental in searching for the all-encompassing theory or the theory of everything (ToE). Some physicists argue that time exists, while others posit that time is only a social or mental construct. The author presents an African thought system on space and time conception, focusing on the African (Bantu) view of space and time. The author argues
that before the advent of the Western linear view of space and time, Africans had their own vision
regarding these two concepts. Their conception of time appears to be holistic, highly philosophical, nonlinear, and thought-provoking. The author hopes that exploring these two concepts from an African
perspective will provide a new and more in-depth insight into reality's nature. A scientific investigation of space and time from an African-centered perspective is a worthy and necessary endeavor in the quest for the ToE.
International Journal of Recent advances in Physics (IJRAP)ijrap
International Journal of Recent advances in Physics (IJRAP) is a peer-reviewed, open access journal, addresses the impacts and challenges of Physics. The journal documents practical and theoretical results which make a fundamental contribution for the development of Physics.
The Concept of Space and Time: An African Perspectiveijrap
Understanding the concept of space and time is critical, essential, and fundamental in searching for the all-encompassing theory or the theory of everything (ToE). Some physicists argue that time exists, while others posit that time is only a social or mental construct. The author presents an African thought system on space and time conception, focusing on the African (Bantu) view of space and time. The author argues that before the advent of the Western linear view of space and time, Africans had their own vision regarding these two concepts. Their conception of time appears to be holistic, highly philosophical, nonlinear, and thought-provoking. The author hopes that exploring these two concepts from an African perspective will provide a new and more in-depth insight into reality's nature. A scientific investigation of space and time from an African-centered perspective is a worthy and necessary endeavor in the quest for the ToE.
The majority of physicists take it for granted that the universe is made up of matter. In turn, matter is composed of atoms; atoms are made up of particles such as electrons, protons, neutrons, etc. Also, protons
and neutrons are composed of quarks, etc. Furthermore, that everything in nature is governed by the known laws of physics and chemistry. The author only partially shares this view. He argues that many phenomena in the universe may depend on rules or factors as yet incorporated by the physical sciences.
The last few years have led him to reflect on the many unsolved physics problems, such as the quest for the theory of everything (ToE), the arrow of time, the interpretation of quantum mechanics, the fine-tuned
universe, etc. to mention just a few. The author posits that a field carries information, performs various mathematical and computational operations, and behaves as an intelligent entity embedded with consciousness.
Call For Papers - International Journal of Recent advances in Physics (IJRAP)ijrap
International Journal of Recent advances in Physics (IJRAP) is a peer-reviewed, open access journal, addresses the impacts and challenges of Physics. The journal documents practical and theoretical results which make a fundamental contribution for the development of Physics.
Call For Papers - International Journal of Recent advances in Physics (IJRAP)ijrap
International Journal of Recent advances in Physics (IJRAP) is a peer-reviewed, open access journal, addresses the impacts and challenges of Physics. The journal documents practical and theoretical results which make a fundamental contribution for the development of Physics.
Call For Papers - International Journal of Recent advances in Physics (IJRAP)ijrap
International Journal of Recent advances in Physics (IJRAP) is a peer-reviewed, open access journal, addresses the impacts and challenges of Physics. The journal documents practical and theoretical results which make a fundamental contribution for the development of Physics.
Call For Papers - International Journal of Recent advances in Physics (IJRAP)ijrap
International Journal of Recent advances in Physics (IJRAP) is a peer-reviewed, open access journal, addresses the impacts and challenges of Physics. The journal documents practical and theoretical results which make a fundamental contribution for the development of Physics
Unlock TikTok Success with Sociocosmos..SocioCosmos
Discover how Sociocosmos can boost your TikTok presence with real followers and engagement. Achieve your social media goals today!
https://www.sociocosmos.com/product-category/tiktok/
Buy Pinterest Followers, Reactions & Repins Go Viral on Pinterest with Socio...SocioCosmos
Get more Pinterest followers, reactions, and repins with Sociocosmos, the leading platform to buy all kinds of Pinterest presence. Boost your profile and reach a wider audience.
https://www.sociocosmos.com/product-category/pinterest/
Enhance your social media strategy with the best digital marketing agency in Kolkata. This PPT covers 7 essential tips for effective social media marketing, offering practical advice and actionable insights to help you boost engagement, reach your target audience, and grow your online presence.
Your Path to YouTube Stardom Starts HereSocioCosmos
Skyrocket your YouTube presence with Sociocosmos' proven methods. Gain real engagement and build a loyal audience. Join us now.
https://www.sociocosmos.com/product-category/youtube/
Improving Workplace Safety Performance in Malaysian SMEs: The Role of Safety ...AJHSSR Journal
ABSTRACT: In the Malaysian context, small and medium enterprises (SMEs) experience a significant
burden of workplace accidents. A consensus among scholars attributes a substantial portion of these incidents to
human factors, particularly unsafe behaviors. This study, conducted in Malaysia's northern region, specifically
targeted Safety and Health/Human Resource professionals within the manufacturing sector of SMEs. We
gathered a robust dataset comprising 107 responses through a meticulously designed self-administered
questionnaire. Employing advanced partial least squares-structural equation modeling (PLS-SEM) techniques
with SmartPLS 3.2.9, we rigorously analyzed the data to scrutinize the intricate relationship between safety
behavior and safety performance. The research findings unequivocally underscore the palpable and
consequential impact of safety behavior variables, namely safety compliance and safety participation, on
improving safety performance indicators such as accidents, injuries, and property damages. These results
strongly validate research hypotheses. Consequently, this study highlights the pivotal significance of cultivating
safety behavior among employees, particularly in resource-constrained SME settings, as an essential step toward
enhancing workplace safety performance.
KEYWORDS :Safety compliance, safety participation, safety performance, SME
“To be integrated is to feel secure, to feel connected.” The views and experi...AJHSSR Journal
ABSTRACT: Although a significant amount of literature exists on Morocco's migration policies and their
successes and failures since their implementation in 2014, there is limited research on the integration of subSaharan African children into schools. This paperis part of a Ph.D. research project that aims to fill this gap. It
reports the main findings of a study conducted with migrant children enrolled in two public schools in Rabat,
Morocco, exploring how integration is defined by the children themselves and identifying the obstacles that they
have encountered thus far. The following paper uses an inductive approach and primarily focuses on the
relationships of children with their teachers and peers as a key aspect of integration for students with a migration
background. The study has led to several crucial findings. It emphasizes the significance of speaking Colloquial
Moroccan Arabic (Darija) and being part of a community for effective integration. Moreover, it reveals that the
use of Modern Standard Arabic as the language of instruction in schools is a source of frustration for students,
indicating the need for language policy reform. The study underlines the importanceof considering the
children‟s agency when being integrated into mainstream public schools.
.
KEYWORDS: migration, education, integration, sub-Saharan African children, public school
Surat Digital Marketing School is created to offer a complete course that is specifically designed as per the current industry trends. Years of experience has helped us identify and understand the graduate-employee skills gap in the industry. At our school, we keep up with the pace of the industry and impart a holistic education that encompasses all the latest concepts of the Digital world so that our graduates can effortlessly integrate into the assigned roles.
This is the place where you become a Digital Marketing Expert.
Grow Your Reddit Community Fast.........SocioCosmos
Sociocosmos helps you gain Reddit followers quickly and easily. Build your community and expand your influence.
https://www.sociocosmos.com/product-category/reddit/
Multilingual SEO Services | Multilingual Keyword Research | Filosemadisonsmith478075
Multilingual SEO services are essential for businesses aiming to expand their global presence. They involve optimizing a website for search engines in multiple languages, enhancing visibility, and reaching diverse audiences. Filose offers comprehensive multilingual SEO services designed to help businesses optimize their websites for search engines in various languages, enhancing their global reach and market presence. These services ensure that your content is not only translated but also culturally and contextually adapted to resonate with local audiences.
Visit us at -https://www.filose.com/
STRUCTURAL, OPTICAL AND ELECTRICAL STUDIES ON SPRAY DEPOSITED MERCURY DOPED CADMIUM SULPHIDE THIN FILMS
1. International Journal of Recent advances in Physics (IJRAP) Vol.3, No.1, February 2014
17
STRUCTURAL, OPTICAL AND ELECTRICAL STUDIES
ON SPRAY DEPOSITED MERCURY DOPED CADMIUM
SULPHIDE THIN FILMS
Vijaya M G
Department of Physics, MGM College, Udupi 576 102, Karnataka.
ABSTRACT :
Thin films of cadmium sulphide have been prepared using home built spray pyrolysis unit on glass
substrate at 400 C. Aqueous solutions of cadmium chloride and thiourea were used for the cadmium
sulphide (CdS) films and different proportions by weight/volume of mercury II chloride was used for
doping Hg onto cadmium sulphide (Cd1-xHgxS) films. The films obtained are having continuous, smooth
surface with good transmittance. The thickness of all films is of the order of 320 nm. Determination of the
crystalline nature has been done using XRD pattern. The effect of Hg on the surface morphology of CdS
film has been studied by Scanning Electron Microscopy. The optical band gap has been calculated using
the data from transmission spectra. Resistance before and after doping with Hg is also presented in the
paper.
KEY WORDS: spray pyrolysis, CdS thin film, (Cd1-xHgxS)
1. INTRODUCTION
A layer of material having thickness of the order of few nanometres is generally called ‘thin film’.
The surface effect and interface effects are mainly responsible for the thin films to exhibit
completely different properties from the bulk. The use of thin film has been growing at rapidly
increasing rate due to their potential applications in various fields of science & technology. There
are different physical and chemical methods for preparing thin films namely - pulsed laser
deposition, ion beam sputtering, thermal evaporation, vacuum deposition, chemical vapour
deposition, co-precipitation, sol-gel, chemical bath deposition etc. Chemical spray pyrolysis
technique, because of its simplicity and inexpensiveness has found to be better chemical method
for the preparation of thin films with larger area. It also provides an easy method of doping an
element in the required proportion through solution method. It is found that in the chemical spray
pyrolysis technique, various parameters like air pressure, rate of deposition, substrate
temperature, distance between nozzle to substrate, cooling rate after deposition affect the
physical, electrical and optical properties of the thin films [1-4]. Cadmium Sulphide (CdS) is a
semiconductor belonging to II-VI group of compounds which has been used in making
heterojunction thin solar cells. CdS is preferred because it is a wide band gap semiconductor
having good thermal stability & can be used as light dependent resistors sensitive to visible &
near infrared light. The addition of different dopants to different extents has also found to alter the
properties of pure CdS thin films [4-9]. The effect of Hg on structural, optical and electrical
properties of CdS on glass substrate obtained by newly fabricated spray pyrolysis unit has been
reported in the paper.
2. International Journal of Recent advances in Physics (IJRAP) Vol.3, No.1, February 2014
18
2. FABRICATION OF THE INSTRUMENT
Figure 1 shows the photograph of the home built spray pyrolysis unit fabricated with the help of
Neha Scientific Internationals, Bengaluru, India. It contains a spray nozzle, a heater for heating
the substrate, thermocouple included temperature controller and an air compressor. The spraying
system and heater are kept inside a metallic chamber of size 90 cm × 60 cm × 80 cm and the
outlet of the box is connected to an exhaust fan to remove the toxic gases produced during the
experiment. The inner surface of the box is coated with epoxy liquid to reduce the heat loss
through the surface.
Figure 1. Photograph of spray pyrolysis unit
3. EXPERIMENTAL DETAILS
In the preparation of Sample 1, pure CdS thin film, an equal amount of solutions of 0.1 M
cadmium chloride (pure CdCl2 H2O procured from Sisco Research Laboratories, India) and 0.2
M thiourea (pure CH4N2S procured from Sisco Research Laboratories, India) was mixed with
distilled water in the ratio of 3:2. Different volumes of Mercury II chloride (procured from
MERCK, India) of 0.02 M were used, for Hg doped CdS films. Solutions of cadmium sulphide
and Mercury II chloride were taken in the volume ratio of 5:1 respectively for Sample 2, 4:1 for
Sample 3 and 2:1 for Sample 4. In the preparation of all samples, cleaned glass substrate was
maintained at a temperature of 4000
C, the distance between nozzle & substrate was kept at 25 cm
and the solution was sprayed at a rate of 15 cm3
per minute. The thickness of the films was
calculated using gravimetric method and the average thickness of the film deposited was found to
be 320 nm.
4. RESULTS AND DISCUSSION
4.1. Structural study and Surface morphology
XRD patterns obtained using XRD, Miniflex 600, Rigaku corporation - Japan, for pure CdS,
Sample 1 and Hg doped CdS, Sample 2 is shown in Figure 2. XRD patterns for the other doped
samples are also similar to that of Sample 2. This clearly indicates that, the crystallinity is lost
with the addition of Mercury as dopant.
3. International Journal of Recent advances in Physics (IJRAP) Vol.3, No.1, February 2014
19
Figure 2. XRD spectra
Figure 3 shows the SEM micrographs obtained using SEM EVO MA18 with Oxford EDS (X-
act) for pure CdS, Sample 1 and Hg doped CdS, Sample 2. There are some spheroid shape growth
appears as the creation of nucleation centre on the film surface. These are probably aggregates
due to colloidal particles formed in solution & then absorbed on the film.
Figure 3. SEM micrographs
4.2. Compositional studies
During deposition, Hg was incorporated with different concentrations. Hence Cd was substituted
by Hg in the films. Figure 4.1 and 4.2 shows EDX spectra of Samples 1 and 2.
Figure 4.1 EDX spectra
4. International Journal of Recent advances in Physics (IJRAP) Vol.3, No.1, February 2014
20
Figure 4. EDX spectra
Table 1 shows the quantitative results of pure CdS and Hg doped CdS from EDX analysis.
Sulphur deficiency has been observed in all the films. This may be due to the fact that Sulphur
has great affinity towards Oxygen, so it might have converted to SO2 and then evaporated. A
strong peak is observed which corresponds to Si due to substrate. At high operating voltage, the
electron beam penetrates the film and reaches the glass surface, which results in the Si peak. For
different concentrations of Hg in the solution, there is also Hg peak in the spectra. This confirms
the presence of Mercury atoms in the doped sample.
Table 1. Quantitative results from EDX analysis
5. International Journal of Recent advances in Physics (IJRAP) Vol.3, No.1, February 2014
21
4.3. Optical studies
The optical band gap of all the films was calculated using the transmission spectra obtained in the
region 300 nm to 800 nm using SHIMADZU UV-3600, UV-VIS-NIR spectrophotometer.
Figure 5. Energy gap of pure CdS Figure 6. Energy gap of CdS doped with Hg
All films have good transmittance greater than 75%. The optical band gap was estimated [10]
using the relation,
α h ν = A ( h ν - Eg )n
(1)
where, α is the absorption coefficient, Eg is the band gap corresponding to a particular transition,
A is a constant, ν is the transition frequency and n characterizes the nature of band transition. α
the absorbance, is calculated [10], using the relation
α = [ln(1/T)] / d (2)
where T is the raw transmission data obtained from the experiment and d is the thickness of the
film expressed in cm.
The graph of ( hν) verses ( α h ν )2
is shown in Figure 5 & 6. The extrapolation of the linear
region of the curve with X-axis gives the value of energy band gap of thin films. Energy gap for
pure cadmium sulphide is found to be 2.42 eV which is in good agreement with the earlier reports
[2,4]. Addition of mercury as dopant has found to decrease the energy gap considerably to 1.9 eV.
4.4. Electrical resistance
Resistance of CdS films doped with Hg by different compositions is shown in Figure 7. The
decrease is resistance may be explained on the basis of formation of Cd ions or Cd vacancies
being formed for charge compensation.
Figure 7. Variation of resistance with concentration of Mercury
During the film deposition, Mercury replaces divalent cadmium & there is every possibility of
formation of Cd ions rather than Cd vacancies as Hg and Cd are deposited simultaneously.
6. International Journal of Recent advances in Physics (IJRAP) Vol.3, No.1, February 2014
22
5. CONCLUSIONS
Cadmium sulphide thin films were deposited by homemade spray pyrolysis unit using solutions
of cadmium chloride and thiourea. Mercury doped films were prepared by adding solution of
mercury II chloride in different proportions of volume. The films were deposited onto glass
substrate at temperature of 400° C. The films obtained were found to be uniform, smooth and
compact. The XRD studies suggest that addition of mercury results in the loss of crystallinity.
SEM micrographs show that addition of mercury has no considerable effect on the surface
morphology. The optical studies have shown that, with the addition of mercury, the energy gap
has been decreased from 2.42 eV to 1.9 eV. Study on electrical resistance has shown an
enhancement in the conductivity with the addition of mercury atoms as dopants.
REFERENCES
[1] Goswani A, Book on ‘Thin film fundamentals’. New Age International (P) Ltd, 2008
[2] Jae- Hyeong Lee ‘Structural and optical properties of CdS thin films on organic substrates for
flexible solar cell applications’ J Electroceram, 17 (2006) 1103-1108
[3] O A Ileperuma et al, ‘Comparison of CdS thin films prepared by different techniques for
applications in solar cells as window materials’, Jl. of Mat. Sci., 9 (1998) 367 – 372
[4] A Palafox et al, ‘Physical properties of CdS and CdS:In thin films obtained by chemical spray
over different substrates’, Solar Energy Materials and Solar Cells, 55 (1998) 31-41
[5] V Ciupina, C Baan, A Petcu, A Petcu and G Prodan. ‘On the optical properties of CdS thin films’
Journal of optoelectronics and advanced materials, 10 (2008) 665 – 667
[6] Bhavana Godbale, Nitu Badera, S B Shrivatsav and V Ganesan. ‘A simple chemical spray
pyrolysis apparatus for thin film preparation’, Jl. of Ins. Soc. of India, 39 (2009) 42 – 45
[7] R S Meshram, B M Suryavanshi & R M Thombre.‘Structural and optical properties of CdS thin films
obtained by spray pyrolysis. Advances in Applied Sci. Res.,3 (2012) 1563-1571
[8] C Santiago Tepantlan et al ‘Structural, optical and electrical properties of CdS thin films obtained
by spray pyrolysis’. Revista Mexicana de fisica, 54 (2008) 112-117
[9] A Hasnet and J Podder. ‘Structural and electrical transport properties of CdS and Al-doped CdS thin
films deposited by spray pyrolysis’. Journal of Sci. Res., 4 (2012) 11-19
[10] Sze S M, Book on ‘Physics of Semiconductor devices’, New York; Wiley 2edn, 1969
Author :
M G VIJAYA
Obtained M.Sc. from Mysore university in 1983, M.Phil. from Mangalore
university in 1987 and Ph.D. from Mangalore university in 2005. Joined the
teaching profession in 1985 and currently working in Mahatma Gandhi
Memorial College, Udupi, Karnataka, India. Attended many conferences and
given number of invited lectures on various topics in Physics for students of
neighbouring schools & colleges.