SUBJECT - CHEMICAL REACTION ENGINEERING – 1
What Is Recycle Reactor ??
 In certain situations it is found to be advantageous to
divide the product stream from a plug flow reactor and
return a portion of it to the entrance of the reactor.
 Let the recycle ratio R be defined as :
What Is Recycle Reactor ??
 This recycle ratio can be made to vary from zero to
infinity.
 Reflection suggests that as the recycle ratio is
raised the behaviour shifts from plug (R=0) to
mixed flow.
 Thus recycling provides a means for obtaining
various degrees of backmixing with a plug flow
reactor.
 Let us develop the performance equation for the
recycle reactor.
Recycle Reactor
 Figure of Recycle Reactor :
Derivation Of Performance
Equation
 Consider a recycle reactor with nomenclature as shown
in figure. Across the reactor itself equation for plug flow
gives,
 ---------(1)
 Where F’A0 would be the feed rate of A if the stream
entering the reactor (fresh feed plus recycle) were
unconverted.
Derivation Of Performance
Equation
 Since F’A0 and XA1 are not known directly, they
must be written in terms of known quantities before
the above equation can be used.
 The flow entering the reactor includes both fresh
feed and the recycle stream. Measuring the flow
split at point L we then have
 Now to evaluate XA1 from above equation we can
write ;
 ------- (2)
 Now, equation of CA1 can be written as ;
----(3)
Combining Eqns (2) & (3) we will get ;
----------(4)
Finally putting value of (4) in Eqn (1) we will get ;
Conversion :
Concentration :
These expressions are represented graphically in Fig. 6.14.
Advantages
 Less time required for desired
conversion than the PFR due to Back
Mixing
 We can get different percentage of
conversion by only changing Recycle
Ratio
Disadvantages
 Fixed cost is high because of higher
volume of reactor required
 Operating cost is also high due to
recycle
 Volume requred is higher than PFR
due to recycle
 Conversion is also less than PFR
Application
 The production unit in which we want
high conversion as well as production
in Lesser time then we can use this
type of reactor.
 It is generally used in petroleum
industry and when the system is
needed to recycle such as Enzyme
Rich stream back into the reactor.
Recycle Reactor (Basics & Design Eqn)
Recycle Reactor (Basics & Design Eqn)

Recycle Reactor (Basics & Design Eqn)

  • 1.
    SUBJECT - CHEMICALREACTION ENGINEERING – 1
  • 2.
    What Is RecycleReactor ??  In certain situations it is found to be advantageous to divide the product stream from a plug flow reactor and return a portion of it to the entrance of the reactor.  Let the recycle ratio R be defined as :
  • 3.
    What Is RecycleReactor ??  This recycle ratio can be made to vary from zero to infinity.  Reflection suggests that as the recycle ratio is raised the behaviour shifts from plug (R=0) to mixed flow.  Thus recycling provides a means for obtaining various degrees of backmixing with a plug flow reactor.  Let us develop the performance equation for the recycle reactor.
  • 4.
    Recycle Reactor  Figureof Recycle Reactor :
  • 5.
    Derivation Of Performance Equation Consider a recycle reactor with nomenclature as shown in figure. Across the reactor itself equation for plug flow gives,  ---------(1)  Where F’A0 would be the feed rate of A if the stream entering the reactor (fresh feed plus recycle) were unconverted.
  • 6.
    Derivation Of Performance Equation Since F’A0 and XA1 are not known directly, they must be written in terms of known quantities before the above equation can be used.  The flow entering the reactor includes both fresh feed and the recycle stream. Measuring the flow split at point L we then have
  • 7.
     Now toevaluate XA1 from above equation we can write ;  ------- (2)  Now, equation of CA1 can be written as ; ----(3)
  • 8.
    Combining Eqns (2)& (3) we will get ; ----------(4) Finally putting value of (4) in Eqn (1) we will get ; Conversion : Concentration :
  • 9.
    These expressions arerepresented graphically in Fig. 6.14.
  • 13.
    Advantages  Less timerequired for desired conversion than the PFR due to Back Mixing  We can get different percentage of conversion by only changing Recycle Ratio
  • 14.
    Disadvantages  Fixed costis high because of higher volume of reactor required  Operating cost is also high due to recycle  Volume requred is higher than PFR due to recycle  Conversion is also less than PFR
  • 15.
    Application  The productionunit in which we want high conversion as well as production in Lesser time then we can use this type of reactor.  It is generally used in petroleum industry and when the system is needed to recycle such as Enzyme Rich stream back into the reactor.