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International Journal of Trend in Scientific Research and Development (IJTSRD)
Volume 4 Issue 6, September-October 2020 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470
@ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1833
Experimental Investigation of Solar Water Heater
Integrated with a Nanocomposite Phase Change Material
Shashi Kumar1, Prof. Ranjeet Arya2
1M Tech Scholar, 2Assistant Professor,
1,2Department of Mechanical Engineering,
1,2Corporate Institute of Science & Technology, Bhopal, Madhya Pradesh, India
ABSTRACT
This present work contributes to the improvement in thermal energy
storage capacity of an all-glass evacuated tube solar water heater by
integrating it with a phase change material (PCM) and with a
nanocomposite phase change material (NCPCM)..
Paraffin wax as PCM and a nanocompositeofparaffinwax with1.0mass%
GeO2 nanoparticles as NCPCM had been used during the experiments.
Three different cases, namely, without PCM, with PCM, and with NCPCM,
were considered.
The testing procedure involved the observation of total temperature
variation in the tank water from 6.00 a.m. to 6.00 a.m. of next morning.
OBJECTIVE
The main objective of my project is to increase the performanceofsolarwater
heater integrated storage tank with PCM and NCPCM which would serve the
varying demands.
How to cite this paper: Shashi Kumar |
Prof. Ranjeet Arya "Experimental
Investigation of Solar Water Heater
Integrated with a Nanocomposite Phase
Change Material"
Published in
International Journal
of Trend in Scientific
Research and
Development(ijtsrd),
ISSN: 2456-6470,
Volume-4 | Issue-6,
October 2020, pp.1833-1837, URL:
www.ijtsrd.com/papers/ijtsrd35820.pdf
Copyright © 2020 by author(s) and
International Journal ofTrendinScientific
Research and Development Journal. This
is an Open Access article distributed
under the terms of
the Creative
CommonsAttribution
License (CC BY 4.0)
(http://creativecommons.org/licenses/by/4.0)
INTRODUCTION
Solar water heater is most alternative source to
the conventional electric heater to meet the
domestic and industrial hot water demand,
where energy utilized is from the renewable
source. It is abundant renewable energy source. It
brings the hopeful scope for the solar thermal
industries for producing commercially successful and
competent products to cater the customer needs
Phase change materials (PCMs) are considered to
be the potential resources, since they can absorb or
release a lot of heat energy at the constant temperature
during their phase transitions. They are having great
energy densities compared to other form of
thermal storage materials
LITERATURE REVIEW
The system consists of two simultaneouslyfunctioningheat-
absorbing units. The storage unit stores the heat in PCMs
during the day supplies hot water during the night.
M. V. Kulkarni, Dr. D. S Deshmukh (2017). An Innovative
design of solar water heater flat plate collector is developed
and tested. The collector is made-up of rectangular
aluminium having size 0.97 m X 1.81 m total surface area for
heat conduction is 1.9845 m2. The absorber is made of
Aluminium box with one large surface exposed to sunlight
having size 1.94 m x 1.1 m x 0.1 m, glass 4 mm thick
toughened to cover the box large open surface, black paint
for absorbing solar radiation and insulationlayer.Maximum
temperature of water obtained at outlet of collector is 73.3
0C. Also an innovative storage tank is investigated. The
storage tank is made up of MS plate, 50 mm puff insulation,
outer- cladding cover, inside coating with Fiber
Reinforcement plastic and 60%-40% partition for hot and
cold water. Due to this FRP coating thermal conductivity of
tank material and night heat losses get reduced. In
conventional hot water storage tank night temperature
losses is found to be 9 0C while in modified FRP coating tank
with partition night temperature losses is found to be 4 0C
International Journal of Scientific Engineering and Research
(IJSER) (2015). We are blessed with Solar Energy in
abundance at no cost. The solar radiation incident on the
surface of the earth can be conveniently utilized for the
benefit of human society. One of the popular devices that
harness the solar energy is solar hot water system (SHWS).
The solar energy is the most capable of the alternative
energy sources. Due to increasing Demand for energy and
rising cost of fossil type fuels (i.e., gas or oil) solar energy is
considered an attractivesourceofrenewable energythatcan
be used for water hearing in both homes and industry.
Heating water consumes nearly 20% of total energy
consumption for an average family. Solar water heating
systems are the cheapest and most easily affordable clean
IJTSRD35820
International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1834
energy available to homeowners that may provide most of
hot water required by a family. Solarheaterisa devicewhich
is used for heating the water, for producing the steam for
domestic and industrial purposes by utilizing the solar
energy. Solar energy is the energy which is coming from sun
in the form of solar radiations in infiniteamount, whenthese
solar radiations falls on absorbing surface, then they gets
converted into the heat, this heat is used for heating the
water. This type of thermal collector suffersfromheatlosses
due toradiation and convection. Such lossesincreaserapidly
as the temperature of the working fluid increases.
Journal of Engineering and Development, Vol. 18, No.2,
March 2014 The crucial pointindesigninganysolarcollector
is to allow maximum possible amount of solar radiation to
reach the absorber part of the collector, and concurrently,
reducing thermal losses from the absorber to the minimum.
Evacuated-Tube Solar Collector (ETSC) offers feasible
solution to this problem. An evacuated tube is composed of
two coaxial glass tubes forming an annulus (Figure. 1). The
space between the two tubes is evacuated to eliminate
convective losses. The outer tube is the transparent cover
while the inner tube is the absorber which is coated from
outside (vacuum side) with a selective paint to maximize
solar absorptance. One end of the evacuated tube is closed
while the other is left open. The solar collector usually
incorporates several evacuated tubes forming a parallel
array. Heat can be extracted from the tubes by a variety of
ways. The simplest way is achieved by the direct connection
of the tubes to the storage unit. The working fluid can be
either a liquid or a gas. When water is used as the working
fluid, it is directly circulated between the tank and tube
cavity via natural circulation. The temperature range in this
type is limited by water boiling point. However, air or other
gases may also be used as working fluids which necessitates
the use of an appropriate fan or blower to circulate the fluid.
The first systematic study on an ETSC was done by Eberlein
(1976). He analyzed thermal performance of an ETSC
employing air as the working fluid. The solar collector
studied by Eberlein consisted of an array of several
evacuated tubes. Air is introduced in the middle way
between top and bottom of each tube using additional
concentric delivery conduit.Itcirculatesintheannularspace
between the delivery conduit and the absorbing tube to
collect solar thermal energy. This analytical study proposed
several mathematical models useful in the design of air
ETSCs but it was not validated by experimental tests. A
detailed numerical studyonthenatural circulationinside the
evacuated tube cavity was done by Gaa F.O. et. al. (1998). A
numerical model of the inclined open thermosyphon has
been developed using a finite difference algorithm to solve
the vorticity vector potential form of the Navier-Stokes
equations. The study was experimentallyverifiedusinglaser
doppler anemometry to measure the velocity profile at the
tube exit.
Photographic view of an experimental setup of evacuated tube solar water heater with measuring instruments b
PCM/NCPCM containers and their integration with the water storage tank
Experimental procedure
The experiments were conducted during the months of January,February,andMarch of2020,andtheaverageofat least3days
for each case had been monitored to ascertain the reliability and accuracy of the results. The test results belonging to the days
having similar solar insolation were deliberated for the further analysis. The water temperature of the collector storage tank
was monitored with three K-type thermocouples with an accuracy of ± 0.1 ℃, which had been placed in equidistance from the
bottom of the tank in order to measure the average hot water temperature during the experiment.
International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1835
Hourly measurement of atmospheric temperature for
the three cases on three similar solar days
Energy stored in the solar collector tank for the three
cases of experiments
Exergy efficiency of the evacuated tube solar collector
for the three cases of experiment
Energy analysis
Qi = Qs+Qb+Ql 1
Qs = Qw + QPCM 2
Qs= [mwxCp,w(Tw,f-Tw,i)] + {mpcm[Cp,pcm(Tpcm,f-
Tpcm,i) +am Δhpcm] 3
Qi = AcxHt 4
Ac =N xLxD 5
ηc= (Qs/Qi )x 100 6
Exin = Exstored + Exloss + Irrevesibility 7
Exin = Ac Ht [1+1 / 3 (Ta/Tsun)
4
4/3 (Ta/Tsun)] 8
Exstored = Exw + Expcm 9
Exw =mw xCp;w [ (Tw,f -Tw,i) - TaIn (Tw,f / Tw,i) ] 10
Expcm = Q pcm (1- Ta/ Tpcm) 11
ψc = Exstored /Exm x 100 12
Schematic diagram of the all-glass evacuated tube solar
water heater with PCM container and measuring
instruments.
Energy efficiency of the evacuated tube solar collector
for the three cases of experiments
Energy stored in the solar collector tank for the three
cases of experiments
International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1836
Daily energy efficiency of solar water heater for the three
different cases
Description
Description Daily energy
efficiency (g)/%
Solar water heater
without PCM
58.74
Solar water heater
with PCM
69.62
Solar water heater
with NCPCM
74.79
Exergy stored in the solar collector tank for the three
cases of experiments
Exergy stored in the solar collector tank for the three
cases of experiments
Conclusions
The all-glass evacuated tube solar water heater was
fabricated with built-in storage tank.
The experiments were conducted for 24 h from 6.00 a.m. to
6.00 a.m. of next day morning for all the cases.
The performance of the collector was investigated in terms
of energy efficiency, exergy efficiency, and temperature of
hot water supply during next day morning for the three
cases, namely, the first case without PCM, the second case
with PCM, and the third case with NCPCM.
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Experimental Investigation of Solar Water Heater Integrated with a Nanocomposite Phase Change Material

  • 1. International Journal of Trend in Scientific Research and Development (IJTSRD) Volume 4 Issue 6, September-October 2020 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470 @ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1833 Experimental Investigation of Solar Water Heater Integrated with a Nanocomposite Phase Change Material Shashi Kumar1, Prof. Ranjeet Arya2 1M Tech Scholar, 2Assistant Professor, 1,2Department of Mechanical Engineering, 1,2Corporate Institute of Science & Technology, Bhopal, Madhya Pradesh, India ABSTRACT This present work contributes to the improvement in thermal energy storage capacity of an all-glass evacuated tube solar water heater by integrating it with a phase change material (PCM) and with a nanocomposite phase change material (NCPCM).. Paraffin wax as PCM and a nanocompositeofparaffinwax with1.0mass% GeO2 nanoparticles as NCPCM had been used during the experiments. Three different cases, namely, without PCM, with PCM, and with NCPCM, were considered. The testing procedure involved the observation of total temperature variation in the tank water from 6.00 a.m. to 6.00 a.m. of next morning. OBJECTIVE The main objective of my project is to increase the performanceofsolarwater heater integrated storage tank with PCM and NCPCM which would serve the varying demands. How to cite this paper: Shashi Kumar | Prof. Ranjeet Arya "Experimental Investigation of Solar Water Heater Integrated with a Nanocomposite Phase Change Material" Published in International Journal of Trend in Scientific Research and Development(ijtsrd), ISSN: 2456-6470, Volume-4 | Issue-6, October 2020, pp.1833-1837, URL: www.ijtsrd.com/papers/ijtsrd35820.pdf Copyright © 2020 by author(s) and International Journal ofTrendinScientific Research and Development Journal. This is an Open Access article distributed under the terms of the Creative CommonsAttribution License (CC BY 4.0) (http://creativecommons.org/licenses/by/4.0) INTRODUCTION Solar water heater is most alternative source to the conventional electric heater to meet the domestic and industrial hot water demand, where energy utilized is from the renewable source. It is abundant renewable energy source. It brings the hopeful scope for the solar thermal industries for producing commercially successful and competent products to cater the customer needs Phase change materials (PCMs) are considered to be the potential resources, since they can absorb or release a lot of heat energy at the constant temperature during their phase transitions. They are having great energy densities compared to other form of thermal storage materials LITERATURE REVIEW The system consists of two simultaneouslyfunctioningheat- absorbing units. The storage unit stores the heat in PCMs during the day supplies hot water during the night. M. V. Kulkarni, Dr. D. S Deshmukh (2017). An Innovative design of solar water heater flat plate collector is developed and tested. The collector is made-up of rectangular aluminium having size 0.97 m X 1.81 m total surface area for heat conduction is 1.9845 m2. The absorber is made of Aluminium box with one large surface exposed to sunlight having size 1.94 m x 1.1 m x 0.1 m, glass 4 mm thick toughened to cover the box large open surface, black paint for absorbing solar radiation and insulationlayer.Maximum temperature of water obtained at outlet of collector is 73.3 0C. Also an innovative storage tank is investigated. The storage tank is made up of MS plate, 50 mm puff insulation, outer- cladding cover, inside coating with Fiber Reinforcement plastic and 60%-40% partition for hot and cold water. Due to this FRP coating thermal conductivity of tank material and night heat losses get reduced. In conventional hot water storage tank night temperature losses is found to be 9 0C while in modified FRP coating tank with partition night temperature losses is found to be 4 0C International Journal of Scientific Engineering and Research (IJSER) (2015). We are blessed with Solar Energy in abundance at no cost. The solar radiation incident on the surface of the earth can be conveniently utilized for the benefit of human society. One of the popular devices that harness the solar energy is solar hot water system (SHWS). The solar energy is the most capable of the alternative energy sources. Due to increasing Demand for energy and rising cost of fossil type fuels (i.e., gas or oil) solar energy is considered an attractivesourceofrenewable energythatcan be used for water hearing in both homes and industry. Heating water consumes nearly 20% of total energy consumption for an average family. Solar water heating systems are the cheapest and most easily affordable clean IJTSRD35820
  • 2. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1834 energy available to homeowners that may provide most of hot water required by a family. Solarheaterisa devicewhich is used for heating the water, for producing the steam for domestic and industrial purposes by utilizing the solar energy. Solar energy is the energy which is coming from sun in the form of solar radiations in infiniteamount, whenthese solar radiations falls on absorbing surface, then they gets converted into the heat, this heat is used for heating the water. This type of thermal collector suffersfromheatlosses due toradiation and convection. Such lossesincreaserapidly as the temperature of the working fluid increases. Journal of Engineering and Development, Vol. 18, No.2, March 2014 The crucial pointindesigninganysolarcollector is to allow maximum possible amount of solar radiation to reach the absorber part of the collector, and concurrently, reducing thermal losses from the absorber to the minimum. Evacuated-Tube Solar Collector (ETSC) offers feasible solution to this problem. An evacuated tube is composed of two coaxial glass tubes forming an annulus (Figure. 1). The space between the two tubes is evacuated to eliminate convective losses. The outer tube is the transparent cover while the inner tube is the absorber which is coated from outside (vacuum side) with a selective paint to maximize solar absorptance. One end of the evacuated tube is closed while the other is left open. The solar collector usually incorporates several evacuated tubes forming a parallel array. Heat can be extracted from the tubes by a variety of ways. The simplest way is achieved by the direct connection of the tubes to the storage unit. The working fluid can be either a liquid or a gas. When water is used as the working fluid, it is directly circulated between the tank and tube cavity via natural circulation. The temperature range in this type is limited by water boiling point. However, air or other gases may also be used as working fluids which necessitates the use of an appropriate fan or blower to circulate the fluid. The first systematic study on an ETSC was done by Eberlein (1976). He analyzed thermal performance of an ETSC employing air as the working fluid. The solar collector studied by Eberlein consisted of an array of several evacuated tubes. Air is introduced in the middle way between top and bottom of each tube using additional concentric delivery conduit.Itcirculatesintheannularspace between the delivery conduit and the absorbing tube to collect solar thermal energy. This analytical study proposed several mathematical models useful in the design of air ETSCs but it was not validated by experimental tests. A detailed numerical studyonthenatural circulationinside the evacuated tube cavity was done by Gaa F.O. et. al. (1998). A numerical model of the inclined open thermosyphon has been developed using a finite difference algorithm to solve the vorticity vector potential form of the Navier-Stokes equations. The study was experimentallyverifiedusinglaser doppler anemometry to measure the velocity profile at the tube exit. Photographic view of an experimental setup of evacuated tube solar water heater with measuring instruments b PCM/NCPCM containers and their integration with the water storage tank Experimental procedure The experiments were conducted during the months of January,February,andMarch of2020,andtheaverageofat least3days for each case had been monitored to ascertain the reliability and accuracy of the results. The test results belonging to the days having similar solar insolation were deliberated for the further analysis. The water temperature of the collector storage tank was monitored with three K-type thermocouples with an accuracy of ± 0.1 ℃, which had been placed in equidistance from the bottom of the tank in order to measure the average hot water temperature during the experiment.
  • 3. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1835 Hourly measurement of atmospheric temperature for the three cases on three similar solar days Energy stored in the solar collector tank for the three cases of experiments Exergy efficiency of the evacuated tube solar collector for the three cases of experiment Energy analysis Qi = Qs+Qb+Ql 1 Qs = Qw + QPCM 2 Qs= [mwxCp,w(Tw,f-Tw,i)] + {mpcm[Cp,pcm(Tpcm,f- Tpcm,i) +am Δhpcm] 3 Qi = AcxHt 4 Ac =N xLxD 5 ηc= (Qs/Qi )x 100 6 Exin = Exstored + Exloss + Irrevesibility 7 Exin = Ac Ht [1+1 / 3 (Ta/Tsun) 4 4/3 (Ta/Tsun)] 8 Exstored = Exw + Expcm 9 Exw =mw xCp;w [ (Tw,f -Tw,i) - TaIn (Tw,f / Tw,i) ] 10 Expcm = Q pcm (1- Ta/ Tpcm) 11 ψc = Exstored /Exm x 100 12 Schematic diagram of the all-glass evacuated tube solar water heater with PCM container and measuring instruments. Energy efficiency of the evacuated tube solar collector for the three cases of experiments Energy stored in the solar collector tank for the three cases of experiments
  • 4. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1836 Daily energy efficiency of solar water heater for the three different cases Description Description Daily energy efficiency (g)/% Solar water heater without PCM 58.74 Solar water heater with PCM 69.62 Solar water heater with NCPCM 74.79 Exergy stored in the solar collector tank for the three cases of experiments Exergy stored in the solar collector tank for the three cases of experiments Conclusions The all-glass evacuated tube solar water heater was fabricated with built-in storage tank. The experiments were conducted for 24 h from 6.00 a.m. to 6.00 a.m. of next day morning for all the cases. The performance of the collector was investigated in terms of energy efficiency, exergy efficiency, and temperature of hot water supply during next day morning for the three cases, namely, the first case without PCM, the second case with PCM, and the third case with NCPCM. REFERENCES [1] Golic ´ K, Kosoric ´ V, Furundz ˇic ´ AK. General model of solar water heating system integration in residential building refurbishment—potential energy savings and environmental impact. Renew Sustain Energy Rev. 2011; 15(3):1533–44. [2] Shukla R, Sumathy K, Erickson P, Gong J. Recent advances in the solarwaterheatingsystems:a review. Renew Sustain Energy Rev. 2013; 19:173–90. [3] RedpathDA.Thermosyphonheat-pipeevacuatedtube solar water heaters for northern maritime climates. Sol Energy. 2012; 86(2):705–15. [4] Ayompe LM, Duffy A, Mc Keever M, Conlon M, McCormack SJ. Comparative field performance study of flat plate and heat pipe evacuated tube collectors (ETCs) for domestic water heating systems in a temperate climate. Energy. 2011; 36(5):3370–8. [5] Kim JT, Ahn HT, Han H, Kim HT, Chun W. The performance simulation of all-glass vacuum tubes with coaxial fluid conduit. Int Commun Heat Mass Transf. 2007; 34(5):587–97. [6] Rosen MA, Tang R, Dincer I. Effect of stratification on energy and exergy capacities in thermal storage systems. Int J Energy Res. 2004; 28(2):177–93. [7] Jordan U, Furbo S. Thermal stratification in small solar domestic storage tanks caused by draw-offs.Sol Energy. 2005; 78(2):291–300. [8] Sharma A, Tyagi VV, Chen CR, Buddhi D. Review on thermal energy storage with phase change materials and applications. Renew Sustain Energy Rev. 2009; 13(2):318–45. [9] Kim S, Drzal LT. High latent heat storage and high thermal conductive phase change materials using exfoliated graphite nanoplatelets. Sol Energy Mater Sol Cells. 2009; 93:136–42. [10] Zalba B, Marın JM, Cabeza LF, Mehling H. Review on thermal energy storage with phase change:materials, heat transfer analysis and applications. Appl Therm Eng. 2003; 23(3):251–83. [11] Sharif MA, Al-Abidi AA, Mat S, Sopian K, Ruslan MH, Sulaiman MY, Rosli MA. Review of the application of phase change material for heating and domestic hot water systems. Renew Sustain Energy Rev. 2015; 42:557–68. [12] Cabeza LF, Ibanez M, Sole C, Roca J, Nogues M. Experimentation with a water tank including a PCM
  • 5. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD35820 | Volume – 4 | Issue – 6 | September-October 2020 Page 1837 module. Sol Energy Mater Sol Cells. 2006; 90(9):1273–82. [13] Chaabane M, Mhiri H, Bournot P. Thermal performance of an integrated collector storage solar water heater (ICSSWH) with phase change materials (PCM). Energy Convers Manag. 2014; 78:897–903. [14] Anghel EM, Georgiev A, Petrescu S, Popov R, Constantinescu M. Thermo-physical characterization of some paraffins used as phase change materials for thermal energy storage. J Therm Anal Calorim. 2014; 117(2):557–66. [15] Ahmed SF, Khalid M, Rashmi W, Chan A, Shahbaz K. Recent progress in solarthermal energystorageusing nanomaterials. Renew Sustain Energy Rev. 2017; 67:450–60. [16] Zeng JL, Sun LX, Xu F, Tan ZC, Zhang ZH, Zhang J, Zhang T. Study of a PCM based energy storage system containing Ag nanoparticles. J Therm Anal Calorim. 2007; 87(2):371–5. [17] Zeng JL, Cao Z, Yang DW, Sun LX, Zhang L. Thermal conductivity enhancement of Ag nanowires on an organic phase change material. J Therm Anal Calorim. 2010; 101(1):385–9. [18] Mettawee EB, Assassa GM. Thermal conductivity enhancement in a latent heat storage system. Sol Energy. 2007; 81(7):839–45. [19] Luo R, Wang S, Wang T, Zhu C, Nomura T, Akiyama T. Fabrication of paraffin@ GeO2 shape-stabilized composite phase change material via chemical precipitation method for building energy conservation. Energy Build. 2015; 108:373–80. [20] Redhwan AA, Azmi WH, Sharif MZ, Mamat R, Zawawi NN. Comparative study of thermo-physical properties of GeO2 and Al2O3 nanoparticles dispersed in PAG lubricant. Appl Therm Eng. 2017; 116:823–32. [21] Tang R, Yang Y, Gao W. Comparative studies on thermal performance of water-in-glass evacuated tube solar water heaters with different collector tilt- angles. Sol Energy. 2011; 85(7):1381–9. [22] Wu SY, Wang H, Xiao S, Zhu DS. An investigation of melting/ freezing characteristics of nanoparticle- enhanced phase change materials. J Therm Anal Calorim. 2011; 110(3):1127–31. [23] Jesumathy S, Udayakumar M, Suresh S. Experimental study of enhanced heat transfer by addition of CuO nanoparticle. Heat [24] Ceylan I. Energy and exergyanalysesofa temperature controlled solar water heater. Energy Build. 2012; 47:630–5.