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REcent advances in
Natural Dyeing
Mr. Muksit Ahamed Chowdhury
Associate Professor
Department of Textile Engineering
Ms. Nahida Akter
Assistant Professor
Department of Textile Engineering
Presented For Presented By
Abidur Rahman Lisun | 170206097
Arindam Dey Gourov | 170206102
Saima Hossain Shanta | 170206104
MD.Zamil Hasan Talukder | 170206142
Mahim Karmaker Mugdha | 170106130
What is Dye?
It is a colouring substance which water soluble or insoluble and contain
chromophoric and auxochrome groups and also have the affinity to the
textile materials.
What is Natural Dye?
The word ‘natural dye’ refers to all the dyes derived from the natural
sources. Its mainly obtained from different plants, animal and minerals
resources. It is mostly non-substantive and must be applied on textiles
by the help of mordants.
170206102
Types of Natural Dyes
Obtained from leaves,
flower, skins of fruit, bark,
roots, wood etc
Plant dyes
01
Obtained from various dried
bodies of insects.
Insect Dyes
02
Obtained from created from
shellfish Carmine, Cochineal
and so on.
Animal Dyes
03
170206102
Sources of different natural dyestuffs
Part of the Plants Dyestuffs
1. Root Turmeric, Onions, Madder, Beet-root, etc.
2. Bark Purple bark, Sappan wood, Shillicorai, Khair, Sandalwood,
etc.
3. Leaf Henna, Indigo, Lemon Grass, Eucalyptus, Tea, Cardamon,
Coral Jasmine, etc.
4. Flowers Marigold, Dahlia, Kusum, Tesu, etc.
5. Fruits or Seeds Latkan, Pomegranate rind, Beetle nut, Myrobolan, etc.
170206102
Natural dyes are very suitable for dyeing of protein fibres as compared to cellulosic fibres.
Synthetic fibres which contain polar groups such as nylon, acrylic and viscose are also accessible
to natural dyes. Natural dyes are thermo unstable and have poor chemical stability, which make
the natural dyes unfit for dyeing at high temperature and pressure. The presence of hydrogen
bond and Van der Waals force of attraction play important role in the fixation of natural dyes on
the fibre. Natural dyes are having poor exhaustion value due to subdued affinity for fibre
materials, so to increase the exhaustion of dyes, common salt/Glauber’s salt are added in the
dye bath. The isotherm of the natural dyes sorption obeys Nernst isotherm.
Theory of dyeing
170206102
Theory of dyeing
170206104
The amount of natural dyes present in natural
products are very less, They need specific
technique to remove dye from their original
source.
• Aqueous extraction
• Acid and alkali extraction
• Ultrasonic microwave extraction
• By fermentation
• Solvent extraction
Extraction of natural dyes
170206104
Turmeric
Turmeric is commonly
known as Indian saffron.
It consists of dried, as
well as fresh rhizomes of
the plant Curcuma longa
Linn.
Turmeric contains about
5% of volatile oil, resin
and yellow colouring
substances known as
curcuminoids
170206104
Henna
Henna is widely used in the
cosmetic industry as dyeing
agent. It consists of fresh or
dried leaves of the plant
“Lawsonia inermis”.It has
medicinal importance along
with dyeing property.
170206104
POMEGRANATE
It consists of fresh and dried
fruits of the plant
Punicagranatum.
It contains chief constituents
such as punicalagin, punicalin,
gallagic and ellagic acids.
It also contains alkaloids like
isopelletierine.
170206142
Marigold
Marigold flowers [Tagetes ],
which are yellow to orange red
in colour, are a rich source of
lutein, a carotenoid pigment.
This pigment has acquired
greater significance because of
its excellent colour value.
Although marigold flower
extract has been used in
veterinary feeds, the potential
use of marigold as a natural
textile colorant has not been
exploited to its full extent.
170206142
Dragon fruit
Dragon fruit is a tropical fruit that has
become increasingly popular in recent
years.The effort to utilize the red
dragon fruit peel is by extracting
anthocyanin pigments using the
maceration extraction method.
Dragon fruit peel contains high
enough natural anthocyanin dyes.
This study aims to determine the ratio
of the 10% citric acid solution with
the time of maceration to obtain the
highest anthocyanin levels and to
determine the stability of the red
dragon fruit peel extract.
170206142
Dyeing method of natural dyes
Different researchers had proposed different methods of dyeing of natural and
synthetic fibres with natural dyes. The dyeing of textile substrates depends on
dyeing parameters which are fibre structure, temperature, time and pH of the dye
bath and dye molecule characteristics. The fastness properties of dyes on textile
substrates depend on bonding of dyes with fibre.
• Conversational method
• Dyeing of cotton fabric
• Dyeing of synthetic fibres
• Dyeing of protein fibres
• Fixation of natural dyes
170206142
Fastness properties of natural dyes
The fastness properties give idea about the quality of dyeing. In natural dyes, the
fastness properties are strongly related to substrate type and mordant used for
dyestuff fixation. Besides the dyestuff itself, there are many factors such as water,
chemicals, temperature, humidity, light, pretreatments, after treatments, dyestuff
distribution in fibre and fixation of dyestuff affect the fastness properties.
• Light fastness
• Washing fastness
• Rubbing fastness
Fig.: Rubbing Fastness tester Fig.: Washing Fastness tester Fig.: Light Fastness tester
170206097
sustainability aspects of Natural Textile Dyeing:
•Environmental
•Socio-economic
170206097
Technological advancements in textile coloration with
natural dyes
Coloration is an integral part of ever expanding
complex chemical wet processing of textiles,
which involves use of many types of chemical
entities and physico-chemical processes.
Environmental concerns arising due to
accelerated development in textile wet
processing industry paved the way for ongoing
interest in the development of cleaner
production strategies for making cost effective
value added textile products.
170206097
Advantages of Natural Dyes
• Natural dyes shades are lustrous, soft, and
soothing to the human eye.
• Natural dyestuff can provide a wide range of
colour’s by mix and match system. That is not
easily possible with synthetic dyestuffs.
• Natural dyestuffs produce rare color ideas
which are automatically harmonizing.
• Waste in natural dyeing process becomes an
ideal fertilizer for use in agricultural fields.
• Many natural dyes plants thrive on wastelands.
Thus, wasteland utilization is an added merit of
the natural dye.
170206097
Advantages of Natural Dyes
• Application of natural dyes has strong potential to
reduce the consumption of fossil fuel-based
synthetic dyes.
• Some of the natural dyes are enhanced with age. But
synthetic dyes fade with time.
• This is a labor-intensive industry. As a result, these
processes providing job opportunities for all those
engaged in cultivation, extraction, and application of
natural dyes on textiles, food, leather, etc
• Natural dyes are proved that it’s safe for human skin
contact and are mostly non-hazardous to human
health.
• Natural dyes are usually renewable and
biodegradable. 170106130
Limitations Natural Dyes:
• Natural dyeing processing and colour development doesn’t only depend on
colour component but also on materials.
• It is difficult to reproduce shades by using natural dye.
• Natural dyeing requires skilled and experience workmanship which is expensive.
• It is difficult to standardize a recipe for the use of natural dye.
170106130
Limitations Natural Dyes:
• Low colour yield of source natural dye thus necessitates the use of more
dyestuffs, larger dyeing time and excess cost for mordants and mordanting.
• Lack of availability of precise technical knowledge on extraction and natural
dyeing techniques.
• Natural dyed textile can be changed colour when exposed to the sun, sweat and
air.
• Natural dyes colour fastness performance ratings are inadequate for modern
textile usage & Science involved in natural dyeing is still need to be explored.
170106130
conclusions
Natural dyes, generally supposed to be cheap, nontoxic, renewable and
sustainable resource with minimal environmental impact, have attracted the
attention of the scientific community to use them in a variety of traditional and
newly discovered application disciplines. Although ,past few years have witnessed
substantial growth in our understanding of technological details required for
efficient utilization of colorants obtained from natural sources, but still there are
a number of technical challenges in each area of natural dye application that
must be over come before these technologies can be adopted on a practical large
scale.
Reference's
• Gupta, V. K. (2019). Fundamentals of natural dyes and its application on textile
substrates. Chemistry and technology of natural and synthetic dyes and pigments, 2019.
• Khan, S. A., Ahmad, A., Khan, M. I., Yusuf, M., Shahid, M., Manzoor, N., & Mohammad, F. (2012).
Antimicrobial activity of wool yarn dyed with Rheum emodi L.(Indian Rhubarb). Dyes and
Pigments, 95(2), 206-214.
• Ammayappan, L., & Jose, S. (2015). Functional aspects, ecotesting, and environmental impact of
natural dyes. Handbook of sustainable apparel production, 333(350), 333-350.
• Grifoni, D., Bacci, L., Zipoli, G., Albanese, L., & Sabatini, F. (2011). The role of natural dyes in the
UV protection of fabrics made of vegetable fibres. Dyes and Pigments, 91(3), 279-285.
• Samanta, A. K., Awwad, N., & Algarni, H. M. (Eds.). (2020). Chemistry and Technology of Natural
and Synthetic Dyes and Pigments. BoD–Books on Demand.
• Ratnapandian, S., Fergusson, S. M., & Wang, L. (2012). Application of acacia natural dyes on
cotton by pad dyeing. Fibers and Polymers, 13(2), 206-211.
Reference's
• Ratnapandian, S., Fergusson, S. M., & Wang, L. (2012). Application of acacia natural dyes on cotton
by pad dyeing. Fibers and Polymers, 13(2), 206-211.
• Vankar, P. S. (2017). Natural dyes for textiles: Sources, chemistry and applications. Woodhead
Publishing.
• Guha, A. K. (2019). A review on sources and application of natural dyes in textiles. International
Journal of Textile Science, 8(2), 38-40.
• Vankar, P. S., & Shukla, D. (2019). New trends in natural dyes for textiles. Woodhead Publishing.
• Samanta, P. (2020). A review on application of natural dyes on textile fabrics and its revival
strategy. Chemistry and technology of natural and synthetic dyes and pigments, 1-24.
• Singhee, D. (2020). Review on natural dyes for textiles from wastes. In Chemistry and Technology
of Natural and Synthetic Dyes and Pigments. Rijeka, Croatia: IntechOpen.
• Gupta, V. K. (2019). Fundamentals of natural dyes and its application on textile
substrates. Chemistry and technology of natural and synthetic dyes and pigments, 2019.
• Pargai, D., Jahan, S., & Gahlot, M. (2020). Functional properties of natural dyed textiles. Chemistry
and technology of natural and synthetic dyes and pigments, 1-19.
THANKS!
From Group 4

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Recent Advances in Natural Dyeing.pdf

  • 2. Mr. Muksit Ahamed Chowdhury Associate Professor Department of Textile Engineering Ms. Nahida Akter Assistant Professor Department of Textile Engineering Presented For Presented By Abidur Rahman Lisun | 170206097 Arindam Dey Gourov | 170206102 Saima Hossain Shanta | 170206104 MD.Zamil Hasan Talukder | 170206142 Mahim Karmaker Mugdha | 170106130
  • 3. What is Dye? It is a colouring substance which water soluble or insoluble and contain chromophoric and auxochrome groups and also have the affinity to the textile materials. What is Natural Dye? The word ‘natural dye’ refers to all the dyes derived from the natural sources. Its mainly obtained from different plants, animal and minerals resources. It is mostly non-substantive and must be applied on textiles by the help of mordants. 170206102
  • 4. Types of Natural Dyes Obtained from leaves, flower, skins of fruit, bark, roots, wood etc Plant dyes 01 Obtained from various dried bodies of insects. Insect Dyes 02 Obtained from created from shellfish Carmine, Cochineal and so on. Animal Dyes 03 170206102
  • 5. Sources of different natural dyestuffs Part of the Plants Dyestuffs 1. Root Turmeric, Onions, Madder, Beet-root, etc. 2. Bark Purple bark, Sappan wood, Shillicorai, Khair, Sandalwood, etc. 3. Leaf Henna, Indigo, Lemon Grass, Eucalyptus, Tea, Cardamon, Coral Jasmine, etc. 4. Flowers Marigold, Dahlia, Kusum, Tesu, etc. 5. Fruits or Seeds Latkan, Pomegranate rind, Beetle nut, Myrobolan, etc. 170206102
  • 6. Natural dyes are very suitable for dyeing of protein fibres as compared to cellulosic fibres. Synthetic fibres which contain polar groups such as nylon, acrylic and viscose are also accessible to natural dyes. Natural dyes are thermo unstable and have poor chemical stability, which make the natural dyes unfit for dyeing at high temperature and pressure. The presence of hydrogen bond and Van der Waals force of attraction play important role in the fixation of natural dyes on the fibre. Natural dyes are having poor exhaustion value due to subdued affinity for fibre materials, so to increase the exhaustion of dyes, common salt/Glauber’s salt are added in the dye bath. The isotherm of the natural dyes sorption obeys Nernst isotherm. Theory of dyeing 170206102
  • 8. The amount of natural dyes present in natural products are very less, They need specific technique to remove dye from their original source. • Aqueous extraction • Acid and alkali extraction • Ultrasonic microwave extraction • By fermentation • Solvent extraction Extraction of natural dyes 170206104
  • 9. Turmeric Turmeric is commonly known as Indian saffron. It consists of dried, as well as fresh rhizomes of the plant Curcuma longa Linn. Turmeric contains about 5% of volatile oil, resin and yellow colouring substances known as curcuminoids 170206104
  • 10. Henna Henna is widely used in the cosmetic industry as dyeing agent. It consists of fresh or dried leaves of the plant “Lawsonia inermis”.It has medicinal importance along with dyeing property. 170206104
  • 11. POMEGRANATE It consists of fresh and dried fruits of the plant Punicagranatum. It contains chief constituents such as punicalagin, punicalin, gallagic and ellagic acids. It also contains alkaloids like isopelletierine. 170206142
  • 12. Marigold Marigold flowers [Tagetes ], which are yellow to orange red in colour, are a rich source of lutein, a carotenoid pigment. This pigment has acquired greater significance because of its excellent colour value. Although marigold flower extract has been used in veterinary feeds, the potential use of marigold as a natural textile colorant has not been exploited to its full extent. 170206142
  • 13. Dragon fruit Dragon fruit is a tropical fruit that has become increasingly popular in recent years.The effort to utilize the red dragon fruit peel is by extracting anthocyanin pigments using the maceration extraction method. Dragon fruit peel contains high enough natural anthocyanin dyes. This study aims to determine the ratio of the 10% citric acid solution with the time of maceration to obtain the highest anthocyanin levels and to determine the stability of the red dragon fruit peel extract. 170206142
  • 14. Dyeing method of natural dyes Different researchers had proposed different methods of dyeing of natural and synthetic fibres with natural dyes. The dyeing of textile substrates depends on dyeing parameters which are fibre structure, temperature, time and pH of the dye bath and dye molecule characteristics. The fastness properties of dyes on textile substrates depend on bonding of dyes with fibre. • Conversational method • Dyeing of cotton fabric • Dyeing of synthetic fibres • Dyeing of protein fibres • Fixation of natural dyes 170206142
  • 15. Fastness properties of natural dyes The fastness properties give idea about the quality of dyeing. In natural dyes, the fastness properties are strongly related to substrate type and mordant used for dyestuff fixation. Besides the dyestuff itself, there are many factors such as water, chemicals, temperature, humidity, light, pretreatments, after treatments, dyestuff distribution in fibre and fixation of dyestuff affect the fastness properties. • Light fastness • Washing fastness • Rubbing fastness Fig.: Rubbing Fastness tester Fig.: Washing Fastness tester Fig.: Light Fastness tester 170206097
  • 16. sustainability aspects of Natural Textile Dyeing: •Environmental •Socio-economic 170206097
  • 17. Technological advancements in textile coloration with natural dyes Coloration is an integral part of ever expanding complex chemical wet processing of textiles, which involves use of many types of chemical entities and physico-chemical processes. Environmental concerns arising due to accelerated development in textile wet processing industry paved the way for ongoing interest in the development of cleaner production strategies for making cost effective value added textile products. 170206097
  • 18. Advantages of Natural Dyes • Natural dyes shades are lustrous, soft, and soothing to the human eye. • Natural dyestuff can provide a wide range of colour’s by mix and match system. That is not easily possible with synthetic dyestuffs. • Natural dyestuffs produce rare color ideas which are automatically harmonizing. • Waste in natural dyeing process becomes an ideal fertilizer for use in agricultural fields. • Many natural dyes plants thrive on wastelands. Thus, wasteland utilization is an added merit of the natural dye. 170206097
  • 19. Advantages of Natural Dyes • Application of natural dyes has strong potential to reduce the consumption of fossil fuel-based synthetic dyes. • Some of the natural dyes are enhanced with age. But synthetic dyes fade with time. • This is a labor-intensive industry. As a result, these processes providing job opportunities for all those engaged in cultivation, extraction, and application of natural dyes on textiles, food, leather, etc • Natural dyes are proved that it’s safe for human skin contact and are mostly non-hazardous to human health. • Natural dyes are usually renewable and biodegradable. 170106130
  • 20. Limitations Natural Dyes: • Natural dyeing processing and colour development doesn’t only depend on colour component but also on materials. • It is difficult to reproduce shades by using natural dye. • Natural dyeing requires skilled and experience workmanship which is expensive. • It is difficult to standardize a recipe for the use of natural dye. 170106130
  • 21. Limitations Natural Dyes: • Low colour yield of source natural dye thus necessitates the use of more dyestuffs, larger dyeing time and excess cost for mordants and mordanting. • Lack of availability of precise technical knowledge on extraction and natural dyeing techniques. • Natural dyed textile can be changed colour when exposed to the sun, sweat and air. • Natural dyes colour fastness performance ratings are inadequate for modern textile usage & Science involved in natural dyeing is still need to be explored. 170106130
  • 22. conclusions Natural dyes, generally supposed to be cheap, nontoxic, renewable and sustainable resource with minimal environmental impact, have attracted the attention of the scientific community to use them in a variety of traditional and newly discovered application disciplines. Although ,past few years have witnessed substantial growth in our understanding of technological details required for efficient utilization of colorants obtained from natural sources, but still there are a number of technical challenges in each area of natural dye application that must be over come before these technologies can be adopted on a practical large scale.
  • 23. Reference's • Gupta, V. K. (2019). Fundamentals of natural dyes and its application on textile substrates. Chemistry and technology of natural and synthetic dyes and pigments, 2019. • Khan, S. A., Ahmad, A., Khan, M. I., Yusuf, M., Shahid, M., Manzoor, N., & Mohammad, F. (2012). Antimicrobial activity of wool yarn dyed with Rheum emodi L.(Indian Rhubarb). Dyes and Pigments, 95(2), 206-214. • Ammayappan, L., & Jose, S. (2015). Functional aspects, ecotesting, and environmental impact of natural dyes. Handbook of sustainable apparel production, 333(350), 333-350. • Grifoni, D., Bacci, L., Zipoli, G., Albanese, L., & Sabatini, F. (2011). The role of natural dyes in the UV protection of fabrics made of vegetable fibres. Dyes and Pigments, 91(3), 279-285. • Samanta, A. K., Awwad, N., & Algarni, H. M. (Eds.). (2020). Chemistry and Technology of Natural and Synthetic Dyes and Pigments. BoD–Books on Demand. • Ratnapandian, S., Fergusson, S. M., & Wang, L. (2012). Application of acacia natural dyes on cotton by pad dyeing. Fibers and Polymers, 13(2), 206-211.
  • 24. Reference's • Ratnapandian, S., Fergusson, S. M., & Wang, L. (2012). Application of acacia natural dyes on cotton by pad dyeing. Fibers and Polymers, 13(2), 206-211. • Vankar, P. S. (2017). Natural dyes for textiles: Sources, chemistry and applications. Woodhead Publishing. • Guha, A. K. (2019). A review on sources and application of natural dyes in textiles. International Journal of Textile Science, 8(2), 38-40. • Vankar, P. S., & Shukla, D. (2019). New trends in natural dyes for textiles. Woodhead Publishing. • Samanta, P. (2020). A review on application of natural dyes on textile fabrics and its revival strategy. Chemistry and technology of natural and synthetic dyes and pigments, 1-24. • Singhee, D. (2020). Review on natural dyes for textiles from wastes. In Chemistry and Technology of Natural and Synthetic Dyes and Pigments. Rijeka, Croatia: IntechOpen. • Gupta, V. K. (2019). Fundamentals of natural dyes and its application on textile substrates. Chemistry and technology of natural and synthetic dyes and pigments, 2019. • Pargai, D., Jahan, S., & Gahlot, M. (2020). Functional properties of natural dyed textiles. Chemistry and technology of natural and synthetic dyes and pigments, 1-19.