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Outlines:
 Fossil fuels-Formation
 Coal-Types-Formation
 Coal resources, production and
consumption
 Coal mining technology
Environmental impacts of coal
mining
Fossil Fuels
2
Fossil Fuels
85% of the world’s
commercial energy
Coal
Natural gas
Oil
 Fossil fuels are fuels formed by natural processes
such as anaerobic decomposition of buried dead
organisms, containing energy originating in
ancient photosynthesis.
 The age of the organisms and their resulting fossil
fuels is typically millions of years, and sometimes
exceeds 650 million years.
 Fossil fuels contain high percentages of carbon and
include petroleum, coal, and natural gas.
3
Kerosene, also known as
paraffin, lamp oil and
coal oil (an obsolete
term), is a combustible
hydrocarbon liquid,
derived from petroleum,
widely used as a fuel in
industry and households.
4
5
 Partially decayed remains of plants,
animals and microorganisms
 300 million years ago
• much of earth’s climate was mild and
warm
– plants grew year round in vast
swamps
• as swamp plants and aquatic
microorganisms died
What are Fossil Fuels
6
 fell into or sunk in water,
decomposed very little due to
lack of oxygen
heat and pressure that
accompanied burial of organic
material by sediments
 converted decomposed
organic material into carbon-rich
materials we now call fossil fuels
What are Fossil Fuels Contd….
7
Industrial societies need a lot of
energy and, at the moment, rely
on fossil fuels as the main source
of this energy.
 Coal, oil and natural gas are
fossil fuels. They are carbon-
based materials that formed over
millions of years from the
remains of ancient plants and
animals.
What are Fossil Fuels Contd….
8
Fossil fuels are so useful because
they contain stored chemical
energy, which is converted into
large amounts of useful heat
energy when the fuels are
burned.
the total amount of fossil fuels
available is limited and so
 they are classed as non-
renewable energy resources
Fossil Fuels
9
Formation Fossil Fuels
 High Organic Production
 Burial of organic material
 Reducing conditions – little or no
free oxygen
 Reducing conditions preserve
organic matter
Common conditions
10
Petroleum
Natural Gas
Coal
Kerogen (“Oil Shale”)
Bitumen (“Tar Sands”)
Types of Fossil Fuels
11
Declining Fossil Fuels
Forecasts Boyle, Renewable Energy, Oxford
University Press (2004)
12
Coal
13
Coal
Solid fossil fuel formed in several
stages
Land plants that lived 300-400 million
years ago
Subjected to intense heat and pressure
over many millions of years
Mostly carbon, small amounts of sulfur
14
Coal – what do we use it for?
 Stages of coal formation
• 300 million year old forests
• peat > lignite > bituminous > anthracite
• Primarily strip-mined
 Used mostly for generating electricity
• 62% of the world’s electricity
• 52% of the U.S. electricity
 Enough coal for about 200-1000 years
• U.S. has 25% of world’s reserves
High environmental impact
15
How coal was formed
About 350 million years ago,
trees and other plants
photosynthesized and stored
the Sun’s energy.
Dead plants fell into swampy
water and the mud prevented
them from rotting away.
Over the years, the mud piled up and squashed the
plant remains.
After millions of years under this pressure, the mud
became rock and the dead plants became coal.
16
Formation of Coal
The formation of coal from dead plant matter
requires burial, pressure, heat and time
The process works best under anaerobic
conditions (no oxygen) since the reaction with
oxygen during decay destroys the organic
matter
It is the carbon content of the coal that
supplies most of its heating value
The greater the carbon to oxygen ratio the
harder the coal, the more reduced the state of
the carbons and the more potential energy it
contains
Formation of coal in flow diagram
Formation of Coal
The Formation of Coal Involves Several Steps:
2) Formation of Lignite Coal.
 Compaction of the peat due to burial drives
off volatile components like water and
methane, eventually producing a black-
colored, organic-rich coal called lignite .
Burial
1) Formation of Peat.
 Swamps are areas where organic matter
from plants accumulate. As the plants die
and get buried they compact to become
peat. With time and more compaction,
almost all of the water is lost and three
different grades of coal result.
Peat
Compactio
n
Lignite Coal Seam
Burial
 Soft coal which consist of about 85% carbon
and burns readily but produces a lot of
smoke.
Compaction
Bituminous
Formation of Coal
The Formation of Coal Involves Several Steps:
 Anthracite coal produces the most energy
when burned.
3) Formation of Bituminous Coal.
 Further compaction and heating results in a
more carbon- rich coal called bituminous
coal.
Burial
4) Formation of Anthracite Coal.
 If the rock becomes metamorphosed, a high
grade coal called anthracite is produced.
Burial
Metamorphis
m
 Hard dark coal which consist of 90% to 95%
carbon and burns very hot and clean. Forms
as a result of metamorphic conditions.
Anthracite
Coal Seam
http://earthsci.org
Cycle of Coal Formation
21
Classification of Coal
The products of coalification are divided into four
major categories based on the carbon content of the
material
Peat Lignite
Bituminous Anthracite
22
Classification of Coal
23
Nature of coal formation
exposed during formation to
– higher heat and pressure
» drier (lower water content)
» more compact (harder)
» higher heating value (=higher energy
content)
– lower heat and pressure
» wetter (higher water content)
» less compact (softer)
» lower heating value (=lower energy
content)
Coal types and composition
Natural
Graphite
Anthracite
Bituminous
fixed carbon
ash
kJ/g
35
35
35
sub-
bituminous
Lignite
Peat
Wood volatile matter
moisture content
27
25
21
20
Fuel Efficiency
As the coals becomes
harder, their carbon
content increases,
and so does the
amount of heat
released
Anthracite produces
twice the energy
(BTUs) of lignite
26
Coal overview
Overview BP website (BP.com)
Coal resource, production, consumption
27
Terminology- Resource and Reserve
Resource : is how much coal is actually in the ground
Reserve: This term refers to coal which is both “demonstrated” (meaning we
know it exists) and is deemed to be economically and technologically
mineable at any time
http://www.groundtruthtre
kking.org/Issues/Alaska
Coal/CoalTerminology.ht
ml
28
Proved coal reserve at the end of 2004
2004 BP website (BP.com)
29
Coal production-Coal consumption
2004BP website (BP.com)
Coal Mining
Strip Mining Subsurface Mining
Coal Mine
Coal occur in seams or beds
Thickness from inches to more
than 100 ft
Two types of mining e.g.
Strip (60%) and sub-surface
Strip: removed overburden rock and placed aside
Disadvantage of strip mining: erosion, acid mine
drainage, hazardous to surrounding vegetation and
aquatic life
Environmental Concerns
 Acid Mine Drainage
 Acid rain
 Increasing atmospheric
CO2
 subsidence
 Coal seam fires
Acid Mine Drainage
 Sulphur in the exposed coal
combine with oxygen and water
vapor to form sulfuric acid
(H2SO4)
 This acidic water is harmful to
vegetation and aquatic life.
First Chemical Reaction:
Oxidization of Pyrite
+2
FeS2 + O2 + H2O –> Fe + H2SO4
or (pyrite + dissolved oxygen + water) ->
(ferrous iron + sulfuric acid)
Second Chemical Reaction:
Oxidization of Soluble Iron
+2 + +3
Fe + O2 + H –> Fe + H2O
or (ferrous iron + oxygen +hydronium) -> (ferric iron + water)
Third Chemical Reaction:
Precipitation of Insoluble Iron
+3 +
Fe + H2O –> Fe(OH)3 + H
or (ferric iron + water) -> (iron hydroxide + hydronium )
Acid Rain
 From burning of coal releases SO2.
 There are 1 to 2% S
Increasing Carbon Dioxide
39
Global Fossil Carbon Emission
40
Emission of Carbon Dioxide
41
Carbon Dioxide & Mean Temp.
42
Global temp.
Subsidence and Coal Seam Fires
Subsidence Coal Seam Fire
The fuel is burned and the heat
produced is used to boil water. This
creates high-pressure, superheated
steam, which is then used to turn a
turbine.
How do fossil fuels produce electricity?
The turbine turns a generator and
so generates electricity.
Power stations that are fuelled by coal and oil, operate on the
same basic principle.
The cooling towers cool the steam, which condenses as water
and can then be recycled in the power station.
directly to turn the turbine.
Natural-gas-fired power stations do not use steam. The
natural gas is burnt and the hot gases produced are used
45
Thank you……….
46

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Fossil Fuel

  • 1. 1 Outlines:  Fossil fuels-Formation  Coal-Types-Formation  Coal resources, production and consumption  Coal mining technology Environmental impacts of coal mining Fossil Fuels
  • 2. 2 Fossil Fuels 85% of the world’s commercial energy Coal Natural gas Oil
  • 3.  Fossil fuels are fuels formed by natural processes such as anaerobic decomposition of buried dead organisms, containing energy originating in ancient photosynthesis.  The age of the organisms and their resulting fossil fuels is typically millions of years, and sometimes exceeds 650 million years.  Fossil fuels contain high percentages of carbon and include petroleum, coal, and natural gas. 3
  • 4. Kerosene, also known as paraffin, lamp oil and coal oil (an obsolete term), is a combustible hydrocarbon liquid, derived from petroleum, widely used as a fuel in industry and households. 4
  • 5. 5  Partially decayed remains of plants, animals and microorganisms  300 million years ago • much of earth’s climate was mild and warm – plants grew year round in vast swamps • as swamp plants and aquatic microorganisms died What are Fossil Fuels
  • 6. 6  fell into or sunk in water, decomposed very little due to lack of oxygen heat and pressure that accompanied burial of organic material by sediments  converted decomposed organic material into carbon-rich materials we now call fossil fuels What are Fossil Fuels Contd….
  • 7. 7 Industrial societies need a lot of energy and, at the moment, rely on fossil fuels as the main source of this energy.  Coal, oil and natural gas are fossil fuels. They are carbon- based materials that formed over millions of years from the remains of ancient plants and animals. What are Fossil Fuels Contd….
  • 8. 8 Fossil fuels are so useful because they contain stored chemical energy, which is converted into large amounts of useful heat energy when the fuels are burned. the total amount of fossil fuels available is limited and so  they are classed as non- renewable energy resources Fossil Fuels
  • 9. 9 Formation Fossil Fuels  High Organic Production  Burial of organic material  Reducing conditions – little or no free oxygen  Reducing conditions preserve organic matter Common conditions
  • 10. 10 Petroleum Natural Gas Coal Kerogen (“Oil Shale”) Bitumen (“Tar Sands”) Types of Fossil Fuels
  • 11. 11 Declining Fossil Fuels Forecasts Boyle, Renewable Energy, Oxford University Press (2004)
  • 13. 13 Coal Solid fossil fuel formed in several stages Land plants that lived 300-400 million years ago Subjected to intense heat and pressure over many millions of years Mostly carbon, small amounts of sulfur
  • 14. 14 Coal – what do we use it for?  Stages of coal formation • 300 million year old forests • peat > lignite > bituminous > anthracite • Primarily strip-mined  Used mostly for generating electricity • 62% of the world’s electricity • 52% of the U.S. electricity  Enough coal for about 200-1000 years • U.S. has 25% of world’s reserves High environmental impact
  • 15. 15 How coal was formed About 350 million years ago, trees and other plants photosynthesized and stored the Sun’s energy. Dead plants fell into swampy water and the mud prevented them from rotting away. Over the years, the mud piled up and squashed the plant remains. After millions of years under this pressure, the mud became rock and the dead plants became coal.
  • 16. 16 Formation of Coal The formation of coal from dead plant matter requires burial, pressure, heat and time The process works best under anaerobic conditions (no oxygen) since the reaction with oxygen during decay destroys the organic matter It is the carbon content of the coal that supplies most of its heating value The greater the carbon to oxygen ratio the harder the coal, the more reduced the state of the carbons and the more potential energy it contains
  • 17. Formation of coal in flow diagram
  • 18. Formation of Coal The Formation of Coal Involves Several Steps: 2) Formation of Lignite Coal.  Compaction of the peat due to burial drives off volatile components like water and methane, eventually producing a black- colored, organic-rich coal called lignite . Burial 1) Formation of Peat.  Swamps are areas where organic matter from plants accumulate. As the plants die and get buried they compact to become peat. With time and more compaction, almost all of the water is lost and three different grades of coal result. Peat Compactio n Lignite Coal Seam Burial
  • 19.  Soft coal which consist of about 85% carbon and burns readily but produces a lot of smoke. Compaction Bituminous Formation of Coal The Formation of Coal Involves Several Steps:  Anthracite coal produces the most energy when burned. 3) Formation of Bituminous Coal.  Further compaction and heating results in a more carbon- rich coal called bituminous coal. Burial 4) Formation of Anthracite Coal.  If the rock becomes metamorphosed, a high grade coal called anthracite is produced. Burial Metamorphis m  Hard dark coal which consist of 90% to 95% carbon and burns very hot and clean. Forms as a result of metamorphic conditions. Anthracite Coal Seam
  • 21. 21 Classification of Coal The products of coalification are divided into four major categories based on the carbon content of the material Peat Lignite Bituminous Anthracite
  • 23. 23 Nature of coal formation exposed during formation to – higher heat and pressure » drier (lower water content) » more compact (harder) » higher heating value (=higher energy content) – lower heat and pressure » wetter (higher water content) » less compact (softer) » lower heating value (=lower energy content)
  • 24. Coal types and composition Natural Graphite Anthracite Bituminous fixed carbon ash kJ/g 35 35 35 sub- bituminous Lignite Peat Wood volatile matter moisture content 27 25 21 20
  • 25. Fuel Efficiency As the coals becomes harder, their carbon content increases, and so does the amount of heat released Anthracite produces twice the energy (BTUs) of lignite
  • 26. 26 Coal overview Overview BP website (BP.com) Coal resource, production, consumption
  • 27. 27 Terminology- Resource and Reserve Resource : is how much coal is actually in the ground Reserve: This term refers to coal which is both “demonstrated” (meaning we know it exists) and is deemed to be economically and technologically mineable at any time http://www.groundtruthtre kking.org/Issues/Alaska Coal/CoalTerminology.ht ml
  • 28. 28 Proved coal reserve at the end of 2004 2004 BP website (BP.com)
  • 30. Coal Mining Strip Mining Subsurface Mining
  • 31. Coal Mine Coal occur in seams or beds Thickness from inches to more than 100 ft Two types of mining e.g. Strip (60%) and sub-surface Strip: removed overburden rock and placed aside Disadvantage of strip mining: erosion, acid mine drainage, hazardous to surrounding vegetation and aquatic life
  • 32. Environmental Concerns  Acid Mine Drainage  Acid rain  Increasing atmospheric CO2  subsidence  Coal seam fires
  • 33. Acid Mine Drainage  Sulphur in the exposed coal combine with oxygen and water vapor to form sulfuric acid (H2SO4)  This acidic water is harmful to vegetation and aquatic life.
  • 34. First Chemical Reaction: Oxidization of Pyrite +2 FeS2 + O2 + H2O –> Fe + H2SO4 or (pyrite + dissolved oxygen + water) -> (ferrous iron + sulfuric acid)
  • 35. Second Chemical Reaction: Oxidization of Soluble Iron +2 + +3 Fe + O2 + H –> Fe + H2O or (ferrous iron + oxygen +hydronium) -> (ferric iron + water)
  • 36. Third Chemical Reaction: Precipitation of Insoluble Iron +3 + Fe + H2O –> Fe(OH)3 + H or (ferric iron + water) -> (iron hydroxide + hydronium )
  • 37. Acid Rain  From burning of coal releases SO2.  There are 1 to 2% S
  • 41. 41 Carbon Dioxide & Mean Temp.
  • 43. Subsidence and Coal Seam Fires Subsidence Coal Seam Fire
  • 44. The fuel is burned and the heat produced is used to boil water. This creates high-pressure, superheated steam, which is then used to turn a turbine. How do fossil fuels produce electricity? The turbine turns a generator and so generates electricity. Power stations that are fuelled by coal and oil, operate on the same basic principle. The cooling towers cool the steam, which condenses as water and can then be recycled in the power station. directly to turn the turbine. Natural-gas-fired power stations do not use steam. The natural gas is burnt and the hot gases produced are used
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