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“Towards a new generation of composite panel
 products utilizing acetylated wood elements”

               Michel Maes, Chris Adair

                            Presented
       Forest Products Society 65th International Convention
                          20 June 2011
                         Portland, Oregon
The ”Achilles Heel” of wood



o Dimensionally unstable
o Poor microbial and insect durability

         Acetylated wood offers a solution




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
The Acetylation Process
    o Acetylation transforms accessible hydroxyl groups in wood to
      acetyl groups
    o Reduction in “bound water” content     dimensional stability
    o Wood is no longer food source for microorganisms




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Acetylation returns wood to original
green volume
                                                                     Drying
                                                                                                                                            Original Wood
                                                             Water uptake


       “Free” water                                  “Bound” water                                                           Acetylation
        (Cell lumen)                                  (Cell wall)


                                                   Acetylated                                                                                 Water uptake
                                                   Wood

                                                                                                                                                             “Free” water
                                                                                                                                                              (Cell lumen)
Wood cannot swell in water because it is as large as it can get

ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Accoya® as a reference point




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
                                                                                                                                                          6
Tricoya® Acetylation Technology

                                          ®
   o Accoya wood benefits can be translate to wood-
     based composites:
     - Enhanced dimensional stability
     - Superior durability

   o Using acetylated wood, wood-composites
     will enter previously untouchable markets




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Acetylated fibre-boards




               14 years in ground contact with soil high in brown rot of
    Westin, Rowell              acetylated Aspen MDF                                                                                                      8



ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Developing the Business


               Joint Development with Medite Europe Ltd


   Accsys Technologies                                                                                                  Medite provides:
   provides:                                                                                                            • Process facility
   •Technology                                                                                                          • Panel forming solutions
   •Concepts                                                                                                            • Market awareness
   •Branding



ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Medite Tricoya® Thickness Swell
(EN 317)




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
                                                                                                                                                          11
Thickness swelling over time




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Dimensional changes due to
  changes in humidity
                                                                                                    Tricoya® MDF




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Dry versus wet strength




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Medite Tricoya® Internal Bond
    Strength




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
                                                                                                                                                          15
Weather-resistance testing


                                                                                                                                                          Freeze/Thaw Cycles:
                                                                                                                                                          - 2 to 3 hours freezing at – 20 oC
                                                                                                                                                          - 2 to 3 hours in water of +20 oC

                                                                                                                                                          Wet/Dry Cycles:
                                                                                                                                                          - 18h storage in water (> 5 ºC)
                                                                                                                                                          - 6h storage at 60 ºC / 20% RH




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Acetylated MDF (6% pMDI)

                After 25 Cycles                                                              After 25 Cycles                                              Before




                                                         No cracking or delamination

ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Acetylated MDF Comparison
               After 25 Cycles                                                                                    Before

                                                                                                                                                          Acetylated MDF,
                                                                                                                                                             Before
                                                                                                                                                            pMDI resin




                                                                                                                                                           Unacetylated
                                                                                                                                                          “exterior” MDF




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Acetylated particleboard comparison

              After 25 Cycles                                                                       Before
                                                                                                                                                           Acetylated Particle
                                                                                                                                                                 Board,
                                                                                                                                                               MUF resin



                                                                                                                                                          Un-acetylated Particle
                                                                                                                                                            Board, MUF resin




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Acetylated OSB Comparison


                  After 25 Cycles                                                                  Before
                                                                                                                                                          Acetylated OSB,
                                                                                                                                                            pMDI resin




                                                                                                                                                          Unacetylated OSB/3,
                                                                                                                                                              pMDI resin




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Medite Tricoya® is fully resistant
 to decay




                               Summary of average mass loss (%). DD ENV 12038: 2002
                               A mass loss of less than 3% indicates a material is fully resistant to decay by basidiomycetes


ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
                                                                                                                                                          21
Tricoya® - New Technology for
 New Markets

         Value
                                                                                                             Exterior
                                                                                                           Applications




                                                                                            Wet Interior Applications




                                                                        Furniture & General Interior Applications
     Volume
                                                                                                                                                          22

ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
New Applications


                                                                                                                                     New (exterior)
      Old (interior)
      -        Household furniture
      -        Cabinetry
      -        Moulding
      -        Laminate flooring
      -        Store fixtures
      -        Decorative interior
      -        Doors
      -        Structural




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Medite Tricoya®
stability at level of non-wood material




 ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
 and may not be used or reproduced without written permission.
                                                   pemission.
                                                                                                                                                           24
Medite Tricoya® – Key
         applications
                   Key Applications

          Exterior cladding / facades
          Shop fronts / signage /
          billboards
          Entrance doors

          Garden / outdoor

          Playground

          Backing Board- interior

          Cubicles and Wet rooms

          Wet furniture

          Flooring

          Shipbuilding / marine


ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
                                                                                                                                                          25
Conclusion
      Medite Tricoya® value will be based on performance:
                   o Extended service life
                   o Lower maintenance costs
                   o Reliability in-use due to dimensional stability and durability
                   o Machinability using normal woodworking tooling
                   o Damaged coating /core will not effect durability
                   o No edge treatment required
                   o It will also displace other cladding materials like metal,
                       fiber-cement, plastic, (ply-)wood
                   o Sustainable option
                     60 Year Service Life as validated by the
                     British Research Establishment (BRE)
ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
                                                                                                                                                          26
Thank you and I am happy to
                                    answer your questions




ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.
Disclaimer
       The images and written contents of this presentation are the
       property of Accsys Technologies, its customers, partners and
       licensees and may not be copied, reproduced, extracted, used by
       or shown to other parties without the prior written consent of
       Accsys Technologies’ Marketing Department.

       To the best of the knowledge and belief of Accsys Technologies,
       the information contained in this presentation is accurate and is
       provided on the basis that Accsys Technologies and/or any of its
       affiliates, officers employees or advisers are not liable for any
       loss or damage whatsoever in respect of the accuracy or
       completeness of such information or the result of having acted
       upon it.
       Accsys Technologies is a trading name of Titan Wood Inc.



ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC,
and may not be used or reproduced without written permission.
                                                  pemission.

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Session 13 ic2011 adair

  • 1. “Towards a new generation of composite panel products utilizing acetylated wood elements” Michel Maes, Chris Adair Presented Forest Products Society 65th International Convention 20 June 2011 Portland, Oregon
  • 2. The ”Achilles Heel” of wood o Dimensionally unstable o Poor microbial and insect durability Acetylated wood offers a solution ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 3. The Acetylation Process o Acetylation transforms accessible hydroxyl groups in wood to acetyl groups o Reduction in “bound water” content dimensional stability o Wood is no longer food source for microorganisms ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 4. Acetylation returns wood to original green volume Drying Original Wood Water uptake “Free” water “Bound” water Acetylation (Cell lumen) (Cell wall) Acetylated Water uptake Wood “Free” water (Cell lumen) Wood cannot swell in water because it is as large as it can get ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 5. Accoya® as a reference point ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 6. ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission. 6
  • 7. Tricoya® Acetylation Technology ® o Accoya wood benefits can be translate to wood- based composites: - Enhanced dimensional stability - Superior durability o Using acetylated wood, wood-composites will enter previously untouchable markets ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 8. Acetylated fibre-boards 14 years in ground contact with soil high in brown rot of Westin, Rowell acetylated Aspen MDF 8 ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 9. Developing the Business Joint Development with Medite Europe Ltd Accsys Technologies Medite provides: provides: • Process facility •Technology • Panel forming solutions •Concepts • Market awareness •Branding ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 10. ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 11. Medite Tricoya® Thickness Swell (EN 317) ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission. 11
  • 12. Thickness swelling over time ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 13. Dimensional changes due to changes in humidity Tricoya® MDF ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 14. Dry versus wet strength ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 15. Medite Tricoya® Internal Bond Strength ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission. 15
  • 16. Weather-resistance testing Freeze/Thaw Cycles: - 2 to 3 hours freezing at – 20 oC - 2 to 3 hours in water of +20 oC Wet/Dry Cycles: - 18h storage in water (> 5 ºC) - 6h storage at 60 ºC / 20% RH ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 17. Acetylated MDF (6% pMDI) After 25 Cycles After 25 Cycles Before No cracking or delamination ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 18. Acetylated MDF Comparison After 25 Cycles Before Acetylated MDF, Before pMDI resin Unacetylated “exterior” MDF ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 19. Acetylated particleboard comparison After 25 Cycles Before Acetylated Particle Board, MUF resin Un-acetylated Particle Board, MUF resin ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 20. Acetylated OSB Comparison After 25 Cycles Before Acetylated OSB, pMDI resin Unacetylated OSB/3, pMDI resin ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 21. Medite Tricoya® is fully resistant to decay Summary of average mass loss (%). DD ENV 12038: 2002 A mass loss of less than 3% indicates a material is fully resistant to decay by basidiomycetes ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission. 21
  • 22. Tricoya® - New Technology for New Markets Value Exterior Applications Wet Interior Applications Furniture & General Interior Applications Volume 22 ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 23. New Applications New (exterior) Old (interior) - Household furniture - Cabinetry - Moulding - Laminate flooring - Store fixtures - Decorative interior - Doors - Structural ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 24. Medite Tricoya® stability at level of non-wood material ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission. 24
  • 25. Medite Tricoya® – Key applications Key Applications Exterior cladding / facades Shop fronts / signage / billboards Entrance doors Garden / outdoor Playground Backing Board- interior Cubicles and Wet rooms Wet furniture Flooring Shipbuilding / marine ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission. 25
  • 26. Conclusion Medite Tricoya® value will be based on performance: o Extended service life o Lower maintenance costs o Reliability in-use due to dimensional stability and durability o Machinability using normal woodworking tooling o Damaged coating /core will not effect durability o No edge treatment required o It will also displace other cladding materials like metal, fiber-cement, plastic, (ply-)wood o Sustainable option 60 Year Service Life as validated by the British Research Establishment (BRE) ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission. 26
  • 27. Thank you and I am happy to answer your questions ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.
  • 28. Disclaimer The images and written contents of this presentation are the property of Accsys Technologies, its customers, partners and licensees and may not be copied, reproduced, extracted, used by or shown to other parties without the prior written consent of Accsys Technologies’ Marketing Department. To the best of the knowledge and belief of Accsys Technologies, the information contained in this presentation is accurate and is provided on the basis that Accsys Technologies and/or any of its affiliates, officers employees or advisers are not liable for any loss or damage whatsoever in respect of the accuracy or completeness of such information or the result of having acted upon it. Accsys Technologies is a trading name of Titan Wood Inc. ACCOYA®, TRICOYA® and the Trimarque Device are registered trademarks owned by Titan Wood Limited, a wholly owned subsidiary of Accsys Technologies PLC, and may not be used or reproduced without written permission. pemission.