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Mineral Composition of Tap Water in
Israel
The possible deficiency of
magnesium as a result of
desalinated water use
Vasiliy V. Rosen1
Yona Chen2
Orit Gal Garber1
1ZBM Analytical Laboratory
2The Department of Soil and Water Sciences
The Hebrew University of Jerusalem
The Robert H Smith Faculty of Agriculture, Food and Environment
1
Introduction
➢ The problem of drinking water deficiency.
➢ Sea water desalination as a solution.
The State of Israel: 4 desalination plants working.
2
Introduction
Water Authority
2015
3
Introduction
After Rejwan A., 2011. The State of Israel: National Water Efficiency Report
(www.water.gov.il)
Desalinated water
➢ Desalinated water as a drinking water:
possible health problem. 4
Introduction
Patients were not supplied
by desalinated water (total 3078)
Patients were supplied
by desalinated water (total 1600)
5
SURVIVAL
%
Mg in the tap water : Israel Ministry of Health data
July-September 2016
North, South and Center regions
Minimal Mg concentration in drinking water,
recommended by WHO (10 mg L-1)
After http://www.health.gov.il,
Periodical Reports of Water Quality (in Hebrew)
Introduction
6
Mg in the tap water : Israel Ministry of Health data
July-September 2016 After http://www.health.gov.il,
Periodical Reports of Water Quality (in Hebrew)
27
samples
Introduction
7
❑ How much Mg does the tap water contain?
❑ Does the tap water contain some harmful
elements?
❑ Do we need to perform the home filtration
of the tap water?
❑ What are the main mineral components of our
tap water?
8
Sampling points on the map (28 points)
9
The area with highest population density was investigat
10
Sampling points
11
❑ How much Mg does the
tap water contain?
12
27
samples
13
14
Water is ranked from
moderately hard to very
hard
How much Mg do we need?
USA recommendations
15
How much Mg do we need?
UK recommendations
16
Assumptions
❑ Drinking water demand is 2 L per day
❑ Tap water is the only source of drinking water
❑ RNI is 300 mg Mg per day
17
Assumptions
❑ Drinking water demand is 2 L per day
❑ Bottled water is the only source of drinking water
❑ RNI is 300 mg Mg per day
Bottled water
18
19
Mineral composition of tap water in several Israel cities in 2008
Cation/Anion Ramat A Sharon
Rehovot (Campus of the
Faculty of Agriculture)
Rehovot (city center) Aloney Aba Nes Ziona Tel Aviv Carmiel
ICP-OES data
Ca 79.3 92.1 127.9 48.99 120.57 83.87 94.8
Mg 37.7 23.8 32.32 32.78 15.5 34.11 37.7
Na 74.24 60.9 74.12 74.36 72.49 74.52 29.3
K 7.02 1.82 2.29 11.12 1.92 7.94 2.0
B 0.06 0.07 0.048 0.069 0.082 0.067 0.018
Ba 0.09 0.13 0.10 0.055 0.087 0.10 0.04
Cu <0.002 0.08 0.04 0.012 0.02 <0.002 0.09
Fe <0.001 0.61 <0.001 <0.001 <0.001 0.01 <0.001
Li 0.01 0.07 0.003 0.022 0.0028 0.01 0.0013
Si 6.48 9.04 10.98 3.737 8.18 6.74 6.04
Sr 0.82 0.50 0.84 0.698 0.39 0.75 0.21
Zn 0.08 2.73 0.13 0.015 0.83 0.22 0.25
IC data
F-
0.58 0.32 0.12 0.79 0.1 0.58 0.4
Cl
-
165 108 181 255 116 179 38
NO2
-
0.31 0.82 0.18 <0.01 0.13 0.16 0.08
Br-
0.58 0.87 0.32 1.41 0.25 0.73 0.04
NO3
-
4.31 54 58 0.04 62 17.1 3.28
SO4
2-
41 41 45 64 64 41 1.8
PO4
3-
0.02 1.04 0.05 0.04 0.04 0.02 0.11
Total (Ca+Mg) hardness
as mg/L CaCO3
349 323 446 255 359 346 387
Ca/Mg Ratio 2.1 3.9 4.0 1.5 7.8 2.5 2.5
Hardness very hard very hard very hard very hard very hard very hard very hard
mg L
-1
2016
Mineral composition of tap water in several Israel cities in 2008
20
❑ What are the main mineral components of our
tap water?
❑ Does the tap water contain some harmful
elements?
21
ICP-OES data (mg L-1)
Ion Chromatograph data (mg L-1)
The main
components are:
Chlorides and
Sulfates (and
Bicarbonates) of
Ca, Na, Mg and K.
Toxic elements are
<LOQ
22
The daily changes of the tap water mineral content
Mg 7.16±4.8
CV=67.3%
Mg
9.53±4.4
CV=46.3%
Mg
4.96±0.03
CV=0.67%
3.3 % of
RNI
6.4 % of
RNI
4.8 % of
RNI
23
❑ Do we need to perform the home filtration
of the tap water?
24
❑From 23.7 to 45.6% (depending on city) of the interviewed
Israel citizens use home water filter of any kind.
25
Brita filter experiment
Rehovot tap water
26
Brita filter experiment
Jerusalem tap water
27
❑ How much Mg does the tap water contain?
❑ Does the tap water contain some harmful
elements?
❑ Do we need to perform the home filtration
of the tap water?
❑ What are the main mineral components of our
tap water?
Not pretty
much
Chlorides and sulphates
of Ca, Mg, Na and K
NO
NO!
28
ACKNOWLEGEMENTS
❑To Adi Maoz (M.Sc.): water survey in 2008
❑To Sarah Steiner (M.Sc.): IC water analyses
❑To all our sampling volunteers, especially to all “Dr.Golik”
company staff and specially to Darina Rosen (B.Sc., MBA)
29

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Rosen 2017 Isranalytica Mg in Tap Water.pdf

  • 1. Mineral Composition of Tap Water in Israel The possible deficiency of magnesium as a result of desalinated water use Vasiliy V. Rosen1 Yona Chen2 Orit Gal Garber1 1ZBM Analytical Laboratory 2The Department of Soil and Water Sciences The Hebrew University of Jerusalem The Robert H Smith Faculty of Agriculture, Food and Environment 1
  • 2. Introduction ➢ The problem of drinking water deficiency. ➢ Sea water desalination as a solution. The State of Israel: 4 desalination plants working. 2
  • 4. Introduction After Rejwan A., 2011. The State of Israel: National Water Efficiency Report (www.water.gov.il) Desalinated water ➢ Desalinated water as a drinking water: possible health problem. 4
  • 5. Introduction Patients were not supplied by desalinated water (total 3078) Patients were supplied by desalinated water (total 1600) 5 SURVIVAL %
  • 6. Mg in the tap water : Israel Ministry of Health data July-September 2016 North, South and Center regions Minimal Mg concentration in drinking water, recommended by WHO (10 mg L-1) After http://www.health.gov.il, Periodical Reports of Water Quality (in Hebrew) Introduction 6
  • 7. Mg in the tap water : Israel Ministry of Health data July-September 2016 After http://www.health.gov.il, Periodical Reports of Water Quality (in Hebrew) 27 samples Introduction 7
  • 8. ❑ How much Mg does the tap water contain? ❑ Does the tap water contain some harmful elements? ❑ Do we need to perform the home filtration of the tap water? ❑ What are the main mineral components of our tap water? 8
  • 9. Sampling points on the map (28 points) 9
  • 10. The area with highest population density was investigat 10
  • 12. ❑ How much Mg does the tap water contain? 12
  • 14. 14 Water is ranked from moderately hard to very hard
  • 15. How much Mg do we need? USA recommendations 15
  • 16. How much Mg do we need? UK recommendations 16
  • 17. Assumptions ❑ Drinking water demand is 2 L per day ❑ Tap water is the only source of drinking water ❑ RNI is 300 mg Mg per day 17
  • 18. Assumptions ❑ Drinking water demand is 2 L per day ❑ Bottled water is the only source of drinking water ❑ RNI is 300 mg Mg per day Bottled water 18
  • 19. 19 Mineral composition of tap water in several Israel cities in 2008
  • 20. Cation/Anion Ramat A Sharon Rehovot (Campus of the Faculty of Agriculture) Rehovot (city center) Aloney Aba Nes Ziona Tel Aviv Carmiel ICP-OES data Ca 79.3 92.1 127.9 48.99 120.57 83.87 94.8 Mg 37.7 23.8 32.32 32.78 15.5 34.11 37.7 Na 74.24 60.9 74.12 74.36 72.49 74.52 29.3 K 7.02 1.82 2.29 11.12 1.92 7.94 2.0 B 0.06 0.07 0.048 0.069 0.082 0.067 0.018 Ba 0.09 0.13 0.10 0.055 0.087 0.10 0.04 Cu <0.002 0.08 0.04 0.012 0.02 <0.002 0.09 Fe <0.001 0.61 <0.001 <0.001 <0.001 0.01 <0.001 Li 0.01 0.07 0.003 0.022 0.0028 0.01 0.0013 Si 6.48 9.04 10.98 3.737 8.18 6.74 6.04 Sr 0.82 0.50 0.84 0.698 0.39 0.75 0.21 Zn 0.08 2.73 0.13 0.015 0.83 0.22 0.25 IC data F- 0.58 0.32 0.12 0.79 0.1 0.58 0.4 Cl - 165 108 181 255 116 179 38 NO2 - 0.31 0.82 0.18 <0.01 0.13 0.16 0.08 Br- 0.58 0.87 0.32 1.41 0.25 0.73 0.04 NO3 - 4.31 54 58 0.04 62 17.1 3.28 SO4 2- 41 41 45 64 64 41 1.8 PO4 3- 0.02 1.04 0.05 0.04 0.04 0.02 0.11 Total (Ca+Mg) hardness as mg/L CaCO3 349 323 446 255 359 346 387 Ca/Mg Ratio 2.1 3.9 4.0 1.5 7.8 2.5 2.5 Hardness very hard very hard very hard very hard very hard very hard very hard mg L -1 2016 Mineral composition of tap water in several Israel cities in 2008 20
  • 21. ❑ What are the main mineral components of our tap water? ❑ Does the tap water contain some harmful elements? 21
  • 22. ICP-OES data (mg L-1) Ion Chromatograph data (mg L-1) The main components are: Chlorides and Sulfates (and Bicarbonates) of Ca, Na, Mg and K. Toxic elements are <LOQ 22
  • 23. The daily changes of the tap water mineral content Mg 7.16±4.8 CV=67.3% Mg 9.53±4.4 CV=46.3% Mg 4.96±0.03 CV=0.67% 3.3 % of RNI 6.4 % of RNI 4.8 % of RNI 23
  • 24. ❑ Do we need to perform the home filtration of the tap water? 24
  • 25. ❑From 23.7 to 45.6% (depending on city) of the interviewed Israel citizens use home water filter of any kind. 25
  • 28. ❑ How much Mg does the tap water contain? ❑ Does the tap water contain some harmful elements? ❑ Do we need to perform the home filtration of the tap water? ❑ What are the main mineral components of our tap water? Not pretty much Chlorides and sulphates of Ca, Mg, Na and K NO NO! 28
  • 29. ACKNOWLEGEMENTS ❑To Adi Maoz (M.Sc.): water survey in 2008 ❑To Sarah Steiner (M.Sc.): IC water analyses ❑To all our sampling volunteers, especially to all “Dr.Golik” company staff and specially to Darina Rosen (B.Sc., MBA) 29