Relative viscosity Specific viscosity and so on....

1. VISCOSITY MEASUREMENT
Ubbelohde Viscometer, for measuring
viscocity of dilute solution
upper and lower level
(measure the flow time t, of
solution, drop from upper level
to lower level)
h = krt
k = viscometer constant
r = density of solution
t = flow time
If, t = time for solution
to = time for solvent
r = ro dilute solution
ro = solvent density

2. Dilute Solution Viscosity Designationsa
Common name IUPAC name Definition
= = t
h
h h
rel t
o o
t t
-
= rel
= - 1
-
=
o
o
h h
o
o
sp t
h
h
h
h h
sp rel
C C
red
-1
= =
h
C
rel
inh
h
h ln =
ö
æ
=
sp h
0 ) ( ] [ = = ÷ ÷ø
ç çè
=
C
C inh
c o
h
h
Relative viscosity Viscosity ratio
Specific viscosity -
Reduced viscosity Viscosity number
Inherent viscosity Logarithmic viscosity
number
Intrinsic viscosity Limiting viscosity
number
aConcentrations (most commonly expressed in
grams per 100 mL of solvent) of about 0.5 g/dL

3. All Dilute Solution Viscosity Designations can be
obtained for dilute polymer solution using
viscometer by measuring the flow time between
the two level for dilute polymer solution and the
solvent.
c co c1 c2 c3 c4 c5
t to t1 t2 t3 t4 t5
hsp / c
{ln hr}/ c

4. Huggins (a ) & Kramer (b) Equations
(a)h/ c = [h] + k[h]2C
sp 1 (b){ln hr}/ c = [h] + k[h]2
C
2 Graph,:
k1 + k2 = 1/2
[h]
(a)
(b)
x
x x
x
x
xx
x
x x
hsp / c
or
{ln hr}/ c
C
Concentration C x 10-2 (g cm-3)

5. Intrinssic visscosity is the most useful of the various
Viscosity designations because it can be related to
molecular weight by the Mark-Houwink-Sakurada equation:
a
-
K M v
[h] =
where , v M -
is the viscosity average molecular weight, defined as
a
- +
M N M
1 1/
i i
a
i i
S
v N M
ö
÷ ÷ø
ç çè æ
S
=
Log [ ŋ ] = log K + a log Mv

6. Log K and a are the intercept and slope, respectively,
of a plot of log [h] versus log Mv
Log [ ŋ ] = log K + a log Mv
Value of K between 0.001 – 0.5 and a between 0.5 – 0.8
…………. Mv can be calculated (approximation value)
Measurement of [ ŋ ], just for estimation, can also be conducted from a
value of one solution concentration using Schulz dan Blaschke Equation
Value of [ ŋ ] can be calculated using the following
equation
Ŋsp / C
[ ŋ ] =
1 + kn Ŋsp
For most of polymer solvent system,
kn = 0.28

7. During measurement:
 Viscometer: Vertical
 no dirt or suspension
 Temperature. Should be constant
Importance of Molecular Weight, why?
Properties of polymers are closely
related to their molecular weight
Hard, soft, impact resistance,
tensile strenght etc.