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 Electromeric Effect is a temporary effect.
 It is observed only in those organic compounds which having multiple
bonds (double bond or triple bond).
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 It is the movement of shared pair of pi-electrons from one atom to other
atom, when it is attacked by reagent.
 The atom to which the electron is completely transferred becomes
negatively charged and the other atom becomes positively charged.
 As the reagent is removed, then the compound comes into its original state.
Here, B is more electronegative than
A
A B A+ B-
Electrophilic Reagent
Reagent Removal
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Positive electromeric effect –
If the attacking species is an electrophile, then pi- electrons are transferred
towards the positively charged atom.
All the alkyl groups have positive electromeric effect.
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Negative electromeric effect –
If the attacking species is an nucleophile, then pi- electrons are transferred
away from attacking reagent.
All the unsaturated groups have negative electromeric effect.
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Thank you
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Electromeric effect

  • 1. Follow me on - Shaivikchemistryclasses.blogspot.com
  • 2.  Electromeric Effect is a temporary effect.  It is observed only in those organic compounds which having multiple bonds (double bond or triple bond). Follow me on - Shaivikchemistryclasses.blogspot.com
  • 3.  It is the movement of shared pair of pi-electrons from one atom to other atom, when it is attacked by reagent.  The atom to which the electron is completely transferred becomes negatively charged and the other atom becomes positively charged.  As the reagent is removed, then the compound comes into its original state. Here, B is more electronegative than A A B A+ B- Electrophilic Reagent Reagent Removal Follow me on - Shaivikchemistryclasses.blogspot.com
  • 4. Positive electromeric effect – If the attacking species is an electrophile, then pi- electrons are transferred towards the positively charged atom. All the alkyl groups have positive electromeric effect. Follow me on - Shaivikchemistryclasses.blogspot.com
  • 5. Negative electromeric effect – If the attacking species is an nucleophile, then pi- electrons are transferred away from attacking reagent. All the unsaturated groups have negative electromeric effect. Follow me on - Shaivikchemistryclasses.blogspot.com
  • 6. Thank you Follow me on – https://shaivikchemistryclasses.blogspot. com/