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造粒 Granulation ,[object Object],[object Object],[object Object],Che5700  陶瓷粉末處理
Direct Granulation Che5700  陶瓷粉末處理 ,[object Object],[object Object],[object Object],[object Object]
Formation of Granule Che5700  陶瓷粉末處理 Can be viewed as nucleation & growth process;    At first, binder solution droplet touch particle    nucleus; capillary force and binder flocculation provide strength  ,[object Object],[object Object]
Spray granulation   uniformity closely related to liquid content;  Hardness: mostly related to binder (and particle characteristics)
Spray Granulation ,[object Object],[object Object],[object Object]
Spray Granulation 2 ,[object Object],[object Object]
Spray Drying ,[object Object],[object Object],[object Object],[object Object],Che5700  陶瓷粉末處理
Spray Drying (2) ,[object Object],[object Object],[object Object]
Taken from TA Ring, 1996 Droplet/particle: mean residence time ~ 30 sec Three basic steps: (a)atomization, (b)droplet drying, (c) gas-droplet mixing
Spray dried samples: donut particle, temperature rise too fast, surface dried (sealed), vaporization of internal liquid    pores (viscous binder fluid may flow toward inside)
Spraying Drying (3) ,[object Object],[object Object],[object Object],[object Object],[object Object],Che5700  陶瓷粉末處理
Atomization ,[object Object],[object Object],[object Object],Che5700  陶瓷粉末處理 u 1 : interfacial velocity between gas and liquid; D d max  = at critical Weber number, largest stable size
Droplet Size ,[object Object],[object Object],[object Object],N v  = dimension-less viscosity;
 
Droplet Drying ,[object Object],[object Object],[object Object],[object Object]
[object Object],----------------
[object Object],Che5700  陶瓷粉末處理
Classification Che5700  陶瓷粉末處理
Principle and Techniques ,[object Object],[object Object],Che5700  陶瓷粉末處理
Taken from TA Ring, 1996; can add some baffles, to separate large particles
Size Selectivity ,[object Object],[object Object],[object Object],[object Object],Che5700  陶瓷粉末處理
取自 TA Ring 1996;  Cut size; bypass;  Sharpness index b-b’ curve: normal case
Recovery & Yield Che5700  陶瓷粉末處理 ,[object Object],[object Object],[object Object]
Che5700  陶瓷粉末處理
phase transformation during calcination Gibbsite, Bayerite Al(OH) 3 ; Boehmite AlOOH Diaspore α-AlOOH

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Granulation

  • 1.
  • 2.
  • 3.
  • 4. Spray granulation  uniformity closely related to liquid content; Hardness: mostly related to binder (and particle characteristics)
  • 5.
  • 6.
  • 7.
  • 8.
  • 9. Taken from TA Ring, 1996 Droplet/particle: mean residence time ~ 30 sec Three basic steps: (a)atomization, (b)droplet drying, (c) gas-droplet mixing
  • 10. Spray dried samples: donut particle, temperature rise too fast, surface dried (sealed), vaporization of internal liquid  pores (viscous binder fluid may flow toward inside)
  • 11.
  • 12.
  • 13.
  • 14.  
  • 15.
  • 16.
  • 17.
  • 18. Classification Che5700 陶瓷粉末處理
  • 19.
  • 20. Taken from TA Ring, 1996; can add some baffles, to separate large particles
  • 21.
  • 22. 取自 TA Ring 1996; Cut size; bypass; Sharpness index b-b’ curve: normal case
  • 23.
  • 25. phase transformation during calcination Gibbsite, Bayerite Al(OH) 3 ; Boehmite AlOOH Diaspore α-AlOOH