The document discusses organic semiconductors and their operation in organic solar cells. It describes how organic materials can act as conductors when their molecular structure forms alternating single and double bonds. The source of free electrons in these materials is pi bonds between carbon atoms. When light is absorbed in the materials, excitons are formed which are electron-hole pairs. At the interface between an organic donor material and an organic acceptor material in a solar cell, the excitons can dissociate into free charge carriers. However, the charges remain bound as polarons which need to be separated by an external voltage before being transported to the electrodes.