Hibernate is an object-relational mapping tool for Java. It uses configuration and mapping files to establish connections to a database and map Java classes and their properties to database tables and columns. The main Hibernate objects are the Configuration, which reads configuration files; the SessionFactory, which is a factory for Session objects; and the Session, which provides the interface to work with the database and manage transactions using Transaction objects. Hibernate uses object-relational mapping to convert between object-oriented and relational structures.