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“NANO BASED TECHNOLOGY FOR RENEWABLE ENERGY
                GENERATION”




                 MR. ANIL KUMAR
            M.PHIL./PH.D. NANOSCIENCE, (2012-13)
CENTRE FOR NANOSCIENCE, CUG, SEC-30, GANDHINAGAR, GUJARAT1
                     kmr.nano@yahoo.com
Contents
Introduction of Renewable Energy
Solar Electric Power Plants
What is a Photovoltaic Cell
How PV Cells Work
Dye-Sensitized and Silicon-based Solar
Cells Compared
Dye-Sensitized Solar Cells
So What Does this Mean for Solar Cells
Absorption of Light by Ionic
Compounds
Absorption of Light by Atoms
But Not All Energy is Converted
Application of Energy
Natural Forming sources of Energy,
Application and effects
Renewable sources of Energy,
                                         2
Application and effects
Introduction of Renewable Energy

 Nanotechnologies      have    significant   potential   to   assist
  economies in meeting their energy efficiency goals, enabling
  adoption of new approaches, techniques and materials with a
  wide range of applications, from efficient usage of traditional
  energy sources to development and implementation of new
  generation technologies based on renewable sources.


 The   nanotechnology     impact    is   especially   important       for
  renewable energy, which together with energy efficiency are
  pillars of sustainable energy policy.                            3
Solar Electric Power Plants

• Main types:
  1. Solar thermal
     energy
       • Has mirrored surface
         that reflects sunlight                                     Array of mirrored solar collectors at
         to heat up liquid to                                       FPL Energy site in California
         make steam to
         generate electricity
  2. Photovoltaic
       • Uses photovoltaic
         cells that absorb
         direct sunlight
                                                                  Concentrated solar collector (parabolic)
                                                                                                       4
   Sources: http://en.wikipedia.org/wiki/Solar_energ , http://www.fplenergy.com/portfolio/solar/facts.shtml#glance
What is a Photovoltaic Cell?
• Is a device of generating electrical power by converting solar radiation into
  direct current electricity using semiconductors that exhibit the photovoltaic
  effect.
• Photovoltaic power generation employs solar panels composed of a number
  of solar cells containing a photovoltaic material.
• Materials presently used for photovoltaics include monocrystalline silicon,
  polycrystalline silicon, amorphous silicon, cadmium telluride, and copper
  indium gallium selenide or sulfide….. etc.


                   How PV Cells Work?
 1. Photons in sunlight hit the solar panel and are absorbed by
 semiconducting materials, such as silicon.
 2. Electrons (negatively charged) are knocked loose from their atoms,
 allowing them to flow through the material to produce electricity.
 3. An array of solar cells converts solar energy into a usable amount of direct
 current (DC) electricity.
                                                                             5
Dye-Sensitized and Silicon-based Solar
           Cells Compared
• Dye-Sensitized                             “Nano”         • Traditional                     “Single-crystal silicon”


  1. Relatively                                                1. Expensive
     inexpensive                                               2. Long return
  2. Short return on                                              on investment
     investment




                                                                                                                         6
  Sources: http://www.imo.uhasselt.be/polytech/images/zonnecel1.jpg, http://www.norfolksolar.co.uk/img/system.gif
Dye-Sensitized(“nano”) Solar Cells

• Relatively inexpensive
  1. Made      in  non-vacuum
     setting mainly at room
     temperature
  2. Relatively         simple
     manufacturing process
• Need little TLC
  1. Thin, lightweight, flexible
• Short return on investment
  1. Takes approx 3 months to
     produce energy savings
     equivalent to cost of
     production

                                                                                  7
               Source: http://www.imo.uhasselt.be/polytech/images/zonnecel1.jpg
So What Does this Mean for Solar Cells?

• In dye-sensitized solar
  cells…
  – Talk about highest
    occupied molecular
    orbital (HOMO) and
    lowest unoccupied
    molecular orbital
    (LUMO)
• In single-crystal silicon
  solar cells…
  – Talk about “conduction
    band” (excited states) and
    “valence band” (ground
    states)                         8
Absorption of Light by Ionic Compounds

• Electrons can
  jump between
  “bands”

• Incident light with
  energy ≥ than the
  “band gap” energy
  can be used to
  excite the
  electrons
                                                                                   9
          Source: Image adapted from http://www.3dchem.com/molecules.asp?ID=135#
Absorption of Light by Atoms


• Absorption occurs only when the energy of
  the light equals the energy of transition of
  an electron


     Single electron
     transition in an
     isolated atom




                                                                                                                        10
Sources: http://members.aol.com/WSRNet/tut/absorbu.htm, http://csep10.phys.utk.edu/astr162/lect/light/absorption.html
But Not All Energy is Converted

• Like chloroplasts in plants, solar cells can only
  absorb specific wavelengths of light.
• In both, light that isn’t absorbed is either
  transmitted through or reflected back.
• Whether a certain wavelength of lights gets
  absorbed depends on its energy.



                                                     Chlorophyll molecules
                                                     absorb blue and red
                                                     light, but reflect green
                                                     light

                                                                                11
           Source: http://ebiomedia.com/prod/cyclops/images/image004.jpg
Application of Energy


Natural form for sources of Energy
  Hydro-Carbon
  Nuclear Power
  Hydro Power
  Alternative Energy
Nanotechnology Approaches for Renewable Energy
Generataion
   Solar Energy
   Wind Energy
   Geothermal steam
   Biomass                                12
Natural Forming sources of Energy, Application
                  and effects
We know that, our main energy sources for human       Flow chart of Energy sources
activity are fossil and mineral fuels, nuclear and
hydroelectric sources.
They are very harmful to environment because
they cause global warning, ozone layer depletion,
biosphere   and    geosphere    destruction,   and
ecological devastation. Around 80 wt% of CO2
emissions in the world are originated by the energy
sector
Changes towards environmental improvements are
becoming more politically acceptable globally,
especially in developed countries. Society is
slowly moving towards seeking more sustainable
production methods, waste minimization, reduced
air pollution from vehicles, distributed energy
generation, conservation of native forests, and
reduction of greenhouse gas emissions.                                                          13
                                                                 Source Figure: Elena Serrano, et al. 2009
Renewable sources of Energy, Application and
                     effects

Flow chart of Renewable Energy sources                        Nanotechnology is generating a lot
                                                              of   attention    these      days        and
                                                              therefore         building           great
                                                              expectations in renewable energy
                                                              challenges with nano-sciences in
                                                              21th century, the governments, and
                                                              industry.

                                                              For renewable energy are solar,
                                                              hydrogen    and     new      generation
                                                              batteries and supercapacitors are
                                                              described as the most significant
                                                              examples of the contributions of
                                                              nanotechnology      in    the   energy

                  Source Figure: Elena Serrano, et al. 2009
                                                              sector.                             14
THANKING YOU                             FOR A KIND ATTENTION…….




                                                                   15
     Source Figure : Elena Serrano, et al. 2009

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Nano-Based Solar Cells for Renewable Energy

  • 1. “NANO BASED TECHNOLOGY FOR RENEWABLE ENERGY GENERATION” MR. ANIL KUMAR M.PHIL./PH.D. NANOSCIENCE, (2012-13) CENTRE FOR NANOSCIENCE, CUG, SEC-30, GANDHINAGAR, GUJARAT1 kmr.nano@yahoo.com
  • 2. Contents Introduction of Renewable Energy Solar Electric Power Plants What is a Photovoltaic Cell How PV Cells Work Dye-Sensitized and Silicon-based Solar Cells Compared Dye-Sensitized Solar Cells So What Does this Mean for Solar Cells Absorption of Light by Ionic Compounds Absorption of Light by Atoms But Not All Energy is Converted Application of Energy Natural Forming sources of Energy, Application and effects Renewable sources of Energy, 2 Application and effects
  • 3. Introduction of Renewable Energy  Nanotechnologies have significant potential to assist economies in meeting their energy efficiency goals, enabling adoption of new approaches, techniques and materials with a wide range of applications, from efficient usage of traditional energy sources to development and implementation of new generation technologies based on renewable sources.  The nanotechnology impact is especially important for renewable energy, which together with energy efficiency are pillars of sustainable energy policy. 3
  • 4. Solar Electric Power Plants • Main types: 1. Solar thermal energy • Has mirrored surface that reflects sunlight Array of mirrored solar collectors at to heat up liquid to FPL Energy site in California make steam to generate electricity 2. Photovoltaic • Uses photovoltaic cells that absorb direct sunlight Concentrated solar collector (parabolic) 4 Sources: http://en.wikipedia.org/wiki/Solar_energ , http://www.fplenergy.com/portfolio/solar/facts.shtml#glance
  • 5. What is a Photovoltaic Cell? • Is a device of generating electrical power by converting solar radiation into direct current electricity using semiconductors that exhibit the photovoltaic effect. • Photovoltaic power generation employs solar panels composed of a number of solar cells containing a photovoltaic material. • Materials presently used for photovoltaics include monocrystalline silicon, polycrystalline silicon, amorphous silicon, cadmium telluride, and copper indium gallium selenide or sulfide….. etc. How PV Cells Work? 1. Photons in sunlight hit the solar panel and are absorbed by semiconducting materials, such as silicon. 2. Electrons (negatively charged) are knocked loose from their atoms, allowing them to flow through the material to produce electricity. 3. An array of solar cells converts solar energy into a usable amount of direct current (DC) electricity. 5
  • 6. Dye-Sensitized and Silicon-based Solar Cells Compared • Dye-Sensitized “Nano” • Traditional “Single-crystal silicon” 1. Relatively 1. Expensive inexpensive 2. Long return 2. Short return on on investment investment 6 Sources: http://www.imo.uhasselt.be/polytech/images/zonnecel1.jpg, http://www.norfolksolar.co.uk/img/system.gif
  • 7. Dye-Sensitized(“nano”) Solar Cells • Relatively inexpensive 1. Made in non-vacuum setting mainly at room temperature 2. Relatively simple manufacturing process • Need little TLC 1. Thin, lightweight, flexible • Short return on investment 1. Takes approx 3 months to produce energy savings equivalent to cost of production 7 Source: http://www.imo.uhasselt.be/polytech/images/zonnecel1.jpg
  • 8. So What Does this Mean for Solar Cells? • In dye-sensitized solar cells… – Talk about highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) • In single-crystal silicon solar cells… – Talk about “conduction band” (excited states) and “valence band” (ground states) 8
  • 9. Absorption of Light by Ionic Compounds • Electrons can jump between “bands” • Incident light with energy ≥ than the “band gap” energy can be used to excite the electrons 9 Source: Image adapted from http://www.3dchem.com/molecules.asp?ID=135#
  • 10. Absorption of Light by Atoms • Absorption occurs only when the energy of the light equals the energy of transition of an electron Single electron transition in an isolated atom 10 Sources: http://members.aol.com/WSRNet/tut/absorbu.htm, http://csep10.phys.utk.edu/astr162/lect/light/absorption.html
  • 11. But Not All Energy is Converted • Like chloroplasts in plants, solar cells can only absorb specific wavelengths of light. • In both, light that isn’t absorbed is either transmitted through or reflected back. • Whether a certain wavelength of lights gets absorbed depends on its energy. Chlorophyll molecules absorb blue and red light, but reflect green light 11 Source: http://ebiomedia.com/prod/cyclops/images/image004.jpg
  • 12. Application of Energy Natural form for sources of Energy Hydro-Carbon Nuclear Power Hydro Power Alternative Energy Nanotechnology Approaches for Renewable Energy Generataion  Solar Energy  Wind Energy  Geothermal steam  Biomass 12
  • 13. Natural Forming sources of Energy, Application and effects We know that, our main energy sources for human Flow chart of Energy sources activity are fossil and mineral fuels, nuclear and hydroelectric sources. They are very harmful to environment because they cause global warning, ozone layer depletion, biosphere and geosphere destruction, and ecological devastation. Around 80 wt% of CO2 emissions in the world are originated by the energy sector Changes towards environmental improvements are becoming more politically acceptable globally, especially in developed countries. Society is slowly moving towards seeking more sustainable production methods, waste minimization, reduced air pollution from vehicles, distributed energy generation, conservation of native forests, and reduction of greenhouse gas emissions. 13 Source Figure: Elena Serrano, et al. 2009
  • 14. Renewable sources of Energy, Application and effects Flow chart of Renewable Energy sources Nanotechnology is generating a lot of attention these days and therefore building great expectations in renewable energy challenges with nano-sciences in 21th century, the governments, and industry. For renewable energy are solar, hydrogen and new generation batteries and supercapacitors are described as the most significant examples of the contributions of nanotechnology in the energy Source Figure: Elena Serrano, et al. 2009 sector. 14
  • 15. THANKING YOU FOR A KIND ATTENTION……. 15 Source Figure : Elena Serrano, et al. 2009