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Covalent bonding

          Sharing outside electrons




PES '07            Ellesmere College
Remember.

      How many atoms in the following:-
         Sulphuric acid     H2SO4

                    2 Hydrogen      1 Sulphur   4 Oxygen

          7 atoms; 3 different elements.

  Sodium hydrogen carbonate NaHCO3

          6 atoms; 4 different elements
PES '07         Ellesmere College
If both elements in a compound are
            non-metals
   Neither of them need to lose electrons.

   Both of them need to gain electrons.

   To fill both outer shells they must share.



PES '07          Ellesmere College
Hydrogen - 1H

Electronic structure 1 – each H needs 1 more


             HH             HH



Forming H2 molecules allows each Hydrogen
 atom to have a share of a full outside shell
PES '07        Ellesmere College
Hydrogen formulae
 The displayed formula of Hydrogen shows
    the pair of electrons as a single bond.


                 H
                     H-H     H

The molecular formula just counts the atoms
                  present

                       H2
PES '07       Ellesmere College
Chlorine Cl2

Electronic structure 2.8.7 – each needs 1 more




 Forming Cl2 molecules allows each Chlorine
  atom to have a share of a full outside shell
 PES '07        Ellesmere College
Chlorine
Displayed formula                Cl-Cl

Molecular formula                Cl2




PES '07      Ellesmere College
Methane – CH4
              6C  (2.4)          1H  (1)

          Carbon needs 4 more electrons.
          

       Each Hydrogen needs 1 more electron
H                          H

H
                                       H
              H           C
H


H
                           H
PES '07            Ellesmere College
Methane
                                          H
Displayed                  H
                                        H-C-H
Formula
                                    H
                                          H
            H            C


Molecular                 H
                                        CH4
Formula
PES '07         Ellesmere College
Water - H2O
        8O  (2.6)                        1   H  (1)
            Oxygen needs to 2 more electrons
        Each hydrogen needs 1 more electron
    H
                              O
                                          H
   H              H


Each Hydrogen has a share of 2 electrons; the Oxygen
                 has a share of 8
  PES '07             Ellesmere College
Water
Displayed                                O
Formula                                 H H
                         O
                                    H
            H

Molecular
                                        H2O
Formula

PES '07         Ellesmere College
Oxygen

               O  (2.6)8

Both Oxygen atoms need to 2 more electrons



                 O          O            O   O


          Both oxygen share an outer shell of 8.
      2 pairs of electrons are shared – a double bond.
PES '07              Ellesmere College
Oxygen

Displayed
Formula                             O=O
               O
                                O



Molecular
Formula
                                    O2
PES '07     Ellesmere College
Carbon dioxide – CO2
6C  (2.4)       Carbon needs 4 more electrons
8O  (2.6)       Each Oxygen needs 2 more electrons


       O                                 O
                               C
                    O

       O
All atoms have a share of 8 electrons in their outer shell.
              Two double bonds          O=C=O
    PES '07         Ellesmere College
Carbon Dioxide
Displayed
                                  O=C=O
Formula

              O              C     O


Molecular
Formula
                                       CO2
PES '07       Ellesmere College
Consequences of Covalent
                 bonding.

    There are no charged particles to move
                     about.
      So covalent compounds are poor
                  conductors.
     Molecules form that are only weakly
            attracted to each other.
      So boiling/melting points are low.

PES '07         Ellesmere College
Periodic Table
                  Elements in a group (column) share similar
                chemical properties because they have similar
                             electronic structures
              Group 1                                        0
                   Group 2          Group 3        4 5 6 7
Period 1
Period 2
Period 3
    etc
Elements in
a row are
not similar


   PES '07             Ellesmere College
Group 1
Each element
   has the 1
electron in the
  outer shell.


  So group 1
elements react
in similar ways
Each group 0
Group 0     element has a
            full outer shell.
          So every element
              has similar
              properties.

           Because each
           outer shell is full
            with different
           numbers we say
            the next shell
           has 0 electrons
Period 3




Elements in period 3 have some electrons in the
      first 3 shells and none in the fourth
Period 2




Each element has electrons in the first 2 shells.
Some need to gain electrons, some need to lose
  electrons. Neon already has a full outer shell.
            They behave differently

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Covalent bonding

  • 1. Covalent bonding Sharing outside electrons PES '07 Ellesmere College
  • 2. Remember. How many atoms in the following:- Sulphuric acid H2SO4 2 Hydrogen 1 Sulphur 4 Oxygen 7 atoms; 3 different elements. Sodium hydrogen carbonate NaHCO3 6 atoms; 4 different elements PES '07 Ellesmere College
  • 3. If both elements in a compound are non-metals  Neither of them need to lose electrons.  Both of them need to gain electrons.  To fill both outer shells they must share. PES '07 Ellesmere College
  • 4. Hydrogen - 1H Electronic structure 1 – each H needs 1 more HH HH Forming H2 molecules allows each Hydrogen atom to have a share of a full outside shell PES '07 Ellesmere College
  • 5. Hydrogen formulae The displayed formula of Hydrogen shows the pair of electrons as a single bond. H H-H H The molecular formula just counts the atoms present H2 PES '07 Ellesmere College
  • 6. Chlorine Cl2 Electronic structure 2.8.7 – each needs 1 more Forming Cl2 molecules allows each Chlorine atom to have a share of a full outside shell PES '07 Ellesmere College
  • 7. Chlorine Displayed formula Cl-Cl Molecular formula Cl2 PES '07 Ellesmere College
  • 8. Methane – CH4 6C  (2.4) 1H  (1) Carbon needs 4 more electrons.   Each Hydrogen needs 1 more electron H H H H H C H H H PES '07 Ellesmere College
  • 9. Methane H Displayed H H-C-H Formula H H H C Molecular H CH4 Formula PES '07 Ellesmere College
  • 10. Water - H2O 8O  (2.6) 1 H  (1) Oxygen needs to 2 more electrons Each hydrogen needs 1 more electron H O H H H Each Hydrogen has a share of 2 electrons; the Oxygen has a share of 8 PES '07 Ellesmere College
  • 11. Water Displayed O Formula H H O H H Molecular H2O Formula PES '07 Ellesmere College
  • 12. Oxygen O  (2.6)8 Both Oxygen atoms need to 2 more electrons O O O O Both oxygen share an outer shell of 8. 2 pairs of electrons are shared – a double bond. PES '07 Ellesmere College
  • 13. Oxygen Displayed Formula O=O O O Molecular Formula O2 PES '07 Ellesmere College
  • 14. Carbon dioxide – CO2 6C  (2.4) Carbon needs 4 more electrons 8O  (2.6) Each Oxygen needs 2 more electrons O O C O O All atoms have a share of 8 electrons in their outer shell. Two double bonds O=C=O PES '07 Ellesmere College
  • 15. Carbon Dioxide Displayed O=C=O Formula O C O Molecular Formula CO2 PES '07 Ellesmere College
  • 16. Consequences of Covalent bonding. There are no charged particles to move about. So covalent compounds are poor conductors. Molecules form that are only weakly attracted to each other. So boiling/melting points are low. PES '07 Ellesmere College
  • 17. Periodic Table Elements in a group (column) share similar chemical properties because they have similar electronic structures Group 1 0 Group 2 Group 3 4 5 6 7 Period 1 Period 2 Period 3 etc Elements in a row are not similar PES '07 Ellesmere College
  • 18. Group 1 Each element has the 1 electron in the outer shell. So group 1 elements react in similar ways
  • 19. Each group 0 Group 0 element has a full outer shell. So every element has similar properties. Because each outer shell is full with different numbers we say the next shell has 0 electrons
  • 20. Period 3 Elements in period 3 have some electrons in the first 3 shells and none in the fourth
  • 21. Period 2 Each element has electrons in the first 2 shells. Some need to gain electrons, some need to lose electrons. Neon already has a full outer shell. They behave differently