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Chemistry of
Carbon
From group 3 
Contents
Uses
Carbon cycle
Compounds of
carbon
Allotropes
Properties of
carbon
Carbon Elements
The elements in
group 4 and
second period
of the periodic
table, on the
right, are called
the carbon.
Ditemukan oleh seorang ilmuwan bernama
Antoine Lavoisier. Kemudian, ia menetapkan
bahwa karbon sebagai unsur kimia (1789).
HISTORY
Carbo (Bahasa Latin) :
Karbon
Arti : Batubara
Termasuk gol. : IV A
Nomor atom : 6
Konfigurasi e - : 1s2 2s2 2p2
Massa Ar : 12,011
Jari-jari atom : 70 pm
Titik didih : 4827 C
Titik lebur : 3825 C
Elektronegatifitas : 2,549
Energi ionisasi : -
Tingkat oksidasi Max. : +4
Wujud pada suhu ruangan : padat
Carbon
2, 4
Carbon have four
elecrons in it’s
outer shell
Electron structure of carbon
The
propertie
s of
carbon
Non metal
Has propensity for bonding to
in chains or rings
Can make single bonds (C-C)
multiple bonds (C═C or CC)
The Allotropes’s colour of carbon :
is white bright. is black.Graphite
Allotrope of Carbon
Diamond
Diamond is another important
allotrope of carbon. In diamonds,
each carbon atoms has
sp3 hybridization and forms
covalent bonds with four other
carbon atoms at the corners of
the tetrahedral structure.
Sifat – Sifat Diamon
• Intan merupakan mineral alami yang paling keras.
• Memiliki titik lelh yang sangat tinggi yakni 48270C.
• Tidak larut dalam air
• Tidak dapat menghantarkan arus listrik.
Grafit
Graphite is a soft, black and
slippery solid.
Graphite has a unique
honeycomb layered structure.
Each layer is composed of
planar hexagonal rings of
carbon atoms in which carbon-
carbon bond length within the
layer is 141.5 picometers.
Sifat – Sifat Grafit
• Grafit memiliki titik leleh yang tinggi.
• Memiliki sifat lunak, terasa licin dan digunakan pada
pensil
• Tidak larut dalam air
• Jika dibandingkan dengan intan, grafit memiliki massa
jenis yang lebih kecil.
• Dapat menghantarkan listrik
Fullerence
fullerene is a molecule of carbon in
the form of a hollow sphere.
Fullerenes are similar in structure to
graphite, which is composed of a
sheet of linked hexagonal rings, but
they contain pentagonal (or
sometimes heptagonal) rings that
prevent the sheet from being planar.c
Sifat – Sifat Fullurena
• Tidak larut dalam air, tetapi larut dalam pelarut
organik.
• Sebagai superkonduktor atau penyerap panas yang
baik.
Carbon
Nanotube
Carbon nanotubes are allotropes
of carbon with a cylindrical
nanostructure.
Sifat karbon
nanotubes
Sifat konduktivitas
listrik dan panas,
juga memiliki
kekuatan maknetik.
Oxide Cyanogenides
Cyanides Sulfides
Halides Carbides
Compounds of Carbon
1
• Carbon monoxide (CO)
2
• Carbon dioxide (CO2)
Oxide of carbon
CO formed when carbon is burned in limited
supply of oxygen. It also present in the
exhaust fumes of cars due to the incomplete
combustion of petrol.
Carbon monoxide
(CO)
Colorless and
odorless toxic gas
CO2 formed in all forms of combustion of carbon and
carbon compound in excess of O2. It is involved in
geochemical cycle as well as photosynthesis.
Carbon dioxide
(CO2)
Colorless and odorless gas
and nontoxic
Cyanogenides
Example: Cyanogens
((CN)2)
2 Cu2+ + 4 CN- 
2 CuCN + (CN)2
Toxic and
extremely
flammable gas
It can be obtained
from CN- by
aqueous solution
using Cu2+
HCN is a covalent molecular substance but capable of
dissociation in aqueous solution. It is a colorless gas
having the aroma of bitter almonds. This gas is
extremely poisonous.
Hydrogen cyanide can be prepared by
treating sodium cyanide or
potassium cyanide with acid
Cyanides
NaCN + HCl  NaCl
+ HCN
Cyanide ions are extremely toxic because
they bind almost irreversibly to Fe(III) ion
in cytochrome oxidase, a key enzyme in
metabolic processes
Carbon disulfide is made
by heating CH4
with sulfur.
CH4 + S CS2 + 2 H2S
Compound with C-S bond.
Sulfide highly toxic liquid
with pale yellow color and
extremely flammable
Example : carbon disulfide
(CS2)
Sulfide
• Halides
Ex : CCl4
• Colorless liquid
and produced by
the sequence
reaction in which
CS2 is recycled
CS2 + Cl2 
CCl4 + S2Cl2
•CCl4 had been widely
used as solvent and
for the chlorination
of inorganic
compounds.
CCl4
C
A
R
b
I
D
e
Ionic carbides
Interstitial carbides
Covalent carbides
Karbida
Ionic
carbides are
formed by
metals from
group IA, IIA,
and
aluminum, for
example
Na2C2, CaC2,
and Al4C3
Transition
metals with
rrmetal < 130 pm
,e.g. Cr give
carbides that are
intermediate
between
typically ionic
and interstitial
carbides. The
name of this
typical is
cova;ent
carbides
Interstitial
carbides are
formed by
heating C
with d-block
(transition
group) metals
having rrmetal
> 130 pm, e.g.
Ti.
All living things on Earth contain carbon.
But, what is carbon?
Why is it important?
Carbon dioxide (CO2) is a gas
found in our atmosphere. It is
colorless and odorless.
CO2 helps insulate the Earth and keep
our atmosphere at just the right
temperature for life to exist.
People and animals all
contain carbon. We get
our carbon from eating
plants or other animals.
We breathe in oxygen
which mixes with the
carbon and then we
breathe out carbon
dioxide (CO2)
Like people and animals,
fish and other sea
creatures breathe in
oxygen. Their oxygen is
found in the oceans
water. Just like animals
and people, they also
breathe out CO2 (carbon
dioxide).
Plants get carbon by taking carbon dioxide
out of the air or water. All green plants
breathe, except they breathe in carbon
dioxide and release oxygen.
– http://science.howstuffworks.com/environmental/earth/geophysics/earth3.htm
Plants that live in water also use
photosynthesis to make their own food.
They take in carbon from the water and
release oxygen.
Plants and animals eventually die and
decay on the earth or in water. Carbon
now enters the earth or the water.
Over millions of years the decaying plants
and animals became oil, coal, and natural
gas. We call these fossil fuels. We drill, dig,
and
pump these fuels
out of the earth
to use them
for powering
things that
need energy.
By burning fossil fuels to energize our
lives we add carbon dioxide into the
atmosphere.
The carbon dioxide enters the
atmosphere. The cycle starts over.
Carb
on
cycle
The uses of carbon
Used as a decorative tool in
jewelry items
Carbon is used as a base for the
ink that is used in inkjet printers.
Uses for fotosintesis
Use for respiration
Chemistry of carbon

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Chemistry of carbon

  • 3. Carbon Elements The elements in group 4 and second period of the periodic table, on the right, are called the carbon.
  • 4. Ditemukan oleh seorang ilmuwan bernama Antoine Lavoisier. Kemudian, ia menetapkan bahwa karbon sebagai unsur kimia (1789). HISTORY Carbo (Bahasa Latin) : Karbon Arti : Batubara
  • 5. Termasuk gol. : IV A Nomor atom : 6 Konfigurasi e - : 1s2 2s2 2p2 Massa Ar : 12,011 Jari-jari atom : 70 pm Titik didih : 4827 C Titik lebur : 3825 C Elektronegatifitas : 2,549 Energi ionisasi : - Tingkat oksidasi Max. : +4 Wujud pada suhu ruangan : padat
  • 6. Carbon 2, 4 Carbon have four elecrons in it’s outer shell Electron structure of carbon
  • 7. The propertie s of carbon Non metal Has propensity for bonding to in chains or rings Can make single bonds (C-C) multiple bonds (C═C or CC) The Allotropes’s colour of carbon : is white bright. is black.Graphite
  • 8. Allotrope of Carbon Diamond Diamond is another important allotrope of carbon. In diamonds, each carbon atoms has sp3 hybridization and forms covalent bonds with four other carbon atoms at the corners of the tetrahedral structure.
  • 9. Sifat – Sifat Diamon • Intan merupakan mineral alami yang paling keras. • Memiliki titik lelh yang sangat tinggi yakni 48270C. • Tidak larut dalam air • Tidak dapat menghantarkan arus listrik.
  • 10. Grafit Graphite is a soft, black and slippery solid. Graphite has a unique honeycomb layered structure. Each layer is composed of planar hexagonal rings of carbon atoms in which carbon- carbon bond length within the layer is 141.5 picometers.
  • 11. Sifat – Sifat Grafit • Grafit memiliki titik leleh yang tinggi. • Memiliki sifat lunak, terasa licin dan digunakan pada pensil • Tidak larut dalam air • Jika dibandingkan dengan intan, grafit memiliki massa jenis yang lebih kecil. • Dapat menghantarkan listrik
  • 12. Fullerence fullerene is a molecule of carbon in the form of a hollow sphere. Fullerenes are similar in structure to graphite, which is composed of a sheet of linked hexagonal rings, but they contain pentagonal (or sometimes heptagonal) rings that prevent the sheet from being planar.c
  • 13. Sifat – Sifat Fullurena • Tidak larut dalam air, tetapi larut dalam pelarut organik. • Sebagai superkonduktor atau penyerap panas yang baik.
  • 14. Carbon Nanotube Carbon nanotubes are allotropes of carbon with a cylindrical nanostructure.
  • 15. Sifat karbon nanotubes Sifat konduktivitas listrik dan panas, juga memiliki kekuatan maknetik.
  • 16. Oxide Cyanogenides Cyanides Sulfides Halides Carbides Compounds of Carbon
  • 17. 1 • Carbon monoxide (CO) 2 • Carbon dioxide (CO2) Oxide of carbon
  • 18. CO formed when carbon is burned in limited supply of oxygen. It also present in the exhaust fumes of cars due to the incomplete combustion of petrol. Carbon monoxide (CO) Colorless and odorless toxic gas
  • 19. CO2 formed in all forms of combustion of carbon and carbon compound in excess of O2. It is involved in geochemical cycle as well as photosynthesis. Carbon dioxide (CO2) Colorless and odorless gas and nontoxic
  • 20. Cyanogenides Example: Cyanogens ((CN)2) 2 Cu2+ + 4 CN-  2 CuCN + (CN)2 Toxic and extremely flammable gas It can be obtained from CN- by aqueous solution using Cu2+
  • 21. HCN is a covalent molecular substance but capable of dissociation in aqueous solution. It is a colorless gas having the aroma of bitter almonds. This gas is extremely poisonous. Hydrogen cyanide can be prepared by treating sodium cyanide or potassium cyanide with acid Cyanides NaCN + HCl  NaCl + HCN Cyanide ions are extremely toxic because they bind almost irreversibly to Fe(III) ion in cytochrome oxidase, a key enzyme in metabolic processes
  • 22. Carbon disulfide is made by heating CH4 with sulfur. CH4 + S CS2 + 2 H2S Compound with C-S bond. Sulfide highly toxic liquid with pale yellow color and extremely flammable Example : carbon disulfide (CS2) Sulfide
  • 23. • Halides Ex : CCl4 • Colorless liquid and produced by the sequence reaction in which CS2 is recycled CS2 + Cl2  CCl4 + S2Cl2 •CCl4 had been widely used as solvent and for the chlorination of inorganic compounds. CCl4
  • 25. Karbida Ionic carbides are formed by metals from group IA, IIA, and aluminum, for example Na2C2, CaC2, and Al4C3 Transition metals with rrmetal < 130 pm ,e.g. Cr give carbides that are intermediate between typically ionic and interstitial carbides. The name of this typical is cova;ent carbides Interstitial carbides are formed by heating C with d-block (transition group) metals having rrmetal > 130 pm, e.g. Ti.
  • 26. All living things on Earth contain carbon. But, what is carbon? Why is it important?
  • 27. Carbon dioxide (CO2) is a gas found in our atmosphere. It is colorless and odorless.
  • 28. CO2 helps insulate the Earth and keep our atmosphere at just the right temperature for life to exist.
  • 29.
  • 30. People and animals all contain carbon. We get our carbon from eating plants or other animals. We breathe in oxygen which mixes with the carbon and then we breathe out carbon dioxide (CO2)
  • 31. Like people and animals, fish and other sea creatures breathe in oxygen. Their oxygen is found in the oceans water. Just like animals and people, they also breathe out CO2 (carbon dioxide).
  • 32. Plants get carbon by taking carbon dioxide out of the air or water. All green plants breathe, except they breathe in carbon dioxide and release oxygen.
  • 34. Plants that live in water also use photosynthesis to make their own food. They take in carbon from the water and release oxygen.
  • 35. Plants and animals eventually die and decay on the earth or in water. Carbon now enters the earth or the water.
  • 36. Over millions of years the decaying plants and animals became oil, coal, and natural gas. We call these fossil fuels. We drill, dig, and pump these fuels out of the earth to use them for powering things that need energy.
  • 37. By burning fossil fuels to energize our lives we add carbon dioxide into the atmosphere.
  • 38. The carbon dioxide enters the atmosphere. The cycle starts over.
  • 40. The uses of carbon Used as a decorative tool in jewelry items Carbon is used as a base for the ink that is used in inkjet printers. Uses for fotosintesis Use for respiration