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Impact Factor Value 3.441 e-ISSN: 2456-3463
International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017
www.ijies.net
18
A Review on Thermal Energy Storage for
Concentrating Solar Power Plants
Junaid Sheikh
Department of Mechanical Engineering, G.H.Raisoni College of Engineering, Nagpur, India
Abstract - Thermal applications are drawing increasing
attention in the solar energy research field, due to their
high performance in energy storage density and energy
conversion efficiency. This paper focuses to provide a
detailed review on solar thermal energy storage especially
for concentrating solar power plants. Thermal energy
storage systems are reviewed on the basis on their designs,
material selection and different thermal storage
technologies. Thermal energy storage for concentrating
solar thermal power (CSP) plants can help in overcoming
the intermittency of the solar resource and also reduce the
levelized cost of energy by utilizing the power block for
extended periods of time.
INTRODUCTION
Solar thermal energy (STE) is a form of energy and a
technology for harnessing solar energy to generate thermal
energy or electrical energy for use in industry, and in the
residential and commercial sectors. Concentrated solar
thermal power (also called concentrating solar power and
CSP) systems use mirrors to concentrate sunlight from a
large area to a small area where it is absorbed and
converted to heat at high temperatures. The high
temperature heat is then used to drive a power block
(usually a steam turbine connected to an electrical power
generator) similar to the power block of a conventional
thermal power plant. In a concentrating solar power (CSP)
system, the sun's rays are reflected onto a receiver, which
creates heat that is used to generate electricity that can be
used immediately or stored for later use. This enables CSP
systems to be flexible, or dispatch able, options for
providing clean, renewable energy. A major advantage of
CSP plants over solar photovoltaic (PV) power plants is
that CSP plants may be coupled with conventional fuels
and can utilize thermal energy storage to overcome the
intermittency of solar energy. TES systems can collect
energy during sunshine hours and store it in order to shift
its delivery to a later time or to smooth out plant output
during cloudy weather conditions. Hence, the operation of
a solar thermal power plant can be extended beyond
periods of no solar radiation without the need to burn fossil
fuels. Energy storage not only reduces the mismatch
between supply and demand but also improves the
performance and reliability of energy systems and plays an
important role in conserving energy [1]. By extending the
hours of usage of the power block beyond the sunshine
hours a thermal energy storage system can reduce the
levelized Cost of Energy for the plant.
2. CRITERIA FOR DESIGN
There are three main aspects that need to be considered in
the design of a solar thermal energy storage system:
technical properties, cost effectiveness and environmental
impact. Excellent technical properties are the key factors to
ensure the technical feasibility of a solar thermal energy
storage system. Firstly, a high thermal storage capacity
(sensible heat, latent heat or chemical energy) is essential
to reduce the system volume and increase the system
efficiency. Secondly, a good heat transfer rate must be
maintained between the heat storage material and heat
transfer fluid, to ensure that thermal energy can be
released/absorbed at the required speed. Thirdly, the
storage material needs to have good stability to avoid
chemical and mechanical degradation after a certain
number of thermal cycles.
3. THERMAL ENERGY STORAGE TECHNOLOGIES
3.1 Two-Tank Direct System
Solar thermal energy in this system is stored in the same
fluid used to collect it. The fluid is stored in two tanks—
Impact Factor Value 3.441 e-ISSN: 2456-3463
International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017
www.ijies.net
19
one at high temperature and the other at low temperature.
Fluid from the low-temperature tank flows through the
solar collector or receiver, where solar energy heats it to a
high temperature, and it then flows to the high-temperature
tank for storage. Fluid from the high-temperature tank
flows through a heat exchanger, where it generates steam
for electricity production. The fluid exits the heat
exchanger at a low temperature and returns to the low-
temperature tank.
Table.1. Important Factors Regarding Design Criteria
Criteria Important factors
Technical
Criteria
ī‚ˇ High thermal energy storage capacity
(the most important)
ī‚ˇ Good mechanical and chemical
stability of storage material
ī‚ˇ Low thermal losses and ease of
control
Cost
Effectiveness
ī‚ˇ The cost of thermal energy storage
materials
ī‚ˇ The cost of the space and/or
enclosure for the thermal energy
storage
Environment ī‚ˇ Operation strategy
ī‚ˇ Maximum load
ī‚ˇ Integration to the power plant
Two-tank direct storage was used in early parabolic trough
power plants (such as Solar Electric Generating Station I)
and at the Solar Two power tower in California. The
trough plants used mineral oil as the heat-transfer and
storage fluid; Solar Two used molten salt as shown in
Fig.1.
3.2. Two-Tank Indirect System
Two-tank indirect systems function in the same way as
two-tank direct systems, except different fluids are used as
the heat-transfer and storage fluids. This system is used in
plants in which the heat-transfer fluid is too expensive or
not suited for use as the storage fluid. The storage fluid
from the low-temperature tank flows through an extra heat
exchanger, where it is heated by the high-temperature heat-
transfer fluid. The high-temperature storage fluid then
flows back to the high-temperature storage tank. The fluid
exits this heat exchanger at a low temperature and returns
to the solar collector or receiver, where it is heated back to
a high temperature. Storage fluid from the high-
temperature tank is used to generate steam in the same
manner as the two-tank direct system. The indirect system
requires an extra heat exchanger, which adds cost to the
system. This system will be used in many of the parabolic
power plants in Spain and has also been proposed for
several U.S. parabolic plants. The plants will use organic
oil as the heat-transfer fluid and molten salt as the storage
fluid.
3.3 Single Tank Thermocline System
Single-tank thermocline systems store thermal energy in a
solid medium—most commonly, silica sand—located in a
single tank. At any time during operation, a portion of the
medium is at high temperature, and a portion is at low
temperature. The hot- and cold-temperature regions are
separated by a temperature gradient or thermocline. High-
temperature heat-transfer fluid flows into the top of the
thermocline and exits the bottom at low temperature. This
process moves the thermocline downward and adds
thermal energy to the system for storage. Reversing the
flow moves the thermocline upward and removes thermal
energy from the system to generate steam and electricity.
Buoyancy effects create thermal stratification of the fluid
within the tank, which helps to stabilize and maintain the
thermocline. Using a solid storage medium and only
needing one tank reduces the cost of this system relative to
two-tank systems. This system was demonstrated at the
Solar One power tower, where steam was used as the heat-
transfer fluid and mineral oil was used as the storage fluid.
4. THERMAL ENERGY STORAGE MATERIALS
The materials used for solar thermal energy storage are
classified into three main categories according to different
storage mechanisms: sensible heat storage, latent heat
storage and chemical heat storage (with their storage
capacity in ascending order)
4.1. Sensible heat storage
Sensible heat storage is achieved by raising the
temperature of a material - liquids such as water, oil-based
liquids, molten salts etc. or solids such as rocks, metals,
and others. The amount of heat stored is a function of the
medium's heat capacity and is linearly dependent on the
temperature increase. The larger the difference between
the high temperature and low temperature system, the
higher is the heat stored by the material. All of the
currently installed thermal energy storage systems in solar
thermal electric plants store energy use sensible heat. The
current systems use two-tanks with either oil or molten
Impact Factor Value 3.441 e-ISSN: 2456-3463
International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017
www.ijies.net
20
salt. Both oil and molten salt systems were found to be
technically feasible. In sensible heat storage, thermal
energy is stored during the rising or dropping of
temperatures of thermal storage media, which can be either
solid state or liquid state.
4.2. Latent heat storage materials
Storage systems based on PCMs can be smaller, more
efficient and provide a lower cost alternative to sensible
thermal storage systems. There have been many studies on
solar TES systems using PCMs of the different forms of
phase change processes, the solid-liquid transition is
efficient in terms of low volumetric expansion compared
to the liquid- gas transition and high latent heat compared
to the solid- solid transition. During phase change, heat is
stored in the medium without an increase in the
temperature. Due to this reason, PCMs can store larger
amounts of heat compared to sensible storage media, for
the same operating temperatures. Several types of PCMs
are available based on the type of application. For
example, for melting ranges between 00C and 2000C,
PCMs such as paraffins, fatty acids, polymers, salt
hydrates and sugar alcohols may be used. For higher
melting temperatures, salts, salt eutectics, high
performance polymers, metal alloys and carbonates are
available. Several methods employed by researchers to
enhance the heat transfer in PCMs include using extended
surfaces, employing multiple PCM’s, thermal conductivity
enhancement using metallic structures, PCM impregnated
foams, dispersion of highly conductive particles and
encapsulation of PCM. Figure shows some methods used
for enhancing the heat transfer in PCM thermal storage
systems. Other problems with using PCMs include super
cooling, large volumetric changes during phase transition
and incongruent melting. Moreover, some of the PCMs
such as salts are corrosive in nature.
4.3 Chemical heat storage materials
Special chemicals can absorb/release a large amount of
thermal energy when they break/form certain chemical
bonds during endothermal/exothermal reactions. Based on
such characteristics, the storage method making use of
chemical heat has been invented. Suitable materials for
chemical heat storage can be organic or inorganic, as long
as their reversible chemical reactions involve
absorbing/releasing a large amount of heat. When
designing a chemical storage system, three basic criteria
need to be considered: excellent chemical reversibility,
large chemical enthalpy change and simple reaction
conditions (reactions cannot be too complicated to be
realised). However, chemical storage has not yet been
extensively researched, and its application is limited due to
the following problems: complicated reactors needed for
specific chemical reactions, weak long-term durability
(reversibility) and chemical stability.
5. CONCLUSION
The review shows that solar energy can be the best
solution in terms of energy generation. Concentrating solar
collectors can play a great role in energy generation.
Various types of thermal solar collector technology have
been reviewed and all types of thermal storage materials
have been discussed. Thermal Energy Storage can not only
overcome the intermittency of solar energy resource, but it
can reduce the LCOE by as much as 20% with the current
costs of TES systems and by more than 30% if the costs of
TES is reduced to $10/kWhth. Ongoing research at USF is
developing a system based on macro-encapsulated PCM,
which has the potential to reduce the cost of thermal
energy storage to less than $15/kWhth. This development
is based on an industrially scalable encapsulation
technique. The process is being optimized in order to
implement it successfully at a large scale.
REFERENCE
1. H. P. Garg, S. C. Mullick, and A. K. Bhargava, Solar
Thermal Energy Storage: Springer, 1985.
2. U. Herrmann, B. Kelly, and H. Price, "Two-tank molten salt
storage for parabolic trough solar power plants," Energy, vol.
29, pp. 883-893, 2004.
3. U. Hermann and D. Kearney, "Survey of Thermal Storage for
Parabolic Trough Power Plants," Journal of Solar Energy
Engineering, Transactions of the ASME, vol. 124, p. 8, 2002.
4. C. Turchi, M. Mehos, C. Ho, and G. Kolb, "Current and
Future Costs for Parabolic Trough and Power Tower Systems
in the US Market," NREL/CP-5500-49303, 2010.
5. D. Y. Goswami, F. Kreith, and J. F. Kreider, Principles of
Solar Engineering: Taylor and Francis, 2000.
6. J. A. Duffie and W. A. Beckman, Solar Energy Thermal
Processes: John Wiley & Sons, Inc., 1989.
7. R.Z. Wang, X.Q. Zhai Development of solar thermal
technologies in China Energy, 35 (2012), pp. 4407-4416
8. D. Laing, C. Bahl, T. Bauer, M. Fiss, N. Breidenbach, and M.
Hempel, "High-Temperature Solid-Media Thermal Energy
Storage for Solar Thermal Power Plants," Proceedings of the
IEEE, vol. PP, pp. 1-9, 2011.
Impact Factor Value 3.441 e-ISSN: 2456-3463
International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017
www.ijies.net
21
Fig.1.Two-Tank Direct system
Fig.2.Two-Tank indirect storage system Fig.3.A single-tank thermocline thermal energy
Impact Factor Value 3.441 e-ISSN: 2456-3463
International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017
www.ijies.net
22
Fig.4.Heat transfer Enhancement procedures employed for various PCMs

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A Review On Thermal Energy Storage For Concentrating Solar Power Plants

  • 1. Impact Factor Value 3.441 e-ISSN: 2456-3463 International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017 www.ijies.net 18 A Review on Thermal Energy Storage for Concentrating Solar Power Plants Junaid Sheikh Department of Mechanical Engineering, G.H.Raisoni College of Engineering, Nagpur, India Abstract - Thermal applications are drawing increasing attention in the solar energy research field, due to their high performance in energy storage density and energy conversion efficiency. This paper focuses to provide a detailed review on solar thermal energy storage especially for concentrating solar power plants. Thermal energy storage systems are reviewed on the basis on their designs, material selection and different thermal storage technologies. Thermal energy storage for concentrating solar thermal power (CSP) plants can help in overcoming the intermittency of the solar resource and also reduce the levelized cost of energy by utilizing the power block for extended periods of time. INTRODUCTION Solar thermal energy (STE) is a form of energy and a technology for harnessing solar energy to generate thermal energy or electrical energy for use in industry, and in the residential and commercial sectors. Concentrated solar thermal power (also called concentrating solar power and CSP) systems use mirrors to concentrate sunlight from a large area to a small area where it is absorbed and converted to heat at high temperatures. The high temperature heat is then used to drive a power block (usually a steam turbine connected to an electrical power generator) similar to the power block of a conventional thermal power plant. In a concentrating solar power (CSP) system, the sun's rays are reflected onto a receiver, which creates heat that is used to generate electricity that can be used immediately or stored for later use. This enables CSP systems to be flexible, or dispatch able, options for providing clean, renewable energy. A major advantage of CSP plants over solar photovoltaic (PV) power plants is that CSP plants may be coupled with conventional fuels and can utilize thermal energy storage to overcome the intermittency of solar energy. TES systems can collect energy during sunshine hours and store it in order to shift its delivery to a later time or to smooth out plant output during cloudy weather conditions. Hence, the operation of a solar thermal power plant can be extended beyond periods of no solar radiation without the need to burn fossil fuels. Energy storage not only reduces the mismatch between supply and demand but also improves the performance and reliability of energy systems and plays an important role in conserving energy [1]. By extending the hours of usage of the power block beyond the sunshine hours a thermal energy storage system can reduce the levelized Cost of Energy for the plant. 2. CRITERIA FOR DESIGN There are three main aspects that need to be considered in the design of a solar thermal energy storage system: technical properties, cost effectiveness and environmental impact. Excellent technical properties are the key factors to ensure the technical feasibility of a solar thermal energy storage system. Firstly, a high thermal storage capacity (sensible heat, latent heat or chemical energy) is essential to reduce the system volume and increase the system efficiency. Secondly, a good heat transfer rate must be maintained between the heat storage material and heat transfer fluid, to ensure that thermal energy can be released/absorbed at the required speed. Thirdly, the storage material needs to have good stability to avoid chemical and mechanical degradation after a certain number of thermal cycles. 3. THERMAL ENERGY STORAGE TECHNOLOGIES 3.1 Two-Tank Direct System Solar thermal energy in this system is stored in the same fluid used to collect it. The fluid is stored in two tanks—
  • 2. Impact Factor Value 3.441 e-ISSN: 2456-3463 International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017 www.ijies.net 19 one at high temperature and the other at low temperature. Fluid from the low-temperature tank flows through the solar collector or receiver, where solar energy heats it to a high temperature, and it then flows to the high-temperature tank for storage. Fluid from the high-temperature tank flows through a heat exchanger, where it generates steam for electricity production. The fluid exits the heat exchanger at a low temperature and returns to the low- temperature tank. Table.1. Important Factors Regarding Design Criteria Criteria Important factors Technical Criteria ī‚ˇ High thermal energy storage capacity (the most important) ī‚ˇ Good mechanical and chemical stability of storage material ī‚ˇ Low thermal losses and ease of control Cost Effectiveness ī‚ˇ The cost of thermal energy storage materials ī‚ˇ The cost of the space and/or enclosure for the thermal energy storage Environment ī‚ˇ Operation strategy ī‚ˇ Maximum load ī‚ˇ Integration to the power plant Two-tank direct storage was used in early parabolic trough power plants (such as Solar Electric Generating Station I) and at the Solar Two power tower in California. The trough plants used mineral oil as the heat-transfer and storage fluid; Solar Two used molten salt as shown in Fig.1. 3.2. Two-Tank Indirect System Two-tank indirect systems function in the same way as two-tank direct systems, except different fluids are used as the heat-transfer and storage fluids. This system is used in plants in which the heat-transfer fluid is too expensive or not suited for use as the storage fluid. The storage fluid from the low-temperature tank flows through an extra heat exchanger, where it is heated by the high-temperature heat- transfer fluid. The high-temperature storage fluid then flows back to the high-temperature storage tank. The fluid exits this heat exchanger at a low temperature and returns to the solar collector or receiver, where it is heated back to a high temperature. Storage fluid from the high- temperature tank is used to generate steam in the same manner as the two-tank direct system. The indirect system requires an extra heat exchanger, which adds cost to the system. This system will be used in many of the parabolic power plants in Spain and has also been proposed for several U.S. parabolic plants. The plants will use organic oil as the heat-transfer fluid and molten salt as the storage fluid. 3.3 Single Tank Thermocline System Single-tank thermocline systems store thermal energy in a solid medium—most commonly, silica sand—located in a single tank. At any time during operation, a portion of the medium is at high temperature, and a portion is at low temperature. The hot- and cold-temperature regions are separated by a temperature gradient or thermocline. High- temperature heat-transfer fluid flows into the top of the thermocline and exits the bottom at low temperature. This process moves the thermocline downward and adds thermal energy to the system for storage. Reversing the flow moves the thermocline upward and removes thermal energy from the system to generate steam and electricity. Buoyancy effects create thermal stratification of the fluid within the tank, which helps to stabilize and maintain the thermocline. Using a solid storage medium and only needing one tank reduces the cost of this system relative to two-tank systems. This system was demonstrated at the Solar One power tower, where steam was used as the heat- transfer fluid and mineral oil was used as the storage fluid. 4. THERMAL ENERGY STORAGE MATERIALS The materials used for solar thermal energy storage are classified into three main categories according to different storage mechanisms: sensible heat storage, latent heat storage and chemical heat storage (with their storage capacity in ascending order) 4.1. Sensible heat storage Sensible heat storage is achieved by raising the temperature of a material - liquids such as water, oil-based liquids, molten salts etc. or solids such as rocks, metals, and others. The amount of heat stored is a function of the medium's heat capacity and is linearly dependent on the temperature increase. The larger the difference between the high temperature and low temperature system, the higher is the heat stored by the material. All of the currently installed thermal energy storage systems in solar thermal electric plants store energy use sensible heat. The current systems use two-tanks with either oil or molten
  • 3. Impact Factor Value 3.441 e-ISSN: 2456-3463 International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017 www.ijies.net 20 salt. Both oil and molten salt systems were found to be technically feasible. In sensible heat storage, thermal energy is stored during the rising or dropping of temperatures of thermal storage media, which can be either solid state or liquid state. 4.2. Latent heat storage materials Storage systems based on PCMs can be smaller, more efficient and provide a lower cost alternative to sensible thermal storage systems. There have been many studies on solar TES systems using PCMs of the different forms of phase change processes, the solid-liquid transition is efficient in terms of low volumetric expansion compared to the liquid- gas transition and high latent heat compared to the solid- solid transition. During phase change, heat is stored in the medium without an increase in the temperature. Due to this reason, PCMs can store larger amounts of heat compared to sensible storage media, for the same operating temperatures. Several types of PCMs are available based on the type of application. For example, for melting ranges between 00C and 2000C, PCMs such as paraffins, fatty acids, polymers, salt hydrates and sugar alcohols may be used. For higher melting temperatures, salts, salt eutectics, high performance polymers, metal alloys and carbonates are available. Several methods employed by researchers to enhance the heat transfer in PCMs include using extended surfaces, employing multiple PCM’s, thermal conductivity enhancement using metallic structures, PCM impregnated foams, dispersion of highly conductive particles and encapsulation of PCM. Figure shows some methods used for enhancing the heat transfer in PCM thermal storage systems. Other problems with using PCMs include super cooling, large volumetric changes during phase transition and incongruent melting. Moreover, some of the PCMs such as salts are corrosive in nature. 4.3 Chemical heat storage materials Special chemicals can absorb/release a large amount of thermal energy when they break/form certain chemical bonds during endothermal/exothermal reactions. Based on such characteristics, the storage method making use of chemical heat has been invented. Suitable materials for chemical heat storage can be organic or inorganic, as long as their reversible chemical reactions involve absorbing/releasing a large amount of heat. When designing a chemical storage system, three basic criteria need to be considered: excellent chemical reversibility, large chemical enthalpy change and simple reaction conditions (reactions cannot be too complicated to be realised). However, chemical storage has not yet been extensively researched, and its application is limited due to the following problems: complicated reactors needed for specific chemical reactions, weak long-term durability (reversibility) and chemical stability. 5. CONCLUSION The review shows that solar energy can be the best solution in terms of energy generation. Concentrating solar collectors can play a great role in energy generation. Various types of thermal solar collector technology have been reviewed and all types of thermal storage materials have been discussed. Thermal Energy Storage can not only overcome the intermittency of solar energy resource, but it can reduce the LCOE by as much as 20% with the current costs of TES systems and by more than 30% if the costs of TES is reduced to $10/kWhth. Ongoing research at USF is developing a system based on macro-encapsulated PCM, which has the potential to reduce the cost of thermal energy storage to less than $15/kWhth. This development is based on an industrially scalable encapsulation technique. The process is being optimized in order to implement it successfully at a large scale. REFERENCE 1. H. P. Garg, S. C. Mullick, and A. K. Bhargava, Solar Thermal Energy Storage: Springer, 1985. 2. U. Herrmann, B. Kelly, and H. Price, "Two-tank molten salt storage for parabolic trough solar power plants," Energy, vol. 29, pp. 883-893, 2004. 3. U. Hermann and D. Kearney, "Survey of Thermal Storage for Parabolic Trough Power Plants," Journal of Solar Energy Engineering, Transactions of the ASME, vol. 124, p. 8, 2002. 4. C. Turchi, M. Mehos, C. Ho, and G. Kolb, "Current and Future Costs for Parabolic Trough and Power Tower Systems in the US Market," NREL/CP-5500-49303, 2010. 5. D. Y. Goswami, F. Kreith, and J. F. Kreider, Principles of Solar Engineering: Taylor and Francis, 2000. 6. J. A. Duffie and W. A. Beckman, Solar Energy Thermal Processes: John Wiley & Sons, Inc., 1989. 7. R.Z. Wang, X.Q. Zhai Development of solar thermal technologies in China Energy, 35 (2012), pp. 4407-4416 8. D. Laing, C. Bahl, T. Bauer, M. Fiss, N. Breidenbach, and M. Hempel, "High-Temperature Solid-Media Thermal Energy Storage for Solar Thermal Power Plants," Proceedings of the IEEE, vol. PP, pp. 1-9, 2011.
  • 4. Impact Factor Value 3.441 e-ISSN: 2456-3463 International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017 www.ijies.net 21 Fig.1.Two-Tank Direct system Fig.2.Two-Tank indirect storage system Fig.3.A single-tank thermocline thermal energy
  • 5. Impact Factor Value 3.441 e-ISSN: 2456-3463 International Journal of Innovations in Engineering and Science, Vol. 2, No.10, 2017 www.ijies.net 22 Fig.4.Heat transfer Enhancement procedures employed for various PCMs