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This presentation is about electromagnetic fields, history of this theory and personalities contributing to this theory. Applications of electromagnetism. Vector Analysis and coordinate systems.
This presentation is about electromagnetic fields, history of this theory and personalities contributing to this theory. Applications of electromagnetism. Vector Analysis and coordinate systems.
This first lecture describes what EMT is. Its history of evolution. Main personalities how discovered theories relating to this theory. Applications of EMT . Scalars and vectors and there algebra. Coordinate systems. Field, Coulombs law and electric field intensity.volume charge distribution, electric flux density, gauss's law and divergence
conceptual-problems-in-physics-for-iit-jee (1)APEX INSTITUTE
APEX INSTITUTE was conceptualized in May 2008, keeping in view the dreams of young students by the vision & toil of Er. Shahid Iqbal. We had a very humble beginning as an institute for IIT-JEE / Medical, with a vision to provide an ideal launch pad for serious JEE students . We actually started to make a difference in the way students think and approach problems. We started to develop ways to enhance students IQ. We started to leave an indelible mark on the students who have undergone APEX training. That is why APEX INSTITUTE is very well known of its quality of education and the dedication towards its target.
Previous Year Question Paper For JEE 2019 Advance PreparationPrabha Gupta
Candidates who deserve and would like to apply for JEE Advanced 2019 can visit at Aglasem and collect the previous year question paper for preparation. Visit @ https://admission.aglasem.com/jee-advanced-2019-registration/
2018 JEE Advanced Paper 1 Question PapersMiso Study
Class 11th & 12th Physics, Chemistry & Mathematics exam paper to practice for preparation of JEE Advanced 2019 exam by expert faculty. This is previous year paper on JEE Advanced exam. You can download free from https://bit.ly/2UsDFQK
Class 11th & 12th Physics, Chemistry & Mathematics exam paper to practice for preparation of JEE Advanced 2019 exam by expert faculty. This is previous year paper on JEE Advanced exam. You can download free from https://bit.ly/2ORf0zu
This first lecture describes what EMT is. Its history of evolution. Main personalities how discovered theories relating to this theory. Applications of EMT . Scalars and vectors and there algebra. Coordinate systems. Field, Coulombs law and electric field intensity.volume charge distribution, electric flux density, gauss's law and divergence
conceptual-problems-in-physics-for-iit-jee (1)APEX INSTITUTE
APEX INSTITUTE was conceptualized in May 2008, keeping in view the dreams of young students by the vision & toil of Er. Shahid Iqbal. We had a very humble beginning as an institute for IIT-JEE / Medical, with a vision to provide an ideal launch pad for serious JEE students . We actually started to make a difference in the way students think and approach problems. We started to develop ways to enhance students IQ. We started to leave an indelible mark on the students who have undergone APEX training. That is why APEX INSTITUTE is very well known of its quality of education and the dedication towards its target.
Previous Year Question Paper For JEE 2019 Advance PreparationPrabha Gupta
Candidates who deserve and would like to apply for JEE Advanced 2019 can visit at Aglasem and collect the previous year question paper for preparation. Visit @ https://admission.aglasem.com/jee-advanced-2019-registration/
2018 JEE Advanced Paper 1 Question PapersMiso Study
Class 11th & 12th Physics, Chemistry & Mathematics exam paper to practice for preparation of JEE Advanced 2019 exam by expert faculty. This is previous year paper on JEE Advanced exam. You can download free from https://bit.ly/2UsDFQK
Class 11th & 12th Physics, Chemistry & Mathematics exam paper to practice for preparation of JEE Advanced 2019 exam by expert faculty. This is previous year paper on JEE Advanced exam. You can download free from https://bit.ly/2ORf0zu
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1. JEE ADVANCED 2015
PAPER 2 CODE 3
Physics
1. A monochromatic beam of light is incident at 60 𝑜
on one face of an equilateral prism of refractive index 𝑛
and emerges from the opposite face making an angle 𝜃(𝑛) with the normal (see the figure). For 𝑛 = √3
the value of 𝜃 is 60 𝑜
and
𝑑𝜃
𝑑𝑛
= 𝑚. The value of 𝑚 is
Answer Key: (2)
2. In the following circuit, the current through the resistor 𝑅(= 2Ω) is 𝐼 Amperse. The value of 𝐼 is
Answer Key: (1)
SECTION 1(Maximum Marks: 32)
This section contains EIGHT questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9 both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme:
+4 If the bubble corresponding to the answer is darkened
0 In all other cases
2. 3. An electron in an excited state of 𝐿𝑖2+
ion has angular momentum
3ℎ
2𝜋
. The de Broglie wavelength of the
electron in this state is 𝑝𝜋𝛼0 (where 𝑎0 is the Bohr radius). The value of 𝑝 is
Answer Key: (2)
4. A large spherical mass 𝑀 is fixed at one position and two identical point masses 𝑚 are kept on a line
passing through the centre of 𝑀 (see figure). The point masses are connected by a rigid massless rod of
length 𝑙 and this assembly is free to move along the line connecting them. All three masses interact only
through their mutual gravitational interaction. When the point mass nearer to 𝑀 is at a distance 𝑟 = 3𝑙
from 𝑀, the tension in the rod is zero for 𝑚 = 𝑘 (
𝑀
288
). The value of 𝑘 is
Answer Key: (7)
5. The energy of a system as a function of time 𝑡 is given as 𝐸( 𝑡) = 𝐴2(−𝑎𝑡), where 𝑎 = 0.2 𝑠−1
. The
measurement of 𝐴 has an error of 1.25%. If the error in the measurement of time is 1.50%, the
percentage error in the value of 𝐸(𝑡) at 𝑡 = 5s is
Answer Key: (4)
6. The densities of two solid spheres 𝐴 and 𝐵 of the same radii 𝑅 vary with radial distance 𝑟 as 𝜌 𝐴( 𝑟) =
𝑘 (
𝑟
𝑅
) and 𝜌 𝐵( 𝑟) = 𝑘 (
𝑟
𝑅
)
5
, respectively, where 𝑘 is a constant. The moments of inertia of the individual
spheres about axes passing through their centres are 𝐼𝐴 and 𝐼 𝐵, respectively. If
𝐼 𝐵
𝐼 𝐴
=
𝑛
10
, the value of 𝑛 is
Answer Key: (6)
7. Four harmonic waves of equal frequencies and equal intensities 𝐼0 have phase angles 0,
𝜋
3
,
2𝜋
3
and 𝜋.
When they are superposed, the intensity of the resulting wave is 𝑛𝐼0. The value of 𝑛 is
Answer Key: (3)
8. For a radioactive material, its activity 𝐴 and rate of change of its activity 𝑅 are defined as 𝐴 = −
𝑑𝑁
𝑑𝑡
and
𝑅 = −
𝑑𝐴
𝑑𝑡
, where 𝑁(𝑡) is the number of nuclei at time 𝑡. Two radioactive sources 𝑃 (mean life 𝜏) and 𝑄
(mean life 2𝜏) have the same activity at 𝑡 = 0. Their rates of change of activities at 𝑡 = 2𝜏 are 𝑅 𝑃 and 𝑅 𝑄,
respectively. If
𝑅 𝑃
𝑅 𝑄
=
𝑛
𝑒
, then the value of 𝑛 is
Answer Key: (2)
3. 9. A spherical body of radius 𝑅 consists of a fluid of constant density and is in equilibrium under its own
gravity. If 𝑃(𝑟) is the pressure at 𝑟(𝑟 < 𝑅), then the correct option(s) is (are)
(A) 𝑃 = ( 𝑟 = 0) = 0
(B)
𝑃(𝑟 =
3𝑅
4
)
𝑃(𝑟 =
2𝑅
3
)
=
63
80
(C)
𝑃(𝑟 =
3𝑅
5
)
𝑃(𝑟 =
2𝑅
5
)
=
16
21
(D)
𝑃(𝑟 =
𝑅
2
)
𝑃(𝑟 =
𝑅
3
)
=
20
27
Answer Key: (B,C)
10. A parallel plate capacitor having plates of area 𝑆 and plate separation 𝑑, has capacitance 𝐶1 in air. When
two dielectrics of different relative permittivities (𝜀1 = 2 and 𝜀2 = 4) are introduced between the two
plates as shown in the figure, the capacitance becomes 𝐶2. The ratio
𝐶2
𝐶1
is
(A)
6
5
(B)
5
3
(C)
7
5
SECTION 2 (Maximum Marks: 32)
This section contains EIGHT questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in
the ORS
Marking scheme:
+4 If only the bubble(s) corresponding to all the correct option(s) darkened
0 If none of the bubbles is darkened
-2 In all other cases
4. (D)
7
3
Answer Key: (D)
11. An ideal monoatomic gas is confined in a horizontal cylinder by a spring loaded piston (as shown in the
figure).Initially the gas is at temperature 𝑇1, pressure 𝑃1 and volume 𝑉1 and the spring is in its relaxed
state. The gas is then heated very slowly to temperature 𝑇2, pressure 𝑃2 and volume 𝑉2. During this
process the piston moves out by a distance 𝑥. Ignoring the friction between the piston the cylinder, the
correct statement(s) is (are)
(A) If 𝑉2 = 2𝑉1 and 𝑇2 = 3𝑇1, then the energy stored in the spring is
1
4
𝑃1 𝑉1
(B) If 𝑉2 = 2𝑉1 and 𝑇2 = 3𝑇1, then the change in internal energy is 3𝑃1 𝑉1
(C) If 𝑉2 = 3𝑉1 and 𝑇2 = 4𝑇1, then the work done by the gas is
7
3
𝑃1 𝑉1
(D) If 𝑉2 = 3𝑉1 and 𝑇2 = 4𝑇1, then the heat supplied to the gas is
17
6
𝑃1 𝑉1
Answer Key: (A,B,C)
12. A fission reaction is given by 𝑈92
236
→ 𝑋𝑒54
140
→ 𝑆𝑟38
94
+ 𝑥 + 𝑦, where 𝑥 and 𝑦 are two particles.
Considering 𝑈92
236
to be at rest, the kinetic energies of the products are denoted by 𝐾 𝑋𝑒, 𝐾𝑆𝑟, 𝐾𝑥(2 𝑀𝑒𝑉)
and 𝐾 𝑦(2 𝑀𝑒𝑉), respectively. Let the binding energies per nucleon of 𝑈92
236
, 𝑋𝑒54
140
and 𝑆𝑟38
94
be 7.5 MeV,
8.5 MeV, respectively. Considering different conservation laws, the correct option(s) is (are)
(A) 𝑥 = 𝑛, 𝑦 = 𝑛, 𝐾𝑆𝑟 = 129 𝑀𝑒𝑉, 𝐾 𝑋𝑒 = 86 𝑀𝑒𝑉
(B) 𝑥 = 𝑝, 𝑦 = 𝑒−
, 𝐾𝑆𝑟 = 129 𝑀𝑒𝑉, 𝐾 𝑋𝑒 = 86 𝑀𝑒𝑉
(C) 𝑥 = 𝑝, 𝑦 = 𝑛, 𝐾𝑆𝑟 = 129 𝑀𝑒𝑉, 𝐾 𝑋𝑒 = 86 𝑀𝑒𝑉
(D) 𝑥 = 𝑛, 𝑦 = 𝑛, 𝐾𝑆𝑟 = 86 𝑀𝑒𝑉, 𝐾 𝑋𝑒 = 129 𝑀𝑒𝑉
Answer Key: (A)
13. Two spheres 𝑃 and 𝑄 of equal radii have densities 𝜌1 and 𝜌2, respectively. The spheres are connected by
a massless string and placed in liquids 𝐿1 and 𝐿2 of densities 𝜎1and 𝜎2 and viscosities 𝜂1and 𝜂2,
respectively. They float in equilibrium with the sphere 𝑃 in 𝐿1 and sphere 𝑄 in 𝐿2 and the string being
taut (see figure). If sphere 𝑃 alone in 𝐿2 has terminal velocity 𝑉⃗ 𝑃 and 𝑄 alone in 𝐿1 has terminal velocity
𝑉⃗ 𝑄, then
5. (A)
|𝑉⃗⃗ 𝑃|
|𝑉⃗⃗ 𝑄|
=
𝜂1
𝜂2
(B)
|𝑉⃗⃗ 𝑃|
|𝑉⃗⃗ 𝑄|
=
𝜂2
𝜂1
(C) 𝑉⃗ 𝑃. 𝑉⃗ 𝑄 > 0
(D) 𝑉⃗ 𝑃. 𝑉⃗ 𝑄 < 0
Answer Key: (A,D)
14. In terms of potential difference 𝑉, electic current 𝐼, permittivity 𝜀0, permeability 𝜇0 and speed of light 𝑐,
the dimensionally correct equation(s) is (are)
(A) 𝜇0 𝐼2
= 𝜀0 𝑉2
(B) 𝜀0 𝐼 = 𝜇0 𝑉
(C) 𝐼 = 𝜀0 𝑐𝑉
(D) 𝜇0 𝑐𝐼 = 𝜀0 𝑉
Answer Key: (A,C)
15. Consider a uniform spherical charge distribution of radius 𝑅1 centred at the origin O. In this distribution, a
spherical cavity of radius 𝑅2, centred at 𝑃 with distance 𝑂𝑃 = 𝑎 = 𝑅1 − 𝑅2 (see figure) is made. If the
electric field inside the cavity at position 𝑟 is 𝐸⃗ (𝑟), then the correct statement(s) is (are)
(A) 𝐸⃗ is uniform, its magnitude is independent of 𝑅2 but its direction depends on 𝑟
(B) 𝐸⃗ is uniform, its magnitude is depends on 𝑅2 and its direction depends on 𝑟
(C) 𝐸⃗ is uniform, its magnitude is dependent of a but its direction depends on 𝑎
6. (D) 𝐸⃗ is uniform and both its magnitude and direction depend on 𝑎
Answer Key: (D)
16. In plotting stress versus strain curves for two materials 𝑃 and 𝑄, a student by mistake puts strain on the
𝑦-axis and stress on the 𝑥- axis as shown in the figure. Then the correct statement(s) is(are)
(A) 𝑃 has more tensile strength than 𝑄
(B) 𝑃 is more ductile than 𝑄
(C) 𝑃 is more brittle than 𝑄
(D) The Young’s modulus of 𝑃 is more than that of 𝑄
Answer Key: (A,B)
SECTION 3 (Maximum Marks: 16)
This section contains TWO Paragraph
Based on each paragraph, there will be TWO questions
Each questions has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four options(s) is(are) correct
For each question, darken the bubble(s) corresponding to the correct option(s) in the
ORS
Marking scheme:
+4 If the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
-2 In all other cases
7. Paragraph 1
In a thin rectangular metallic strip a constant current 𝐼 flows along the positive 𝑥-difection, as
shown in the figure. The length, width and thickness of the strip are 𝑙, 𝑤 and 𝑑, respectively.
A uniform magnetic field 𝐵⃗ is applied on the strip along positive 𝑦-direction. Due to this the charge
carriers experience a net deflection along the 𝑧-direction. This results in accumulation of charge
carriers on the surface 𝑃𝑄𝑅𝑆 and appearance of equal opposite charges on the face opposite to
𝑃𝑄𝑅𝑆. A potential difference along the 𝑧-direction is thus developed. Charge accumulation
continues until the magnetic force is balanced by the electric force. The current is assumed to be
uniformly distributed on the cross section of the strip and carried by electrons.
17. Consider two different metallic strips (1 and 2) of the same material. Their lengths are the same, widths
are 𝑤1 and 𝑤2 and thicknesses are 𝑑1 and 𝑑2, respectively. Two points 𝐾 and 𝑀 are symmetrically
located on the opposite faces parallel to the 𝑥-𝑦 plane (see figure). 𝑉1 and 𝑉2 are the potential differences
between 𝐾 and 𝑀 in strips 1 and 2 respectively. Then, for a given current 𝐼 flowing through them in a
given magnetic field strength 𝐵, the correct statement(s) is (are)
(A) If 𝑤1 = 𝑤2 and 𝑑1 = 2𝑑2, then 𝑉2 = 2𝑉1
(B) If 𝑤1 = 𝑤2 and 𝑑1 = 2𝑑2, then 𝑉2 = 𝑉1
(C) If 𝑤1 = 2𝑤2 and 𝑑1 = 𝑑2, then 𝑉2 = 2𝑉1
(D) If 𝑤1 = 2𝑤2 and 𝑑1 = 𝑑2, then 𝑉2 = 𝑉1
Answer Key: (A,D)
18. Consider two different metallic strips (1 and 2) of same dimensions (length 𝑙, width 𝑤and thickness 𝑑)
with carrier densities 𝑛1 and 𝑛2, respectively. Strip 1 is placed in magnetic field 𝐵1 and strip 2 is placed in
magnetic field 𝐵2, both along positive 𝑦-directions. Then 𝑉1 and 𝑉2 are the potential differences
developed between 𝐾 and 𝑀 in strips 1 and 2 respectively.
Assuming that the current 𝐼 is the same for both strips, the correct option(s) is (are)
(A) If 𝐵1 = 𝐵2 and 𝑛1 = 2𝑛2, then 𝑉2 = 2𝑉1
(B) If 𝐵1 = 𝐵2 and 𝑛1 = 2𝑛2, then 𝑉2 = 𝑉1
(C) If 𝐵1 = 2𝐵2 and 𝑛1 = 𝑛2, then 𝑉2 = 0.5𝑉1
(D) If 𝐵1 = 2𝐵2 and 𝑛1 = 𝑛2, then 𝑉2 = 𝑉1
8. Answer Key: (A,C)
Paragraph 2
Light guidance in an optical fiber can be understood by considering a structure comprising of thin
solid glass cylinder of refractive index 𝑛1 surrounded by a medium of lower refractive index 𝑛2. The
light guidance in the structure takes place due to successive total internal reflections at the interface
of the media 𝑛1 and 𝑛2 as shown in the figure. All rays with the angle of incidence 𝑖 less than a
particular value 𝑖 𝑚 are confined in the medium of refractive index 𝑛1. The numerical aperture (NA) of
the structure is defined as sin 𝑖 𝑚.
19. For two structures namely 𝑆1 with 𝑛1 =
√45
4
and 𝑛2 =
3
2
, and 𝑆2 with 𝑛1 =
8
5
and 𝑛2 =
7
5
and taking the
refractive index of water to be
4
3
and that of air to be 1, the correct option(s) is (are)
(A) NA of 𝑆1 immersed in water is the same as that of 𝑆2 immersed in a liquid of refractive index
16
3√15
(B) NA of 𝑆1 immersed in liquid of refractive index
6
√15
is the same as that of 𝑆2 immersed in water
(C) NA of 𝑆1 placed in air is the same as that of 𝑆2 immersed in liquid of refractive index
4
√15
(D) NA of 𝑆1 placed in air is the same as that of 𝑆2 placed in water
Answer Key: (A,C)
20. If two structures of same cross-sectional area, but different numerical apertures 𝑁𝐴1 and 𝑁𝐴2
( 𝑁𝐴2 < 𝑁𝐴1) are joined longitudinally, the numerical aperture of the combined structure is
(A)
𝑁𝐴1 𝑁𝐴2
𝑁𝐴1+𝑁𝐴2
(B) 𝑁𝐴1 + 𝑁𝐴2
(C) 𝑁𝐴1
(D) 𝑁𝐴2
Answer Key: (D)
9. CHEMISTRY
21. The molar conductivity of a solution of a weak acid HX (0.01 M) is 10 times smaller than the molar
conductivity of a solution of a weak acid HY (0.10 M). If λX−
0
≈ λY−
0
, the difference in their pKa values,
pKa(HX) − pKa(HY) , is (Consider degree of ionization of both acids to << 1)
Answer Key: (3)
22. A closed vessel with rigid walls contains 1 mol of U92
238
and 1 mol of air at 298 K. Considering complete
decay of U92
238
to Pb82
206
, the ratio of the final pressure to the initial pressure of the system at 298 K is
Answer Key: (9)
23. In dilute aqueous H2SO4 , the complex diaquodioxalatoferrate (II) is oxidized by MnO4
−
. For this reaction,
the ratio of the rate of change of [H+] to the rate of change of [MnO4
−
] is
Answer Key: (8)
24. The number of hydroxyl group(s) in Q is
Answer Key: (4)
25. Among the following, the number of reaction(s) that produce(s) benzaldehyde is
SECTION 1 (Maximum Marks: 32)
This section contains EIGHT questions.
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
For each question, darken the bubble corresponding to the correct integer in the ORS.
Marking scheme:
+4 If the bubble corresponding to the answer is darkened.
0 In all other cases.
10. Answer Key: (4)
26. In the complex acetylbromidodicarbonylbis(triethylphosphine)iron (II), the number of Fe − C bond (s) is
Answer Key: (3)
27. Among the complex ions, [Co(NH2 − CH2 − CH2 −
NH2)2Cl2]+
, [CrCl2(C2O4)2]3−
, [Fe(H2O)4(OH)2]+
, [Fe(NH3)2(CN)4]−
, [Co(NH2 − CH2 −
NH2)2(NH3)(H2O)Cl]2+
, the number of complex ion(s) that show(s) cis-trans isomerism is
Answer Key: (6)
28. Three moles of B2H6 are completely reacted with methanol. The number of moles of boron containing
product formed is
Answer Key: (6)
SECTION 2 (Maximum Marks: 40)
This section contains EIGHT questions.
Each questions has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four options(s) is (are) correct.
For each question, darken the bubble(s) corresponding to all the correct option(s) in
the ORS.
Marking scheme:
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened.
0 If none of the bubbles is darkened.
−2 In all other cases.
11. 29. The pair(s) of ions where BOTH the ions are precipitated upon passing H2S gas in presence of dilute HCl,
is (are)
(A) Ba2+
, Zn2+
(B) Bi3+
, Fe3+
(C) Cu2+
, Pb2+
(D) Hg2+
, Bi3+
Answer Key: (C,D)
30. Under hydrolytic conditions, the compounds used for preparation of linear polymer and for chain
termination, respectively, are
(A) CH3SiCl3 and Si(CH3)4
(B) (CH3)2SiCl2 and (CH3)3SiCl
(C) (CH3)2SiCl2 and CH3SiCl3
(D) SiCl4 and (CH3)3SiCl
Answer Key: (B)
31. When O2 is adsorbed on a metallic surface, electron transfer occurs from the metal to O2. The TRUE
statement(s) regarding this adsorption is(are)
(A) O2 is physisorbed
(B) Heat is released
(C) Occupancy of π2p
∗
of O2 is increased
(D) Bond length of O2 is increased
Answer Key: (B,C,D)
32. One mole of a monoatomic real gas satisfied the equation p(V − b) = RT where b is a constant. The
relationship of interatomic potential V(r) and interatomic distance r for the gas is given by
(A)
(B)
13. (D)
Answer Key: (A)
34. The major product U in the following reactions is
(A)
(B)
(C)
(D)
Answer Key: (B)
14. 35. In the following reactions, the major product W is
(A)
(B)
(C)
(D)
Answer Key: (A)
36. The correct statement(s) regarding,
(i) HClO
(ii) HClO2
(iii) HClO3 and
(iv) HClO4 is are
15. (A) The number of Cl = O bonds in (ii) and (iii) together is two.
(B) The number of lone pairs of electrons on Cl in (ii) and (iii) together is three.
(C) The hybridization of Cl in (iv) is sp3
(D) Amongst (i) to (iv), the strongest acid (i)
Answer Key: (B,C)
PARAGRAPH 1
In the following reactions
37. Compound X is
(A)
(B)
SECTION 3 (Maximum Marks: 16)
This section contains TWO paragraphs
Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four options(s) is(are) correct.
For each question, darken the bubbles(s) corresponding to all the correct option(s) in the
ORS.
Marking scheme:
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
0 If none of the bubbles is darkened.
−2 In all other cases.
17. PARAGRAPH 2
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at
constant pressure, a temperature increase of 5.7o
C was measured for the beaker and its contents
(Expt.1). Because the enthalpy of neutralization of a strong acid with a strong base is a constant
(−57.0 kJ mol−1
) , this experiment could be used to measure the calorimeter constant. In a
second experiment (Expt. 2), 100 mL of 2.0 M acetic acid (Ka = 2.0 × 10−5
) was mixed with 100
mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6o
C was
measured.
(Consider heat capacity of all solutions as 4.2 J g−1
K−1
and density of all solutions as 1.0 g mL−1
)
39. Enthalpy of dissociation (in kJ mol−1
) of acetic acid obtained from the Expt. 2 is
(A) 1.0
(B) 10.0
(C) 24.5
(D) 51.4
Answer Key: (A)
40. The pH of the solution after Expt. 2 is
(A) 2.8
(B) 4.7
(C) 5.0
(D) 7.0
Answer Key: (B)
18. Mathematics
41. If 𝛼 = ∫ (𝑒9𝑥+3 tan−1 𝑥) (
12+9𝑥2
1+𝑥2
)
1
0
𝑑𝑥
Where tan−1
𝑥 takes only principal values, then the value of (log 𝑒|1 + 𝛼| −
3𝜋
4
) is
Answer Key: (9)
42. Let 𝑓 ∶ ℝ → ℝ be a continuous odd function, which vanishes exactly at one point and 𝑓(1) =
1
2
. Suppose
that 𝐹( 𝑥) = ∫ 𝑓(𝑡)
𝑥
−1
𝑑𝑡 for all 𝑥 ∈ [−1, 2] and 𝐺( 𝑥) = ∫ 𝑡|𝑓(𝑓( 𝑡))|𝑑𝑡
𝑥
−1
for all 𝑥 ∈ [−1, 2]. If
lim
𝑥→1
𝐹(𝑥)
𝐺(𝑥)
=
1
14
, then the value of 𝑓 (
1
2
) is
Answer Key: (7)
43. Suppose that 𝑝, 𝑞 𝑎𝑛𝑑 𝑟 are three non – coplanar vectors in ℝ3
. Let the components of a vector 𝑠 along
(−𝑝 + 𝑞 + 𝑟), ( 𝑝 − 𝑞 + 𝑟) 𝑎𝑛𝑑 (− 𝑝 − 𝑞 + 𝑟) are x, y and z, respectively, then the value of 2𝑥 + 𝑦 +
𝑧 is
Answer Key: (9)
44. For any integer 𝑘, let 𝛼 𝑘 = cos (
𝑘𝜋
7
) + 𝑖 sin (
𝑘𝜋
7
) , 𝑤ℎ𝑒𝑟𝑒 𝑖 = √−1. The value of the expression
∑ |𝛼 𝑘+1−𝛼 𝑘|12
𝑘=1
∑ |𝛼4𝑘−1−𝛼4𝑘−2|3
𝑘=1
is
Answer Key: (4)
45. Suppose that all the terms of an arithmetic progression (A.P.) are natural numbers. If the ratio of the
sum of the first seven terms to the sum of the first eleven terms is 6 : 11 and the seventh terms lies in
between 130 and 140, then the common difference of this A.P. is
Answer Key: (9)
46. The coefficient of 𝑥9
in the expansion of (1 + 𝑥) (1 + 𝑥2) (1 + 𝑥3) … … (1 + 𝑥100) is
Answer Key: (8)
SECTION 1 (Maximum Marks: 32)
This section contains EIGHT questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme:
+4 If the bubble corresponding to the answer is darkened
0 In all other cases
19. 47. Suppose that the foci of the ellipse
𝑥2
9
+
𝑦2
5
= 1 are ( 𝑓1, 0) 𝑎𝑛𝑑 (𝑓2, 0) where 𝑓1 > 0 𝑎𝑛𝑑 𝑓2 < 0. Let
𝑃1 𝑎𝑛𝑑 𝑃2 be two parabolas with a common vertex at (0, 0) and with foci at ( 𝑓!, 0) 𝑎𝑛𝑑 (2𝑓2, 0),
respectively. Let 𝑇1 be a tangent to 𝑃1 which passes through (2𝑓2, 0) 𝑎𝑛𝑑 𝑇2 be a tangent to 𝑃2 which
passes through (𝑓1, 0). If 𝑚1 is the slope of 𝑇1 𝑎𝑛𝑑 𝑚2 is the slope of 𝑇2, then the value of (
1
𝑚1
2 + 𝑚2
2
) is
Answer Key: (4)
48. Let m and n be two positive integers greater than 1. If lim
𝛼→0
(
𝑒cos(𝛼 𝑛 )−𝑒
𝛼 𝑚 ) = − (
𝑒
2
)
then the value of
𝑚
𝑛
is
Answer Key: (2)
49. The option(s) with the value of a and L that satisfy the following equation is(are)
∫ 𝑒 𝑡(sin6
𝑎𝑡 + cos4
𝑎𝑡) 𝑑𝑡
4𝜋
0
∫ (sin6 𝑎𝑡 + cos4 𝑎𝑡) 𝑑𝑡
𝜋
0
= 𝐿 ?
(A) 𝑎 = 2, 𝐿 =
𝑒4𝜋−1
𝑒 𝜋−1
(B) 𝑎 = 2, 𝐿 =
𝑒4𝜋+1
𝑒 𝜋+1
(C) 𝑎 = 4, 𝐿 =
𝑒4𝜋−1
𝑒 𝜋−1
(D) 𝑎 = 4, 𝐿 =
𝑒4𝜋+1
𝑒 𝜋+1
Answer Key: (A,B)
50. Let 𝑓, 𝑔 ∶ [−1, 2] → ℝ be continuous functions which are twice differentiable on the interval (-1, 2). Let
the values of 𝑓 and 𝑔 at the points -1, 0 and 2 be as given in the following table:
𝑥 = −1 𝑥 = 0 𝑥 = 2
𝑓(𝑥) 3 6 0
𝑔( 𝑥) 0 1 -1
In each of the intervals (-1, 0) and (0, 2) the function (𝑓 − 3𝑔)" never vanishes. Then the correct
statement(s) is(are)
(A) 𝑓′( 𝑥) − 3𝑔′( 𝑥) = 0 has exactly three solutions in (−1, 0) ∪ (0, 2)
(B) 𝑓′( 𝑥) − 3𝑔′( 𝑥) = 0 has exactly one solution in (-1, 0)
Section 2 (Maximum Marks: 32)
This section contains EIGHT questions
Each question has FOUR options (A), (B), (C) and (D), ONE OR MORE THAN ONE of these
four options (s) is(are) correct
For each question, darken the bubble (s) corresponding to all the correct option (s) in the
ORS
Marking scheme:
+4 If only the bubble (s) corresponding to all the correct option (s) is (are) darkened
0 If none of the bubbles is darkened
-2 In all other cases
20. (C) 𝑓′( 𝑥) − 3𝑔′( 𝑥) = 0 has exactly one solution in (0, 2)
(D) 𝑓′( 𝑥) − 3𝑔′( 𝑥) = 0 has exactly two solutions in (-1, 0) and exactly two solutions in (0, 2)
Answer Key: (B,C)
51. Let 𝑓( 𝑥) = 7 tan8
𝑥 + 7 tan6
𝑥 − 3 tan4
𝑥 − 3 tan2
𝑥 for all 𝑥 ∈ (−
𝜋
2
,
𝜋
2
). Then the correct expression(S)
is(are)
(A) ∫ 𝑥 𝑓( 𝑥) 𝑑𝑥 =
1
12
𝜋
4
0
(B) ∫ 𝑥 𝑓( 𝑥) 𝑑𝑥 = 0
𝜋
4
0
(C) ∫ 𝑥 𝑓( 𝑥) 𝑑𝑥 =
1
6
𝜋
4
0
(D) ∫ 𝑥 𝑓( 𝑥) 𝑑𝑥 = 1
𝜋
4
0
Answer Key: (A,B)
52. Let 𝑓′( 𝑥) =
193𝑥3
2+sin4 𝜋𝑥
for all 𝑥 ∈ ℝ with 𝑓 (
1
2
) = 0. If 𝑚 ≤ ∫ 𝑓( 𝑥) 𝑑𝑥 ≤ 𝑀,
1
1
2
then the possible values of
m and M are
(A) 𝑚 = 13, 𝑀 = 24
(B) 𝑚 =
1
4
, 𝑀 =
1
2
(C) 𝑚 = −11, 𝑀 = 0
(D) 𝑚 = 1, 𝑀 = 12
Answer Key: (D)
53. Let S be the set of all non – zero real numbers 𝛼 such that the quadratic equation 𝛼𝑥2
− 𝑥 + 𝛼 = 0 has
two distinct real roots 𝑥1 𝑎𝑛𝑑 𝑥2 satisfying the inequality | 𝑥1 − 𝑥2| < 1. Which of the following intervals
is(are) a subset(s) of S?
(A) (−
1
2
, −
1
√5
)
(B) (−
1
√5
, 0)
(C) (0,
1
√5
)
(D) (
1
√5
,
1
2
)
Answer Key: (A,D)
54. If 𝛼 = 3 sin−1 (
6
11
) 𝑎𝑛𝑑 𝛽 = 3 cos−1 (
4
9
) , where the inverse trigonometric functions take only the
principal values, then the correct options(s) is(are)
(A) cos 𝛽 > 0
(B) sin 𝛽 < 0
(C) cos( 𝛼 + 𝛽) > 0
(D) cos 𝛼 < 0
Answer Key: (B,C,D)
21. 55. Let 𝐸1 𝑎𝑛𝑑 𝐸2 be two ellipse whose centers are at the origin. The major axes of 𝐸1 𝑎𝑛𝑑 𝐸2 lie along the x
– axis and the y – axis, respectively. Let S be the circle 𝑥2
+ ( 𝑦 − 1)2
= 2. The straight line 𝑥 + 𝑦 = 3
touches the curves S, 𝐸1 𝑎𝑛𝑑 𝐸2 at P, Q and R, respectively. Suppose that 𝑃𝑄 = 𝑃𝑅 =
2√2
3
. 𝐼𝑓 𝑒1 𝑎𝑛𝑑 𝑒2
are the eccentricities of 𝐸1 𝑎𝑛𝑑 𝑒2, respectively, then the correct expression(s) is(are)
(A) 𝑒1
2
+ 𝑒2
2
=
43
40
(B) 𝑒1 𝑒2 =
√7
2√10
(C) |𝑒1
2
− 𝑒2
2
| =
5
8
(D) 𝑒1 𝑒2 =
√3
4
Answer Key: (A,B)
56. Consider the hyperbola 𝐻 ∶ 𝑥2
− 𝑦2
= 1 and a circle S with center 𝑁( 𝑥2, 0). Suppose that H and S touch
each other at point 𝑃( 𝑥1, 𝑦1) with 𝑥1 > 1 𝑎𝑛𝑑 𝑦1 > 0. The common tangent to H and S at P intersects
the x – axis at point M. If (𝑙, 𝑚) is the centroid of the triangle Δ𝑃𝑀𝑁, then the correct expression(s)
is(are)
(A)
𝑑𝑙
𝑑𝑥1
= 1 −
1
3𝑥1
2 𝑓𝑜𝑟 𝑥1 > 1
(B)
𝑑𝑚
𝑑𝑥1
=
𝑥1
3(√𝑥1
2−1)
𝑓𝑜𝑟 𝑥1 > 1
(C)
𝑑𝑙
𝑑𝑥1
= 1 +
1
3𝑥1
2 𝑓𝑜𝑟 𝑥1 > 1
(D)
𝑑𝑚
𝑑𝑦1
=
1
3
𝑓𝑜𝑟 𝑦1 > 0
Answer Key: (A,B,D)
SECTION 3 (Maximum Marks: 16)
This section contains TWO Paragraph
Based on each paragraph, there will be TWO questions
Each questions has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four options(s) is(are) correct
For each question, darken the bubble(s) corresponding to the correct option(s) in the
ORS
Marking scheme:
+4 If the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
-2 In all other cases
22. 57. One of the two boxes, box I and box II, was selected at random and a ball was drawn randomly out of
this box. The balls was found to be red. If the probability that this red ball was drawn from box II is
1
3
,
then the correct option(s) with the possible values of 𝑛1, 𝑛2, 𝑛3 𝑎𝑛𝑑 𝑛4 is(are)
(A) 𝑛1 = 3, 𝑛2 = 3, 𝑛3 = 5, 𝑛4 = 15
(B) 𝑛1 = 3, 𝑛2 = 6, 𝑛3 = 10, 𝑛4 = 50
(C) 𝑛1 = 8, 𝑛2 = 6, 𝑛3 = 5, 𝑛4 = 20
(D) 𝑛1 = 6, 𝑛2 = 12, 𝑛3 = 5, 𝑛4 = 20
Answer Key: (A,B)
58. A ball is drawn at random from box I and transferred to box II. If the probability of drawing a red ball
from box I, after this transfer, is
1
3
, then the correct options(s) with the possible values of 𝑛1 𝑎𝑛𝑑 𝑛2
is(are)
(A) 𝑛1 = 4 𝑎𝑛𝑑 𝑛2 = 6
(B) 𝑛1 = 2 𝑎𝑛𝑑 𝑛2 = 3
(C) 𝑛1 = 10 𝑎𝑛𝑑 𝑛2 = 20
(D) 𝑛1 = 3 𝑎𝑛𝑑 𝑛2 = 6
Answer Key: (C,D)
59. The correct statement(s) is(are)
(A) 𝑓′(1) < 0
(B) 𝑓(2) < 0
(C) 𝑓′( 𝑥) ≠ 0 𝑓𝑜𝑟 𝑎𝑛𝑦 𝑥 ∈ (1, 3)
(D) 𝑓′( 𝑥) = 0 𝑓𝑜𝑟 𝑠𝑜𝑚𝑒 𝑥 ∈ (1, 3)
Answer Key: (A,B,C)
60. If ∫ 𝑥2
𝐹′( 𝑥) 𝑑𝑥 = −12
3
1
and ∫ 𝑥3
𝐹′′( 𝑥) 𝑑𝑥 = 40,
3
1
then the correct expression(s) is(are)
(A) 9𝑓′(3) + 𝑓′(1) − 32 = 0
(B) ∫ 𝑓( 𝑥) 𝑑𝑥 = 12
3
1
(C) 9𝑓′(3) − 𝑓′(1) + 32 = 0
(D) ∫ 𝑓( 𝑥) 𝑑𝑥 = −12
3
1
Answer Key: (C,D)
PARAGRAPH 1
Let 𝑛1 𝑎𝑛𝑑 𝑛2 be the number of red and black balls, respectively, in box I. Let 𝑛3 𝑎𝑛𝑑 𝑛4 be the
number of red and black balls, respectively, in box II.
PARAGRAPH 2
Let 𝐹 ∶ ℝ → ℝ be a thrice differentiable function. Suppose that 𝐹(1) = 0, 𝐹(3) = −4 and 𝐹′( 𝑥) < 0
all 𝑥 ∈ (
1
2
, 3). Let 𝑓( 𝑥) = 𝑥𝐹(𝑥) for all 𝑥 ∈ ℝ.