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carboydrates.ppt
1.
Chapter 5 Lecture General,
Organic, and Biological Chemistry: An Integrated Approach Laura Frost, Todd Deal and Karen Timberlake by Richard Triplett Ā© 2011 Pearson Education, Inc. Carbohydrates: Lifeās Sweet Molecules Chapter 5
2.
Chapter 5 2 Ā©
2011 Pearson Education, Inc. Chapter Outline 5.1 Classes of Carbohydrates 5.2 Monosaccharides 5.3 Oxidation and Reduction Reactions 5.4 Ring FormationāThe Truth about Monosaccharide Structure 5.5 Disaccharides 5.6 Polysaccharides 5.7 Carbohydrates and Blood
3.
Chapter 5 3 Ā©
2011 Pearson Education, Inc. Introduction to Carbohydrates ā¢ Carbohydrates are sugars and provide energy when consumed. ā¢ Our bodies break down carbohydrates to extract energy. Carbon dioxide and water are released in the process. ā¢ Glucose is the primary carbohydrate our bodies use to produce energy. ā¢ Carbohydrates are classified as biomolecules.
4.
Chapter 5 4 Ā©
2011 Pearson Education, Inc. Introduction to Carbohydrates, Continued ā¢ Simple carbohydrates are referred to as simple sugars and are often sweet to the taste. ā¢ Consumption of more sugar than is needed for energy results in conversion of these sugars to fat. ā¢ Complex carbohydrates include starches and the plant and wood fibers known as cellulose.
5.
Chapter 5 5 Ā©
2011 Pearson Education, Inc. Introduction to Carbohydrates, Continued ā¢ Carbohydrates are found on the surface of cells where they act as āroad signsā allowing molecules to distinguish one cell from another. ā¢ ABO blood markers found on red blood cells are made up of carbohydrates. They allow us to distinguish our bodyās blood type from a foreign blood type. ā¢ Carbohydrates in our body prevent blood clots. They are also found in our genetic material.
6.
Chapter 5 6 Ā©
2011 Pearson Education, Inc. 5.1 Classes of Carbohydrates ā¢ Monosaccharides are the simplest carbohydrates. They cannot be broken down to smaller carbohydrates. ā¢ Disaccharides consist of two monosaccharide units joined together; they can be split into two monosaccharides. Sucrose, table sugar, can be broken down into glucose and fructose. ā¢ Oligosaccharides contain anywhere from three to nine monosaccharide units. ABO blood groups are oligosaccharides.
7.
Chapter 5 7 Ā©
2011 Pearson Education, Inc. 5.1 Classes of Carbohydrates, Continued Polysaccharides are large molecules containing 10 or more monosaccharide units. Carbohydrate units are connected in one continuous chain or the chain can be branched.
8.
Chapter 5 8 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides ā¢ Monosaccharides contain the elements carbon, hydrogen, and oxygen, and have the general formula Cn(H2O)n, where n is a whole number 3 or greater. ā¢ Monosaccharides contain several functional groups. They contain the hydroxyl group represented as āOH. They also contain a carbonyl group, which is an oxygen double bonded to a carbon atom. The carbonyl group may be an aldehyde or a ketone.
9.
Chapter 5 9 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued The functional groups of glucose are shown in the figure below.
10.
Chapter 5 10 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Functional Groups in Monosaccharidesā Alcohols, Aldehydes, and Ketones Alcohols ā¢ Alcohol is an organic compound containing the āOH group. ā¢ Ethanol is one of the simplest alcohols and is prepared from the fermentation of simple sugars in grains and fruits. Ethanol is present in beer and liquors, and is used as an alternative fuel blend, such as gasohol and E85 (85% ethanol and 15% gasoline).
11.
Chapter 5 11 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Alcohols ā¢ Alcohols are classified by the number of alkyl groups attached to the carbon atom containing the hydroxyl group. The number of alkyl groups impacts the reactivity of the alcohol. ā¢ Primary (1o) alcohols have one alkyl group attached to the alcoholic carbon. ā¢ Secondary (2o) alcohols have two alkyl groups attached to the alcoholic carbon. ā¢ Tertiary (3o) alcohols have three alkyl groups attached to the alcoholic carbon.
12.
Chapter 5 12 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Alcohols ā¢ Monosaccharides contain both primary and secondary alcohols.
13.
Chapter 5 13 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Aldehydes ā¢ An aldehyde is an organic compound containing the carbonyl group. ā¢ Benzaldehyde, a compound responsible for the aroma of almonds and cherries, is one example.
14.
Chapter 5 14 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Aldehydes ā¢ Members of this family always contain a carbonyl group with a hydrogen atom bonded to one side and an alkyl or aromatic bonded to the other. An exception is formaldehyde (a preservative), which has two hydrogens bonded to the carbonyl group.
15.
Chapter 5 15 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Aldehydes ā¢ Monosaccharides can contain an aldehyde group on one end of the molecule in addition to multiple hydroxyl groups.
16.
Chapter 5 16 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Ketones ā¢ A ketone also contains the carbonyl group, but has an alkyl or aromatic group on both sides of the carbonyl group. ā¢ Acetone is the simplest ketone. It is the main component of fingernail polish remover.
17.
Chapter 5 17 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Ketones ā¢ A wide variety of biologically important compounds contain a ketone group. ā¢ Pyruvate is a ketone-containing compound formed during the breakdown of glucose. ā¢ Butanedione, the flavor of butter, contains two ketone groups.
18.
Chapter 5 18 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Monosaccharides that contain an aldehyde group are referred to as an aldose. Those that contain a ketone group are referred to as a ketose. ā¢ Monosaccharides are classified according to the number of carbon atoms. Most common monosaccharides have three to six carbon atoms. ā Triose contains three carbons. ā Tetrose contains four carbons. ā Pentose contains five carbons. ā Hexose contains six carbons.
19.
Chapter 5 19 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Carbohydrates are further classified on whether they contain an aldehyde or ketone group. ā¢ For example, glucose, the most abundant monosaccharide found is nature, contains six carbons and an aldehyde group. It is classified as an aldohexose. ā¢ Fructose, known as fruit sugar, contains six carbons and a ketone group. It is classified as a ketohexose.
20.
Chapter 5 20 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Aldohexose and ketopentose differ in the number of carbon atoms and in the type of carbonyl group they contain.
21.
Chapter 5 21 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Stereochemistry in Monosaccharides Multiple chiral centers ā¢ Recall that a chiral center is a carbon atom that has four different atoms or groups of atoms attached to it. ā¢ Glucose, a ketohexose, contains four different chiral centers, each with a tetrahedral geometry.
22.
Chapter 5 22 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Multiple chiral centers ā¢ Carbons 2 through 5 of glucose are tetrahedral and have four different atoms or groups of atoms attached. Carbons 1 and 6 are not chiral centers. Why?
23.
Chapter 5 23 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Multiple chiral centers ā¢ Groups bonded to each chiral center have two different arrangements or mirror images, which result in stereoisomers. ā¢ The number of stereoisomers for a molecule increases with the number of chiral centers in the molecule. ā¢ The general formula for determining the number of stereoisomers is 2n, where n is the number of chiral centers present in the molecule. ā¢ Glucose has 4 chiral centers, so there are 16 stereoisomers, 24 = 16.
24.
Chapter 5 24 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Representing stereoisomersāthe Fischer projection ā¢ Fischer projection is a simple way of indicating chiral molecules by showing their three- dimensional structure in two dimensions, without showing all the wedges and dashes on all the chiral centers. ā¢ In the Fischer projection, horizontal lines on a chiral center represent wedges, and vertical lines on a chiral center represent dashes.
25.
Chapter 5 25 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Representing stereoisomersāthe Fischer projection ā In the Fischer projection, a chiral carbon is not shown, but is implied at the intersection of lines. ā Consider the Fischer projection of glyceraldehyde, the simplest aldose, shown on the next slide.
26.
Chapter 5 26 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Representing stereoisomersāthe Fischer projection
27.
Chapter 5 27 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Representing stereoisomersāthe Fischer projection ā¢ D and L designations of sugars are based on the Fischer projection positioning in glyceraldehyde. ā¢ All D-sugars have the āOH on the chiral carbon farthest from the carbonyl group on the right side of the molecule. ā¢ All L-sugars have the āOH on the chiral carbon farthest from the carbonyl group on the left side of the molecule. ā¢ Most sugars in nature have the D designation.
28.
Chapter 5 28 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Representing stereoisomersāthe Fischer projection ā¢ Enantiomers are written as if there is a mirror placed between the two molecules. ā¢ Enantiomers of D- and L-glucose are:
29.
Chapter 5 29 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Stereoisomers that are not enantiomers ā¢ How are all stereoisomers of D-glucose related since only one mirror image exists for any stereoisomer? ā¢ Stereoisomers that are not enantiomers are called diastereomers. ā¢ Diastereomers are stereoisomers that are not exact mirror images.
30.
Chapter 5 30 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued
31.
Chapter 5 31 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued Some Important Monosaccharides ā¢ Glucose is the most abundant monosaccharide found in nature. ā¢ Glucose is also known as dextrose, blood sugar, and grape sugar. ā¢ Glucose is broken down in cells to produce energy.
32.
Chapter 5 32 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Diabetics have difficulty getting glucose in their cells, which is why they must monitor their blood glucose levels regularly. ā¢ Glucose is one of the monosaccharides of sucrose (table sugar) and lactose (milk sugar) as well as the polysaccharides glycogen, starch, and cellulose.
33.
Chapter 5 33 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Galactose is found combined with glucose in the disaccharide lactose, which is present in milk and other dairy products. ā¢ A single chiral center (carbon 4) in galactose is arranged opposite that of glucose, which makes it a diastereomer of glucose. ā¢ Diastereomers that differ by one chiral center are called epimers.
34.
Chapter 5 34 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Mannose, a monosaccharide, is found in some fruits and vegetables. ā¢ Cranberries contain high amounts of mannose, which has been shown to be effective in urinary tract infections. ā¢ Mannose is an epimer of glucose.
35.
Chapter 5 35 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Fructose, a ketose, is commonly referred to as fruit sugar or levulose. ā¢ Fructose is combined with glucose to give sucrose, or table sugar. ā¢ Fructose is the sweetest monosaccharide and is found in fruits, vegetables, and honey. ā¢ Fructose is not an epimer of glucose, but it can be broken down for energy in the body.
36.
Chapter 5 36 Ā©
2011 Pearson Education, Inc. 5.2 Monosaccharides, Continued ā¢ Pentoses are five-carbon sugars and include ribose and 2-deoxyribose, which are parts of nucleic acids that make up genetic material. ā¢ Ribonucleic acid (RNA) contains ribose, and deoxyribonucleic acid (DNA) contains 2-deoxyribose. ā¢ The difference between these two pentoses is the absence of an oxygen atom on carbon 2 of deoxyribose. ā¢ Ribose is also found in the vitamin riboflavin and other biologically important molecules.
37.
Chapter 5 37 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions Oxidation and Reduction ā¢ Oxidation and reduction reactions are commonly called redox reactions. ā¢ Oxidation is a loss of electrons. ā¢ Reduction is a gain of electrons. ā¢ The mnemonic āOIL RIGā helps remember redox reactions. Oxidation Is Loss, Reduction Is Gain.
38.
Chapter 5 38 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued ā¢ When copper metal (shiny orange metal) is exposed to oxygen, an ionic compound, copper(II) oxide, is produced. This compound is greenish in color. This reaction is shown as: ā¢ The copper atoms in the reactant lose electrons to form the Cu2+ ions in the product. The copper has undergone oxidation.
39.
Chapter 5 39 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued ā¢ The electrons lost by copper atoms are transferred to the oxygen atom, which then becomes O2-. Oxygen has undergone reduction. ā¢ While the copper was being oxidized, oxygen was being reduced. ā¢ Copper then becomes the reducing agent (causing oxygen to be reduced) and oxygen is the oxidizing agent (causing copper to be oxidized).
40.
Chapter 5 40 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued ā¢ Organic molecules are oxidized if they gain oxygen or lose hydrogen, and they are reduced if they lose oxygen or gain hydrogen. ā¢ Some biological reactions undergo oxidation and reduction. A summary of these characteristics are as follows:
41.
Chapter 5 41 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued Monosaccharides and Redox ā¢ An aldehyde functional group can undergo oxidation by gaining oxygen or it can undergo reduction by gaining hydrogen. ā¢ During oxidation, aldehydes form carboxylic acids, and during reduction, they form alcohols. ā¢ In monosaccharides, oxidation produces a sugar acid, and reduction produces a sugar alcohol.
42.
Chapter 5 42 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued ā¢ Benedictās test is a useful test to determine the presence of an oxidation reaction that occurs with sugars. ā¢ Aldose sugars are oxidized by Cu2+ ion, while the Cu2+ ion is reduced to Cu+ ion.
43.
Chapter 5 43 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued The product of this reaction, copper(I) oxide (Cu2O), is not soluble and forms a brick red precipitate in solution.
44.
Chapter 5 44 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued ā¢ Aldoses are easily oxidized. They serve as reducing agents and are referred to as reducing sugars. ā¢ Fructose and other ketoses are also reducing sugars, even though they do not contain an aldehyde group. ā¢ The oxidizing agents can cause a rearrangement of the ketose to an aldose.
45.
Chapter 5 45 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued This rearrangement can be shown as:
46.
Chapter 5 46 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued ā¢ Benedictās test can be used in urine dipsticks to determine the level of glucose in urine. Excess glucose in urine suggests high levels of glucose in blood, which is an indicator of diabetes. ā¢ Aldoses or ketoses can be reduced by hydrogen under the correct conditions, producing sugar alcohols. ā¢ Sugar alcohols are produced commercially as artificial sweeteners and found in sugar-free foods.
47.
Chapter 5 47 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued Reduction of glucose produces the sugar alcohol, sorbitol, which is an artificial sweetener.
48.
Chapter 5 48 Ā©
2011 Pearson Education, Inc. 5.3 Oxidation and Reduction Reactions, Continued ā¢ When glucose levels are high in the blood stream, sorbitol can be produced by an enzyme called aldose reductase. ā¢ High levels of sorbitol can contribute to cataracts, which is a clouding of the lens in the eye. ā¢ Cataracts are commonly seen in diabetics.
49.
Chapter 5 49 Ā©
2011 Pearson Education, Inc. 5.4 Ring FormationāThe Truth about Monosaccharide Structure ā¢ Carbonyl groups can also react with a hydroxyl functional group (āOH). ā¢ When this happens, a hemiacetal functional group is formed as shown:
50.
Chapter 5 50 Ā©
2011 Pearson Education, Inc. 5.4 Ring FormationāThe Truth about Monosaccharide Structure, Continued A hemiacetal can form within a monosaccharide since it contains both a carbonyl and several hydroxyl functional groups.
51.
Chapter 5 51 Ā©
2011 Pearson Education, Inc. 5.4 Ring FormationāThe Truth about Monosaccharide Structure, Continued ā¢ The carbonyl carbon that reacts to form the hemiacetal is referred to as the anomeric carbon. ā¢ Two ring arrangements can be produced. These are termed anomers, and are referred to as the alpha (ļ”) and beta (Ī²) anomer. ā¢ The position of the āOH group on the anomeric carbon relative to the position of the carbon outside the ring determines the type of anomer present.
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Chapter 5 52 Ā©
2011 Pearson Education, Inc. 5.4 Ring FormationāThe Truth about Monosaccharide Structure, Continued ā¢ In the six-member ring (five carbons and an oxygen) form of D-isomers, called a pyranose, carbon 6 is always drawn on the top side of the ring. ā¢ In the ļ” anomer, the āOH on the anomeric carbon is trans to the carbon outside the ring. ā¢ In the Ī² anomer, the āOH on the anomeric carbon is cis to the carbon outside the ring.
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Chapter 5 53 Ā©
2011 Pearson Education, Inc. 5.4 Ring FormationāThe Truth about Monosaccharide Structure, Continued ā¢ D-Fructose contains both a ketone group and several hydroxyl groups. ā¢ The ring structure of D-fructose contains four carbons and an oxygen to form a five-membered ring called a furanose. ā¢ In a furanose, carbons 1 and 6 remain outside the ring.
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Chapter 5 54 Ā©
2011 Pearson Education, Inc. 5.4 Ring FormationāThe Truth about Monosaccharide Structure, Continued
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Chapter 5 55 Ā©
2011 Pearson Education, Inc. 5.4 Ring FormationāThe Truth about Monosaccharide Structure, Continued ā¢ In a five-membered and six-membered ring, the anomers are distinguished similarly. ā¢ In the alpha anomer, the āOH on the anomeric carbon is trans to the carbon outside the ring. ā¢ In the beta anomer, the āOH on the anomeric carbon is cis to the carbon outside the ring.
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Chapter 5 56 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides Condensation and HydrolysisāForming and Breaking Glycosidic Bonds ā¢ The āOH group that is most reactive in a monosaccharide is the one on the anomeric carbon. ā¢ When this hydroxyl group reacts with another hydroxyl group on another monosaccharide a glycosidic bond is formed.
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Chapter 5 57 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Formation of glycosides is an example of another type of organic reaction. During this reaction, a molecule of water is eliminated as two molecules join.
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Chapter 5 58 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued ā¢ Condensation reaction is a type of reaction that occurs when two molecules are joined and a water molecule is produced. This type of reaction is referred to as a dehydration reaction. ā¢ Hydrolysis reaction is the reverse of a condensation reaction. A larger molecule forms two smaller molecules and water is consumed as a reactant.
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Chapter 5 59 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Condensation reactions occur between different types of functional groups that contain an āH in a polar bond, like OāH or NāH, and an āOH group that can be removed to form water.
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Chapter 5 60 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Naming Glycosidic Bonds ā¢ In the slide showing the formation of maltose, we observed that the glycosidic bond was in the alpha position. If that bond had been in the beta position, a different molecule would have been formed with a different three-dimensional structure. ā¢ In naming glycosidic bonds, it is necessary to name the configuration as well as the carbons involved in the bond formation.
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Chapter 5 61 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued ā¢ In the case of maltose, the glycosidic bond is specified as Ī±(1ā4) and is simply stated as alpha-one-four. ā¢ If the āOH group had been in the beta configuration when the glycosidic bond was formed, the bond would be in the Ī²(1ā4) configuration. The molecule formed would be named cellobiose and would have a different two-dimensional and three-dimensional shape than maltose.
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Chapter 5 62 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued
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Chapter 5 63 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Three Important DisaccharidesāMaltose, Lactose, and Sucrose The formation of these three common disaccharides is outlined below.
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Chapter 5 64 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Maltose ā¢ Maltose is known as malt sugar. ā¢ It is formed by the breakdown of starch. ā¢ Malted barley, a key ingredient in beer, contains high levels of maltose. ā¢ During germination of barley seeds, the starch goes through hydrolysis to form maltose. This process is halted by drying and roasting barley seeds prior to their germination. ā¢ One of the anomeric carbons is free, so maltose is a reducing sugar.
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Chapter 5 65 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Maltose, Continued ā¢ The glycosidic bond is Ī±(1ā4).
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Chapter 5 66 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Lactose ā¢ Lactose is known as milk sugar. ā¢ It is found in milk and milk products. ā¢ An intolerance to lactose can occur in people who inherit or lose the ability to produce the enzyme lactase that hydrolyzes lactose into its monosaccharide units. ā¢ The glycosidic bond is ļ¢(1ā4). ā¢ One of the anomeric carbons is free, so lactose is a reducing sugar.
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Chapter 5 67 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued
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Chapter 5 68 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued Sucrose ā¢ Sucrose is known as table sugar. ā¢ It is the most abundant disaccharide found in nature. ā¢ Sucrose is found in sugar cane and sugar beets. ā¢ The glycosidic bond is ļ¢ (1ā2). ā¢ Both anomeric carbons of the monosaccharides in sucrose are bonded, therefore, sucrose is not a reducing sugar. It will not react with Benedictās reagent.
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Chapter 5 69 Ā©
2011 Pearson Education, Inc. 5.5 Disaccharides, Continued
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Chapter 5 70 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides Polysaccharides Polysaccharides are large molecules of monosaccharides that are connected to each other through their anomeric carbons. There are two types of polysaccharides: 1. Storage polysaccharides contain only ļ” -glucose units. Three important ones are starch, glycogen, and amylopectin. 2. Structural polysaccharides contain only ļ¢-glucose units. Two important ones are cellulose and chitin. Chitin contains a modified ļ¢-glucose unit.
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Chapter 5 71 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued Storage and structural polysaccharides are made up of glucose units, but they are structurally and functionally different because of their glycosidic bonds and difference in branching.
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Chapter 5 72 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued
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Chapter 5 73 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued Storage Polysaccharides Amylose and amylopectināstarch ā¢ Starch is a mixture of amylose and amylopectin and is found in plant foods. ā¢ Amylose makes up 20% of plant starch and is made up of 250ā4000 D-glucose units bonded Ī±(1ā4) in a continuous chain. ā¢ Long chains of amylose tend to coil. ā¢ Amylopectin makes up 80% of plant starch and is made up of D-glucose units connected by Ī±(1ā4) glycosidic bonds.
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Chapter 5 74 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued Amylose and amylopectināstarch ā¢ About every 25 glucose units of amylopectin, a branch of glucose units are connected to the glucose by an Ī±(1ā6) glycosidic bond. ā¢ During fruit ripening, starch undergoes hydrolysis of the Ī±(1ā4) bonds to produce glucose and maltose, which are sweet. ā¢ When we consume starch, our digestive system breaks it down into glucose units for use by our bodies.
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Chapter 5 75 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued
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Chapter 5 76 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued Glycogen ā¢ Glycogen is a storage polysaccharide found in animals. ā¢ Glycogen is stored in the liver and muscles. ā¢ Its structure is identical to amylopectin, except that Ī±(1ā6) branching occurs about every 12 glucose units. ā¢ When glucose is needed, glycogen is hydrolyzed in the liver to glucose.
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Chapter 5 77 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued Structural Polysaccharides Cellulose ā¢ Cellulose contains glucose units bonded ļ¢(1ā4). ā¢ This glycosidic bond configuration changes the three-dimensional shape of cellulose compared with that of amylose. ā¢ The chain of glucose units is straight. This allows chains to align next to each other to form a strong rigid structure.
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Chapter 5 78 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued
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Chapter 5 79 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued Cellulose ā¢ Cellulose is an insoluble fiber in our diet because we lack the enzyme cellulase to hydrolyze the ļ¢(1ā4) glycosidic bond. ā¢ Whole grains are a good source of cellulose. ā¢ Cellulose is important in our diet because it assists with digestive movement in the small and large intestine. ā¢ Some animals and insects can digest cellulose because they contain bacteria that produce cellulase.
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Chapter 5 80 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued Chitin ā¢ Chitin makes up the exoskeleton of insects and crustaceans and cell walls of some fungi. ā¢ It is made up of N-acetylglucosamine containing ļ¢(1ā4) glycosidic bonds. ā¢ It is structurally strong. ā¢ Chitin is used as surgical thread that biodegrades as a wound heals. ā¢ It serves as a protection from water in insects. ā¢ Chitin is also used to waterproof paper, and in cosmetics and lotions to retain moisture.
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Chapter 5 81 Ā©
2011 Pearson Education, Inc. 5.6 Polysaccharides, Continued
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Chapter 5 82 Ā©
2011 Pearson Education, Inc. 5.7 Carbohydrates and Blood ABO Blood Types ā¢ ABO blood types refer to carbohydrates on red blood cells. ā¢ These chemical markers are oligosaccharides that contain either three or four sugar units. ā¢ Sugar units are D-galactose, L-fucose, N-acetylglucosamine, and N-acetylgalactosamine.
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Chapter 5 83 Ā©
2011 Pearson Education, Inc. 5.7 Carbohydrates and Blood, Continued The following shows the carbohydrates and their attachments in type O, type A, and type B blood. Type AB blood has both type A and type B sets on their blood cells.
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Chapter 5 84 Ā©
2011 Pearson Education, Inc. 5.7 Carbohydrates and Blood, Continued ā¢ Type O blood is considered the universal donor while type AB blood is considered the universal acceptor. ā¢ The following table shows the compatibility of blood groups.
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Chapter 5 85 Ā©
2011 Pearson Education, Inc. 5.7 Carbohydrates and Blood, Continued Heparin ā¢ Heparin is a medically important polysaccharide because it prevents clotting in the bloodstream. ā¢ It is a highly ionic polysaccharide of repeating disaccharide units of an oxidized monosaccharide and D-glucosamine. Heparin also contains sulfate groups that are negatively charged. ā¢ It belongs to a group of polysaccharides called glycosaminoglycans.
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Chapter 5 86 Ā©
2011 Pearson Education, Inc. 5.7 Carbohydrates and Blood, Continued
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Chapter 5 87 Ā©
2011 Pearson Education, Inc. Chapter Summary 5.1 Classes of Carbohydrates Carbohydrates are classified as monosaccharides (simple sugars), disaccharides (two monosaccharide units), oligosaccharides (three to nine monosaccharide units), and polysaccharides (many monosaccharide units).
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Chapter 5 88 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.2 Monosaccharides ā¢ A monosaccharide has a molecular formula of Cn(H2O)n, where n = 3ā6. ā¢ Fischer projections that highlight chiral centers are used to represent monosaccharides. ā¢ Most monosaccharides in nature are D-isomers.
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Chapter 5 89 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.2 Monosaccharides, Continued ā¢ Multiple chiral centers lead to enantiomers or diastereomers. ā¢ Important monosaccharides are glucose, galactose, fructose, mannose, ribose, and deoxyribose.
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Chapter 5 90 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.3 Oxidation and Reduction Reactions ā¢ Oxidation is a loss of electrons and reduction is a gain of electrons. ā¢ These are common types of reactions in organic molecules. ā¢ For organic molecules, oxidation is the addition of oxygen and reduction is the addition of hydrogen.
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Chapter 5 91 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.3 Oxidation and Reduction Reactions, Continued ā¢ The anomeric carbon of carbohydrates is highly reactive and can be oxidized to a carboxylic acid or reduced to an alcohol. ā¢ Monosaccharides are considered reducing sugars because their anomeric carbon can react.
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Chapter 5 92 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.4 Ring FormationāThe Truth about Monosaccharide Structure ā¢ A hydroxyl group and the carbonyl group can react to enclose the hydroxylās oxygen in a ring. ā¢ Because the carbonyl group is planar, two possible ring arrangements about the anomeric carbon occur when the ring forms. These are termed the Ī± and ļ¢ anomers.
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Chapter 5 93 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.5 Disaccharides ā¢ Condensation and hydrolysis are common reactions that occur in biomolecules. ā¢ Condensation reactions produce a water molecule while bonding two molecules together. ā¢ Hydrolysis reactions consume a molecule of water while a molecule is broken into two smaller molecules.
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Chapter 5 94 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.5 Disaccharides, Continued ā¢ Carbohydrates form glycosides when an anomeric carbon reacts with a hydroxyl group on a second molecule. The bond formed is called a glycosidic bond. ā¢ Glycosidic bonds are named by designating the anomer of the reacting monosaccharide and the carbons that are bonded, for example, Ī±(1ā4).
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Chapter 5 95 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.6 Polysaccharides ā¢ A polysaccharide consists of many monosaccharide units bonded together through glycosidic bonds. ā¢ Glucose is stored as glycogen in animals and starch in plants. ā¢ Starch consists of amylose, a linear chain of glucose, and amylopectin, a branched chain of glucose.
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Chapter 5 96 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.6 Polysaccharides, Continued ā¢ Glycogen contains many more branches in its structure than amylopectin. ā¢ Two important polysaccharides are cellulose in plants and chitin in arthropods and fungi. ā¢ Cellulose consists of ļ¢(1ā4) and is the structural component of plants. It has a linear structure.
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Chapter 5 97 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.6 Polysaccharides, Continued ā¢ Chitin is linear. It contains N-acetylglucosamine. ā¢ Cellulose and chitin form strong, water-resistant materials when the linear chains are aligned to each other.
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Chapter 5 98 Ā©
2011 Pearson Education, Inc. Chapter Summary, Continued 5.7 Carbohydrates and Blood ā¢ The ABO blood groups are oligosaccharides on the surface of red blood cells. ā¢ The O blood group is considered the universal donor. ā¢ Heparin, a polysaccharide, functions in the blood as an anticoagulant and is found as a coating on medical tubing and syringes during blood transfusions.
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