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Instructions
Experiments
                               Instruction Manual
Sample Data                             No. 012-08745A




               Energy Transfer–
                Thermoelectric
                     ET-8782
Energy Transfer–Thermoelectric                                                                                         Model No. ET-8782




                                                Table of Contents



Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Experiment 1:
Conservation of Energy and the First Law of Thermodynamics . . . . . . . . . . . . . . . . . . . . . 9

Experiment 1:
Teachers’ Notes–Conservation of Energy and the First Law of Thermodynamics . . . . . 15

Experiment 2:
Load Resistance and Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

Experiment 2:
Teachers’ Notes–Load Resistance and Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23

Experiment 3:
A Model Refrigerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25

Experiment 3:
Teachers’ Notes–A Model Refrigerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29

Experiment 4:
Coefficient of Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

Experiment 4:
Teachers’ Notes–Coefficient of Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

Experiment 5:
Teachers’ Notes–Carnot Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39

Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

Technical Support . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

Copyright and Warranty Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Model No. ET-8782                                                      Energy Transfer–Thermoelectric




            Energy Transfer–Thermoelectric
                                             Model No. ET-8782



                                                                             1




6




5




                                                                         2                    3   4



           Included Equipment                                      Replacement Part Number

           1. Thermoelectric circuit board                                   ET-8782

           2. Foam insulators (qty. 2)                                       648-08724

           3. Heat sink                                                       624-013

           4. Thumbscrew                                               617-018 and 615-031

           5. Temperature cables (qty. 2)                                    PS-2515

           6. Banana patch cords (qty. 8)                                    SE-7123

           7. CD-ROM containing editable experiment instructions       Contact Tech Support
              and DataStudio® files (not pictured)




            ®                                                                                         3
Energy Transfer–Thermoelectric                                                                       Introduction




         Additional Equipment Required                                       Model Number

         DC Power Supply (10 V, 1 A minimum)                               SE-9720A or equivalent

         Temperature Sensor(s), compatible with 10 kΩ thermistors          Various, see note below

         Voltage and Current Sensor(s)                                     Various, see note below

         PASCO Computer Interface                                          Various, see note below

         DataStudio software                                                 See PASCO catalog




         Optional Equipment                                                  Model Number

         Fast Response Temperature Probes                                     PS-2135 (3-pack)

         Decade Resistance Box                                              SE-7122 or equivalent




    Note

    The most convenient combination of interface and sensors for use with the Thermoelectric circuit
    board is:

    •   PS-2001 PowerLink interface
    •   PS-2143 Quad Temperature Sensor
    •   PS-2115 Voltage/Current Sensor
    •   PS-2135 Fast Response Temperature Probes (3-pack), optional

    This is the equipment called for by the experiments in this manual and on the CD-ROM. There are
    other options for PASPORT™ and ScienceWorkshop® sensors and interfaces, and stand-alone
    multimeters. Please contact Tech Support, or see the PASCO catalog or website for details.


Introduction

    The Energy Transfer–Thermoelectric circuit board provides students with a hands-on example of
    a thermoelectric heat engine. Using measurements from temperature, voltage and current sensors,
    students will quantitatively study the energy, work and heat flow associated with heat engines,
    heat pumps and refrigerators.

    This manual includes instructions for five experiments with sample data and teachers’ notes. You
    can photocopy the student instructions or print them from the editable copy of this manual
    included on the CD-ROM. Experiment #5 is a DataStudio workbook, which contains the student
    instructions within the DataStudio file.

    In addition to the experiments detailed here, the Thermoelectric board is well-suited for self-
    guided exploration. The following sections will familiarize you with the components of the
    experimental set-up.

4                                                                                                              ®
Model No. ET-8782                                                                             Introduction


                                                  5
                                                                        4




                                                                                                       2
  6




                             1                        3




   1. Peltier Device with Hot and Cold Reservoirs

   The Peltier Device is constructed of two ceramic plates with p and n semiconductors in between.
   As DC current passes through the device, it pumps heat from one side to the other. Aluminum
   blocks are fastened to each side of the peltier in thermal contact with the ceramic plates. These
   blocks add thermal mass to the system and act as the traditional Hot and Cold Reservoirs. When
   there is a temperature difference across the peltier, it can be switched to Heat Engine Mode, in
   which spontaneous heat flow through the device generates an electric current. Do not touch the
   hot aluminum block when it is running in Heat Pump Mode. The temperature of this block can
   reach 90 °C or higher.

   Do not allow the peltier device to reach temperatures above 100 ºC. Always monitor the
   temperature of the hot side when the peltier is operating in Heat Pump Mode. Operation between
   80 °C and 100 °C will shorten the life of the device; if you operate the device in that temperature
   range, do so for the briefest possible time. You can operate the peltier device without damage at
   temperatures below 80 °C.




            ®                                                                                              5
Energy Transfer–Thermoelectric                                                                 Introduction


    2. Input Power

    Input Power for the board must be supplied from an external DC power supply capable of 1 amp
    at 10 volts. Connect the power supply via the red and black banana jacks on the right-hand side of
    the board. Note the polarity: red must be positive. Do not input more than 10 volts.


    3. Load Resistors

    In Heat Engine Mode, a jumper cable must be connected from the bottom banana jack terminal to
    one of the terminals labeled A through D. The load resistance depends on how you connect the
    jumper cables. If, for example, the jumper is connected to terminal A, then all of the resistors are
    in series in the circuit, and the total load resistance is 20 Ω + 7 Ω + 3 Ω = 30 Ω. If the jumper is
    connected to terminal C, the load resistance is 3 Ω. A second jumper can also be used across a
    resistor to remove it from the circuit. For example, if the main jumper from the bottom connector
    is plugged into terminal A, and a second jumper is connected between B and D, the total load
    resistance is 20 Ω; the 7 Ω and 3 Ω resistors are bypassed.
    The possible combinations are 3 Ω, 7 Ω, 10 Ω, 20 Ω, 23 Ω, 27 Ω and 30 Ω. If you use a decade
    resistance box instead of the on-board resistors, you can supply any value you want. You can also
    connect the jumper from the bottom terminal directly to terminal D, which reduces the load
    resistance to a few tenths of an ohm (due to the internal resistance of the circuit).


    4. Knife Switch

    The single pole double throw Knife Switch on the right side of the board is used to select the
    mode of operation. In Heat Pump Mode, external power is applied to the peltier device, and heat
    is pumped from the aluminum block on the cold side to the block on the hot side. In Heat Engine
    Mode, the external power is disconnected, and heat flows back through the peltier, generating
    electric current through the load resistor.


    5. Voltage and Current
    Voltage and current sensors connected to the banana jacks at the top of the board will measure
    voltage across and current through the peltier. Note the polarity when you connect the sensors. A
    single PASPORT Voltage/Current sensor can be used for both measurements. If you plan to run
    the peltier without a current sensor, you must connect a jumper between the current terminals to
    complete the circuit.

    From the measured voltage and current, DataStudio will calculate the power supplied to the
    peltier (in Heat Pump mode) or power generated by the peltier (in Heat Engine mode). DataStudio
    will plot a graph of power versus time, which it will use to calculate input or output energy.


    6. Temperature Ports

    Each aluminum block has a 10 kΩ thermistor embedded in it. Use the provided Temperature
    Cables to connect temperature sensors to the thermistors through the hot-side and cold-side

6                                                                                                          ®
Model No. ET-8782                                                                               Introduction


   Temperature Ports. The temperature sensor measures the resistance of the thermistor and
   translates it into a temperature reading. If you are using a PASPORT Quad Temperature sensor,
   you will connect both temperature ports (and up to two additional probes) to a single sensor.

   From the measured temperature change, DataStudio will calculate the heat flow into or out of the
   aluminum blocks.

                                           7




                                     8                  9



   7. Foam Insulators and Heat Sink

   The Foam Insulators are used to insulate one side or both sides of the peltier. For conservation of
   energy studies, use both insulators to minimize heat exchange with the environment. If needed,
   you can put a rubber band around them to hold them tightly together.

   The Heat Sink, which helps to dissipate heat, fastens to the hot-side aluminum block with the
   provided thumb screw. For more efficient cooling, the fins of the heat sink should be vertical. Be
   careful when removing the heat sink because it can get very hot.

   In some experiments, you will have an insulator on the cold side, and the heat sink on the hot side.


   8. Cooling Fan

   The Cooling Fan and heat sink act together to dissipate heat from the hot reservoir. The fan is used
   when demonstrating a refrigerator. You can also use it to cool the aluminum blocks back to room
   temperature, which is a required initial condition in some experiments.

   The fan is operated through a switch in the center of the board and it is powered by the same
   external power supply that powers the peltier. The fan has a built-in regulator, so it will run at a
   constant speed when the input voltage is 6 volts or higher. Do not use the fan when the input
   voltage is below 4 volts.

            ®                                                                                             7
Energy Transfer–Thermoelectric                                                                Introduction


    9. Temperature Sensor Clamps

    When modeling a refrigerator it is useful to observe the heat flow around the heat sink. Two
    Temperature Sensor Clamps (one high, one low) are provided to position Fast Response
    Temperature Probes (not included) in the air stream from the fan before and after the air has
    passed through the heat sink.




8                                                                                                       ®
Model No. ET-8782                                                          Energy Transfer–Thermoelectric




Experiment 1:
Conservation of Energy and the First Law of
Thermodynamics

           Equipment Required                                                 Part Number

           Thermoelectric circuit board                                        part of ET-8782

           Foam insulators (qty. 2)                                            part of ET-8782

           Banana patch cords (qty. 5)                                         part of ET-8782

           Temperature cables (qty. 2)                                         part of ET-8782

           DC Power Supply (10 V, 1 A minimum)                             SE-9720A or equivalent

           PASPORT Voltage/Current Sensor                                         PS-2115

           PASPORT Quad Temperature Sensor                                        PS-2143

           PASPORT interface(s)                                             PS-2001 or equivalent

           DataStudio software                                              See PASCO catalog

           “Conservation of Energy” configuration file for DataStudio          part of ET-8782




Introduction
   In this activity you will study the flow of energy in the experimental set-up as you run it through a
   cycle.

   First you will operate the apparatus in Heat Pump mode, in which energy is supplied to the peltier,
   and the peltier pumps heat from one aluminum block to the other. After a temperature difference
   has been established between the blocks, you will switch the peltier into Heat Engine mode, in
   which heat flows from the hot block, through the peltier, and into the cold block. The peltier will
   convert some of the heat that flows out of the hot block to electrical energy, which it will supply to
   the load resistor.

   During this cycle you will follow the energy as in moves in different forms from the power supply
   to the peltier (electrical energy), in and out of the aluminum blocks (heat or thermal energy), and
   into the load resistor (electrical energy). As you do the experiment, bear in mind the law of
   conservation of energy and the first law of thermodynamics. How do they relate to the transfer of
   energy within the system?


Set-Up
   1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up).
      Connect the power supply using banana patch cords to the input power terminals on the
      circuit board as shown in picture below. Note the polarity.

             ®                                                                                              9
Energy Transfer–Thermoelectric                Conservation of Energy and the First Law of Thermodynamics


     2. Load Resistance: Connect a jumper from                                           Voltage/Current
                                                                                             Sensor
        the terminal at the bottom of the board to
        Terminal B. This makes the load resistance
        3 Ω + 7 Ω = 10 Ω.

     3. Insulators: Place both foam insulators on
        the aluminum blocks.

     4. Temperature: Connect the cables from the
        temperature ports to the Quad Temperature
        Sensor. Connect the Cold Side to Channel 1         Ch 2

        of the sensor and the Hot Side to Channel 2.       Temperature                              Power Supply
                                                             Sensor
     5. Voltage: Connect the voltage leads of the
        Voltage/Current Sensor to the Voltage Ports        Ch 1
        on the board. Note the polarity.

     6. Current: Connect separate red and
        black banana patch cords from the
        current input of the Voltage/Current
        sensor to the Current Ports on the
        board. Note the polarity.
     7. Computer: Connect the sensors to the
        computer through the PASPORT
        interface. Open the pre-configured
        DataStudio file “Conservation of
        Energy”. The display should look as
        shown here.


Background
     DataStudio has been configured to measure and record the temperature of both aluminum blocks,
     the voltage and current applied to the peltier during Heat Pump mode, and the voltage and current
     generated by the peltier during Heat Engine mode. From these measured quantities, DataStudio
     will calculate and display heat flow, power and work. The following sections explain how
     DataStudio makes those calculations.


     Heat vs. Temperature

     Each digits display shows the heat (Q hot or Q cold) that flows into or out of the aluminum block on
     either the hot or cold side of the peltier. The relationship between heat flow and temperature
     change is given by

                                                 Q = mc∆T

     where:


10                                                                                                                 ®
Model No. ET-8782           Experiment 1: Conservation of Energy and the First Law of Thermodynamics


       Q   = heat transferred,
       m   = mass of the aluminum block,
       c   = specific heat of aluminum = 0.90 J/(g·°C),
      ∆T   = change in temperature.

   A positive value of Q may represent heat transferred into or out of the aluminum block,
   depending on whether the block is on the hot side or the cold side of the peltier, and whether the
   peltier is operating as a heat pump or a heat engine.

   The temperature of each block is measured by the embedded thermistor. DataStudio calculates the
   heat flow from the measured temperature change, and pre-entered values of m and c. Click on the
   calculator icon in the tool bar and look at the equations used; note the constants, m and c, in the
   bottom section of the calculator window. (The mass of each block is about 19 g. If you would like
   to enter your own value for the mass, measure the blocks with calipers and use the density of
   aluminum, 2.7 g/cc, to calculate the mass, then enter it in the calculator.)


   Input Power and Work Done by the Peltier Heat Pump

   In Heat Pump mode, Input Power from the power supply equals the rate at which the peltier does
   work to pump heat out of the cold reservoir and into the hot reservoir. The Voltage/Current Sensor
   measures the voltage applied to the peltier, and the current that flows through it. DataStudio
   calculates the Input Power using the equation: Power = Voltage × Current.

   The area under the plot of Input Power versus time equals the energy supplied to the peltier, which
   equals the work done by the peltier.


   Power Generated and Work Done by the Peltier Heat Engine
   In Heat Engine mode, Power Generated is the rate at which the peltier does work on the load
   resistor. The Voltage/Current sensor measures the voltage across the resistor and the current
   through it. From these measurements, DataStudio calculates the power supplied to the load
   resistor. The area under the plot of Power Generated versus time equals the work that the peltier
   has done on the resistor.


Procedure
   Before you start, the aluminum blocks should both be at room temperature. The knife switch
   should be in neutral position (straight up) and the fan should be switched off.

   Set the DC Voltage to between 3 and 4 volts.

   Start data recording, then set the knife switch to Heat Pump.

   You will see Input Power data appear in the top section of graph. The area under the graph equals
   the energy supplied to the peltier, which equals the work done by the heat pump. The Heat Pump
   digits display shows the heat pumped out of cold reservoir (Q cold) and the heat deposited into the
   hot reservoir (Q hot).

             ®                                                                                           11
Energy Transfer–Thermoelectric                Conservation of Energy and the First Law of Thermodynamics


     Observe how the temperatures of the aluminum blocks change.

     Run the peltier in Heat Pump mode for about a minute (or until the cold side appears to reach a
     minimum temperature), then switch to Heat Engine mode.

     Again, observe how the temperatures of the aluminum blocks change.

     Power Generated data now appears in the bottom section of the graph display. The area under the
     graph equals the energy generated by the heat engine and supplied to the load resistor. The Heat
     Engine digits display shows the heat that has flowed out of the hot reservoir (Q hot) and the heat
     that has flowed into the cold reservoir (Q cold).

     Continue to record until the aluminum blocks are close to the same temperature.


Analysis                                                                                       Hot Reservoir


                                                                                                    Qhot
     Heat Pump Mode
                                                                                                 Heat Pump
     In Heat Pump mode the peltier does work to pump heat out of the cold reservoir
     and into the hot reservoir.                                                                                W

          W = work done by the peltier (equal to the area under the Input Power curve),          Qcold
       Q hot = heat pumped into the hot reservoir,
       Q cold = heat pumped out of the cold reservoir.                                        Cold Reservoir


     By the first law of thermodynamics,

                                               Q hot = Q cold + W

     1) Where did the heat pumped out of the cold reservoir go? Where did the heat pumped into the
        hot reservoir come from? Why was more heat pumped into the hot reservoir than was pumped
        out of the cold reservoir?

     2) Compare your observed values of (Q cold + W) and Q hot. If they are not equal, where did the
        “lost energy” go?

     3) Write an equation in terms of the “lost energy”, E lost, and your observed data, W, Q hot and
        Q cold.
                                                                                                Hot Reservoir

     Heat Engine Mode
                                                                                                    Qhot
     In a heat engine, heat flows out of the hot reservoir, some of the heat is
                                                                                                Heat Engine
     converted to work, and the rest of the heat flows into the cold reservoir.

          W = work done by the heat engine,                                                                     W

       Q hot = heat flow out of the hot reservoir,                                                Qcold
       Q cold = heat flow into the cold reservoir.
                                                                                               Cold Reservoir
     By the first law of thermodynamics,
12                                                                                                              ®
Model No. ET-8782            Experiment 1: Conservation of Energy and the First Law of Thermodynamics


                                                  W = Q hot – Q cold

   4) Compare your observed value of work, Wobserved (which is the area under the Power vs. Time
      plot) to the quantity Q hot – Q cold. Are they equal?

   5) In a real heat engine, only part of the heat that flows out of the two-reservoir system
      (Q hot – Q cold) is converted to useful work. In this experiment, the work that you observed (the
      useful work) was the work done on the load resistor. Can you account for all of the energy
      that flowed out of the hot reservoir with your values of Wobserved, Q hot and Q cold? If not, where
      did the “lost energy” go?

   6) Calculate the proportion of net heat flow from the aluminum blocks that was converted to
      useful work;

                                                       W observed
                                % of useful work = --------------------------- × 100 %
                                                                             -
                                                   Q hot – Q cold

   7) Write an equation in terms of the “lost energy”, E lost, and your observed data, Wobserved, Q hot
      and Q cold.

   8) In this experiment the “useful work” was the work done on the load resistor. What was the
      result of doing work on the resistor? How could you modify the circuit in order to make better
      use of the work done by the heat engine?


   Conservation of Energy

   In the Heat Pump phase of the cycle the power supply put energy into the system. Then, in the
   Heat Engine phase heat flowed out of the hot reservoir and part of it was converted into electrical
   energy, which was supplied to the load resistor.

   9) Calculate the percentage of energy put in during the Heat Pump phase that was recovered as
      useful work during the Heat Engine phase;

                                             energy generated
                               % recovered = ---------------------------------------- × 100 %
                                                                                    -
                                                  energy put in

   10) Is this a good way to store energy?


   Conduction and Heat Flow Through the Insulators

   One of the losses of energy in this experiment has to do with heat flow by conduction through the
   polyethylene foam insulators. The rate of heat flow through the insulator is

                                                                ∆T
                                                   Q i ⁄ t = kA ------
                                                                     -
                                                                  x

   where:


             ®                                                                                              13
Energy Transfer–Thermoelectric                 Conservation of Energy and the First Law of Thermodynamics


       Q i /t = heat flow rate through the insulator,
           k = thermal conductivity of the polyethylene foam = 0.036 W/(m·°C),
          A = area through which the heat flows,
        ∆T = temperature difference across the insulator,
           x = thickness of the insulating material.

     You will estimate the amount of heat that flowed through the foam in contact with the front face
     of the cold block.

     Measure the height and width of the cavity in the insulator that surrounds the aluminum
     block. Calculate the cross-sectional area, A in m2.

     Measure the thickness, x, of the foam that covers the front face of the block. Do not include the
     sides of the foam (you are only calculating the heat flow through the front face). Record your
     measurement in meters.
     From the temperature graph, determine the difference, ∆T, between the temperature of the cold
     block and room temperature. This value changed during the experiment, so record the maximum
     difference, when the cold block was at its coldest. This will give you an estimate of the maximum
     heat flow rate through the insulator.

     11) Calculate the heat flow rate through the foam, Q i /t. This is the heat flow rate in joules/second.
         To find the total amount of heat in joules, multiply this number by the total time in seconds
         that the experiment ran; Q i = (heat flow rate) × (time).
     12) How does your estimate of Q i compare to the heat, Q cold, that was pumped out of the cold
         block in the Heat Pump phase? Is it much larger, much smaller, or similar?

     13) Is your estimate of heat flow through the insulator too high or too low? Remember that you
         ignored the sides in your estimate, and that you used the maximum temperature difference for
         ∆T.

     14) How would the flow of heat through the insulator on the hot side compare to heat flow
         through the insulator on the cold side? Consider both the magnitude and direction of heat
         flow.

     15) Is heat flow through the insulators (on the hot and cold sides) a significant factor in this
         experiment? Could the heat flow through the insulators account for the discrepancy between
         your observed results and the first law of thermodynamics?

     16) How would your results have differed if you had not used the insulators?


Further Investigation
     What are some factors that you could vary in the experimental apparatus and procedure? Predict
     how changing those factors would affect the results. Do an experiment to test one of your
     predictions.



14                                                                                                             ®
Model No. ET-8782                                                            Energy Transfer–Thermoelectric




Experiment 1:
Teachers’ Notes–Conservation of Energy
and the First Law of Thermodynamics




                        This sample data is in the file “Conservation of Energy Data”.


   Heat Pump Mode

                                               Q hot = 172.8 J

                                            Q cold + W = 233.1 J

   1) Most of the heat pumped out of the cold reservoir went into the hot reservoir. The heat
      pumped into the hot reservoir is greater than the heat pumped out of the cold reservoir
      because Q hot also includes the work done by the peltier.

   2) Q hot < Q cold + W. Some energy was lost. Part of it flowed through the insulator to the
      environment. Part of it was dissipated in other parts of the circuit.

   3)                                     Q hot = Q cold + W – E lost


   Heat Engine Mode

                                             Wobserved = 0.572 J

                                            Q hot – Q cold = 3.3 J

   4)                                     Wobserved < Q hot – Q cold
            ®                                                                                           15
Energy Transfer–Thermoelectric                                              Teachers’ Notes–Conservation of Energy


     5) Most of the heat that flowed out of the two-reservoir system was lost. Some of it flowed
        through the foam insulators to the environment. Some of it was dissipated in other parts of the
        circuit.

                                                  ( 0.572 J )
     6)                        % of useful work = --------------------- × 100 % = 17 %
                                                                      -
                                                     ( 3.3 J )

     7)                                     Wobserved = Q hot – Q cold – E lost

     8) The result of doing work on the resistor was that the resistor dissipated heat to the
        environment. For a more practical use of the useful work, the resistor could have been
        replaced with a light bulb, an electric motor, or some other electrical device.


     Conservation of Energy

                                                 0.572 J
     9)                            % recovered = ---------------- × 100 % = 0.9 %
                                                                -
                                                  60.3 J

     10) This is not a good way to store energy.


     Conduction and Heat Flow Through Insulator

                                                                               ( 7 °C )
     11)      Q i ⁄ t = [ 0.36 W/(m·°C) ] × [ ( 0.033 m ) × ( 0.037 m ) ] × --------------------- = 0.031 J/s
                                                                            ( 0.01 m )

                                         Q i = (0.031 J/s) × (150 s) = 4.6 J

     12) Q i is small compared to Q cold.

     13) This is an estimate of the heat that flowed from the outside air, through the insulator, and into
         the front face of the aluminum block on the cold side. Some more heat flowed in through the
         sides that we ignored. Q i is likely an overestimate because the actual temperature difference
         was not always as large as the ∆T that was used in the calculation, and the surface area of the
         front face is larger than that of the sides.

     14) Heat flow through the insulator on the hot side would be larger in magnitude because there
         was a greater temperature difference between the block and the outside air. Since the block
         was hotter than the air, heat would have flowed out to the environment.

     15) The amounts of “lost energy” in the Heat Pump and Heat Engine phases were 12.5 J and 2.7 J.
         The estimate of Q i suggests that heat flow through the insulators was a significant
         contribution to this unaccounted-for energy. Another possible contribution to the lost energy
         is heat dissipated by other components of the circuit, especially the material inside the peltier.

     16) Without the insulators, it is likely that the net heat flow to the environment would have been
         greater, thus increasing the amount of lost energy.

16                                                                                                               ®
Model No. ET-8782                                                         Energy Transfer–Thermoelectric




Experiment 2:
Load Resistance and Efficiency

           Equipment Required                                                Part Number

           Thermoelectric circuit board                                       part of ET-8782

           Foam insulators (qty. 2)                                           part of ET-8782

           Heat sink and thumbscrew                                           part of ET-8782

           Banana patch cords (qty. 6)                                        part of ET-8782

           Temperature cables (qty. 2)                                        part of ET-8782

           DC Power Supply (10 V, 1 A minimum)                            SE-9720A or equivalent

           PASPORT Voltage/Current Sensor                                        PS-2115

           PASPORT Quad Temperature Sensor                                       PS-2143

           PASPORT interface(s)                                            PS-2001 or equivalent

           DataStudio software                                              See PASCO catalog

           “Load Efficiency” configuration file for DataStudio                part of ET-8782




Introduction
   In this experiment you will examine the relationship between output load resistance and the
   power generated by the peltier when it is operating in heat engine mode.

   You will observe the output power as you vary the load resistance while keeping everything else
   constant (the temperature difference between the blocks, for instance). Since it is not possible to
   hold the blocks at a steady temperature difference, you will take the peltier through several
   identical cycles of heating and cooling, and measure the power each time a certain temperature
   difference occurs. You will repeat the cycle for each value of load resistance that you test, ranging
   from slightly over 0 Ω to 30 Ω.

   Before you start, predict what you will discover about the relationship between output power and
   load resistance. Record your prediction using words, numbers and a graph. Explain your
   reasoning.


Set-Up
   1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up).
      Connect the power supply using banana patch cords to the input power terminals on the
      circuit board as shown in picture. Note the polarity.



             ®                                                                                             17
Energy Transfer–Thermoelectric                                           Load Resistance and Efficiency


     2. Temperature:
        Connect the                                                          Voltage/Current
                                                                                 Sensor
        cables from the
        temperature ports
        to the Quad
        Temperature
        Sensor. Connect
        the Cold Side to
        Channel 1 of the
        sensor and the Hot
        Side to Channel 2.

     3. Voltage: Connect           Ch 2
        the voltage leads
        of the Voltage/                                                                    Power
                                     Temperature                                           Supply
        Current Sensor to              Sensor
        the Voltage Ports
        on the board. Note
                                   Ch 1
        the polarity.
     4. Current: Connect
        separate red and black banana patch cords from the current input of the Voltage/Current
        sensor to the Current Ports on the board. Note the polarity.

     5. Computer: Connect the sensors to the computer through the PASPORT interface. Open the
        pre-configured DataStudio file “Load Efficiency”. The display should look as shown below.




18                                                                                                   ®
Model No. ET-8782                                               Experiment 2: Load Resistance and Efficiency


Background
   This section explains some of the details of the DataStudio configuration file.

   Calculations: DataStudio will measure the temperature of both blocks (T hot and Tcold), the voltage
   across the load resistor, and the current through the load resistor. From these measurements it will
   make two calculations, temperature difference (∆T) and output power (P), using the following
   equations:

                                                ∆T = T hot – Tcold

                                             P = current × voltage

   Start and Stop Conditions: DataStudio has been configured with start and stop conditions, which
   control when it records data. The start condition is that ∆T must drop below 35 °C. Before the
   beginning of each cycle (when ∆T < 35 °C) you will click the Start button; DataStudio will display
   live data, but it will not start recording. Data recording will not start until the ∆T has increased
   above 35 °C and then dropped back below that level. The start condition will enable you to view
   the temperature measurements without recording them. The stop condition will cause data
   recording to stop when ∆T drops below 5 °C.
   Changing the Name of a Data Run: DataStudio will record a separate data run for each load
   resistance. In order to keep track of them, you will rename each data run. By default, the runs are
   named Run #1, Run #2, etc. In order to rename a run, find it in the Summary window (on the left
   side of the screen), click on it once to select it, then click on it again to edit it (be careful to single-
   click twice, and not to double-click). Enter the new name (for instance, “7 ohms”). When
   DataStudio asks if you would like to rename all the data from this run, select Yes.


Procedure
   1. Click the Start button. DataStudio will show live temperature readings in the Digits display,
      but it won’t start recording yet.

   2. Observe the temperature of both sides of the peltier; both should be close to room
      temperature. During the experiment, you will take the peltier through several cycles of
      heating and cooling. You must ensure that both sides of the peltier are close to room
      temperature before each cycle starts. Note the room temperature for future reference.

   3. Set the voltage on power supply to about 6 volts. Set the switch to Heat Pump mode for about
      2 seconds, then return it to the neutral position. If the voltage/current sensor beeps, then the
      current is too high (over 1 amp) and you should decrease the voltage (then close the switch
      again to test it).

   4. Set the switch to the Heat Engine position and allow the blocks to cool. Wait until both sides
      are within a few degrees of room temperature. (To cool faster, install the heat sink on the hot
      block and turn on the cooling fan. It also helps to put a metal object in contact with both
      blocks.)



             ®                                                                                                    19
Energy Transfer–Thermoelectric                                               Load Resistance and Efficiency


     5. Connect the output load jumper to terminal D. This bypasses all of the resistors and reduces
        the load resistance to almost zero. Note that the resistance is not exactly zero because the
        wires and traces on the board have some resistance.

     6. Place both insulators on the blocks.

     7. Set the switch to Heat Pump mode. Watch the difference in temperature between the two
        blocks (∆T). You are waiting for ∆T to reach 35 °C, which will take about one minute.

     8. When ∆T reaches 35 °C, change the switch to Heat Engine Mode. The temperature difference
        will start to decrease. When ∆T drops below 35 °C, DataStudio will automatically start
        recording. You will see data appear on the graph of Power Generated vs. ∆T.

     9. When ∆T drops below 5 °C, data recording will stop automatically.

     10. Change the name of the data run to indicate the load resistance.

     11. Click Start. DataStudio will display temperature data, but it won’t start recording yet.

     12. Remove the insulators and use the fan and heat sink to cool the blocks to within a few degrees
         of room temperature.
     13. Change the output load to 3 Ω (connect the jumper to terminal C).

     14. Replace the insulators and repeat the cycle of heating and cooling. (Go back to step 7.)

     15. Repeat the cycle again for the following values of output load:

     •   7 Ω (Connect the jumper to B, but also connect a shorting jumper from C to D.)
     •   10 Ω (Connect the jumper to B.)
     •   20 Ω (Connect the jumper to A, but also connect a shorting jumper from B to D.)
     •   30 Ω (Connect the jumper to A.)
     When you are finished, you will have acquired power and temperature data for six different
     values of output load resistance.


Analysis
     From the data that has been recorded you will extract the data needed to plot a graph of Power
     Generated (P) versus Load Resistance (R L) at ∆T = 30 °C.

     On the graph of P vs. ∆T use the smart cursor to read the power generated at ∆T = 30 °C for each
     value of load resistance. (Use the zoom select tool to change the scale of the graph and enlarge the
     area around the data at 30 °C in order to read the data precisely.)

     Enter the values in the Power vs. Load table. As you enter data into the table, they will be plotted
     on the Power vs. Load Resistance graph.

     1) At what value of R L is the maximum power generated?


20                                                                                                          ®
Model No. ET-8782                                               Experiment 2: Load Resistance and Efficiency


   2) For output loads less than and greater than the optimal value, why does the peltier generate
      less power?

   All real electrical power supplies (including the peltier heat engine) have an internal resistance,
   R i. They can be modeled as an ideal voltage source in series with a resistor, as shown below (with
   an output load connected).

                                                                     +

                                  Peltier          Ri
                                Heat Engine                       Vout        RL
                                                VNL
                                                            +
                                                            –
                                                                     –

   The voltage of the ideal voltage source, V NL, is called the no-load voltage. For a peltier heat
   engine V NL depends only on ∆T.

   3) Under what condition does the output voltage (Vout ) equal V NL?

   4) How would you directly measure V NL at ∆T = 30 °C?

   5) Write a theoretical equation for output power, P, in terms of V NL, R i and R L. Make a graph of
      P vs. R L (choose some arbitrary values for V NL and R i ). Based on your equation and graphs,
      under what condition is P at its maximum?

   6) In this experiment, one of the data points was taken with R L = 0. According to your equation,
      what is the theoretical power generated when R L = 0? Was this the case in your experiment?

   There is another source of resistance that we haven’t considered yet, which is the resistance of the
   traces, leads and sensors in the circuit. Let’s call it RT. If we add in RT, the circuit can be modeled
   thus:

                                                                 +       RT

                               Peltier        Ri
                             Heat Engine                        Vout           RL
                                              VNL
                                                        +
                                                        –
                                                                 –

   7) Rewrite the theoretical equation for P taking RT into account.

   8) Fit this equation to your experimental data. What is the no-load voltage at ∆T = 30 °C? What
      is the internal resistance of the peltier? What is RT?


Further Investigation
   1. Make a direct measurement of the no-load voltage at ∆T = 30 °C.

   2. Make a direct measurement of RT (or measure as much of it as possible).

             ®                                                                                               21
Energy Transfer–Thermoelectric                                             Load Resistance and Efficiency


     3. Predict how your results would differ if you repeated your analysis for a different value of
        ∆T? Test your prediction.

     4. For your graph of Power vs. Load Resistance, what did you do to ensure that only R L and P
        varied, and that all other experimental parameters stayed constant? Evaluate how successful
        these measures were. Discuss how you could improve them.

     5. In the analysis we assumed that Vout was constant for all values of ∆T = 30 °C. Do an
        experiment to test that assumption.

     6. For any given output load, quantitatively describe the relationship between P and ∆T.




22                                                                                                     ®
Model No. ET-8782                                                             Energy Transfer–Thermoelectric




Experiment 2:
Teachers’ Notes–Load Resistance and Efficiency




                            This sample data is in the file “Load Efficiency Data”.

   For instructions on using the Smart Tool and Zoom Select in the graph display, click on the
   DataStudio Help menu, select Search and look up those terms in the Index.

   1) Power generated was greatest for R L = 7 Ω.

   2) For other values of R L, the peltier generated less power because the load resistance did not
      match the internal resistance.

   3) Vout = V NL when there is no load connected (or when R L = ∞).

   4) To measure V NL, run the cycle with all of the load resistors disconnected, (or leave the knife
      switch open for the cooling phase).

                                                             2
                                                      VNL R L
   5)                                         P = ------------------------
                                                                         -
                                                                         2
                                                  ( Ri + RL )

            ®                                                                                            23
Energy Transfer–Thermoelectric                                          Teachers’ Notes–Load Resistance and Efficiency




                                                                                             Theoretical P vs. R L
                                                                                             (with arbitrary values)
                                                                                             V NL = 10 V
                                                                                             Ri = 5 Ω
          P (W)




                       Max P when
                         RL = Ri




                                                                  RL (W)


     6) Theoretically P = 0 when R L = 0. Experimentally this was not the case.

                                                           2
                                                  VNL ( RL + R T )
     7)                                     P = -------------------------------------
                                                                                    -
                                                                                    2
                                                ( Ri + RL + RT )

     8) Experimental data with curve fit:




                                                                                   V NL = 1.49 ± 0.1 V
                                                                                   R i = 7.4 ± 0.1 Ω
 P (W)




                                                                                   R T = 0.90 ± 0.04 Ω
                                                                                   Root MSE = 0.011 W




                                                                   RL (W)




24                                                                                                                     ®
Model No. ET-8782                                                        Energy Transfer–Thermoelectric




Experiment 3:
A Model Refrigerator

          Equipment Required                                                Part Number

          Thermoelectric circuit board                                      part of ET-8782

          Foam insulator                                                    part of ET-8782

          Heat sink and thumbscrew                                          part of ET-8782

          Banana patch cords (qty. 4)                                       part of ET-8782

          Temperature cables (qty. 2)                                       part of ET-8782

          Fast Response Temperature Probes (qty. 2)                        PS-2135 (3-pack)

          DC Power Supply (10 V, 1 A minimum)                            SE-9720A or equivalent

          PASPORT Voltage/Current Sensor                                        PS-2115

          PASPORT Quad Temperature Sensor                                      PS-2143

          PASPORT interface(s)                                           PS-2001 or equivalent

          DataStudio software                                             See PASCO catalog

          “Refrigerator” configuration file for DataStudio                  part of ET-8782




Introduction
   In this activity you will use the peltier device to model a refrigerator. As you run your model
   refrigerator, DataStudio will display the voltage and current supplied to the peltier, the
   temperature of both blocks, and the temperature of the air flowing past the heat sink. You will use
   these measurements to investigate some of the factors that affect the temperature of a refrigerator


Set-Up
   1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up).
      Connect the power supply using banana patch cords to the input power terminals on the
      circuit board. Note the polarity.

   2. Insulator: Place a foam insulator on the aluminum block on the Cold Side of the peltier.

   3. Block Temperature: Connect the cables from the temperature ports on the circuit board to the
      Quad Temperature Sensor. Connect the Cold Side to Channel 1 of the sensor and the Hot Side
      to Channel 2.

   4. Air Temperature: Set up two Fast Response Temperature Probes to measure the temperature of
      the air before and after it flows through the heat sink. Use the temperature clamps to position the
      probes below and above the heat sink (as shown in the picture). The probes should not touch the
            ®                                                                                            25
Energy Transfer–Thermoelectric                                                      A Model Refrigerator


         heat sink or the aluminum block. Connect the probe below the heat sink to Channel 3 of the Quad
         Temperature Sensor; connect the other probe to Channel 4.




     5. Voltage: Connect the voltage leads of the Voltage/Current Sensor to the Voltage Ports on the
        board. Note the polarity.
     6. Current: Connect separate red and black banana patch cords from the current input of the
        Voltage/Current sensor to the Current Ports on the board. Note the polarity.

     7. Computer: Connect the sensors to the computer through the PASPORT interface. Open the
        pre-configured DataStudio file “Refrigerator”. The display should look as shown below.




26                                                                                                     ®
Model No. ET-8782                                                                 Experiment 3: A Model Refrigerator


Procedure
   As you follow this procedure take notes of your observations and write down the answers to the
   questions.

   1. Put the knife switch in the neutral position (straight up). Set the DC Voltage to about 6 volts.

   2. Turn on the fan.

   3. Start data recording. Set switch to Heat Pump mode. (Check that the current is not more than
      1 amp; if it is, the sensor will beep and you should open the switch, decrease the applied
      voltage, then close the switch again.)

   4. Observe the temperatures of the hot and cold sides of the peltier device. Which side has the
      bigger temperature difference from room temperature? Why are they not the same?

   5. Let the refrigerator run in this mode for at least 5 minutes while the temperatures reach
      equilibrium. Meanwhile, continue on to the next section.


   Air Flow and Heat Transfer

   6. Observe the air temperatures below and above the heat sink. By how much does the air
      temperature increase when it passes through the heat sink? This increase in temperature is
      caused by the heat flowing from the heat sink to the air.

   You will now estimate the rate of heat transfer from the heat sink to the air. For a gas, we can write

                                                   Q = nc∆T

   where, in this experiment:

       Q = heat transferred from the heat sink to the air (in joules),
       n = number of moles of air (not the mass),
      ∆T = change in temperature of the air,
       c = specific heat of air.

   The specific heat of a gas depends on whether it is heated at constant volume or constant pressure.
   In this case the air is heated at constant pressure, so the specific heat is c air = 29.1 J/(mol·°C).

   The manufacturer's specification for the air flow generated by the fan is about 2 liters per second.
   At room temperature, one mole of gas occupies about 24.3 liters, so in one second the quantity of
   gas is

                                                  2L -
                                     n = -------------------------- = 0.082 mol
                                         24.3 L/mol

   7. After the temperatures of the hot and cold blocks have stabilized, calculate the heat, Q,
      transferred to the air every second. Is your estimate likely too high or too low? Explain your
      reasoning.

   The power supplied to the heat pump is
            ®                                                                                                    27
Energy Transfer–Thermoelectric                                                        A Model Refrigerator


                                                  P = IV

     where:

          P = power (in watts = joules/second),
          I = current (in amps),
          V = voltage (in volts).

     8. From the measured values of applied voltage and current, calculate the energy used to run the
        heat pump for one second. How does the energy supplied to the peltier every second compare
        to your estimate of the heat transferred from the heat sink to the air every second? Which is
        bigger? Explain your observations in terms of conservation of energy.


     Insulator, Fan and Heat Sink

     9. When the hot and cold blocks have reached equilibrium, write down the temperatures. Did
        you make a good refrigerator?
     10. Remove the foam insulator (continue recording data). Can you see a change in the cold
         temperature? Put the foam insulator back on. Why did the temperature change?

     11. Turn off the fan (continue recording data). Observe the effect on the temperatures for a few
         minutes. How have the temperatures of both sides changed? How has the temperature
         difference between the hot and cold sides changed? Can you explain why?
     12. Observe the air temperatures. Have they changed from when the fan was on? Do you think
         that the rate of heat transferred from the heat sink to the air has increased, decreased, or
         stayed the same? Explain your reasoning.

     13. If the blocks were allowed to reach equilibrium with the fan off, what do you think the final
         temperature of the “cold” block would be? Would that represent a good refrigerator?
     14. Before the hot side reaches 80 °C open the knife switch or turn the fan back on.

     15. What part of a real refrigerator is represented by the cold block on your model?

     16. In general terms, what does a refrigerator do to make the inside cold? Why does it need
         insulation? Why does it need a heat sink?


Further Investigation
     1. Let the refrigerator run for several minutes with the insulator removed and the fan switched
        on. What is the equilibrium temperature of the cold block in this mode?

     2. Without increasing the power supplied to the peltier, can you make the cold side colder?
        Propose a modification to your model refrigerator and do an experiment to test it.




28                                                                                                       ®
Model No. ET-8782                                                           Energy Transfer–Thermoelectric




Experiment 3:
Teachers’ Notes– A Model Refrigerator




                             This sample data is in the file “Refrigerator Data”.
                     The data shown in the digits displays occurred at Time = 5 minutes.



Answers to Questions
   (Step 4) The hot side of the peltier has a larger temperature difference from room temperature than
   the cold side. Once equilibrium is reached, the heat being pumped out of the cold block is equal to
   the heat flowing into it from its surroundings. The heat flowing out of hot block is equal to the
   heat pumped out of the cold block plus the work done by the peltier. Since the heat flow rate out
   of the hot block is higher than the heat flow rate into the cold block, and heat flow rate is
   proportional to temperature difference, the hot block must have a higher temperature difference.




            ®                                                                                            29
Energy Transfer–Thermoelectric                                         Teachers’ Notes–A Model Refrigerator


     Air Flow and Heat Transfer

                                                 ∆T = 2.6 °C

                     Q = (0.082 mol) [29.1 J/(mol·°C)] (2.6 °C) = 6.2 J (every second)

     (Step 7) This estimate is likely to be high because we are measuring the air that goes straight
     through the heat sink. Much of the air from the fan misses the heat sink, so the average
     temperature rise for all of the air from the fan would be less than 2.6 °C.

                                        P = (0.60 A) (7.1 V) = 4.3 J/s

     (Step 8) The energy supplied to the peltier every second is less than the estimate of energy
     transferred to the air by the heat sink. According to conservation of energy, they would be the
     same if all of the heat lost by the system were transferred to the air through the heat sink. In fact,
     some heat is lost through radiation, and through other parts of the system. It is likely that most of
     the discrepancy between Q and P is due to error in the estimate of Q.


     Insulator, Fan and Heat Sink
     (Step 9) With the cold block at 5 °C (or 18 °C below room temperature) the model represents an
     effective refrigerator.

     (Step 10) With the insulator removed, the temperature of the cold block increases due to increased
     heat flow from the air to the block.

     (Step 11) With the fan turned off, the temperature of the hot block increases because the rate of
     heat transfer to the air decreases. The temperature of the cold block increases at a similar rate.
     The temperature difference between the blocks increases from 41 °C to 47 °C within 3 minutes of
     the fan switching off, after which the difference decreases slowly.

     As the hot block gets hotter and the temperature difference between the blocks increases, the
     tendency for heat to flow from the hot block to the cold block by conduction increases, canceling
     the heat-pumping effect of the peltier.
     (Step 12) When the fan is turned off the temperature change of the air flowing through the heat
     sink increases to about 10 °C. Since the hot block gets hotter, it is evident that the rate of heat
     transfer to the air has decreased. The increased temperature change is due to the decreased air
     flow.

     (Step 13) With the fan turned off, the “cold” block would stabilize at about 40 °C. That is higher
     than room temperature, so it would not be a good refrigerator.

     (Step 15) The cold block corresponds to the interior of a real refrigerator.

     (Step 16) A refrigerator makes the interior cold by pumping heat out of it. It needs insulation to
     reduce the rate of heat flow back into it from the surrounding air. It needs a heat sink to transfer
     away the heat that it has pumped out of the interior, and the heat resulting from the work that it
     does.

30                                                                                                            ®
Model No. ET-8782                                                      Energy Transfer–Thermoelectric




Experiment 4:
Coefficient of Performance

          Equipment Required                                              Part Number

          Thermoelectric circuit board                                     part of ET-8782

          Foam insulator                                                   part of ET-8782

          Heat sink and thumbscrew                                         part of ET-8782

          Banana patch cords (qty. 4)                                      part of ET-8782

          Temperature cables (qty. 2)                                      part of ET-8782

          DC Power Supply (10 V, 1 A minimum)                          SE-9720A or equivalent

          PASPORT Voltage/Current Sensor                                      PS-2115

          PASPORT Quad Temperature Sensor                                     PS-2143

          PASPORT interface(s)                                          PS-2001 or equivalent

          DataStudio software                                           See PASCO catalog

          “Coeff of Performance” configuration file for DataStudio         part of ET-8782




Introduction
   Some heat pumps, such as refrigerators and air conditioners, are used for their cooling effect.
   They pump heat out of a container or a building, making the interior cooler than the surrounding
   environment. But a heat pump can also be used to pump heat into a building, making the interior
   warmer than the surrounding environment.

   An important property of a heat pump is how much energy it uses to move a certain amount of
   heat. In this activity you will measure the Coefficient of Performance of a heat pump working in
   both modes, and discover how a heat pump can be more efficient at heating a building than
   conventional methods.


Set-Up
   1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up).
      Connect the power supply using banana patch cords to the input power terminals on the
      circuit board as shown in picture. Note the polarity.

   2. Heat Sink and Insulator: Attach the heat sink to the aluminum block on the Hot Side of the
      peltier. Place a foam insulator on the other block.




            ®                                                                                         31
Energy Transfer–Thermoelectric                                                   Coefficient of Performance



                                                               Voltage/Current
                                                                   Sensor




                       Ch 2

                                                                             Power
                        Temperature                                          Supply
                          Sensor



                       Ch 1



     3. Temperature: Connect the cables from the temperature ports on the circuit board to the Quad
        Temperature Sensor. Connect the Cold Side to Channel 1 of the sensor and the Hot Side to
        Channel 2.

     4. Voltage: Connect the voltage leads of the Voltage/Current Sensor to the Voltage Ports on the
        board. Note the polarity.

     5. Current: Connect separate red and black banana patch cords from the current input of the
        Voltage/Current sensor to the Current Ports on the board. Note the polarity.

     6. Computer: Connect the sensors to the computer through the PASPORT interface. Open the
        pre-configured DataStudio file “Coeff of Performance”. The display should look as shown
        below.




32                                                                                                       ®
Model No. ET-8782                                                 Experiment 4: Coefficient of Performance


Background
   DataStudio has been configured to measure and record the temperature of both aluminum blocks,
   and the voltage and current applied to the peltier. From these measured quantities, DataStudio will
   calculate and display heat flow, power and work. The following sections explain how DataStudio
   makes these measurements and calculations.


   Heat vs. Temperature

   The digits displays show the heat that flows into the hot block (Q hot) and out of the cold block
   (Q cold). The relationship between heat flow and temperature change is given by

                                                Q = mc∆T

   where:

       Q    = heat transferred,
       m    = mass of the aluminum block,
       c    = specific heat of aluminum = 0.90 J/(g·°C),
      ∆T    = change in temperature.

   A positive value of Q hot represents heat flowing into the hot block, but a positive value of Q cold
   represents heat transferred out of the cold block.

   The temperature of each block is measured by the embedded thermistor. DataStudio calculates the
   heat flow from the measured temperature change, and pre-entered values of m and c. Click on the
   calculator icon in the tool bar and look at the equations used; note the constants, m and c, in the
   bottom section of the calculator window. (The mass of each block is about 19 g. If you would like
   to enter your own value for the mass, measure the blocks with calipers and use the density of
   aluminum, 2.7 g/cc, to calculate the mass, then enter it in the calculator.)


   Input Power and Work Done by the Peltier

   Input Power from the power supply equals the rate at which the peltier does work to pump heat
   out of the cold reservoir and into the hot reservoir. The Voltage/Current Sensor measures the
   voltage applied to the peltier, and the current that flows through it. DataStudio calculates the Input
   Power using the equation: Power = Voltage × Current.

   The area under the plot of Input Power versus time equals the energy supplied to the peltier, which
   equals the work, W, done by the peltier.


   Start Condition

   The configuration file contains a start condition; when you click the Start button (with the knife
   switch open) DataStudio will display live data, but it will not start recording until you close the
   knife switch. This will allow you to monitor the measurements and confirm that both blocks are at
   the same temperature before data recording starts.


              ®                                                                                             33
Energy Transfer–Thermoelectric                                                    Coefficient of Performance


Procedure

     Refrigerator

     Before you start, the knife switch should be in the neutral position (straight up) and the fan should
     be switched off. Make sure that the foam insulator is on the cold block, and that the heat sink is on
     the hot block.

     Set the DC Voltage to about 5 volts.

     Click the Start button.

     Observe the temperatures of the hot and cold blocks; they should be within 0.1 °C of each other.
     (If they are not, turn on the fan and wait until the temperatures have equalized. Then turn the fan
     off and proceed.)

     Set the knife switch to Heat Pump mode. Allow the heat pump to run for 10 to 15 seconds, then
     open the switch. Watch the temperature graphs; once the temperatures have peaked out, stop data
     recording. You need to give the blocks a few seconds to reach a maximum or minimum before
     you stop recording.

     Heat pumps are rated by the Coefficient of Performance, k. In the case of a heat pump used for
     cooling (such as a refrigerator) the Coefficient of Performance is

                                                Q cold
                                            k = ----------- (for cooling)
                                                          -
                                                    W

     The Coefficient of Performance expresses how much heat the heat pump removes from the cold
     side compared to how much energy it uses to move the heat.

     1) Use your values for the heat pumped out of the cold block (Q cold) and the area under the
        Power versus time curve (W) to calculate the Coefficient of Performance, k, for your model
        refrigerator.

     2) For real heat pumps k is usually expected to be greater than 1. Is this the case for your model?

     3) Your heat pump can also be thought of as a model air conditioner, a device used to keep the
        inside of a building cooler than the outside air. In terms of moving heat, what does an air
        conditioner do to keep a building cool? (Keep in mind that an air conditioner does not
        necessarily move air into or out of the building.)

     4) Compare your model to a building being cooled by an air conditioner. What does the peltier
        represent? What does the cold block represent? What does the hot block represent?

     5) If you were selecting an air conditioner to keep your home cool, would you choose one with a
        high or low coefficient of performance? Explain why.




34                                                                                                           ®
Model No. ET-8782                                                  Experiment 4: Coefficient of Performance


   Reversible Heat Pump

   A certain kind of air conditioner, known as a reversible heat pump, can also be used to heat a
   building. You will now use the peltier to model a reversible heat pump being used to keep a
   building warmer than the surrounding air.

   Place the heat sink on the cold block, and the foam insulator on the hot block.

   Delete the data that you have previously recorded. (Click on the Experiment menu and select
   Delete All Data Runs.)

   Click the Start button. Make sure that the hot and cold blocks are within 0.1 °C of each other
   before proceeding. (If they are not, remove the insulator, turn on the fan and wait for the
   temperatures to equalize. Then turn off the fan, replace the insulator and proceed.)

   Set the switch to Heat Pump mode. Allow the heat pump to run for 10 to 15 seconds, then open
   the switch. Watch the temperature graphs; once the temperatures have peaked out, stop data
   recording.
   For a reversible heat pump heating a building, we are interested in the heat pumped into the
   building, Q hot. (This is opposed to the previous case where we were interested in the heat pumped
   out of the building.) Thus the Coefficient of Performance is

                                             Q hot
                                         k = --------- (for heating)
                                                     -
                                                W

   6) Use your values for the heat delivered to the hot block (Q hot) and the area under the Power
      versus time curve (W) to calculate the Coefficient of Performance, k.

   7) If you had used a simple resistor (rather than the peltier) to heat the aluminum block, and used
      the same amount of energy (W), what would have been the maximum amount of heat
      transferred to the block?

   8) Compare your model to a building being heated by a reversible heat pump. What does the
      peltier represent? What does the cold block represent? What does the hot block represent?

   9) Why is it important for k to be greater than 1 for a reversible heat pump? Compare this to a
      simple electrical heater. How much heat is delivered to a building using a simple heater
      supplied with 100 J of electrical energy? How much heat is delivered to a building using a
      heat pump, with k = 2, that uses 100 J of electrical energy to pump heat from outside to inside
      the building?


Further Investigation
   Think of a factor that you can vary in the experimental set-up. Predict how varying that factor
   would affect the coefficient of performance in heating or cooling mode. Do an experiment to test
   your prediction.



            ®                                                                                            35
Energy Transfer–Thermoelectric   Coefficient of Performance




36                                                       ®
Model No. ET-8782                                                           Energy Transfer–Thermoelectric




Experiment 4:
Teachers’ Notes– Coefficient of Performance

   Refrigerator




                     This sample data is in the file “Coeff of Performance Data Refrig”.

                                               76.0 J
   1)                                      k = ------------- = 1.59
                                                           -
                                               47.8 J

   2) This coefficient of performance is similar to that of real heat pumps.

   3) An air conditioner pumps heat out of the building and into the outside air.

   4) The peltier represents the heat pump, the cold block represents the interior of the building,
      and the hot block represents the outside air.

   5) You would choose an air conditioner with a high coefficient of performance because it would
      use less energy to remove heat from the building (and cost less to run).




            ®                                                                                          37
Energy Transfer–Thermoelectric                                      Teachers’ Notes–Coefficient of Performance


     Reversible Heat Pump




                     This sample data is in the file “Coeff of Performance Data Heat Pump”.

                                                116.6 J
     6)                                     k = ---------------- = 2.41
                                                               -
                                                 48.4 J

     7) If you used a simple resistor to heat the block with the same amount of work, the maximum
        heat transferred to the block would be W = 48.4 J.

     8) The peltier represents the heat pump, the cold block represents the outside air, and the hot
        block represents the interior of the building.

     9) The coefficient of performance must be greater than 1 in order for the heat pump to be more
        efficient than a simple heater. A simple heater supplied with 100 J of electrical energy would
        transfer 100 J of heat to the building. A heat pump with k = 2 supplied with 100 J of electrical
        energy would transfer 200 J to the building.

                                                   Q hot = kW




38                                                                                                          ®
Model No. ET-8782                                                      Energy Transfer–Thermoelectric




Experiment 5:
Teachers’ Notes– Carnot Efficiency

          Equipment Required                                              Part Number

          Thermoelectric circuit board                                    part of ET-8782

          Foam insulators (qty. 2)                                        part of ET-8782

          Banana patch cords (qty. 5)                                     part of ET-8782

          Temperature cables (qty. 2)                                     part of ET-8782

          DC Power Supply (10 V, 1 A minimum)                          SE-9720A or equivalent

          PASPORT Voltage/Current Sensor                                      PS-2115

          PASPORT Quad Temperature Sensor                                     PS-2143

          PASPORT interface(s)                                         PS-2001 or equivalent

          DataStudio software                                           See PASCO catalog

          “Carnot Efficiency Workbook” file for DataStudio                part of ET-8782



   With the electronic workbook
                                                    Temperature (°C)




   contained on the CD-ROM,
   students will study the efficiency
   of the peltier heat engine. They
   will record data for ∆T, power
   generated and heat flow, calculate
                                              Power Generated (mW)




   efficiency, and discover the
   relationship between efficiency
   and ∆T. Finally they will compare
   the actual efficiency of the heat
   engine to the Carnot efficiency.

   Have your students open the                                           Time (s)

   DataStudio file “Carnot Efficiency
   Workbook” and follow the on-
   screen instructions. As they go
                                             efficiency (%)




   through the electronic workbook
   they should take notes and record
   their answers to questions on paper.

   You can find sample data in the file
                                               Carnot efficiency (%)




   “Carnot Efficiency Workbook with
   Data”.



                                                                        DT (°C)

            ®                                                                                     39
Energy Transfer–Thermoelectric   Teachers’ Notes–Carnot Efficiency




40                                                              ®
Model No. ET-8782                                                      Energy Transfer–Thermoelectric



Safety                                              Copyright and Warranty
                                                    Information
   Read the instructions before using this
   product. Students should be supervised by
   their instructors. When using this product,      Copyright Notice
   follow the instructions in this manual and all
   local safety guidelines that apply to you.         The PASCO scientific 012-08745A Energy
                                                      Transfer–Thermoelectric Instruction
Technical Support                                     Manual is copyrighted and all rights
                                                      reserved. However, permission is granted to
   For assistance with any PASCO product,             non-profit educational institutions for
   contact PASCO at:                                  reproduction of any part of this manual,
                                                      providing the reproductions are used only for
   Address:    PASCO scientific                       their laboratories and are not sold for profit.
               10101 Foothills Blvd.                  Reproduction under any other
               Roseville, CA 95747-7100               circumstances, without the written consent
     Phone:    (916) 786-3800                         of PASCO scientific, is prohibited.
               (800) 772-8700
      Fax:     (916) 786-3292
      Web:     www.pasco.com
                                                    Limited Warranty
     Email:    techsupp@pasco.com                     For a description of the product warranty, see
                                                      the PASCO catalog.
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  • 1. Instructions Experiments Instruction Manual Sample Data No. 012-08745A Energy Transfer– Thermoelectric ET-8782
  • 2. Energy Transfer–Thermoelectric Model No. ET-8782 Table of Contents Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Experiment 1: Conservation of Energy and the First Law of Thermodynamics . . . . . . . . . . . . . . . . . . . . . 9 Experiment 1: Teachers’ Notes–Conservation of Energy and the First Law of Thermodynamics . . . . . 15 Experiment 2: Load Resistance and Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Experiment 2: Teachers’ Notes–Load Resistance and Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Experiment 3: A Model Refrigerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Experiment 3: Teachers’ Notes–A Model Refrigerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 Experiment 4: Coefficient of Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 Experiment 4: Teachers’ Notes–Coefficient of Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Experiment 5: Teachers’ Notes–Carnot Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Technical Support . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Copyright and Warranty Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
  • 3. Model No. ET-8782 Energy Transfer–Thermoelectric Energy Transfer–Thermoelectric Model No. ET-8782 1 6 5 2 3 4 Included Equipment Replacement Part Number 1. Thermoelectric circuit board ET-8782 2. Foam insulators (qty. 2) 648-08724 3. Heat sink 624-013 4. Thumbscrew 617-018 and 615-031 5. Temperature cables (qty. 2) PS-2515 6. Banana patch cords (qty. 8) SE-7123 7. CD-ROM containing editable experiment instructions Contact Tech Support and DataStudio® files (not pictured) ® 3
  • 4. Energy Transfer–Thermoelectric Introduction Additional Equipment Required Model Number DC Power Supply (10 V, 1 A minimum) SE-9720A or equivalent Temperature Sensor(s), compatible with 10 kΩ thermistors Various, see note below Voltage and Current Sensor(s) Various, see note below PASCO Computer Interface Various, see note below DataStudio software See PASCO catalog Optional Equipment Model Number Fast Response Temperature Probes PS-2135 (3-pack) Decade Resistance Box SE-7122 or equivalent Note The most convenient combination of interface and sensors for use with the Thermoelectric circuit board is: • PS-2001 PowerLink interface • PS-2143 Quad Temperature Sensor • PS-2115 Voltage/Current Sensor • PS-2135 Fast Response Temperature Probes (3-pack), optional This is the equipment called for by the experiments in this manual and on the CD-ROM. There are other options for PASPORT™ and ScienceWorkshop® sensors and interfaces, and stand-alone multimeters. Please contact Tech Support, or see the PASCO catalog or website for details. Introduction The Energy Transfer–Thermoelectric circuit board provides students with a hands-on example of a thermoelectric heat engine. Using measurements from temperature, voltage and current sensors, students will quantitatively study the energy, work and heat flow associated with heat engines, heat pumps and refrigerators. This manual includes instructions for five experiments with sample data and teachers’ notes. You can photocopy the student instructions or print them from the editable copy of this manual included on the CD-ROM. Experiment #5 is a DataStudio workbook, which contains the student instructions within the DataStudio file. In addition to the experiments detailed here, the Thermoelectric board is well-suited for self- guided exploration. The following sections will familiarize you with the components of the experimental set-up. 4 ®
  • 5. Model No. ET-8782 Introduction 5 4 2 6 1 3 1. Peltier Device with Hot and Cold Reservoirs The Peltier Device is constructed of two ceramic plates with p and n semiconductors in between. As DC current passes through the device, it pumps heat from one side to the other. Aluminum blocks are fastened to each side of the peltier in thermal contact with the ceramic plates. These blocks add thermal mass to the system and act as the traditional Hot and Cold Reservoirs. When there is a temperature difference across the peltier, it can be switched to Heat Engine Mode, in which spontaneous heat flow through the device generates an electric current. Do not touch the hot aluminum block when it is running in Heat Pump Mode. The temperature of this block can reach 90 °C or higher. Do not allow the peltier device to reach temperatures above 100 ºC. Always monitor the temperature of the hot side when the peltier is operating in Heat Pump Mode. Operation between 80 °C and 100 °C will shorten the life of the device; if you operate the device in that temperature range, do so for the briefest possible time. You can operate the peltier device without damage at temperatures below 80 °C. ® 5
  • 6. Energy Transfer–Thermoelectric Introduction 2. Input Power Input Power for the board must be supplied from an external DC power supply capable of 1 amp at 10 volts. Connect the power supply via the red and black banana jacks on the right-hand side of the board. Note the polarity: red must be positive. Do not input more than 10 volts. 3. Load Resistors In Heat Engine Mode, a jumper cable must be connected from the bottom banana jack terminal to one of the terminals labeled A through D. The load resistance depends on how you connect the jumper cables. If, for example, the jumper is connected to terminal A, then all of the resistors are in series in the circuit, and the total load resistance is 20 Ω + 7 Ω + 3 Ω = 30 Ω. If the jumper is connected to terminal C, the load resistance is 3 Ω. A second jumper can also be used across a resistor to remove it from the circuit. For example, if the main jumper from the bottom connector is plugged into terminal A, and a second jumper is connected between B and D, the total load resistance is 20 Ω; the 7 Ω and 3 Ω resistors are bypassed. The possible combinations are 3 Ω, 7 Ω, 10 Ω, 20 Ω, 23 Ω, 27 Ω and 30 Ω. If you use a decade resistance box instead of the on-board resistors, you can supply any value you want. You can also connect the jumper from the bottom terminal directly to terminal D, which reduces the load resistance to a few tenths of an ohm (due to the internal resistance of the circuit). 4. Knife Switch The single pole double throw Knife Switch on the right side of the board is used to select the mode of operation. In Heat Pump Mode, external power is applied to the peltier device, and heat is pumped from the aluminum block on the cold side to the block on the hot side. In Heat Engine Mode, the external power is disconnected, and heat flows back through the peltier, generating electric current through the load resistor. 5. Voltage and Current Voltage and current sensors connected to the banana jacks at the top of the board will measure voltage across and current through the peltier. Note the polarity when you connect the sensors. A single PASPORT Voltage/Current sensor can be used for both measurements. If you plan to run the peltier without a current sensor, you must connect a jumper between the current terminals to complete the circuit. From the measured voltage and current, DataStudio will calculate the power supplied to the peltier (in Heat Pump mode) or power generated by the peltier (in Heat Engine mode). DataStudio will plot a graph of power versus time, which it will use to calculate input or output energy. 6. Temperature Ports Each aluminum block has a 10 kΩ thermistor embedded in it. Use the provided Temperature Cables to connect temperature sensors to the thermistors through the hot-side and cold-side 6 ®
  • 7. Model No. ET-8782 Introduction Temperature Ports. The temperature sensor measures the resistance of the thermistor and translates it into a temperature reading. If you are using a PASPORT Quad Temperature sensor, you will connect both temperature ports (and up to two additional probes) to a single sensor. From the measured temperature change, DataStudio will calculate the heat flow into or out of the aluminum blocks. 7 8 9 7. Foam Insulators and Heat Sink The Foam Insulators are used to insulate one side or both sides of the peltier. For conservation of energy studies, use both insulators to minimize heat exchange with the environment. If needed, you can put a rubber band around them to hold them tightly together. The Heat Sink, which helps to dissipate heat, fastens to the hot-side aluminum block with the provided thumb screw. For more efficient cooling, the fins of the heat sink should be vertical. Be careful when removing the heat sink because it can get very hot. In some experiments, you will have an insulator on the cold side, and the heat sink on the hot side. 8. Cooling Fan The Cooling Fan and heat sink act together to dissipate heat from the hot reservoir. The fan is used when demonstrating a refrigerator. You can also use it to cool the aluminum blocks back to room temperature, which is a required initial condition in some experiments. The fan is operated through a switch in the center of the board and it is powered by the same external power supply that powers the peltier. The fan has a built-in regulator, so it will run at a constant speed when the input voltage is 6 volts or higher. Do not use the fan when the input voltage is below 4 volts. ® 7
  • 8. Energy Transfer–Thermoelectric Introduction 9. Temperature Sensor Clamps When modeling a refrigerator it is useful to observe the heat flow around the heat sink. Two Temperature Sensor Clamps (one high, one low) are provided to position Fast Response Temperature Probes (not included) in the air stream from the fan before and after the air has passed through the heat sink. 8 ®
  • 9. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 1: Conservation of Energy and the First Law of Thermodynamics Equipment Required Part Number Thermoelectric circuit board part of ET-8782 Foam insulators (qty. 2) part of ET-8782 Banana patch cords (qty. 5) part of ET-8782 Temperature cables (qty. 2) part of ET-8782 DC Power Supply (10 V, 1 A minimum) SE-9720A or equivalent PASPORT Voltage/Current Sensor PS-2115 PASPORT Quad Temperature Sensor PS-2143 PASPORT interface(s) PS-2001 or equivalent DataStudio software See PASCO catalog “Conservation of Energy” configuration file for DataStudio part of ET-8782 Introduction In this activity you will study the flow of energy in the experimental set-up as you run it through a cycle. First you will operate the apparatus in Heat Pump mode, in which energy is supplied to the peltier, and the peltier pumps heat from one aluminum block to the other. After a temperature difference has been established between the blocks, you will switch the peltier into Heat Engine mode, in which heat flows from the hot block, through the peltier, and into the cold block. The peltier will convert some of the heat that flows out of the hot block to electrical energy, which it will supply to the load resistor. During this cycle you will follow the energy as in moves in different forms from the power supply to the peltier (electrical energy), in and out of the aluminum blocks (heat or thermal energy), and into the load resistor (electrical energy). As you do the experiment, bear in mind the law of conservation of energy and the first law of thermodynamics. How do they relate to the transfer of energy within the system? Set-Up 1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up). Connect the power supply using banana patch cords to the input power terminals on the circuit board as shown in picture below. Note the polarity. ® 9
  • 10. Energy Transfer–Thermoelectric Conservation of Energy and the First Law of Thermodynamics 2. Load Resistance: Connect a jumper from Voltage/Current Sensor the terminal at the bottom of the board to Terminal B. This makes the load resistance 3 Ω + 7 Ω = 10 Ω. 3. Insulators: Place both foam insulators on the aluminum blocks. 4. Temperature: Connect the cables from the temperature ports to the Quad Temperature Sensor. Connect the Cold Side to Channel 1 Ch 2 of the sensor and the Hot Side to Channel 2. Temperature Power Supply Sensor 5. Voltage: Connect the voltage leads of the Voltage/Current Sensor to the Voltage Ports Ch 1 on the board. Note the polarity. 6. Current: Connect separate red and black banana patch cords from the current input of the Voltage/Current sensor to the Current Ports on the board. Note the polarity. 7. Computer: Connect the sensors to the computer through the PASPORT interface. Open the pre-configured DataStudio file “Conservation of Energy”. The display should look as shown here. Background DataStudio has been configured to measure and record the temperature of both aluminum blocks, the voltage and current applied to the peltier during Heat Pump mode, and the voltage and current generated by the peltier during Heat Engine mode. From these measured quantities, DataStudio will calculate and display heat flow, power and work. The following sections explain how DataStudio makes those calculations. Heat vs. Temperature Each digits display shows the heat (Q hot or Q cold) that flows into or out of the aluminum block on either the hot or cold side of the peltier. The relationship between heat flow and temperature change is given by Q = mc∆T where: 10 ®
  • 11. Model No. ET-8782 Experiment 1: Conservation of Energy and the First Law of Thermodynamics Q = heat transferred, m = mass of the aluminum block, c = specific heat of aluminum = 0.90 J/(g·°C), ∆T = change in temperature. A positive value of Q may represent heat transferred into or out of the aluminum block, depending on whether the block is on the hot side or the cold side of the peltier, and whether the peltier is operating as a heat pump or a heat engine. The temperature of each block is measured by the embedded thermistor. DataStudio calculates the heat flow from the measured temperature change, and pre-entered values of m and c. Click on the calculator icon in the tool bar and look at the equations used; note the constants, m and c, in the bottom section of the calculator window. (The mass of each block is about 19 g. If you would like to enter your own value for the mass, measure the blocks with calipers and use the density of aluminum, 2.7 g/cc, to calculate the mass, then enter it in the calculator.) Input Power and Work Done by the Peltier Heat Pump In Heat Pump mode, Input Power from the power supply equals the rate at which the peltier does work to pump heat out of the cold reservoir and into the hot reservoir. The Voltage/Current Sensor measures the voltage applied to the peltier, and the current that flows through it. DataStudio calculates the Input Power using the equation: Power = Voltage × Current. The area under the plot of Input Power versus time equals the energy supplied to the peltier, which equals the work done by the peltier. Power Generated and Work Done by the Peltier Heat Engine In Heat Engine mode, Power Generated is the rate at which the peltier does work on the load resistor. The Voltage/Current sensor measures the voltage across the resistor and the current through it. From these measurements, DataStudio calculates the power supplied to the load resistor. The area under the plot of Power Generated versus time equals the work that the peltier has done on the resistor. Procedure Before you start, the aluminum blocks should both be at room temperature. The knife switch should be in neutral position (straight up) and the fan should be switched off. Set the DC Voltage to between 3 and 4 volts. Start data recording, then set the knife switch to Heat Pump. You will see Input Power data appear in the top section of graph. The area under the graph equals the energy supplied to the peltier, which equals the work done by the heat pump. The Heat Pump digits display shows the heat pumped out of cold reservoir (Q cold) and the heat deposited into the hot reservoir (Q hot). ® 11
  • 12. Energy Transfer–Thermoelectric Conservation of Energy and the First Law of Thermodynamics Observe how the temperatures of the aluminum blocks change. Run the peltier in Heat Pump mode for about a minute (or until the cold side appears to reach a minimum temperature), then switch to Heat Engine mode. Again, observe how the temperatures of the aluminum blocks change. Power Generated data now appears in the bottom section of the graph display. The area under the graph equals the energy generated by the heat engine and supplied to the load resistor. The Heat Engine digits display shows the heat that has flowed out of the hot reservoir (Q hot) and the heat that has flowed into the cold reservoir (Q cold). Continue to record until the aluminum blocks are close to the same temperature. Analysis Hot Reservoir Qhot Heat Pump Mode Heat Pump In Heat Pump mode the peltier does work to pump heat out of the cold reservoir and into the hot reservoir. W W = work done by the peltier (equal to the area under the Input Power curve), Qcold Q hot = heat pumped into the hot reservoir, Q cold = heat pumped out of the cold reservoir. Cold Reservoir By the first law of thermodynamics, Q hot = Q cold + W 1) Where did the heat pumped out of the cold reservoir go? Where did the heat pumped into the hot reservoir come from? Why was more heat pumped into the hot reservoir than was pumped out of the cold reservoir? 2) Compare your observed values of (Q cold + W) and Q hot. If they are not equal, where did the “lost energy” go? 3) Write an equation in terms of the “lost energy”, E lost, and your observed data, W, Q hot and Q cold. Hot Reservoir Heat Engine Mode Qhot In a heat engine, heat flows out of the hot reservoir, some of the heat is Heat Engine converted to work, and the rest of the heat flows into the cold reservoir. W = work done by the heat engine, W Q hot = heat flow out of the hot reservoir, Qcold Q cold = heat flow into the cold reservoir. Cold Reservoir By the first law of thermodynamics, 12 ®
  • 13. Model No. ET-8782 Experiment 1: Conservation of Energy and the First Law of Thermodynamics W = Q hot – Q cold 4) Compare your observed value of work, Wobserved (which is the area under the Power vs. Time plot) to the quantity Q hot – Q cold. Are they equal? 5) In a real heat engine, only part of the heat that flows out of the two-reservoir system (Q hot – Q cold) is converted to useful work. In this experiment, the work that you observed (the useful work) was the work done on the load resistor. Can you account for all of the energy that flowed out of the hot reservoir with your values of Wobserved, Q hot and Q cold? If not, where did the “lost energy” go? 6) Calculate the proportion of net heat flow from the aluminum blocks that was converted to useful work; W observed % of useful work = --------------------------- × 100 % - Q hot – Q cold 7) Write an equation in terms of the “lost energy”, E lost, and your observed data, Wobserved, Q hot and Q cold. 8) In this experiment the “useful work” was the work done on the load resistor. What was the result of doing work on the resistor? How could you modify the circuit in order to make better use of the work done by the heat engine? Conservation of Energy In the Heat Pump phase of the cycle the power supply put energy into the system. Then, in the Heat Engine phase heat flowed out of the hot reservoir and part of it was converted into electrical energy, which was supplied to the load resistor. 9) Calculate the percentage of energy put in during the Heat Pump phase that was recovered as useful work during the Heat Engine phase; energy generated % recovered = ---------------------------------------- × 100 % - energy put in 10) Is this a good way to store energy? Conduction and Heat Flow Through the Insulators One of the losses of energy in this experiment has to do with heat flow by conduction through the polyethylene foam insulators. The rate of heat flow through the insulator is ∆T Q i ⁄ t = kA ------ - x where: ® 13
  • 14. Energy Transfer–Thermoelectric Conservation of Energy and the First Law of Thermodynamics Q i /t = heat flow rate through the insulator, k = thermal conductivity of the polyethylene foam = 0.036 W/(m·°C), A = area through which the heat flows, ∆T = temperature difference across the insulator, x = thickness of the insulating material. You will estimate the amount of heat that flowed through the foam in contact with the front face of the cold block. Measure the height and width of the cavity in the insulator that surrounds the aluminum block. Calculate the cross-sectional area, A in m2. Measure the thickness, x, of the foam that covers the front face of the block. Do not include the sides of the foam (you are only calculating the heat flow through the front face). Record your measurement in meters. From the temperature graph, determine the difference, ∆T, between the temperature of the cold block and room temperature. This value changed during the experiment, so record the maximum difference, when the cold block was at its coldest. This will give you an estimate of the maximum heat flow rate through the insulator. 11) Calculate the heat flow rate through the foam, Q i /t. This is the heat flow rate in joules/second. To find the total amount of heat in joules, multiply this number by the total time in seconds that the experiment ran; Q i = (heat flow rate) × (time). 12) How does your estimate of Q i compare to the heat, Q cold, that was pumped out of the cold block in the Heat Pump phase? Is it much larger, much smaller, or similar? 13) Is your estimate of heat flow through the insulator too high or too low? Remember that you ignored the sides in your estimate, and that you used the maximum temperature difference for ∆T. 14) How would the flow of heat through the insulator on the hot side compare to heat flow through the insulator on the cold side? Consider both the magnitude and direction of heat flow. 15) Is heat flow through the insulators (on the hot and cold sides) a significant factor in this experiment? Could the heat flow through the insulators account for the discrepancy between your observed results and the first law of thermodynamics? 16) How would your results have differed if you had not used the insulators? Further Investigation What are some factors that you could vary in the experimental apparatus and procedure? Predict how changing those factors would affect the results. Do an experiment to test one of your predictions. 14 ®
  • 15. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 1: Teachers’ Notes–Conservation of Energy and the First Law of Thermodynamics This sample data is in the file “Conservation of Energy Data”. Heat Pump Mode Q hot = 172.8 J Q cold + W = 233.1 J 1) Most of the heat pumped out of the cold reservoir went into the hot reservoir. The heat pumped into the hot reservoir is greater than the heat pumped out of the cold reservoir because Q hot also includes the work done by the peltier. 2) Q hot < Q cold + W. Some energy was lost. Part of it flowed through the insulator to the environment. Part of it was dissipated in other parts of the circuit. 3) Q hot = Q cold + W – E lost Heat Engine Mode Wobserved = 0.572 J Q hot – Q cold = 3.3 J 4) Wobserved < Q hot – Q cold ® 15
  • 16. Energy Transfer–Thermoelectric Teachers’ Notes–Conservation of Energy 5) Most of the heat that flowed out of the two-reservoir system was lost. Some of it flowed through the foam insulators to the environment. Some of it was dissipated in other parts of the circuit. ( 0.572 J ) 6) % of useful work = --------------------- × 100 % = 17 % - ( 3.3 J ) 7) Wobserved = Q hot – Q cold – E lost 8) The result of doing work on the resistor was that the resistor dissipated heat to the environment. For a more practical use of the useful work, the resistor could have been replaced with a light bulb, an electric motor, or some other electrical device. Conservation of Energy 0.572 J 9) % recovered = ---------------- × 100 % = 0.9 % - 60.3 J 10) This is not a good way to store energy. Conduction and Heat Flow Through Insulator ( 7 °C ) 11) Q i ⁄ t = [ 0.36 W/(m·°C) ] × [ ( 0.033 m ) × ( 0.037 m ) ] × --------------------- = 0.031 J/s ( 0.01 m ) Q i = (0.031 J/s) × (150 s) = 4.6 J 12) Q i is small compared to Q cold. 13) This is an estimate of the heat that flowed from the outside air, through the insulator, and into the front face of the aluminum block on the cold side. Some more heat flowed in through the sides that we ignored. Q i is likely an overestimate because the actual temperature difference was not always as large as the ∆T that was used in the calculation, and the surface area of the front face is larger than that of the sides. 14) Heat flow through the insulator on the hot side would be larger in magnitude because there was a greater temperature difference between the block and the outside air. Since the block was hotter than the air, heat would have flowed out to the environment. 15) The amounts of “lost energy” in the Heat Pump and Heat Engine phases were 12.5 J and 2.7 J. The estimate of Q i suggests that heat flow through the insulators was a significant contribution to this unaccounted-for energy. Another possible contribution to the lost energy is heat dissipated by other components of the circuit, especially the material inside the peltier. 16) Without the insulators, it is likely that the net heat flow to the environment would have been greater, thus increasing the amount of lost energy. 16 ®
  • 17. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 2: Load Resistance and Efficiency Equipment Required Part Number Thermoelectric circuit board part of ET-8782 Foam insulators (qty. 2) part of ET-8782 Heat sink and thumbscrew part of ET-8782 Banana patch cords (qty. 6) part of ET-8782 Temperature cables (qty. 2) part of ET-8782 DC Power Supply (10 V, 1 A minimum) SE-9720A or equivalent PASPORT Voltage/Current Sensor PS-2115 PASPORT Quad Temperature Sensor PS-2143 PASPORT interface(s) PS-2001 or equivalent DataStudio software See PASCO catalog “Load Efficiency” configuration file for DataStudio part of ET-8782 Introduction In this experiment you will examine the relationship between output load resistance and the power generated by the peltier when it is operating in heat engine mode. You will observe the output power as you vary the load resistance while keeping everything else constant (the temperature difference between the blocks, for instance). Since it is not possible to hold the blocks at a steady temperature difference, you will take the peltier through several identical cycles of heating and cooling, and measure the power each time a certain temperature difference occurs. You will repeat the cycle for each value of load resistance that you test, ranging from slightly over 0 Ω to 30 Ω. Before you start, predict what you will discover about the relationship between output power and load resistance. Record your prediction using words, numbers and a graph. Explain your reasoning. Set-Up 1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up). Connect the power supply using banana patch cords to the input power terminals on the circuit board as shown in picture. Note the polarity. ® 17
  • 18. Energy Transfer–Thermoelectric Load Resistance and Efficiency 2. Temperature: Connect the Voltage/Current Sensor cables from the temperature ports to the Quad Temperature Sensor. Connect the Cold Side to Channel 1 of the sensor and the Hot Side to Channel 2. 3. Voltage: Connect Ch 2 the voltage leads of the Voltage/ Power Temperature Supply Current Sensor to Sensor the Voltage Ports on the board. Note Ch 1 the polarity. 4. Current: Connect separate red and black banana patch cords from the current input of the Voltage/Current sensor to the Current Ports on the board. Note the polarity. 5. Computer: Connect the sensors to the computer through the PASPORT interface. Open the pre-configured DataStudio file “Load Efficiency”. The display should look as shown below. 18 ®
  • 19. Model No. ET-8782 Experiment 2: Load Resistance and Efficiency Background This section explains some of the details of the DataStudio configuration file. Calculations: DataStudio will measure the temperature of both blocks (T hot and Tcold), the voltage across the load resistor, and the current through the load resistor. From these measurements it will make two calculations, temperature difference (∆T) and output power (P), using the following equations: ∆T = T hot – Tcold P = current × voltage Start and Stop Conditions: DataStudio has been configured with start and stop conditions, which control when it records data. The start condition is that ∆T must drop below 35 °C. Before the beginning of each cycle (when ∆T < 35 °C) you will click the Start button; DataStudio will display live data, but it will not start recording. Data recording will not start until the ∆T has increased above 35 °C and then dropped back below that level. The start condition will enable you to view the temperature measurements without recording them. The stop condition will cause data recording to stop when ∆T drops below 5 °C. Changing the Name of a Data Run: DataStudio will record a separate data run for each load resistance. In order to keep track of them, you will rename each data run. By default, the runs are named Run #1, Run #2, etc. In order to rename a run, find it in the Summary window (on the left side of the screen), click on it once to select it, then click on it again to edit it (be careful to single- click twice, and not to double-click). Enter the new name (for instance, “7 ohms”). When DataStudio asks if you would like to rename all the data from this run, select Yes. Procedure 1. Click the Start button. DataStudio will show live temperature readings in the Digits display, but it won’t start recording yet. 2. Observe the temperature of both sides of the peltier; both should be close to room temperature. During the experiment, you will take the peltier through several cycles of heating and cooling. You must ensure that both sides of the peltier are close to room temperature before each cycle starts. Note the room temperature for future reference. 3. Set the voltage on power supply to about 6 volts. Set the switch to Heat Pump mode for about 2 seconds, then return it to the neutral position. If the voltage/current sensor beeps, then the current is too high (over 1 amp) and you should decrease the voltage (then close the switch again to test it). 4. Set the switch to the Heat Engine position and allow the blocks to cool. Wait until both sides are within a few degrees of room temperature. (To cool faster, install the heat sink on the hot block and turn on the cooling fan. It also helps to put a metal object in contact with both blocks.) ® 19
  • 20. Energy Transfer–Thermoelectric Load Resistance and Efficiency 5. Connect the output load jumper to terminal D. This bypasses all of the resistors and reduces the load resistance to almost zero. Note that the resistance is not exactly zero because the wires and traces on the board have some resistance. 6. Place both insulators on the blocks. 7. Set the switch to Heat Pump mode. Watch the difference in temperature between the two blocks (∆T). You are waiting for ∆T to reach 35 °C, which will take about one minute. 8. When ∆T reaches 35 °C, change the switch to Heat Engine Mode. The temperature difference will start to decrease. When ∆T drops below 35 °C, DataStudio will automatically start recording. You will see data appear on the graph of Power Generated vs. ∆T. 9. When ∆T drops below 5 °C, data recording will stop automatically. 10. Change the name of the data run to indicate the load resistance. 11. Click Start. DataStudio will display temperature data, but it won’t start recording yet. 12. Remove the insulators and use the fan and heat sink to cool the blocks to within a few degrees of room temperature. 13. Change the output load to 3 Ω (connect the jumper to terminal C). 14. Replace the insulators and repeat the cycle of heating and cooling. (Go back to step 7.) 15. Repeat the cycle again for the following values of output load: • 7 Ω (Connect the jumper to B, but also connect a shorting jumper from C to D.) • 10 Ω (Connect the jumper to B.) • 20 Ω (Connect the jumper to A, but also connect a shorting jumper from B to D.) • 30 Ω (Connect the jumper to A.) When you are finished, you will have acquired power and temperature data for six different values of output load resistance. Analysis From the data that has been recorded you will extract the data needed to plot a graph of Power Generated (P) versus Load Resistance (R L) at ∆T = 30 °C. On the graph of P vs. ∆T use the smart cursor to read the power generated at ∆T = 30 °C for each value of load resistance. (Use the zoom select tool to change the scale of the graph and enlarge the area around the data at 30 °C in order to read the data precisely.) Enter the values in the Power vs. Load table. As you enter data into the table, they will be plotted on the Power vs. Load Resistance graph. 1) At what value of R L is the maximum power generated? 20 ®
  • 21. Model No. ET-8782 Experiment 2: Load Resistance and Efficiency 2) For output loads less than and greater than the optimal value, why does the peltier generate less power? All real electrical power supplies (including the peltier heat engine) have an internal resistance, R i. They can be modeled as an ideal voltage source in series with a resistor, as shown below (with an output load connected). + Peltier Ri Heat Engine Vout RL VNL + – – The voltage of the ideal voltage source, V NL, is called the no-load voltage. For a peltier heat engine V NL depends only on ∆T. 3) Under what condition does the output voltage (Vout ) equal V NL? 4) How would you directly measure V NL at ∆T = 30 °C? 5) Write a theoretical equation for output power, P, in terms of V NL, R i and R L. Make a graph of P vs. R L (choose some arbitrary values for V NL and R i ). Based on your equation and graphs, under what condition is P at its maximum? 6) In this experiment, one of the data points was taken with R L = 0. According to your equation, what is the theoretical power generated when R L = 0? Was this the case in your experiment? There is another source of resistance that we haven’t considered yet, which is the resistance of the traces, leads and sensors in the circuit. Let’s call it RT. If we add in RT, the circuit can be modeled thus: + RT Peltier Ri Heat Engine Vout RL VNL + – – 7) Rewrite the theoretical equation for P taking RT into account. 8) Fit this equation to your experimental data. What is the no-load voltage at ∆T = 30 °C? What is the internal resistance of the peltier? What is RT? Further Investigation 1. Make a direct measurement of the no-load voltage at ∆T = 30 °C. 2. Make a direct measurement of RT (or measure as much of it as possible). ® 21
  • 22. Energy Transfer–Thermoelectric Load Resistance and Efficiency 3. Predict how your results would differ if you repeated your analysis for a different value of ∆T? Test your prediction. 4. For your graph of Power vs. Load Resistance, what did you do to ensure that only R L and P varied, and that all other experimental parameters stayed constant? Evaluate how successful these measures were. Discuss how you could improve them. 5. In the analysis we assumed that Vout was constant for all values of ∆T = 30 °C. Do an experiment to test that assumption. 6. For any given output load, quantitatively describe the relationship between P and ∆T. 22 ®
  • 23. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 2: Teachers’ Notes–Load Resistance and Efficiency This sample data is in the file “Load Efficiency Data”. For instructions on using the Smart Tool and Zoom Select in the graph display, click on the DataStudio Help menu, select Search and look up those terms in the Index. 1) Power generated was greatest for R L = 7 Ω. 2) For other values of R L, the peltier generated less power because the load resistance did not match the internal resistance. 3) Vout = V NL when there is no load connected (or when R L = ∞). 4) To measure V NL, run the cycle with all of the load resistors disconnected, (or leave the knife switch open for the cooling phase). 2 VNL R L 5) P = ------------------------ - 2 ( Ri + RL ) ® 23
  • 24. Energy Transfer–Thermoelectric Teachers’ Notes–Load Resistance and Efficiency Theoretical P vs. R L (with arbitrary values) V NL = 10 V Ri = 5 Ω P (W) Max P when RL = Ri RL (W) 6) Theoretically P = 0 when R L = 0. Experimentally this was not the case. 2 VNL ( RL + R T ) 7) P = ------------------------------------- - 2 ( Ri + RL + RT ) 8) Experimental data with curve fit: V NL = 1.49 ± 0.1 V R i = 7.4 ± 0.1 Ω P (W) R T = 0.90 ± 0.04 Ω Root MSE = 0.011 W RL (W) 24 ®
  • 25. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 3: A Model Refrigerator Equipment Required Part Number Thermoelectric circuit board part of ET-8782 Foam insulator part of ET-8782 Heat sink and thumbscrew part of ET-8782 Banana patch cords (qty. 4) part of ET-8782 Temperature cables (qty. 2) part of ET-8782 Fast Response Temperature Probes (qty. 2) PS-2135 (3-pack) DC Power Supply (10 V, 1 A minimum) SE-9720A or equivalent PASPORT Voltage/Current Sensor PS-2115 PASPORT Quad Temperature Sensor PS-2143 PASPORT interface(s) PS-2001 or equivalent DataStudio software See PASCO catalog “Refrigerator” configuration file for DataStudio part of ET-8782 Introduction In this activity you will use the peltier device to model a refrigerator. As you run your model refrigerator, DataStudio will display the voltage and current supplied to the peltier, the temperature of both blocks, and the temperature of the air flowing past the heat sink. You will use these measurements to investigate some of the factors that affect the temperature of a refrigerator Set-Up 1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up). Connect the power supply using banana patch cords to the input power terminals on the circuit board. Note the polarity. 2. Insulator: Place a foam insulator on the aluminum block on the Cold Side of the peltier. 3. Block Temperature: Connect the cables from the temperature ports on the circuit board to the Quad Temperature Sensor. Connect the Cold Side to Channel 1 of the sensor and the Hot Side to Channel 2. 4. Air Temperature: Set up two Fast Response Temperature Probes to measure the temperature of the air before and after it flows through the heat sink. Use the temperature clamps to position the probes below and above the heat sink (as shown in the picture). The probes should not touch the ® 25
  • 26. Energy Transfer–Thermoelectric A Model Refrigerator heat sink or the aluminum block. Connect the probe below the heat sink to Channel 3 of the Quad Temperature Sensor; connect the other probe to Channel 4. 5. Voltage: Connect the voltage leads of the Voltage/Current Sensor to the Voltage Ports on the board. Note the polarity. 6. Current: Connect separate red and black banana patch cords from the current input of the Voltage/Current sensor to the Current Ports on the board. Note the polarity. 7. Computer: Connect the sensors to the computer through the PASPORT interface. Open the pre-configured DataStudio file “Refrigerator”. The display should look as shown below. 26 ®
  • 27. Model No. ET-8782 Experiment 3: A Model Refrigerator Procedure As you follow this procedure take notes of your observations and write down the answers to the questions. 1. Put the knife switch in the neutral position (straight up). Set the DC Voltage to about 6 volts. 2. Turn on the fan. 3. Start data recording. Set switch to Heat Pump mode. (Check that the current is not more than 1 amp; if it is, the sensor will beep and you should open the switch, decrease the applied voltage, then close the switch again.) 4. Observe the temperatures of the hot and cold sides of the peltier device. Which side has the bigger temperature difference from room temperature? Why are they not the same? 5. Let the refrigerator run in this mode for at least 5 minutes while the temperatures reach equilibrium. Meanwhile, continue on to the next section. Air Flow and Heat Transfer 6. Observe the air temperatures below and above the heat sink. By how much does the air temperature increase when it passes through the heat sink? This increase in temperature is caused by the heat flowing from the heat sink to the air. You will now estimate the rate of heat transfer from the heat sink to the air. For a gas, we can write Q = nc∆T where, in this experiment: Q = heat transferred from the heat sink to the air (in joules), n = number of moles of air (not the mass), ∆T = change in temperature of the air, c = specific heat of air. The specific heat of a gas depends on whether it is heated at constant volume or constant pressure. In this case the air is heated at constant pressure, so the specific heat is c air = 29.1 J/(mol·°C). The manufacturer's specification for the air flow generated by the fan is about 2 liters per second. At room temperature, one mole of gas occupies about 24.3 liters, so in one second the quantity of gas is 2L - n = -------------------------- = 0.082 mol 24.3 L/mol 7. After the temperatures of the hot and cold blocks have stabilized, calculate the heat, Q, transferred to the air every second. Is your estimate likely too high or too low? Explain your reasoning. The power supplied to the heat pump is ® 27
  • 28. Energy Transfer–Thermoelectric A Model Refrigerator P = IV where: P = power (in watts = joules/second), I = current (in amps), V = voltage (in volts). 8. From the measured values of applied voltage and current, calculate the energy used to run the heat pump for one second. How does the energy supplied to the peltier every second compare to your estimate of the heat transferred from the heat sink to the air every second? Which is bigger? Explain your observations in terms of conservation of energy. Insulator, Fan and Heat Sink 9. When the hot and cold blocks have reached equilibrium, write down the temperatures. Did you make a good refrigerator? 10. Remove the foam insulator (continue recording data). Can you see a change in the cold temperature? Put the foam insulator back on. Why did the temperature change? 11. Turn off the fan (continue recording data). Observe the effect on the temperatures for a few minutes. How have the temperatures of both sides changed? How has the temperature difference between the hot and cold sides changed? Can you explain why? 12. Observe the air temperatures. Have they changed from when the fan was on? Do you think that the rate of heat transferred from the heat sink to the air has increased, decreased, or stayed the same? Explain your reasoning. 13. If the blocks were allowed to reach equilibrium with the fan off, what do you think the final temperature of the “cold” block would be? Would that represent a good refrigerator? 14. Before the hot side reaches 80 °C open the knife switch or turn the fan back on. 15. What part of a real refrigerator is represented by the cold block on your model? 16. In general terms, what does a refrigerator do to make the inside cold? Why does it need insulation? Why does it need a heat sink? Further Investigation 1. Let the refrigerator run for several minutes with the insulator removed and the fan switched on. What is the equilibrium temperature of the cold block in this mode? 2. Without increasing the power supplied to the peltier, can you make the cold side colder? Propose a modification to your model refrigerator and do an experiment to test it. 28 ®
  • 29. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 3: Teachers’ Notes– A Model Refrigerator This sample data is in the file “Refrigerator Data”. The data shown in the digits displays occurred at Time = 5 minutes. Answers to Questions (Step 4) The hot side of the peltier has a larger temperature difference from room temperature than the cold side. Once equilibrium is reached, the heat being pumped out of the cold block is equal to the heat flowing into it from its surroundings. The heat flowing out of hot block is equal to the heat pumped out of the cold block plus the work done by the peltier. Since the heat flow rate out of the hot block is higher than the heat flow rate into the cold block, and heat flow rate is proportional to temperature difference, the hot block must have a higher temperature difference. ® 29
  • 30. Energy Transfer–Thermoelectric Teachers’ Notes–A Model Refrigerator Air Flow and Heat Transfer ∆T = 2.6 °C Q = (0.082 mol) [29.1 J/(mol·°C)] (2.6 °C) = 6.2 J (every second) (Step 7) This estimate is likely to be high because we are measuring the air that goes straight through the heat sink. Much of the air from the fan misses the heat sink, so the average temperature rise for all of the air from the fan would be less than 2.6 °C. P = (0.60 A) (7.1 V) = 4.3 J/s (Step 8) The energy supplied to the peltier every second is less than the estimate of energy transferred to the air by the heat sink. According to conservation of energy, they would be the same if all of the heat lost by the system were transferred to the air through the heat sink. In fact, some heat is lost through radiation, and through other parts of the system. It is likely that most of the discrepancy between Q and P is due to error in the estimate of Q. Insulator, Fan and Heat Sink (Step 9) With the cold block at 5 °C (or 18 °C below room temperature) the model represents an effective refrigerator. (Step 10) With the insulator removed, the temperature of the cold block increases due to increased heat flow from the air to the block. (Step 11) With the fan turned off, the temperature of the hot block increases because the rate of heat transfer to the air decreases. The temperature of the cold block increases at a similar rate. The temperature difference between the blocks increases from 41 °C to 47 °C within 3 minutes of the fan switching off, after which the difference decreases slowly. As the hot block gets hotter and the temperature difference between the blocks increases, the tendency for heat to flow from the hot block to the cold block by conduction increases, canceling the heat-pumping effect of the peltier. (Step 12) When the fan is turned off the temperature change of the air flowing through the heat sink increases to about 10 °C. Since the hot block gets hotter, it is evident that the rate of heat transfer to the air has decreased. The increased temperature change is due to the decreased air flow. (Step 13) With the fan turned off, the “cold” block would stabilize at about 40 °C. That is higher than room temperature, so it would not be a good refrigerator. (Step 15) The cold block corresponds to the interior of a real refrigerator. (Step 16) A refrigerator makes the interior cold by pumping heat out of it. It needs insulation to reduce the rate of heat flow back into it from the surrounding air. It needs a heat sink to transfer away the heat that it has pumped out of the interior, and the heat resulting from the work that it does. 30 ®
  • 31. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 4: Coefficient of Performance Equipment Required Part Number Thermoelectric circuit board part of ET-8782 Foam insulator part of ET-8782 Heat sink and thumbscrew part of ET-8782 Banana patch cords (qty. 4) part of ET-8782 Temperature cables (qty. 2) part of ET-8782 DC Power Supply (10 V, 1 A minimum) SE-9720A or equivalent PASPORT Voltage/Current Sensor PS-2115 PASPORT Quad Temperature Sensor PS-2143 PASPORT interface(s) PS-2001 or equivalent DataStudio software See PASCO catalog “Coeff of Performance” configuration file for DataStudio part of ET-8782 Introduction Some heat pumps, such as refrigerators and air conditioners, are used for their cooling effect. They pump heat out of a container or a building, making the interior cooler than the surrounding environment. But a heat pump can also be used to pump heat into a building, making the interior warmer than the surrounding environment. An important property of a heat pump is how much energy it uses to move a certain amount of heat. In this activity you will measure the Coefficient of Performance of a heat pump working in both modes, and discover how a heat pump can be more efficient at heating a building than conventional methods. Set-Up 1. Input Power: Set the Heat Pump/Heat Engine switch to the neutral position (straight up). Connect the power supply using banana patch cords to the input power terminals on the circuit board as shown in picture. Note the polarity. 2. Heat Sink and Insulator: Attach the heat sink to the aluminum block on the Hot Side of the peltier. Place a foam insulator on the other block. ® 31
  • 32. Energy Transfer–Thermoelectric Coefficient of Performance Voltage/Current Sensor Ch 2 Power Temperature Supply Sensor Ch 1 3. Temperature: Connect the cables from the temperature ports on the circuit board to the Quad Temperature Sensor. Connect the Cold Side to Channel 1 of the sensor and the Hot Side to Channel 2. 4. Voltage: Connect the voltage leads of the Voltage/Current Sensor to the Voltage Ports on the board. Note the polarity. 5. Current: Connect separate red and black banana patch cords from the current input of the Voltage/Current sensor to the Current Ports on the board. Note the polarity. 6. Computer: Connect the sensors to the computer through the PASPORT interface. Open the pre-configured DataStudio file “Coeff of Performance”. The display should look as shown below. 32 ®
  • 33. Model No. ET-8782 Experiment 4: Coefficient of Performance Background DataStudio has been configured to measure and record the temperature of both aluminum blocks, and the voltage and current applied to the peltier. From these measured quantities, DataStudio will calculate and display heat flow, power and work. The following sections explain how DataStudio makes these measurements and calculations. Heat vs. Temperature The digits displays show the heat that flows into the hot block (Q hot) and out of the cold block (Q cold). The relationship between heat flow and temperature change is given by Q = mc∆T where: Q = heat transferred, m = mass of the aluminum block, c = specific heat of aluminum = 0.90 J/(g·°C), ∆T = change in temperature. A positive value of Q hot represents heat flowing into the hot block, but a positive value of Q cold represents heat transferred out of the cold block. The temperature of each block is measured by the embedded thermistor. DataStudio calculates the heat flow from the measured temperature change, and pre-entered values of m and c. Click on the calculator icon in the tool bar and look at the equations used; note the constants, m and c, in the bottom section of the calculator window. (The mass of each block is about 19 g. If you would like to enter your own value for the mass, measure the blocks with calipers and use the density of aluminum, 2.7 g/cc, to calculate the mass, then enter it in the calculator.) Input Power and Work Done by the Peltier Input Power from the power supply equals the rate at which the peltier does work to pump heat out of the cold reservoir and into the hot reservoir. The Voltage/Current Sensor measures the voltage applied to the peltier, and the current that flows through it. DataStudio calculates the Input Power using the equation: Power = Voltage × Current. The area under the plot of Input Power versus time equals the energy supplied to the peltier, which equals the work, W, done by the peltier. Start Condition The configuration file contains a start condition; when you click the Start button (with the knife switch open) DataStudio will display live data, but it will not start recording until you close the knife switch. This will allow you to monitor the measurements and confirm that both blocks are at the same temperature before data recording starts. ® 33
  • 34. Energy Transfer–Thermoelectric Coefficient of Performance Procedure Refrigerator Before you start, the knife switch should be in the neutral position (straight up) and the fan should be switched off. Make sure that the foam insulator is on the cold block, and that the heat sink is on the hot block. Set the DC Voltage to about 5 volts. Click the Start button. Observe the temperatures of the hot and cold blocks; they should be within 0.1 °C of each other. (If they are not, turn on the fan and wait until the temperatures have equalized. Then turn the fan off and proceed.) Set the knife switch to Heat Pump mode. Allow the heat pump to run for 10 to 15 seconds, then open the switch. Watch the temperature graphs; once the temperatures have peaked out, stop data recording. You need to give the blocks a few seconds to reach a maximum or minimum before you stop recording. Heat pumps are rated by the Coefficient of Performance, k. In the case of a heat pump used for cooling (such as a refrigerator) the Coefficient of Performance is Q cold k = ----------- (for cooling) - W The Coefficient of Performance expresses how much heat the heat pump removes from the cold side compared to how much energy it uses to move the heat. 1) Use your values for the heat pumped out of the cold block (Q cold) and the area under the Power versus time curve (W) to calculate the Coefficient of Performance, k, for your model refrigerator. 2) For real heat pumps k is usually expected to be greater than 1. Is this the case for your model? 3) Your heat pump can also be thought of as a model air conditioner, a device used to keep the inside of a building cooler than the outside air. In terms of moving heat, what does an air conditioner do to keep a building cool? (Keep in mind that an air conditioner does not necessarily move air into or out of the building.) 4) Compare your model to a building being cooled by an air conditioner. What does the peltier represent? What does the cold block represent? What does the hot block represent? 5) If you were selecting an air conditioner to keep your home cool, would you choose one with a high or low coefficient of performance? Explain why. 34 ®
  • 35. Model No. ET-8782 Experiment 4: Coefficient of Performance Reversible Heat Pump A certain kind of air conditioner, known as a reversible heat pump, can also be used to heat a building. You will now use the peltier to model a reversible heat pump being used to keep a building warmer than the surrounding air. Place the heat sink on the cold block, and the foam insulator on the hot block. Delete the data that you have previously recorded. (Click on the Experiment menu and select Delete All Data Runs.) Click the Start button. Make sure that the hot and cold blocks are within 0.1 °C of each other before proceeding. (If they are not, remove the insulator, turn on the fan and wait for the temperatures to equalize. Then turn off the fan, replace the insulator and proceed.) Set the switch to Heat Pump mode. Allow the heat pump to run for 10 to 15 seconds, then open the switch. Watch the temperature graphs; once the temperatures have peaked out, stop data recording. For a reversible heat pump heating a building, we are interested in the heat pumped into the building, Q hot. (This is opposed to the previous case where we were interested in the heat pumped out of the building.) Thus the Coefficient of Performance is Q hot k = --------- (for heating) - W 6) Use your values for the heat delivered to the hot block (Q hot) and the area under the Power versus time curve (W) to calculate the Coefficient of Performance, k. 7) If you had used a simple resistor (rather than the peltier) to heat the aluminum block, and used the same amount of energy (W), what would have been the maximum amount of heat transferred to the block? 8) Compare your model to a building being heated by a reversible heat pump. What does the peltier represent? What does the cold block represent? What does the hot block represent? 9) Why is it important for k to be greater than 1 for a reversible heat pump? Compare this to a simple electrical heater. How much heat is delivered to a building using a simple heater supplied with 100 J of electrical energy? How much heat is delivered to a building using a heat pump, with k = 2, that uses 100 J of electrical energy to pump heat from outside to inside the building? Further Investigation Think of a factor that you can vary in the experimental set-up. Predict how varying that factor would affect the coefficient of performance in heating or cooling mode. Do an experiment to test your prediction. ® 35
  • 36. Energy Transfer–Thermoelectric Coefficient of Performance 36 ®
  • 37. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 4: Teachers’ Notes– Coefficient of Performance Refrigerator This sample data is in the file “Coeff of Performance Data Refrig”. 76.0 J 1) k = ------------- = 1.59 - 47.8 J 2) This coefficient of performance is similar to that of real heat pumps. 3) An air conditioner pumps heat out of the building and into the outside air. 4) The peltier represents the heat pump, the cold block represents the interior of the building, and the hot block represents the outside air. 5) You would choose an air conditioner with a high coefficient of performance because it would use less energy to remove heat from the building (and cost less to run). ® 37
  • 38. Energy Transfer–Thermoelectric Teachers’ Notes–Coefficient of Performance Reversible Heat Pump This sample data is in the file “Coeff of Performance Data Heat Pump”. 116.6 J 6) k = ---------------- = 2.41 - 48.4 J 7) If you used a simple resistor to heat the block with the same amount of work, the maximum heat transferred to the block would be W = 48.4 J. 8) The peltier represents the heat pump, the cold block represents the outside air, and the hot block represents the interior of the building. 9) The coefficient of performance must be greater than 1 in order for the heat pump to be more efficient than a simple heater. A simple heater supplied with 100 J of electrical energy would transfer 100 J of heat to the building. A heat pump with k = 2 supplied with 100 J of electrical energy would transfer 200 J to the building. Q hot = kW 38 ®
  • 39. Model No. ET-8782 Energy Transfer–Thermoelectric Experiment 5: Teachers’ Notes– Carnot Efficiency Equipment Required Part Number Thermoelectric circuit board part of ET-8782 Foam insulators (qty. 2) part of ET-8782 Banana patch cords (qty. 5) part of ET-8782 Temperature cables (qty. 2) part of ET-8782 DC Power Supply (10 V, 1 A minimum) SE-9720A or equivalent PASPORT Voltage/Current Sensor PS-2115 PASPORT Quad Temperature Sensor PS-2143 PASPORT interface(s) PS-2001 or equivalent DataStudio software See PASCO catalog “Carnot Efficiency Workbook” file for DataStudio part of ET-8782 With the electronic workbook Temperature (°C) contained on the CD-ROM, students will study the efficiency of the peltier heat engine. They will record data for ∆T, power generated and heat flow, calculate Power Generated (mW) efficiency, and discover the relationship between efficiency and ∆T. Finally they will compare the actual efficiency of the heat engine to the Carnot efficiency. Have your students open the Time (s) DataStudio file “Carnot Efficiency Workbook” and follow the on- screen instructions. As they go efficiency (%) through the electronic workbook they should take notes and record their answers to questions on paper. You can find sample data in the file Carnot efficiency (%) “Carnot Efficiency Workbook with Data”. DT (°C) ® 39
  • 40. Energy Transfer–Thermoelectric Teachers’ Notes–Carnot Efficiency 40 ®
  • 41. Model No. ET-8782 Energy Transfer–Thermoelectric Safety Copyright and Warranty Information Read the instructions before using this product. Students should be supervised by their instructors. When using this product, Copyright Notice follow the instructions in this manual and all local safety guidelines that apply to you. The PASCO scientific 012-08745A Energy Transfer–Thermoelectric Instruction Technical Support Manual is copyrighted and all rights reserved. However, permission is granted to For assistance with any PASCO product, non-profit educational institutions for contact PASCO at: reproduction of any part of this manual, providing the reproductions are used only for Address: PASCO scientific their laboratories and are not sold for profit. 10101 Foothills Blvd. Reproduction under any other Roseville, CA 95747-7100 circumstances, without the written consent Phone: (916) 786-3800 of PASCO scientific, is prohibited. (800) 772-8700 Fax: (916) 786-3292 Web: www.pasco.com Limited Warranty Email: techsupp@pasco.com For a description of the product warranty, see the PASCO catalog.