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Atoms and Elements


Isotopes and Atomic Mass




        24Mg   25Mg   26Mg
        12     12     12


                             1
Isotopes

Isotopes
 Are atoms of the same element that have different
  mass numbers.
 Have the same number of protons, but different
  numbers of neutrons.




                                                      2
Nuclear Symbol

A nuclear symbol
 Represents a particular atom of an element.
 Gives the mass number in the upper left corner and
  the atomic number in the lower left corner.
   Example: An atom of sodium with atomic number
  11 and a mass number 23 has the following atomic
  symbol:
      mass number         23 Na

      atomic number       11


                                                       3
Nuclear Symbols
For an atom, the nuclear symbol gives the number of
 Protons (p+)
 Neutrons (n)
 Electrons (e-)
    16             31                  65
     O                  P                   Zn
     8             15                  30



     8 p+          15 p+               30 p+
     8n            16 n                35 n
     8 e-          15 e-               30 e-
                                                      4
Learning Check

Naturally occurring carbon consists of three isotopes,
12C, 13C, and 14C. State the number of protons,

neutrons, and electrons in each of the following.
            12C          13C          14C
             6           6             6

protons    ______     ______         ______
neutrons   ______     ______         ______
electrons ______      ______         ______



                                                         5
Solution
            12C   13C    14C
            6     6      6

protons    6 p+   6 p+   6 p+
neutrons   6n     7n     8n
electrons 6 e-    6 e-   6 e-




                                6
Learning Check

Write the nuclear symbols for atoms with the
following subatomic particles:
A. 8 p+, 8n, 8e-        ___________

B. 17p+, 20n, 17e-      ___________


C. 47p+, 60 n, 47 e-    ___________



                                               7
Solution

                      16O

A. 8p+, 8n, 8e-        8



B. 17p+, 20 n, 17e-   37Cl
                      17

C. 47p+, 60n, 47e-    107Ag
                      47




                              8
Learning Check

1. Which of the following pairs are isotopes of the
   same element?
2. In which of the following pairs do both atoms have
   8 neutrons?
A. 15X       15X
     8        7

B.   12X     14X
     6        6



C.   15X      16X
      7        8                                        9
Solution

B.   12X       14X

      6         6

     Both nuclear symbols represent isotopes of carbon
     with six protons each, but one has 6 neutrons and the
     other has 8.

C.    15X       16X

      7          8

     An atom of nitrogen (7) and an atom of oxygen (8)
     each have 8 neutrons.
                                                         10
Isotopes of Magnesium
In naturally occurring magnesium,
there are three isotopes.
                        Isotopes of Mg




Atomic Mass           23.99     24.98 25.98
% abundance           78.70 10.13 11.17



Copyright © 2007 by Pearson Education, Inc.
                                              24Mg   25Mg   26Mg
Publishing as Benjamin Cummings               12     12     12

                                                                   11
Isotopes of Sulfur

A sample of naturally
occurring sulfur contains
several isotopes with the
following abundances
Isotope % abundance
32S           95.02
33S            0.75         32S, 33S, 34S, 36S

34S                         16   16   16   16
               4.21
36S            0.02

                                                 12
Atomic Mass

The atomic mass of an element
 Is listed below the symbol of each
                                            Na
  element on the periodic table.
                                           22.99
 Gives the mass of an “average” atom of
  each element compared to 12C.
 Is not the same as the mass number.




                                                   13
Some Elements and Their Atomic
Mass
Most elements have two or more isotopes that
contribute to the atomic mass of that element.

TABLE 2.9




                                 32.07 amu




                                                 14
Atomic Mass for Cl
The atomic mass of chlorine is
 Based on all naturally
  occurring Cl isotopes.
 Not a whole number.
 The weighted average
  of 35Cl and 37Cl.




                                 Copyright © 2007 by Pearson Education, Inc. 15
                                 Publishing as Benjamin Cummings
Learning Check

Using the periodic table, give the atomic mass of
each element:
A. calcium          __________
B. aluminum         __________
C. lead             __________
D. barium           __________
E. iron             __________



                                                    16
Solution

Using the periodic table, give the atomic mass of
each element:
A. calcium          40.08 amu
B. aluminum         26.98 amu
C. lead             207.2 amu
D. barium           137.3 amu
E. iron             55.85 amu



                                                    17
The End


Thanking You

                18

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Atoms and elements by deepika

  • 1. Atoms and Elements Isotopes and Atomic Mass 24Mg 25Mg 26Mg 12 12 12 1
  • 2. Isotopes Isotopes  Are atoms of the same element that have different mass numbers.  Have the same number of protons, but different numbers of neutrons. 2
  • 3. Nuclear Symbol A nuclear symbol  Represents a particular atom of an element.  Gives the mass number in the upper left corner and the atomic number in the lower left corner. Example: An atom of sodium with atomic number 11 and a mass number 23 has the following atomic symbol: mass number 23 Na atomic number 11 3
  • 4. Nuclear Symbols For an atom, the nuclear symbol gives the number of  Protons (p+)  Neutrons (n)  Electrons (e-) 16 31 65 O P Zn 8 15 30 8 p+ 15 p+ 30 p+ 8n 16 n 35 n 8 e- 15 e- 30 e- 4
  • 5. Learning Check Naturally occurring carbon consists of three isotopes, 12C, 13C, and 14C. State the number of protons, neutrons, and electrons in each of the following. 12C 13C 14C 6 6 6 protons ______ ______ ______ neutrons ______ ______ ______ electrons ______ ______ ______ 5
  • 6. Solution 12C 13C 14C 6 6 6 protons 6 p+ 6 p+ 6 p+ neutrons 6n 7n 8n electrons 6 e- 6 e- 6 e- 6
  • 7. Learning Check Write the nuclear symbols for atoms with the following subatomic particles: A. 8 p+, 8n, 8e- ___________ B. 17p+, 20n, 17e- ___________ C. 47p+, 60 n, 47 e- ___________ 7
  • 8. Solution 16O A. 8p+, 8n, 8e- 8 B. 17p+, 20 n, 17e- 37Cl 17 C. 47p+, 60n, 47e- 107Ag 47 8
  • 9. Learning Check 1. Which of the following pairs are isotopes of the same element? 2. In which of the following pairs do both atoms have 8 neutrons? A. 15X 15X 8 7 B. 12X 14X 6 6 C. 15X 16X 7 8 9
  • 10. Solution B. 12X 14X 6 6 Both nuclear symbols represent isotopes of carbon with six protons each, but one has 6 neutrons and the other has 8. C. 15X 16X 7 8 An atom of nitrogen (7) and an atom of oxygen (8) each have 8 neutrons. 10
  • 11. Isotopes of Magnesium In naturally occurring magnesium, there are three isotopes. Isotopes of Mg Atomic Mass 23.99 24.98 25.98 % abundance 78.70 10.13 11.17 Copyright © 2007 by Pearson Education, Inc. 24Mg 25Mg 26Mg Publishing as Benjamin Cummings 12 12 12 11
  • 12. Isotopes of Sulfur A sample of naturally occurring sulfur contains several isotopes with the following abundances Isotope % abundance 32S 95.02 33S 0.75 32S, 33S, 34S, 36S 34S 16 16 16 16 4.21 36S 0.02 12
  • 13. Atomic Mass The atomic mass of an element  Is listed below the symbol of each Na element on the periodic table. 22.99  Gives the mass of an “average” atom of each element compared to 12C.  Is not the same as the mass number. 13
  • 14. Some Elements and Their Atomic Mass Most elements have two or more isotopes that contribute to the atomic mass of that element. TABLE 2.9 32.07 amu 14
  • 15. Atomic Mass for Cl The atomic mass of chlorine is  Based on all naturally occurring Cl isotopes.  Not a whole number.  The weighted average of 35Cl and 37Cl. Copyright © 2007 by Pearson Education, Inc. 15 Publishing as Benjamin Cummings
  • 16. Learning Check Using the periodic table, give the atomic mass of each element: A. calcium __________ B. aluminum __________ C. lead __________ D. barium __________ E. iron __________ 16
  • 17. Solution Using the periodic table, give the atomic mass of each element: A. calcium 40.08 amu B. aluminum 26.98 amu C. lead 207.2 amu D. barium 137.3 amu E. iron 55.85 amu 17