This document summarizes a study on using vacuum saturation and laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) to characterize the pore structure of tight shales. The techniques allow mapping of edge-accessible pores. Preliminary results on shale samples indicate low pore connectivity, which reduces gas diffusion from the shale matrix into fractures and helps explain steep production declines from fractured shales. Future work involves elevated pressure saturation and comparing samples with different properties to further investigate inaccessible pores and pore structure influences on flow.
Effect of organic content on carbonation rate of cement stabilised soilsReza Gholilou
1) Carbonation is a chemical reaction between cement compounds (calcium hydroxide and calcium silicate hydrate) and carbon dioxide that leads to deterioration of cement-stabilized soils in pavements over time.
2) Tests show that carbonation causes a loss of cement products, decrease in pH and strength, and microcracking that can result in pavement distress.
3) The rate of carbonation depends on factors like cement content, moisture level, and carbon dioxide concentration and can range from 0.5-50 mm/year, with organic content in soils found to accelerate the process.
The document discusses sustainable operation of geothermal fields. It identifies several factors that can lead to declining injection rates over time, such as mineral precipitation clogging pipes and wells, fines migration from improper well completion, biofilm and corrosion buildup, and near-wellbore flow occlusion. The author proposes methods to address these issues, like using inhibitors to prevent mineral precipitation, improving stimulation techniques to target the near-wellbore area affected by occlusion, and conducting hazard studies before implementing changes like injection basins. The overall aim is to improve drilling efficiency and maintain sustainable resource exploitation.
Formate fluids are high density, thermally stable, and environmentally friendly drilling and completion fluids. Saturated cesium formate fluid has a density of 19.2 ppg. Formate fluids are polar ionic fluids that are inherently low viscosity, biodegradable, non-toxic, and non-corrosive. They provide improved well control compared to other fluids and minimize formation damage due to their low solids content. Formate fluids also exhibit better shale stability, lower friction pressures, and reduced methane diffusion into the wellbore.
This document discusses the water treatment processes required at a power plant. It describes the primary uses of water as cooling water, service water, and high purity water. It then discusses the major water impurities and types of hardness. The document provides details on the system requirements and treatment processes for the different water systems, including sedimentation, softening, filtration, and demineralization using ion exchange. The key goal of treatment is to provide clean water suitable for uses like cooling and boiler feedwater.
Petrophysics in Unconventional Reservoirs Course Mourad Wassef
This document discusses various types of unconventional resources including tight oil, oil shale, heavy oil, coal bed methane, and shale gas. It describes the geology and extraction techniques used for different unconventional reservoirs. Several parameters important for assessing unconventional resources are covered, including total organic carbon, kerogen type, thermal maturity, porosity, permeability, and elastic properties. Petrophysical analysis methods using well logs are presented for calculating properties like TOC, gas content, water saturation, and reserves. Finally, techniques for modeling thermal history, fracturing, and flow potential in unconventional reservoirs are summarized.
This document provides an overview of the water treatment process at a power plant in Raigarh, Chhattisgarh, India. The process begins with raw water from the Mahanadi River which undergoes clarification, filtration, ultrafiltration, reverse osmosis, and mixed bed demineralization to produce high purity demineralized water. Key steps include solid contact clarification, pressure sand filtration, ultrafiltration to remove particles down to 0.01 microns, and reverse osmosis to remove dissolved minerals before final polishing with mixed bed demineralization. The treated water is then stored in various tanks before use in the plant.
Factors affecting Gold Recovery from Secondary Ore_TatendaTatenda Chingosho
The document discusses factors that affect the recovery of gold from low-grade secondary ore using hydrometallurgical processes. It finds that gold recovery is highly dependent on cyanide concentration, leaching time, and pH level. The highest recoveries were obtained at a cyanide concentration of 0.056M, a pH of 11, and a leaching time of 48 hours. Particle size analysis showed that most of the gold was contained in finer particles. Varying these process parameters can optimize gold recovery from low-grade secondary ores.
This document discusses various methods for water softening including:
1. Removal of temporary hardness can be done by boiling or adding lime to precipitate calcium carbonate.
2. Permanent hardness can be removed through chemical precipitation using lime soda ash or ion exchange which replaces calcium and magnesium ions with sodium ions.
3. Demineralization passes water through cation then anion exchange resins to remove all minerals including hardness.
Effect of organic content on carbonation rate of cement stabilised soilsReza Gholilou
1) Carbonation is a chemical reaction between cement compounds (calcium hydroxide and calcium silicate hydrate) and carbon dioxide that leads to deterioration of cement-stabilized soils in pavements over time.
2) Tests show that carbonation causes a loss of cement products, decrease in pH and strength, and microcracking that can result in pavement distress.
3) The rate of carbonation depends on factors like cement content, moisture level, and carbon dioxide concentration and can range from 0.5-50 mm/year, with organic content in soils found to accelerate the process.
The document discusses sustainable operation of geothermal fields. It identifies several factors that can lead to declining injection rates over time, such as mineral precipitation clogging pipes and wells, fines migration from improper well completion, biofilm and corrosion buildup, and near-wellbore flow occlusion. The author proposes methods to address these issues, like using inhibitors to prevent mineral precipitation, improving stimulation techniques to target the near-wellbore area affected by occlusion, and conducting hazard studies before implementing changes like injection basins. The overall aim is to improve drilling efficiency and maintain sustainable resource exploitation.
Formate fluids are high density, thermally stable, and environmentally friendly drilling and completion fluids. Saturated cesium formate fluid has a density of 19.2 ppg. Formate fluids are polar ionic fluids that are inherently low viscosity, biodegradable, non-toxic, and non-corrosive. They provide improved well control compared to other fluids and minimize formation damage due to their low solids content. Formate fluids also exhibit better shale stability, lower friction pressures, and reduced methane diffusion into the wellbore.
This document discusses the water treatment processes required at a power plant. It describes the primary uses of water as cooling water, service water, and high purity water. It then discusses the major water impurities and types of hardness. The document provides details on the system requirements and treatment processes for the different water systems, including sedimentation, softening, filtration, and demineralization using ion exchange. The key goal of treatment is to provide clean water suitable for uses like cooling and boiler feedwater.
Petrophysics in Unconventional Reservoirs Course Mourad Wassef
This document discusses various types of unconventional resources including tight oil, oil shale, heavy oil, coal bed methane, and shale gas. It describes the geology and extraction techniques used for different unconventional reservoirs. Several parameters important for assessing unconventional resources are covered, including total organic carbon, kerogen type, thermal maturity, porosity, permeability, and elastic properties. Petrophysical analysis methods using well logs are presented for calculating properties like TOC, gas content, water saturation, and reserves. Finally, techniques for modeling thermal history, fracturing, and flow potential in unconventional reservoirs are summarized.
This document provides an overview of the water treatment process at a power plant in Raigarh, Chhattisgarh, India. The process begins with raw water from the Mahanadi River which undergoes clarification, filtration, ultrafiltration, reverse osmosis, and mixed bed demineralization to produce high purity demineralized water. Key steps include solid contact clarification, pressure sand filtration, ultrafiltration to remove particles down to 0.01 microns, and reverse osmosis to remove dissolved minerals before final polishing with mixed bed demineralization. The treated water is then stored in various tanks before use in the plant.
Factors affecting Gold Recovery from Secondary Ore_TatendaTatenda Chingosho
The document discusses factors that affect the recovery of gold from low-grade secondary ore using hydrometallurgical processes. It finds that gold recovery is highly dependent on cyanide concentration, leaching time, and pH level. The highest recoveries were obtained at a cyanide concentration of 0.056M, a pH of 11, and a leaching time of 48 hours. Particle size analysis showed that most of the gold was contained in finer particles. Varying these process parameters can optimize gold recovery from low-grade secondary ores.
This document discusses various methods for water softening including:
1. Removal of temporary hardness can be done by boiling or adding lime to precipitate calcium carbonate.
2. Permanent hardness can be removed through chemical precipitation using lime soda ash or ion exchange which replaces calcium and magnesium ions with sodium ions.
3. Demineralization passes water through cation then anion exchange resins to remove all minerals including hardness.
The Repoperm project studied the mechanical and hydraulic behavior of compacting crushed salt backfill at low porosities. It found that:
1) Measurement of properties like permeability and constitutive relationships for two-phase flow are possible down to gas permeabilities of 10-15 m2.
2) Presently used models have limits and material parameters depend on the specific test, so predictive capability needs improving.
3) Further research is needed to fully characterize hydro-mechanical behavior, understand permeability under unsaturated conditions, and reconcile results from different test types.
This document summarizes the RepoTREND code package and its intercomparison with PFLOTRAN for modeling radionuclide transport in a salt repository system. RepoTREND includes modules for modeling near-field processes like canister corrosion and radionuclide mobilization, as well as transport through the near field and far field. It describes initial CLAYPOS and LOPOS models run for the test case, finding generally good agreement with PFLOTRAN results except for Am-241. The LOPOS models with an additional shaft showed increased outflow for some radionuclides but the shaft acts mainly as a sorbing buffer. Suggestions are made to modify the test case for higher model output comparison
The document discusses various properties of drilling fluids including density, cation exchange capacity, filtration properties, pH, rheology, alkalinity, lubricity, and corrosivity. It defines these key terms and describes methods for measuring properties such as cation exchange capacity, pH, rheology, and corrosivity. Controlling properties like pH and alkalinity is important for drilling fluid performance and stability.
This document summarizes a 51 MLD sewage treatment plant (STP) in Hyderabad that uses C-Tech basin technology. The STP treats wastewater from specific areas to reduce BOD, COD, and TSS and protect the Musi River from pollution. It describes the STP's inlet/screening processes, C-Tech basins, chlorine contact tank, and achieves treated effluent standards. Special features include automation through a SCADA system and PLC-based intelligent control. The plant is achieving its treatment goals and helping improve water quality in the Musi River.
11.[30 39]sorption kinetics for dye removal from aqueous solution using natur...Alexander Decker
This document discusses a study on the kinetics of adsorption of Congo red dye onto natural clay. The researchers investigated how experimental variables like agitation, initial dye concentration, clay mass, and clay particle size affect the external mass transfer coefficient. They found that the mass transfer coefficient increases with agitation and clay mass/surface area, but decreases with initial dye concentration and clay particle size. The mass transfer coefficient could be correlated to these variables using the equation kf = A(variable)B. The results indicate the rate of dye removal is affected by factors that influence the mass transfer process.
This document provides an overview of petrophysics and reservoir engineering concepts. It discusses the classification of rocks including igneous, metamorphic and sedimentary rocks. It then focuses on sedimentary rocks and reservoirs, describing the depositional and diagenetic environments and properties of sandstone and carbonate reservoirs. The document also summarizes well log interpretation, shale distribution effects, porosity, fluid saturation, permeability, and other reservoir parameters. It provides definitions and methods for determining properties like relative permeability, wettability, surface tension and capillary pressure.
This document summarizes specifications and standards for water-saving closets in Japan. It provides an overview of global water usage standards for toilets, showing that Japan has led the way in setting a 5L standard. It then details Japan's changing standards over time as closets shifted to using less than 6L of water. The key requirements for water-saving closets are explained, including maintaining discharge, clean-up and transportation performance according to Japanese industrial standards. Test methods and pass criteria are described for evaluating these performance standards in Japan and other countries.
This document describes the in-situ measurement of seepage velocity and chlorobenzene degradation rates in freshwater sediment. Sediment and groundwater samples were collected and analyzed to develop a conceptual model. Pore water profiles from sediment peepers showed decreasing chlorobenzene but increasing chloride concentrations with depth, indicating chlorobenzene degradation. Quantitative analysis using an analytical transport model estimated the seepage velocity based on chloride data and chlorobenzene degradation half-life of 280-504 days based on pore water concentration profiles, consistent with literature values.
The document describes a plan to inter-compare the PFLOTRAN and RepoTREND reactive transport codes. The plan involves:
1) A batch waste form simulation to compare radionuclide release from a instantly breaching nuclear waste form.
2) A full simulation of a generic salt repository with a mined drift, shaft, and aquifer to compare breakthrough curves and dose calculations.
3) PFLOTRAN has provided first results for the batch simulation showing radionuclide source terms and cumulative release over time. The next step is setting up the full repository simulation in PFLOTRAN.
Understanding hydrodynamics in membrane bioreactor systems for wastewater tre...Nicolas Ratkovich
The document discusses modeling the hydrodynamics of a membrane bioreactor system using computational fluid dynamics (CFD) and empirical modeling. Experiments were conducted to measure shear stress and gas slug velocity in a tube under two-phase slug flow conditions. A CFD model was developed and validated against experimental data. Empirical models were also developed to correlate shear stress measurements and predict bimodal shear stress histograms. The models were then used to analyze pressure drop, energy consumption, and opportunities for optimization in the membrane bioreactor system. Finally, the structure of a PhD thesis modeling the hydrodynamics of a specific Norit airlift membrane system is outlined.
Removal of boron from aqueous solution using reverse osmosisakhilesh kushwaha
This document presents information on removing boron from water using reverse osmosis (RO). It discusses the health risks of boron in drinking water and various boron removal methods. It outlines the RO process, factors that affect it like pH, pressure and temperature. Experimental results show boron rejection increased with higher pH and pressure. The conclusion is that RO can effectively remove boron when optimizing operating conditions.
This document summarizes research on using electrodialysis and reverse osmosis to recover dissolved organic carbon from seawater. The researchers developed a process to concentrate seawater using reverse osmosis, followed by electrodialysis to remove salt, producing a desalinated sample for analysis. Over 15 experiments were conducted using seawater and brackish water samples, recovering 60-90% of dissolved organic carbon. Preliminary results found differences in the recovered high molecular weight fraction compared to previous methods. The combined process allows treatment of large volumes of seawater samples for scientific study of marine dissolved organic carbon.
Boron is a chemical element commonly found in the environment in compounds called borates. It is difficult to remove boron from seawater using reverse osmosis (RO) due to its uncharged and nonpolar nature. Multiple configurations can be used to effectively remove boron including double-pass RO systems, single-pass RO combined with ion exchange resins, and multistage RO systems sometimes incorporating ion exchange or acidification steps. The specific configuration used depends on factors like feed water chemistry and the desired permeate quality.
Using Carbon Isotopes to Monitor CO2 at the CONSOL Energy Inc. Coal Sequestr...Stephen Henry
The use of carbon isotopes is one of the most effective ways of monitoring, verifying and accounting (MVA) for injected CO2 as carbon forms part of the CO2 molecule itself. This study focuses on using carbon isotopes to understand CO2 dissolution, monitor CO2 plume migration, and identify the presence/absence of CO2 leakage into overlying formations and shallow subsurface at the CONSOL Energy Inc. sequestration test site located in Marshall County, West Virginia along the Pennsylvania Fork of Fish Creek. The CO2 gas is being injected, for testing both coal bed methane recovery and carbon sequestration, into the Upper Freeport coal bed at ~1200 feet depth. Ongoing CO2 injection began in 2009, and continuous geochemical environmental monitoring of shallow ground water, Fish Creek, and vadose zone gas began in 2008. In summer 2012 water and gas sampling began for carbon isotopic analysis at or near the test site; water is being sampled and tested from three groundwater monitoring wells, a few domestic groundwater supplies, and Fish Creek. Gas is being sampled and tested from the CO2 injection source gas tank, two deep coal bed methane producing wells, one deep monitoring well, and eight shallow vadose zone monitoring wells. The preliminary data indicate that the CO2 gas used in this sequestration operation has a different isotopic value compared to naturally occurring CO2 in the geologic formations. Initial data indicate that carbon isotopes can be used as an effective “natural built-in tracer” for monitoring the CO2 plume and/or its leakage into overlying shallow aquifers and subsurface.
1) The document discusses methods for determining soil calcium carbonate equivalent (CCE), including volumetric calcimetry and titrimetry.
2) Key parameters that laboratories provided for the volumetric calcimetry method include particle size and sample mass, type and volume of acid used, reaction time, and volume and composition of the calcimeter solution.
3) The document proposes a standardized method for calcimetry using a particle size of 100 mesh, sample mass of 0.5-5g, 4N HCl, 7mL acid, 20mL water, and a 10% NaCl calcimeter solution.
The document discusses the use of chemical tracers to evaluate water injection processes in Romanian oil reservoirs. It describes various types of tracer tests including inter-well tracer tests, two-well tracer tests, and single-well tracer tests. Key factors in tracer selection like detectability, toxicity, and adsorption are outlined. Examples of field tracer tests conducted in Romania are provided, demonstrating uses like identifying injected water flow paths, evaluating fault sealing properties, and assessing water shut-off treatment effectiveness. Over 50 inter-well tracer tests have been performed on 23 Romanian reservoirs to date.
Lecture notes of Environmental Engineering-II as per Solapur university syllabus of TE CIVIL.
Prepared by
Prof S S Jahagirdar,
Associate Professor,
N K Orchid college of Engg and Technology,
Solapur
The document reports on water quality test results from an environmental engineering lab that found several parameters exceeded Bangladesh standards, including color, turbidity, TDS, TSS, iron, arsenic, COD, BOD, and total coliform and fecal coliform counts. It also outlines a wastewater treatment process involving oxidation, nitrification, sedimentation, and denitrification to remove BOD and reduce sludge for effluent disposal.
Не стоит сбрасывать со счетов городские телефоны. Да, дома мы обычно разговариваем по мобильным телефонам. Но в офисе все еще правит прямой городской телефон. Тем более, если он работает с IP-телефонией.
Подробности в этой презентации и на сайте https://youmagic.pro/
The magazine covers both portray rappers in stereotypical ways to appeal to their target audiences. They use similar techniques like bold colors and images of tattooed rappers to represent the genre. However, they differ in the ethnicity and facial expressions of the rappers. The Game appears pained, implying a troubled past, while Eminem looks confident, portraying the gangster image many fans admire. Both aim to inspire audiences with rags-to-riches narratives through hard work overcoming struggles in life.
The Repoperm project studied the mechanical and hydraulic behavior of compacting crushed salt backfill at low porosities. It found that:
1) Measurement of properties like permeability and constitutive relationships for two-phase flow are possible down to gas permeabilities of 10-15 m2.
2) Presently used models have limits and material parameters depend on the specific test, so predictive capability needs improving.
3) Further research is needed to fully characterize hydro-mechanical behavior, understand permeability under unsaturated conditions, and reconcile results from different test types.
This document summarizes the RepoTREND code package and its intercomparison with PFLOTRAN for modeling radionuclide transport in a salt repository system. RepoTREND includes modules for modeling near-field processes like canister corrosion and radionuclide mobilization, as well as transport through the near field and far field. It describes initial CLAYPOS and LOPOS models run for the test case, finding generally good agreement with PFLOTRAN results except for Am-241. The LOPOS models with an additional shaft showed increased outflow for some radionuclides but the shaft acts mainly as a sorbing buffer. Suggestions are made to modify the test case for higher model output comparison
The document discusses various properties of drilling fluids including density, cation exchange capacity, filtration properties, pH, rheology, alkalinity, lubricity, and corrosivity. It defines these key terms and describes methods for measuring properties such as cation exchange capacity, pH, rheology, and corrosivity. Controlling properties like pH and alkalinity is important for drilling fluid performance and stability.
This document summarizes a 51 MLD sewage treatment plant (STP) in Hyderabad that uses C-Tech basin technology. The STP treats wastewater from specific areas to reduce BOD, COD, and TSS and protect the Musi River from pollution. It describes the STP's inlet/screening processes, C-Tech basins, chlorine contact tank, and achieves treated effluent standards. Special features include automation through a SCADA system and PLC-based intelligent control. The plant is achieving its treatment goals and helping improve water quality in the Musi River.
11.[30 39]sorption kinetics for dye removal from aqueous solution using natur...Alexander Decker
This document discusses a study on the kinetics of adsorption of Congo red dye onto natural clay. The researchers investigated how experimental variables like agitation, initial dye concentration, clay mass, and clay particle size affect the external mass transfer coefficient. They found that the mass transfer coefficient increases with agitation and clay mass/surface area, but decreases with initial dye concentration and clay particle size. The mass transfer coefficient could be correlated to these variables using the equation kf = A(variable)B. The results indicate the rate of dye removal is affected by factors that influence the mass transfer process.
This document provides an overview of petrophysics and reservoir engineering concepts. It discusses the classification of rocks including igneous, metamorphic and sedimentary rocks. It then focuses on sedimentary rocks and reservoirs, describing the depositional and diagenetic environments and properties of sandstone and carbonate reservoirs. The document also summarizes well log interpretation, shale distribution effects, porosity, fluid saturation, permeability, and other reservoir parameters. It provides definitions and methods for determining properties like relative permeability, wettability, surface tension and capillary pressure.
This document summarizes specifications and standards for water-saving closets in Japan. It provides an overview of global water usage standards for toilets, showing that Japan has led the way in setting a 5L standard. It then details Japan's changing standards over time as closets shifted to using less than 6L of water. The key requirements for water-saving closets are explained, including maintaining discharge, clean-up and transportation performance according to Japanese industrial standards. Test methods and pass criteria are described for evaluating these performance standards in Japan and other countries.
This document describes the in-situ measurement of seepage velocity and chlorobenzene degradation rates in freshwater sediment. Sediment and groundwater samples were collected and analyzed to develop a conceptual model. Pore water profiles from sediment peepers showed decreasing chlorobenzene but increasing chloride concentrations with depth, indicating chlorobenzene degradation. Quantitative analysis using an analytical transport model estimated the seepage velocity based on chloride data and chlorobenzene degradation half-life of 280-504 days based on pore water concentration profiles, consistent with literature values.
The document describes a plan to inter-compare the PFLOTRAN and RepoTREND reactive transport codes. The plan involves:
1) A batch waste form simulation to compare radionuclide release from a instantly breaching nuclear waste form.
2) A full simulation of a generic salt repository with a mined drift, shaft, and aquifer to compare breakthrough curves and dose calculations.
3) PFLOTRAN has provided first results for the batch simulation showing radionuclide source terms and cumulative release over time. The next step is setting up the full repository simulation in PFLOTRAN.
Understanding hydrodynamics in membrane bioreactor systems for wastewater tre...Nicolas Ratkovich
The document discusses modeling the hydrodynamics of a membrane bioreactor system using computational fluid dynamics (CFD) and empirical modeling. Experiments were conducted to measure shear stress and gas slug velocity in a tube under two-phase slug flow conditions. A CFD model was developed and validated against experimental data. Empirical models were also developed to correlate shear stress measurements and predict bimodal shear stress histograms. The models were then used to analyze pressure drop, energy consumption, and opportunities for optimization in the membrane bioreactor system. Finally, the structure of a PhD thesis modeling the hydrodynamics of a specific Norit airlift membrane system is outlined.
Removal of boron from aqueous solution using reverse osmosisakhilesh kushwaha
This document presents information on removing boron from water using reverse osmosis (RO). It discusses the health risks of boron in drinking water and various boron removal methods. It outlines the RO process, factors that affect it like pH, pressure and temperature. Experimental results show boron rejection increased with higher pH and pressure. The conclusion is that RO can effectively remove boron when optimizing operating conditions.
This document summarizes research on using electrodialysis and reverse osmosis to recover dissolved organic carbon from seawater. The researchers developed a process to concentrate seawater using reverse osmosis, followed by electrodialysis to remove salt, producing a desalinated sample for analysis. Over 15 experiments were conducted using seawater and brackish water samples, recovering 60-90% of dissolved organic carbon. Preliminary results found differences in the recovered high molecular weight fraction compared to previous methods. The combined process allows treatment of large volumes of seawater samples for scientific study of marine dissolved organic carbon.
Boron is a chemical element commonly found in the environment in compounds called borates. It is difficult to remove boron from seawater using reverse osmosis (RO) due to its uncharged and nonpolar nature. Multiple configurations can be used to effectively remove boron including double-pass RO systems, single-pass RO combined with ion exchange resins, and multistage RO systems sometimes incorporating ion exchange or acidification steps. The specific configuration used depends on factors like feed water chemistry and the desired permeate quality.
Using Carbon Isotopes to Monitor CO2 at the CONSOL Energy Inc. Coal Sequestr...Stephen Henry
The use of carbon isotopes is one of the most effective ways of monitoring, verifying and accounting (MVA) for injected CO2 as carbon forms part of the CO2 molecule itself. This study focuses on using carbon isotopes to understand CO2 dissolution, monitor CO2 plume migration, and identify the presence/absence of CO2 leakage into overlying formations and shallow subsurface at the CONSOL Energy Inc. sequestration test site located in Marshall County, West Virginia along the Pennsylvania Fork of Fish Creek. The CO2 gas is being injected, for testing both coal bed methane recovery and carbon sequestration, into the Upper Freeport coal bed at ~1200 feet depth. Ongoing CO2 injection began in 2009, and continuous geochemical environmental monitoring of shallow ground water, Fish Creek, and vadose zone gas began in 2008. In summer 2012 water and gas sampling began for carbon isotopic analysis at or near the test site; water is being sampled and tested from three groundwater monitoring wells, a few domestic groundwater supplies, and Fish Creek. Gas is being sampled and tested from the CO2 injection source gas tank, two deep coal bed methane producing wells, one deep monitoring well, and eight shallow vadose zone monitoring wells. The preliminary data indicate that the CO2 gas used in this sequestration operation has a different isotopic value compared to naturally occurring CO2 in the geologic formations. Initial data indicate that carbon isotopes can be used as an effective “natural built-in tracer” for monitoring the CO2 plume and/or its leakage into overlying shallow aquifers and subsurface.
1) The document discusses methods for determining soil calcium carbonate equivalent (CCE), including volumetric calcimetry and titrimetry.
2) Key parameters that laboratories provided for the volumetric calcimetry method include particle size and sample mass, type and volume of acid used, reaction time, and volume and composition of the calcimeter solution.
3) The document proposes a standardized method for calcimetry using a particle size of 100 mesh, sample mass of 0.5-5g, 4N HCl, 7mL acid, 20mL water, and a 10% NaCl calcimeter solution.
The document discusses the use of chemical tracers to evaluate water injection processes in Romanian oil reservoirs. It describes various types of tracer tests including inter-well tracer tests, two-well tracer tests, and single-well tracer tests. Key factors in tracer selection like detectability, toxicity, and adsorption are outlined. Examples of field tracer tests conducted in Romania are provided, demonstrating uses like identifying injected water flow paths, evaluating fault sealing properties, and assessing water shut-off treatment effectiveness. Over 50 inter-well tracer tests have been performed on 23 Romanian reservoirs to date.
Lecture notes of Environmental Engineering-II as per Solapur university syllabus of TE CIVIL.
Prepared by
Prof S S Jahagirdar,
Associate Professor,
N K Orchid college of Engg and Technology,
Solapur
The document reports on water quality test results from an environmental engineering lab that found several parameters exceeded Bangladesh standards, including color, turbidity, TDS, TSS, iron, arsenic, COD, BOD, and total coliform and fecal coliform counts. It also outlines a wastewater treatment process involving oxidation, nitrification, sedimentation, and denitrification to remove BOD and reduce sludge for effluent disposal.
Не стоит сбрасывать со счетов городские телефоны. Да, дома мы обычно разговариваем по мобильным телефонам. Но в офисе все еще правит прямой городской телефон. Тем более, если он работает с IP-телефонией.
Подробности в этой презентации и на сайте https://youmagic.pro/
The magazine covers both portray rappers in stereotypical ways to appeal to their target audiences. They use similar techniques like bold colors and images of tattooed rappers to represent the genre. However, they differ in the ethnicity and facial expressions of the rappers. The Game appears pained, implying a troubled past, while Eminem looks confident, portraying the gangster image many fans admire. Both aim to inspire audiences with rags-to-riches narratives through hard work overcoming struggles in life.
1) The document discusses the relationship between education and the labor market for young people in Ireland, specifically analyzing unemployment rates and transitions to employment between 2006-2011.
2) It finds that after the 2008 recession, unemployment rates significantly increased for those aged 20-24 while decreasing for 15-19 year olds who opted to stay in education. Degree holders saw increased transitions to employment compared to those with only a leaving certificate or PLC qualification.
3) The document presents economic models analyzing the costs and benefits of higher education participation, finding individuals opt into further education when marginal benefits of increased lifetime earnings outweigh costs of fees, lost wages, and living expenses.
A Decision Support System for the Design and Evaluation of Durable Wastewater...AM Publications
To develop the waste water solutions challenging task. To design sustainable wastewater solution requires information about new ideas, new systems and latest technology. Generally it is assumed that, decision making needs to involve field experts and engineers to define values and brainstorms solution. This paper describes a decision support system model that is designed to help community planners to identify the solution which balance the environmental, economic and social needs. System will be scalable, adaptable and flexible. Our decision support system will take modular description of components and description of community constraints, suggest the design of alternative waste water system, and facilitates evaluating how well each design satisfies the given constraints. Decision support system will give alternatives with visualization of the effect of various trade-offs and their effect in the relation of the community’s goals.
Los animales del bosque se levantaron temprano emocionados porque era el día de la gran carrera de zapatillas que tendría lugar junto al lago, a la que todos se reunieron a las nueve en punto.
Los anti-VEGF se usan en retinopatía diabética más allá del edema macular, incluyendo: 1) retinopatía diabética proliferativa, 2) hemorragia vítrea densa, 3) previo a cirugía vitreoretinal para facilitarla, y 4) post cirugía vitreoretinal para tratar hemorragia vítrea posterior a la cirugía. Los anti-VEGF pueden mejorar los resultados quirúrgicos y reducir las recidivas de hemorragia vítrea.
Edward Anderson - A View from the Outside_ Covert Autobiography in the Social...Edward Anderson
This document discusses Bayard Rustin's social commentaries and how they can be considered a form of covert autobiography. While Rustin's writings were intended as historical analyses and social commentaries, they provide insights into Rustin's influences and values through his objective tone and focus on community over self. The document examines how Rustin's works adhere to some conventions of autobiography through their treatment of his influences and perspective, though in a more indirect, externalized manner than traditional autobiographies like Rousseau's Confessions. It explores how Rustin's focus on truth and community align with aspects of Rousseau's model of autobiography in revealing truths about the author's identity and character.
Agile is a group of software development methodologies based on iterative development and collaboration between cross-functional teams. It emphasizes continuous delivery, welcoming changing requirements, early testing, and customer collaboration. The Scrum framework is one of the main Agile methodologies. It is based on sprints, daily stand-ups, and emphasizes an empirical process control through inspection and adaptation. The Scrum framework aims to be highly flexible and lightweight.
The document provides tips for improving internet security. It recommends doing things like using strong passwords that are at least 12 characters long and include symbols, changing passwords every 30 days, backing up important data regularly, updating software and operating systems, and logging out of accounts when finished. It also recommends not doing things like writing down passwords, opening attachments from unknown senders, or giving personal information to strangers.
Presentation given by Auli Niemi of Uppsala University on "Quantification of Saline Aquifers for Geological Storage of CO2 – Experiences from MUSTANG Project" at the EC FP7 Projects: Leading the way in CCS implementation event, London, 14-15 April 2014
GEOTECHNICAL INTERPRETATION OF SOIL FOR PROPOSED UTILITY TUNNEL FROM KURIL TO...Johana Sharmin
This presentation was prepared for our published paper in IASTEM publications. And this paper was based on research in geotechnical perspective for feasibility study in proposed utility tunnel from Kuril to Malibagh in Dhaka city.
The significance of Surface Logging For The Formation Evaluation Advance Surf...Evangelos Siskos
The significance of Surface Logging For The Formation Evaluation Advance Surface Logging Technology is a Master of Science Thesis presentation for the MSc in Oil & Gas Technology program at Eastern Macedonia and thrace Institute of Technology.
Shale Gas | SPE YP Egypt Educational WeekAhmed Omar
This presentation is a result of intensive search about unconventional shale gas resources. These slides was presented at SPE Egyptian section educational week.
Authors :
Karim Magdy, Suez University, karim_magdy5298@yahoo.com
Karim Mohamed Kamel, The British University in Egypt, kareem.kaml@gmail.com
Ahmed Omar Eissa, Suez University, ahmedomar92@yahoo.com
Ahmed Alhassany, Al-Azhar University, Al7assany@gmail.com
Yunus Ashour, Alazhar University Eng.yunusashour@Gmail.com
Mahmoud Elwan, Cairo University, elwan_92@hotmail.com
Mahmoud Abbas , Suez university mahmoudabbas15@gmail.com
Khaled Elnagar, Suez University
KhElnagar@outlook.com
Presentation given by Auli Niemi of Uppsala University on "PANACEA & TRUST Projects Status update" at the EC FP7 Projects: Leading the way in CCS implementation event, London, 14-15 April 2014
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The document provides information about surface preparation methods for painting inspection at Grade 2/3, including:
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Similar to Barber_GSA_2014_Vacuum Saturation v3 (20)
1. Applying Vacuum Saturation to Study The
Pore Structure of Tight Shales
Troy J. Barber and Q.H. Hu
2014 GSA Annual Meeting
Vancouver, British Columbia
October 21, 2014
2. Outline
I. Tight gas production decline and fracture-
matrix interaction
II. Pore topology and macro scale fluid
migration
III. Vacuum saturation: how we use it
IV. Mapping edge-accessible pores
V. Preliminary Results
VI. Summary and Looking forward
3. Recovery factor of 5‒10% for tight oil (Hoffman, 2012; SPE 154329)
Problem: Steep production decline in tight shale gas
Chong et al., 2010,
SPE-133874
Refrac rebound
???
Slow matrix
diffusion
5. LA ICP-MS
Multiple approaches to pore characterization
Nitrogen sorption
Imbibition Tests
Traced vacuum saturation
• Fluid (API brine; n-decane) and tracer imbibition tests
• Edge-accessible porosity after traced vacuum
saturation
• Liquid and gas diffusion tests
• Mercury intrusion porosimetry and hysteresis
• N2 adsorption isotherm and hysteresis
• Ar ion milling, FE-SEM, and TEM
• 2-D/3-D tracer mapping using Laser Ablation-ICP-MS
• Small-Angle Neutron Scattering (LANL; ORNL; NIST)
Today’s talk will focus
on these two methods
6. T
What is traced vacuum saturation?
FLUID (water, brine, n-decane)
CO2
TO VACUUM
CO2
T
T T
T
T
T
T
T
T
T
T
CO2 highly soluble in water
Several cycles over 6-12hr
removes air
After ~1 hr, vacuum in
connected space =
(0.01/743)Torr = 99.999%
Evacuation Duration:
12-24 hr
API Brine - water wetting
ReO4- (nonsorbing)
Cs+, Co2+, Ce+,
Eu3+
n-decane – oil wetting
Re (nonsorbing)
I-
Different fluids to see
effect of wettability.
Sorbing and nonsorbing
tracers.
After saturation, apply CO2
pressure to liquid surface
12-24 hr.
T
T
T
T
T
7. • Large volumes
• Prone to leaks,
99.91% vacuum
• No flushing or
positive pressure
capability
Our previous apparatus
8. Our current apparatus
Smaller chamber = less waste
99.99% vacuum
Mechanically
sealed, allowing
CO2
flushing/positive
pressure
Sample holder for
easy organization
11. 2D Interior cross section
9.5 mm
Saturation Saturation
Epoxied Sides
100um spot size
500um spacing
~ 2 order of magnitude drop within 500um
from sample edge.
12.
13. Summary and Looking Forward
• Steep 1st year decline and low overall
hydrocarbon production observed in
hydraulically-fractured shales.
• Investigating pore structure in natural
rock requires several complimentary
approaches.
• Traced vacuum saturation paired with
LA-ICP-MS is effective at characterizing
the edge-accessible pores.
• Results indicate low pore connectivity
in shales, which reduces gas diffusion
from matrix to stimulated fractured
network – driving steep production
decline
What’s next?
• Elevated pressure saturation
• Comparing samples of different
mineralogy, maturation, TOC, bedding
orientation, wettability, etc.
• SANS/USANS
o Inaccessible pores
o In-situ P-T conditions
o Pore structure and flow dynamics
My name is Troy Barber. I am an undergraduate at the University of Texas at Arlington. In my lab we characterize pore structure and fluid flow in porous media. Today I am going to talk to you about using vacuum saturation to study pore structure in tight shales.
1) Here are some typical tight shale gas production decline curves. These are from the Barnett Shale in Texas. The blue curve is averaged from horizontal wells completed between 00-04. The red curve from 05-09. Despite the jump in productivity from 2000 to 2005 (which probably results from improving technology and techniques in unconventional), the declines are similar and quite steep, roughly 60% after the first year. 2) And of course one solution is to refracture a well, which results in a rebound in production. But, again, always followed with the steep decline curve typical to unconventional. For the most part, production decline seems to be play independent, with the Barnett, Marcellus, Woodford, Utica, etc. all exhibiting first year declines between ~55-75%. So we know that outside of just refracking a well, technology hasn’t been able to overcome this phenomenon. 3) We also know that despite heterogeneity between plays, the phenomenon is common to pretty much all tight shale gas production. 4) So the million dollar question here is what controls this slow production and can we develop a physics based model to predict it. 5) CLICK Now we know that flow in the fracture network, which is typical Darcian flow, is not the rate limiting characteristic here, 6) CLICK so it appears that the bottleneck is communication between the fracture network and the matrix pore network. So there are a number of factors that are probably contributing to this anomalous matrix diffusion: molecular dynamics, P-T conditions, pore grain composition, multiphase fluid flow and pore structure.
1) In our lab, one of the aspects we focus on is pore structure, in particular pore topology, or connectivity, a largely overlooked aspect of pore structure. 2) CLICK In a porous medium, total porosity can be separated into connected and isolated porosity, which in turn can be split into edge accessible pores and what is known as an infinite cluster, wherein a cluster of connected pores is large enough to extend entirely from one end of the system to the other.
(CLICK) Evacuate and flush several times with CO2 over the course of half a day to remove air. Then we evacuate the sample for at least 24 hours at 0.01 Torr = 99.999% vacuum before. . .
(CLICK) . . . introducing the saturating fluid. For pore distribution mapping we use both oil wetting and water wetting fluids containing sorbing and non-sorbing tracers.
(CLICK) After the fluid has been introduced, the system is subjected to positive pressure for 12-24 hrs. Admittedly, we can currently only reach 60 psi, because the pressure gauge we are using is only rated that high, but we should be able to reach upwards of 15 bar with the current chamber and hope to reach higher pressures with an improved chamber design. By flash freezing, and then freeze drying the saturated samples, the fluid is removed, and the tracers remain in the edge accessible pores.
This is our previous setup
Very large volume chamber, requiring large volumes of saturating fluid and precarious sample organization
System used plastic tubing and was prone to leaks, decreasing the vacuum efficiency.
Lacked the capability to flush with CO2 or apply positive pressure, which was something we wanted to do.
Now I knew nothing about vacuum systems or vacuum saturation when I was given this task, but I had taken some engineering courses and so I did a little research and got to work. It took a couple of iterations, including one ultimately dangerous prototype, but this is what I ended up with. (CLICK)
(CLICK) - The new design has a smaller sample chamber, so we don’t end up wasting as much fluid.
(CLICK) - By replacing most of the plastic tubing with stainless steel, replacing many of the fittings and redesigning the sample chamber, I was able to increase the vacuum efficiency to 99.999%.
(CLICK) - I constructed an easy to use sample holder capable of accommodating up to 64 cubic cm samples.
(CLICK) - By mechanically sealing the chamber lid, I was able to add the ability to flush the system with and apply positive pressure using CO2.
(CLICK)
We then analyze these samples using laser ablation paired with ICP-MS (inductively coupled plasma – mass spectrometry) in order to map the tracer (and hence the pore) distribution in 2 and 3D. Here is our LA ICP-MS setup. We have a UP-213 Nd:YAG laser ablation system, which ablates the sample in craters as small as 4um diameter. We use He as a transport gas to carry the aerosol to our Perkin Elmer ELAN DRC II ICP-MS. We use a constant input of liquid internal standard as well as periodic sampling of NIST glass and USGS rock solid standards for instrument calibration. (CLICK) The laser software allows for generating preset ablation grids, and by calibrating the depth of penetration as a function of laser pulse intensity (Point out the Depth/pulse X-section), we can generate a stackable series of 2 dimensional elemental distribution maps.
(CLICK)
Saturating surface grid
100um spot size
2x2mm grid
4 scans of increasing penetration depth corresponding to 2, 12, 54, and 224 um
ReO4- (nonsorbing tracer) vs Rb (intrinsic element).
(CLICK)
Tracer concentration falls off by 2 orders of magnitude within 225 um from the saturating edge.
Again, by plotting concentration vs distance from the edge, we see that the results agree with our percolation model. (DO THEY?)
(CLICK)
Then we cut the sample parallel to the saturation direction and analyze the interior face, to look at penetration from sample edge in 2 dimensions.
Point out epoxied sides, saturation direction, spot size, resolution
Wall effect between epoxy and sample.
1) This concept of the infinite cluster is based on percolation theory, a mathematical tool which can be used to model the behavior of randomly connected systems. Percolation theory says that for a randomly connected finite lattice of nodes or, in our case, pores, if the probability that any one node is connected to a neighbor exceeds what is known as the percolation threshold, then an infinite cluster is expected to exist between opposite boundaries of the lattice. Previous studies in our lab have confirmed that percolation theory is an effective way to model pore connectivity and its affect on anomalous diffusion in tight geologic media. 2) For example, percolation theory predicts that for a system with connectivity far enough above the percolation threshold, classical Darcian flow and Fickian transport can occur. We have performed spontaneous imbibition experiments, wherein a porous sample is placed in contact with a liquid surface and allowed to imbibe the fluid through capillary pressure. Percolation theory predicts that if a log-log plot of mass imbibed vs time is generated, a medium with a high connectivity probability will yield a slope of 1/2, whereas for a medium very near the percolation threshold a slope of ~1/4 will result. 3) CLICK So here we have two such plots, one for a sample of Berea Sandstone and the other for a sample of Barnett Shale. The sandstone ( a well connected rock) exhibits an imbibition slope of 0.495 and the shale (which we hypothesize to be poorly connected) yields a slope of 0.262, as predicted for a rock of low connectivity by percolation theory. 4) For replicate tests of four other Barnett shale samples the resulting slope is always ~1/4. 5) But this test alone doesn’t tell us anything about the accessible pore distribution, which in samples of low pore connectivity decreases with distance from the sample edge – which is where vacuum saturation comes in handy. (CLICK)