Proton A has the highest signal because it is in the meta position to an electron-rich aromatic methylene group, causing its chemical shift to be more deshielded. Proton E appears at ~3 ppm instead of the expected 1.2-1.6 ppm because it belongs to an aromatic methylene group that is substituted between two phenyl rings, causing it to be downfield shifted by approximately 1.3 ppm. The chemical shifts of protons C and D are shielded compared to A and B due to increased electron density at the para positions of the phenyl and benzylic methylene groups.