2. POLLUTION OF GROUNDWATERPOLLUTION OF GROUNDWATER
About half of U.S. population and 95% inAbout half of U.S. population and 95% in
rural areas use groundwater for drinkingrural areas use groundwater for drinking
Groundwater can be contaminated withGroundwater can be contaminated with
fertilizers, pesticides, gasoline, oil, organicfertilizers, pesticides, gasoline, oil, organic
solvents, paint thinner, chemicals fromsolvents, paint thinner, chemicals from
fracking, etc. – anything put on or in groundfracking, etc. – anything put on or in ground
Cannot be effectively cleansed and hard toCannot be effectively cleansed and hard to
dilute and disperse pollutantsdilute and disperse pollutants
3. Fig. 21-7, p. 501
Coal strip
mine runoff
Polluted air
Deicing
road salt
Pesticides
and fertilizers
Hazardous
waste
injection
well
Pumping
well
Gasoline station
Water
pumping well
Landfill
Sewer
Buried gasoline
and solvent tanks
Cesspool,
septic tank
Groundwater
flow
Confined
aquifer
Confined freshwater aquifer
Unconfined freshwater aquifer
Accidental
spills
Waste lagoon
Leakage
from
faulty
casing
Discharge
4. POLLUTION OF GROUNDWATERPOLLUTION OF GROUNDWATER
Pollutants enter aquifer, formPollutants enter aquifer, form plumeplume ofof
contaminated water can get into drinking andcontaminated water can get into drinking and
irrigation waterirrigation water
Degradable wastesDegradable wastes – takes hundreds to– takes hundreds to
thousands of years to cleansethousands of years to cleanse
Nondegradable wastesNondegradable wastes – (ex: toxic lead,– (ex: toxic lead,
arsenic, flouride) are there permanentlyarsenic, flouride) are there permanently
Slowly degradable wastesSlowly degradable wastes – (ex: DDT) are– (ex: DDT) are
there for decadesthere for decades
5. Fig. 21-8, p. 502
Aquifer
Water well
Migrating
vapor phase
Contaminant plume moves
with the groundwater
Free gasoline
dissolves in
groundwater
(dissolved
phase)
Groundwater
flow
Water
table
Gasoline
leakage plume
(liquid phase)
Leaking
tank
Bedrock
6. POLLUTION OF GROUNDWATERPOLLUTION OF GROUNDWATER
Leaks from a number of sources haveLeaks from a number of sources have
contaminated groundwater in parts of thecontaminated groundwater in parts of the
world – not well studied, expensiveworld – not well studied, expensive
Industrial waste stored in lagoons/ponds withoutIndustrial waste stored in lagoons/ponds without
linersliners
Liquid hazardous waste injected into ground –Liquid hazardous waste injected into ground –
may leak into aquifersmay leak into aquifers
EPA: one or more organic chemicals contaminateEPA: one or more organic chemicals contaminate
45% of municipal groundwater supplies45% of municipal groundwater supplies
By 2008, EPA cleaned up of 357,000 of 479,000By 2008, EPA cleaned up of 357,000 of 479,000
underground tanks leaking gasoline, diesel fuel,underground tanks leaking gasoline, diesel fuel,
home heating oil or toxic solventshome heating oil or toxic solvents
7. POLLUTION OF GROUNDWATERPOLLUTION OF GROUNDWATER
MTBEMTBE – methyl tertiary butyl ether – gasoline– methyl tertiary butyl ether – gasoline
additive since 1979 – suspected carcinogenadditive since 1979 – suspected carcinogen
since 1990since 1990
250,000 gas tanks leaked MTBE and250,000 gas tanks leaked MTBE and
contaminated aquiferscontaminated aquifers
Being phased out, but will contaminate wells forBeing phased out, but will contaminate wells for
decadesdecades
9. POLLUTION OF GROUNDWATERPOLLUTION OF GROUNDWATER
NitratesNitrates – NO– NO33
--
– especially a problem in– especially a problem in
agricultural areas from fertilizersagricultural areas from fertilizers
Can be converted to carcinogenic compoundsCan be converted to carcinogenic compounds
““Blue baby syndrome” blood lacks ability to carryBlue baby syndrome” blood lacks ability to carry
sufficient oxygensufficient oxygen
10. Case Study: Arsenic in Groundwater -Case Study: Arsenic in Groundwater -
a Natural Threata Natural Threat
Toxic Arsenic (Toxic Arsenic (AsAs) can occur naturally at high) can occur naturally at high
levels in soil and rockslevels in soil and rocks
Drilling into aquifers can releaseDrilling into aquifers can release AsAs intointo
drinking water suppliesdrinking water supplies
WHO: > 112 million people drinking waterWHO: > 112 million people drinking water
withwith AsAs levels 5-100X the 10 ppb standardlevels 5-100X the 10 ppb standard
Mostly in Bangladesh, China and West Bengal,Mostly in Bangladesh, China and West Bengal,
IndiaIndia
Figure 21.7
Natural capital degradation: principal sources of groundwater contamination in the United States. Another source is saltwater intrusion from excessive groundwater withdrawal (Figure 14-12, p. 315) (Figure is not drawn to scale.)
Figure 21.8
Natural capital degradation: groundwater contamination from a leaking gasoline tank. As the contaminated water spreads from its source in a widening plume, it can be extracted by wells used to provide water for drinking and irrigation.