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Solid-State
Batteries
“ The only commercially available all-solid-state battery.
Powering vehicles every day, all over the world”
BATTERY TECH USA 2023
Orange County, CA | 7 March 2023
Who are we?
“
”
3
*Group figures from end 2021.
Founded in 1822 as a paper
manufacturer, the French company
and family story successfully
navigated through the 20th and
21st centuries with activities
diversification in Transportation,
Logistics, Energy distribution and
storage as well as Media and
Communications.
The group is publicly listed and
chaired since 2019 by
Cyrille Bolloré.
3
People
73,000*
Revenues
€ 20 Bn*
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
4
A global research & industrial footprint
Unites-States
Palo Alto, CA
Advanced research
Canada
Boucherville, Quebec
Production & Research
France, HQ
Quimper & Grenoble
Production & Research
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
5
500+ people with the experience of delivering
3 Million cells (>1 GWh) since 2011
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
6
R&D
400+ Technicians & Engineers
Production
600 MWh, 48,000m², 2 sites* in France,
Canada & advanced research in the
USA (CA).
IP
Intellectual Property
620 Patents.
Innovation
Gen3 for Commercial vehicles to Gen4
for Passenger EVs.
Sustainability
Innovations et developments in response to major
environmental challenges, committed towards a long-term
positive impact.
Dedication to a decarbonized mobility
*Certified plants
ISO 14001 (environment),
ISO 9001 & IATF 16949 (quality)
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
7
A long & solid history going back 40 years!
2007
80’s 2001
Collaboration
between
CEA/CNRS &
Hydro-
Québec/IREQ
Creation of
Avestor in
Canada
Creation of
Batscap in
France
Bolloré Group
acquires Avestor
and the merger
with Batscap
results in Blue
Solutions
Distance achieved
500 Million km
First electric car, with
250-km range thanks to
its solid-state battery
2011 2019
eCitaro
Electric buses
applications
Designed for the EV
mass market
# of cells produced
3 Million units
Gen4
2026
12m 6m
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
Gen3
8
World pioneer in solid-state cells
High energy density
Safer: high temperature stability.
Cells are intrinsically safe
Solid polymer electrolyte
replacing the flammable liquid
found in lithium-ion batteries
Lithium metal anode, highest
energy density material
Does not require a cooling system
Applications
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
Our Strengths
“
”
10
At the heart of the cells lies chemistry
Solid-state & Lithium metal
chemistries: a 40+ years
expertise
Blue Solutions is the all-solid-state battery pioneer with a unique expertise on:
lithium metal and polymer-type solid electrolyte.
Unparalleled in-depth practical knowledge of interfaces management and
ageing phenomena experienced in batteries.
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
11
Manufacturing at scale of large cells
Blue Solutions masters the
full value chain of solid-
state cells’ industrialization
process
Blue Solutions is the only company in the world to have designed, developed
and industrialised at scale for the last 11 years all-solid-state batteries:
3 million cells have been produced in cumulative.
Blue Solutions’ cells are larger (105 Ah, 610x175mm) than any lithium-ion
ones in the market and without any match from the prototype cells
developed by newcomers in the solid-state space.
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
12
Holistic knowledge
Cells are assembled in modules and packs with a simple pressure system,
illustrating Blue Solutions abilities for system design and in-vehicle (buses,
trucks, cars) and stationary integration.
Blue Solutions develops proprietary software solutions from cell monitoring tools
(temperature, voltage) to overall system control and interfaces with vehicle ECUs.
Modules, packs & BMS:
demonstrating full system
and integration
competences
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
13
Sustainability
Blue Solutions develops its own recycling solutions to re-use all critical metals
and to re-inject them in new cell manufacturing flows, in compliance with
European battery regulation.
Thanks to an unmatched experience with lithium metal, Blue Solutions has filed
a new patent for an innovative method to extract lithium metal from the
heart of the cells.
Key words: Recyclability,
Re-use & Sustainability
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
Next Objective
“
”
15
Cathode; platform-design
allowing automotive standard
materials: NMC, LFP.
Thinner Lithium
metal
Polymer electrolyte suited for
a large range of operating
temperatures
Gen4: towards passenger e-mobility needs
Gen4
Development with the support and collaboration of
global industry & ecosystem partners
Higher energy density:
900 Wh/L - 450 Wh/Kg
Operating at room Temperature
Enabling Fast charging
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
16
Gen 4: Specifications for the EV Market
Chemistry
Performance
Cathode High Voltage Cathode NMC / LMFP - LFP
Electrolyte Polymer-based
Anode Lithium Metal
Volumetric density >900 Wh/L
Safety Fire hazard Thermally stable electrolyte up to 300°C
Cycle life 1000 +/-
Packaging Format
Fast charging rate 3C
Gravimetric density >450 Wh/kg
Pressure <2 bars
Operating temperature Ambient, system operation from -20°C to 60°C
Gen4 targeted properties
Cell designed for integration (cell to pack/chassis)
Manufacturability
Maturity
Know-How
Gen4
Polymer, lithium metal
processing, low stack pressure,
modules & packs, scale-up
experience
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
17
Blue Solutions: Polymer path
as the best choice for SSB
Conductivity
Thermal Stability
Li-Metal Compatibility
Moisture Stability
Manufacturability
Pressure Requirement
SSB Technology Comparison
Polymer
Oxide
Sulfide
Multiple industrialization and
integration roadblocks are
expected for Oxide and Sulfide
technologies: process in inert
environment and high levels of cell
stack pressure required detrimental
to pack-level energy density.
Polymer technology is the most
polyvalent solution, already
industrialized today with major
ramp-up experience and quality
control.
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
18
Benchmark of target specifications
Targeted performance
Consensus target range
Charging rate
for fast charging
Cell volumetric
density
Operating
pressure
Cell gravimetric
density
Operating
temperature
C
Cycles n.a.
Wh/L
n.a.
bar
Wh/ kg
n.a.
n.a.
°C
n.a.
C/20 5C
200 2000
1000
200 1200
1000
3.4 1
>10
100 400 700
600
100 -20
25 room
temperature
>330
1C 4C
900
450
850
500
Cycle life,
At ambient temperature
3C
Better performance
Company G
Company SE
Company SP
Company Q
Company F
Company P
Comparing a set of 6 SSB players value propositions illustrate similar level of targeted performances,
despite various actual cell sizes, number of layers and test conditions.
Blue Solutions’ SSB is expected to be highly competitive on density level vs. start-ups
2
19
0
1
2
3
4
5
0 50 100 150
Rate
(nC)
Capacity (mAh/g)
Where do we stand?
Power performances
New generation cycling capability demonstrated at 20°C with HV cathode material.
Charging performances show promising results by achieving 35% SOC at 3C and 70% SOC at 2C!
35% SOC at 3C
70% SOC at 2C
0
20
40
60
80
100
0
20
40
60
80
100
120
140
160
0 100 200 300 400 500 600 700 800
Efficiency
(%)
Capacity
(mAh/g)
Cycles
Cyclability
20°C
Charging:
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
20
Assembly
Stacking
Cutting
Slitting
Extrusion
Fomation &
Ageing
Degasing
ELT Filling
Assembly
Stacking
Cutting
Slitting
Calendaring
Coating &
Drying
100%
-30%
SSB Manufacturing Differentiation
vs. Li-ion
3-fold advantage for new and
transformed lines: fewer steps,
less m² and less labour
CAPEX
Energy Density
Mixing
Li-ion Battery Steps
Blue Solutions Steps
Mixing
Fomation &
Ageing
Coating &
Drying
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
>>+30%
21
Industrial Roadmap
2028
600 MWh
2022
20 GWh
Gigafactory
Ambition
145 M€ in R&D effort till 2025
and 70+ additional research
engineers to pave the way
towards breakthrough
performances for passenger
cars.
Gigafactories
Launching production
capacity in accordance to the
expanding EV market.
21
Production
Capacity
Energy Density
380 Wh/L
2025
900 Wh/L
Gen4
Pilot line
Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
Thankyou
www.blue-solutions.com
Adrian Tylim
Head Business Development North America
adrian.tylim@blue-solutions.com

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SOLID-STATE BATTERY PERFORMANCE FOR THE EV INDUSTRY - COMMERCIAL TO PASSENGER

  • 1. Solid-State Batteries “ The only commercially available all-solid-state battery. Powering vehicles every day, all over the world” BATTERY TECH USA 2023 Orange County, CA | 7 March 2023
  • 3. 3 *Group figures from end 2021. Founded in 1822 as a paper manufacturer, the French company and family story successfully navigated through the 20th and 21st centuries with activities diversification in Transportation, Logistics, Energy distribution and storage as well as Media and Communications. The group is publicly listed and chaired since 2019 by Cyrille Bolloré. 3 People 73,000* Revenues € 20 Bn* Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 4. 4 A global research & industrial footprint Unites-States Palo Alto, CA Advanced research Canada Boucherville, Quebec Production & Research France, HQ Quimper & Grenoble Production & Research Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 5. 5 500+ people with the experience of delivering 3 Million cells (>1 GWh) since 2011 Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 6. 6 R&D 400+ Technicians & Engineers Production 600 MWh, 48,000m², 2 sites* in France, Canada & advanced research in the USA (CA). IP Intellectual Property 620 Patents. Innovation Gen3 for Commercial vehicles to Gen4 for Passenger EVs. Sustainability Innovations et developments in response to major environmental challenges, committed towards a long-term positive impact. Dedication to a decarbonized mobility *Certified plants ISO 14001 (environment), ISO 9001 & IATF 16949 (quality) Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 7. 7 A long & solid history going back 40 years! 2007 80’s 2001 Collaboration between CEA/CNRS & Hydro- Québec/IREQ Creation of Avestor in Canada Creation of Batscap in France Bolloré Group acquires Avestor and the merger with Batscap results in Blue Solutions Distance achieved 500 Million km First electric car, with 250-km range thanks to its solid-state battery 2011 2019 eCitaro Electric buses applications Designed for the EV mass market # of cells produced 3 Million units Gen4 2026 12m 6m Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions Gen3
  • 8. 8 World pioneer in solid-state cells High energy density Safer: high temperature stability. Cells are intrinsically safe Solid polymer electrolyte replacing the flammable liquid found in lithium-ion batteries Lithium metal anode, highest energy density material Does not require a cooling system Applications Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 10. 10 At the heart of the cells lies chemistry Solid-state & Lithium metal chemistries: a 40+ years expertise Blue Solutions is the all-solid-state battery pioneer with a unique expertise on: lithium metal and polymer-type solid electrolyte. Unparalleled in-depth practical knowledge of interfaces management and ageing phenomena experienced in batteries. Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 11. 11 Manufacturing at scale of large cells Blue Solutions masters the full value chain of solid- state cells’ industrialization process Blue Solutions is the only company in the world to have designed, developed and industrialised at scale for the last 11 years all-solid-state batteries: 3 million cells have been produced in cumulative. Blue Solutions’ cells are larger (105 Ah, 610x175mm) than any lithium-ion ones in the market and without any match from the prototype cells developed by newcomers in the solid-state space. Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 12. 12 Holistic knowledge Cells are assembled in modules and packs with a simple pressure system, illustrating Blue Solutions abilities for system design and in-vehicle (buses, trucks, cars) and stationary integration. Blue Solutions develops proprietary software solutions from cell monitoring tools (temperature, voltage) to overall system control and interfaces with vehicle ECUs. Modules, packs & BMS: demonstrating full system and integration competences Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 13. 13 Sustainability Blue Solutions develops its own recycling solutions to re-use all critical metals and to re-inject them in new cell manufacturing flows, in compliance with European battery regulation. Thanks to an unmatched experience with lithium metal, Blue Solutions has filed a new patent for an innovative method to extract lithium metal from the heart of the cells. Key words: Recyclability, Re-use & Sustainability Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 15. 15 Cathode; platform-design allowing automotive standard materials: NMC, LFP. Thinner Lithium metal Polymer electrolyte suited for a large range of operating temperatures Gen4: towards passenger e-mobility needs Gen4 Development with the support and collaboration of global industry & ecosystem partners Higher energy density: 900 Wh/L - 450 Wh/Kg Operating at room Temperature Enabling Fast charging Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 16. 16 Gen 4: Specifications for the EV Market Chemistry Performance Cathode High Voltage Cathode NMC / LMFP - LFP Electrolyte Polymer-based Anode Lithium Metal Volumetric density >900 Wh/L Safety Fire hazard Thermally stable electrolyte up to 300°C Cycle life 1000 +/- Packaging Format Fast charging rate 3C Gravimetric density >450 Wh/kg Pressure <2 bars Operating temperature Ambient, system operation from -20°C to 60°C Gen4 targeted properties Cell designed for integration (cell to pack/chassis) Manufacturability Maturity Know-How Gen4 Polymer, lithium metal processing, low stack pressure, modules & packs, scale-up experience Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 17. 17 Blue Solutions: Polymer path as the best choice for SSB Conductivity Thermal Stability Li-Metal Compatibility Moisture Stability Manufacturability Pressure Requirement SSB Technology Comparison Polymer Oxide Sulfide Multiple industrialization and integration roadblocks are expected for Oxide and Sulfide technologies: process in inert environment and high levels of cell stack pressure required detrimental to pack-level energy density. Polymer technology is the most polyvalent solution, already industrialized today with major ramp-up experience and quality control. Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 18. 18 Benchmark of target specifications Targeted performance Consensus target range Charging rate for fast charging Cell volumetric density Operating pressure Cell gravimetric density Operating temperature C Cycles n.a. Wh/L n.a. bar Wh/ kg n.a. n.a. °C n.a. C/20 5C 200 2000 1000 200 1200 1000 3.4 1 >10 100 400 700 600 100 -20 25 room temperature >330 1C 4C 900 450 850 500 Cycle life, At ambient temperature 3C Better performance Company G Company SE Company SP Company Q Company F Company P Comparing a set of 6 SSB players value propositions illustrate similar level of targeted performances, despite various actual cell sizes, number of layers and test conditions. Blue Solutions’ SSB is expected to be highly competitive on density level vs. start-ups 2
  • 19. 19 0 1 2 3 4 5 0 50 100 150 Rate (nC) Capacity (mAh/g) Where do we stand? Power performances New generation cycling capability demonstrated at 20°C with HV cathode material. Charging performances show promising results by achieving 35% SOC at 3C and 70% SOC at 2C! 35% SOC at 3C 70% SOC at 2C 0 20 40 60 80 100 0 20 40 60 80 100 120 140 160 0 100 200 300 400 500 600 700 800 Efficiency (%) Capacity (mAh/g) Cycles Cyclability 20°C Charging: Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 20. 20 Assembly Stacking Cutting Slitting Extrusion Fomation & Ageing Degasing ELT Filling Assembly Stacking Cutting Slitting Calendaring Coating & Drying 100% -30% SSB Manufacturing Differentiation vs. Li-ion 3-fold advantage for new and transformed lines: fewer steps, less m² and less labour CAPEX Energy Density Mixing Li-ion Battery Steps Blue Solutions Steps Mixing Fomation & Ageing Coating & Drying Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions >>+30%
  • 21. 21 Industrial Roadmap 2028 600 MWh 2022 20 GWh Gigafactory Ambition 145 M€ in R&D effort till 2025 and 70+ additional research engineers to pave the way towards breakthrough performances for passenger cars. Gigafactories Launching production capacity in accordance to the expanding EV market. 21 Production Capacity Energy Density 380 Wh/L 2025 900 Wh/L Gen4 Pilot line Copyright Blue Solutions 2022 – Do not duplicate or distribute without previous consent from Blue Solutions
  • 22. Thankyou www.blue-solutions.com Adrian Tylim Head Business Development North America adrian.tylim@blue-solutions.com