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Globally Harmonized System (GHS)
December 2013
The Globally Harmonized System (GHS) is an international
approach to hazard communication, providing agreed
criteria for classification of chemical hazards, and a
standardized approach to label elements and safety data
sheets. The GHS was negotiated in a multi-year process by
Hazard communication experts from many different
countries, international organizations, and stakeholder
groups. It is based on major existing systems around the
world, including OSHA's Hazard Communication
Standard and the chemical classification and labeling
systems of other US agencies.
The GHS provides such a standardized approach, including detailed criteria
for determining what hazardous effects a chemical poses, as well as
standardized label elements assigned by hazard class and category.
This will enhance both employer and worker comprehension of the hazards,
which will help to ensure appropriate handling and safe use of workplace
chemicals.
In addition, the safety data sheet requirements establish an order of
Information that is standardized. The harmonized format of the safety data
sheets will enable employers, workers, health professionals, and emergency
responders to access the information more efficiently and effectively, thus
increasing their utility.
Adoption of the GHS in the US and around the world will also help to
improve information received from other countries—since the US is
both a major importer and exporter of chemicals, American workers
often see labels and safety data sheets from other countries. The
diverse and sometimes conflicting national and international
requirements can create confusion among those who seek to use
hazard information effectively.

For example, labels and safety data sheets may include symbols and hazard
statements that are unfamiliar to readers or not well understood. Containers
may be labeled with such a large volume of information that important
statements are not easily recognized.
Given the differences in hazard classification criteria, labels may also be
incorrect when used in other countries. If countries around the world adopt
the GHS, these problems will be minimized, and chemicals crossing borders
will have consistent information, thus improving communication globally.






Hazard classification: The definitions of hazard have
been changed to provide specific criteria for
classification of health and physical hazards, as well as
classification of mixtures. These specific criteria will
help to ensure that evaluations of hazardous effects are
consistent across manufacturers, and that labels and
safety data sheets are more accurate as a result.
Labels: Chemical manufacturers and importers will be
required to provide a label that includes a harmonized
signal word, pictogram, and hazard statement for each
hazard class and category. Precautionary statements
must also be provided.
Safety Data Sheets: Will now have a specified 16section format.
Let’s take a look at each change……….
Hazard Classifications
The hazard classification approach in the revised HCS is quite different. The
revised HCS has specific criteria for each health and physical hazard, along
with detailed instructions for hazard evaluation and determinations as to
whether mixtures or substances are covered. It also establishes both hazard
classes and hazard categories—for most of the effects; the classes are divided
into categories that reflect the relative severity of the effect.
The current HCS does not include categories for most of the health hazards
covered, so this new approach provides additional information that can be
related to the appropriate response to address the hazard.
Labels will require the following elements:
Pictogram: a symbol plus other graphic elements, such as a border, background pattern, or
color that is intended to convey specific information about the hazards of a chemical.
Each pictogram consists of a different symbol on a white background within a red
square frame set on a point (i.e. a red diamond). There are nine pictograms under the
GHS. However, only eight pictograms are required under the HCS.
Signal words: a single word used to indicate the relative level of severity of hazard and alert
the reader to a potential hazard on the label. The signal words used are "danger" and
"warning." "Danger" is used for the more severe hazards, while "warning" is used for less
severe hazards.
Hazard Statement: a statement assigned to a hazard class and category that describes the
nature of the hazard(s) of a chemical, including, where appropriate, the degree of
hazard.

Precautionary Statement: a phrase that describes recommended measures to be taken to
minimize or prevent adverse effects resulting from exposure to a hazardous chemical, or
improper storage or handling of a hazardous chemical.
Safety Data Sheets
The Hazard Communication Standard (HCS) (29 CFR 1910.1200(g)), revised in
2012, requires that the chemical manufacturer, distributor, or importer provide
Safety Data Sheets (SDSs) (formerly MSDSs or Material Safety Data Sheets) for
each hazardous chemical to downstream users to communicate information on
these hazards. The information contained in the SDS is largely the same as the
MSDS, except now the SDSs are required to be presented in a consistent userfriendly, 16-section format. This brief provides guidance to help workers who
handle hazardous chemicals to become familiar with the format and understand
the contents of the SDSs.
The next slide we will look at each section. Please note, Section 12 Ecological
information, Section 13 Disposal considerations, Section 14 Transport
information, Section 15 Regulatory information, Section 16 Other Information are
regulated by other agencies and OSHA will not be enforcing so these may be
blank.
Section 1: Identification includes product identifier, manufacturer or distributor name, address, phone
number, emergency phone, recommended use; restrictions on use.

Section 2: Hazard(s) identification includes all hazards regarding the chemical; required label elements
Section 3: Composition/information on ingredients includes information on chemical ingredients; trade
secret claims.

Section 4: First aid measures includes important symptoms/effects, acute, delayed; required treatment.
Section 5: Fire-fighting measures lists suitable extinguishing techniques, equipment ; chemical hazards
from fire.

Section 6: Accidental release measures lists emergency procedures, protective equipment, proper
methods of containment and clean up.

Section 7: Handling and storage lists precautions for safe handling and storage, including
incompatibilities.

Section 8: Exposures controls/personal protection lists OSHA’s Permissible Exposure Limits (PELs),
Threshold Limit Values (TLVs), appropriate engineering controls, personal protective equipment (PPE).

Section 9: Physical and chemical properties lists the chemical’s characteristics.
Section10: Stability and reactivity lists chemical stability and possibility of hazardous reactions.
Section 11: Toxicological information includes routes of exposure, related symptoms, acute and
chronic effects, numerical measures of toxicity.




OSHA has updated the requirements for
labeling of hazardous chemicals under its
Hazard Communication Standard (HCS).
As of June 1, 2015, all labels will be required to
have pictograms, a signal word, hazard and
precautionary statements, the product
identifier, and supplier identification.
Take a look at a sample label






OSHA expects that the modifications to the Hazard
Communication Standard (HCS) will result in increased
safety and health for the affected employees and reduce the
numbers of accidents, fatalities, injuries, and illnesses
associated with exposures to hazardous chemicals.
The GHS revisions to the HCS standard for labeling and
safety data sheets would enable employees exposed to
workplace chemicals to more quickly obtain and to more
easily understand information about the hazards associated
with those chemicals.
In addition, the revisions to HCS are expected to improve
the use of appropriate exposure controls and work practices
that can reduce the safety and health risks associated with
exposure to hazardous chemicals.
Effective 12/1/2013 OSHA has revised its Hazard Communication Standard (HCS) to align with the United Nations’
Globally Harmonized System of Classification and labeling of Chemicals GHS).

True

False
The definitions of Hazard have been changed to provide specific criteria for classification of health and physical
hazards, as well as classification of mixtures.

True

False
Labels will now require chemical manufacturers and importers to provide a label that includes a harmonized signal
word, pictogram, and hazard statement for each hazard class and category. Also, precautionary statements must also
be provided.

True


False

Safety Data Sheets will now have a specified 16-section format.

True

False
Where does Advanced Medical Imaging have their electronic MSDS sheets located:

AMI Intranet

The Disney Channel

AMI Website
Does Advanced Medical Imaging have a MSDS book at each location?

Yes

No

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Hazard communication standard presentation

  • 1. Globally Harmonized System (GHS) December 2013
  • 2. The Globally Harmonized System (GHS) is an international approach to hazard communication, providing agreed criteria for classification of chemical hazards, and a standardized approach to label elements and safety data sheets. The GHS was negotiated in a multi-year process by Hazard communication experts from many different countries, international organizations, and stakeholder groups. It is based on major existing systems around the world, including OSHA's Hazard Communication Standard and the chemical classification and labeling systems of other US agencies.
  • 3. The GHS provides such a standardized approach, including detailed criteria for determining what hazardous effects a chemical poses, as well as standardized label elements assigned by hazard class and category. This will enhance both employer and worker comprehension of the hazards, which will help to ensure appropriate handling and safe use of workplace chemicals. In addition, the safety data sheet requirements establish an order of Information that is standardized. The harmonized format of the safety data sheets will enable employers, workers, health professionals, and emergency responders to access the information more efficiently and effectively, thus increasing their utility.
  • 4. Adoption of the GHS in the US and around the world will also help to improve information received from other countries—since the US is both a major importer and exporter of chemicals, American workers often see labels and safety data sheets from other countries. The diverse and sometimes conflicting national and international requirements can create confusion among those who seek to use hazard information effectively. For example, labels and safety data sheets may include symbols and hazard statements that are unfamiliar to readers or not well understood. Containers may be labeled with such a large volume of information that important statements are not easily recognized. Given the differences in hazard classification criteria, labels may also be incorrect when used in other countries. If countries around the world adopt the GHS, these problems will be minimized, and chemicals crossing borders will have consistent information, thus improving communication globally.
  • 5.    Hazard classification: The definitions of hazard have been changed to provide specific criteria for classification of health and physical hazards, as well as classification of mixtures. These specific criteria will help to ensure that evaluations of hazardous effects are consistent across manufacturers, and that labels and safety data sheets are more accurate as a result. Labels: Chemical manufacturers and importers will be required to provide a label that includes a harmonized signal word, pictogram, and hazard statement for each hazard class and category. Precautionary statements must also be provided. Safety Data Sheets: Will now have a specified 16section format. Let’s take a look at each change……….
  • 6. Hazard Classifications The hazard classification approach in the revised HCS is quite different. The revised HCS has specific criteria for each health and physical hazard, along with detailed instructions for hazard evaluation and determinations as to whether mixtures or substances are covered. It also establishes both hazard classes and hazard categories—for most of the effects; the classes are divided into categories that reflect the relative severity of the effect. The current HCS does not include categories for most of the health hazards covered, so this new approach provides additional information that can be related to the appropriate response to address the hazard.
  • 7. Labels will require the following elements: Pictogram: a symbol plus other graphic elements, such as a border, background pattern, or color that is intended to convey specific information about the hazards of a chemical. Each pictogram consists of a different symbol on a white background within a red square frame set on a point (i.e. a red diamond). There are nine pictograms under the GHS. However, only eight pictograms are required under the HCS. Signal words: a single word used to indicate the relative level of severity of hazard and alert the reader to a potential hazard on the label. The signal words used are "danger" and "warning." "Danger" is used for the more severe hazards, while "warning" is used for less severe hazards. Hazard Statement: a statement assigned to a hazard class and category that describes the nature of the hazard(s) of a chemical, including, where appropriate, the degree of hazard. Precautionary Statement: a phrase that describes recommended measures to be taken to minimize or prevent adverse effects resulting from exposure to a hazardous chemical, or improper storage or handling of a hazardous chemical.
  • 8. Safety Data Sheets The Hazard Communication Standard (HCS) (29 CFR 1910.1200(g)), revised in 2012, requires that the chemical manufacturer, distributor, or importer provide Safety Data Sheets (SDSs) (formerly MSDSs or Material Safety Data Sheets) for each hazardous chemical to downstream users to communicate information on these hazards. The information contained in the SDS is largely the same as the MSDS, except now the SDSs are required to be presented in a consistent userfriendly, 16-section format. This brief provides guidance to help workers who handle hazardous chemicals to become familiar with the format and understand the contents of the SDSs. The next slide we will look at each section. Please note, Section 12 Ecological information, Section 13 Disposal considerations, Section 14 Transport information, Section 15 Regulatory information, Section 16 Other Information are regulated by other agencies and OSHA will not be enforcing so these may be blank.
  • 9. Section 1: Identification includes product identifier, manufacturer or distributor name, address, phone number, emergency phone, recommended use; restrictions on use. Section 2: Hazard(s) identification includes all hazards regarding the chemical; required label elements Section 3: Composition/information on ingredients includes information on chemical ingredients; trade secret claims. Section 4: First aid measures includes important symptoms/effects, acute, delayed; required treatment. Section 5: Fire-fighting measures lists suitable extinguishing techniques, equipment ; chemical hazards from fire. Section 6: Accidental release measures lists emergency procedures, protective equipment, proper methods of containment and clean up. Section 7: Handling and storage lists precautions for safe handling and storage, including incompatibilities. Section 8: Exposures controls/personal protection lists OSHA’s Permissible Exposure Limits (PELs), Threshold Limit Values (TLVs), appropriate engineering controls, personal protective equipment (PPE). Section 9: Physical and chemical properties lists the chemical’s characteristics. Section10: Stability and reactivity lists chemical stability and possibility of hazardous reactions. Section 11: Toxicological information includes routes of exposure, related symptoms, acute and chronic effects, numerical measures of toxicity.
  • 10.   OSHA has updated the requirements for labeling of hazardous chemicals under its Hazard Communication Standard (HCS). As of June 1, 2015, all labels will be required to have pictograms, a signal word, hazard and precautionary statements, the product identifier, and supplier identification. Take a look at a sample label
  • 11.
  • 12.
  • 13.    OSHA expects that the modifications to the Hazard Communication Standard (HCS) will result in increased safety and health for the affected employees and reduce the numbers of accidents, fatalities, injuries, and illnesses associated with exposures to hazardous chemicals. The GHS revisions to the HCS standard for labeling and safety data sheets would enable employees exposed to workplace chemicals to more quickly obtain and to more easily understand information about the hazards associated with those chemicals. In addition, the revisions to HCS are expected to improve the use of appropriate exposure controls and work practices that can reduce the safety and health risks associated with exposure to hazardous chemicals.
  • 14. Effective 12/1/2013 OSHA has revised its Hazard Communication Standard (HCS) to align with the United Nations’ Globally Harmonized System of Classification and labeling of Chemicals GHS).  True  False The definitions of Hazard have been changed to provide specific criteria for classification of health and physical hazards, as well as classification of mixtures.  True  False Labels will now require chemical manufacturers and importers to provide a label that includes a harmonized signal word, pictogram, and hazard statement for each hazard class and category. Also, precautionary statements must also be provided.  True  False Safety Data Sheets will now have a specified 16-section format.  True  False Where does Advanced Medical Imaging have their electronic MSDS sheets located:  AMI Intranet  The Disney Channel  AMI Website Does Advanced Medical Imaging have a MSDS book at each location?  Yes  No