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Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36
Copyright© Faculty of Engineering, University of Maiduguri, Nigeria.
Print ISSN: 1596-2490, Electronic ISSN: 2545-5818
www.azojete.com.ng
MOISTURE-DEPENDENT PHYSICAL PROPERTIES OF ÀBÈÈRÈ (PICRALIMA
NITIDA) SEEDS
Aremu, A. K*. and Duduyemi, A. S.
(Department of Agricultural and Environmental Engineering, University of Ibadan, Ibadan,
Nigeria)
*Corresponding author’s email and phone no: ademolaomooroye@gmail.com,
+2348023843272
Abstract
Some relevant engineering properties of Àbèèrè (Picralima nitida) seeds are needed for the design of its
processing equipments. The geometric, gravimetric and frictional properties of Àbèèrè seed in the moisture
content ranges of 7.98% - 47.77% (wb) were investigated. The average length, width, thickness, arithmetic and
geometric mean diameters, sphericity, surface area, volume, true and bulk densities and angles of repose
increased from 28.76 – 30.75mm, 16.18 – 19.62mm, 5.75 – 7.15mm, 16.90 – 19.17mm, 13.81 – 16.11mm,0.48
– 0.53, 600.94 – 817.83mm2
, 443.00 – 717.92mm3
, 2.49×10-3
– 2.60×10-3
g/mm3
, 1.14×10-3
– 1.50×10-
3
g/mm3
and 27.97o
– 30.26o
respectively as the moisture content increased from 7.98% to 47.77%. However,
values for porosity decreased from 0.54 – 0.42. The static coefficient of friction of Àbèèrè increased linearly
over the three material surfaces – plywood, stainless steel and glass – with increasing moisture content from
0.445 – 0.468, 0.286 – 0.384 and 0.357 – 0.389 respectively. The steel surface had the lowest static coefficient
of friction whereas the plywood gave the highest value at all moisture content levels. The regression models
developed for all the physical properties of the seeds had high coefficient of determination, R2
.
Key words: Àbèèrè, physical properties, moisture content, angle of repose, coefficient of
friction, porosity.
1. Introduction
Picralima nitida, family Apocynaceae, (Common name: Akuamma plant; Igbo: Osi-Igwe;
Yoruba: Àbèèrè) grows as either a shrub or small tree up to 22 m tall, with a trunk diameter
of up to 16 inches. The tree of this plant grows for about 3 to 4 years before it starts bearing
fruits. Its flowers feature a white, creamy or pale yellow corolla. Its fruit is yellow and
smooth. Its numerous local medicinal uses include for fever, leprosy sores, stomach, and liver
problems and as an anthelmintic, especially against internal worms (Schmelzer and
Wageningen, 2008).
It has Berries which have an ellipsoid form, with large size and green in color. When the
fruits (berries) mature on the tree, they often fall on the ground and the green pigment on the
fruit turns to yellow which will initiate the germination of the seeds in the fruit. Although the
berries drop to the ground after maturity, some berries can also ripen on the tree. These
berries are also used in traditional medicines for treating typhoid and fight against muscular
pain (Oyebadejo et al., 2014). Inside the berries are seeds (Figure 1). The seed is an object of
commerce in the local market, and it is collected from the wild thus its availability has been
severely threatened.
Dry seeds of the plant, Picralima nitida K. Schum, are highly valued in African traditional
medicine in the treatment of various human diseases, including diabetes mellitus and obesity
(Adeneye and Adeyemi, 2009a; 2009b). The phytochemical analysis of the “Àbèèrè” seed
revealed the presence of saponins, steroids, tannins, volatile oils, phenols and copious amount
of alkaloids (Falodun et al., 2006).
Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36
25
The proximate composition of the Picralima nitida seed revealed that the seed contains crude
fat content (5.02%), crude protein content (10.20%), ash content (0.88%), crude fibre
(5.64%) and moisture content (3.73%) respectively. The seed is a rich source of carbohydrate
which was 74.53%. The physicochemical properties of the oil of Picralima nitida seed
revealed that the oil is brownish in colour and liquid at room temperature. The free fatty acid
content was 1.41%. The iodine value which indicates the degree of unsaturation was
found to be 136.40 while the refractive index was 1.45. The saponification value was
198.25mg KOH/g. The peroxide value and Unsaponifiable matter were 4.59meqO2/kg Oil
and 1.90%, respectively (Adebowale et al., 2012).
Figure 1: Fresh Àbèèrè Seeds
Despite the widespread abundance and traditional use of Picralima nitida seeds and with the
several research works that have been done on the chemical, phytochemical and
toxicological composition of “Àbèèrè” seed (Picralima nitida) as reported by Falodun et al.
(2014), review of literatures showed that there is no information relating to the effect of
moisture on the engineering properties of the seed.
Presently, the post-harvest handling processes include unit operations such as manual sorting
of seeds, manual decorticating of seeds and manual grounding of the dried seeds. The seeds
are extracted manually by breaking/cutting the fresh fruit with cutlass and allowing the pulp-
covered seed to macerate and washing off in water. Alternatively, the fruits are allowed to
decay and then washed off in water using basket, to extract the seeds. The seeds are ground
with stone or by pounding in a mortar using wooden pestle. Also, the seeds are being stored
using locally woven baskets. These methods of handling and processing seeds are not only
time and energy consuming, but also inefficient as the usage of manual labour throughout the
processing chain decreases the production efficiency on the farm and sometimes results into
wastage of product. This present study is focused on investigating the physical properties of
“Àbèèrè” (Picralima nitida) seeds (axial dimensions, mean diameters, sphericity, surface
area, seed mass, bulk density, true density, porosity, angle of repose, and static coefficient of
friction) at different moisture levels for design and improvement of relevant machines and
Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11:
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26
facilities for harvesting, storing, handling, processing and packaging. These parameters are
important for the design and fabrication of the equipment involved in processes such as seed
decorticating and seed oil extraction.
2. Materials and Methods
A bulk quantity of Picralima nitida seeds were purchased from a farm in Ile-Ife, Osun State,
Nigeria and stored in a laboratory at room temperature before carrying out the experiment.
The seeds were cleaned to remove all foreign materials such as dirt, dust, stone and chaff as
well as immature and damaged seeds while they were identified at the Department of
Botany’s Herbarium, University of Ibadan, Ibadan, Oyo State, Nigeria. The following
methods were used in the determination of some physical properties of Àbèèrè seeds
(Picralima nitida).
The moisture content of the Picralima nitida seeds were obtained according to ASAE
Standard S352.3 (1994) by drying the seeds in an electric oven at a temperature of 105(±2)°C
for 24 hours until there was no change in the seeds’ mass at the Department of Animal
Science, University of Ibadan, Ibadan, Oyo State and weighing the samples using a digital
weighing balance (AND Ek-6100i) reading to 0.01 g. The moisture content of the seeds was
varied at five major levels.
The moisture content of the sample in percentage wet basis was calculated using the equation
shown below.
(1)
where: Ms is the Moisture content of the seeds (%wb), Wi is the Initial Mass (in grams) and
Wf is the Final Mass after oven drying (in grams).
A method for adjusting the seed’s moisture content without damaging its morphology was
developed to prepare samples for subsequent tests. After it was soaked in water for 2, 3, 5, 7
and 10 hours, the samples were wrapped in a foil paper and kept in a refrigerator at 5 ˚C (±2
˚C) for 5 days for the moisture to distribute uniformly throughout the seed (Obi et al., 2014).
The moisture content of samples after equilibration was determined before each test was
conducted. Accordingly, moisture levels of 7.98, 17.98, 25.11, 37.77 and 47.77% w.b. were
obtained. For each test the required quantity of seeds were taken out and allowed to
equilibrate with the room temperature. Every test was repeated five times to determine the
mean values.
2.1 Determination of size and shape
Fifty Àbèèrè (Picralima nitida) seeds were randomly selected for each of the moisture
content considered and labelled for easy identification. The linear dimensions of the Àbèèrè
seeds were determined by using a digital Vernier caliper (Carrera Precision Instrument,
reading to 0.01 mm) to measure the length, thickness and width of the fruit denoted as L, T
and W (all in mm) respectively.
Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36
27
2.2 Determination of Mean Diameters
The Arithmetic Mean Diameter (mm), Da, and Geometric Mean diameter (mm), Dm, were
calculated using equations 2 and 3 respectively..
(2)
√ (3)
The surface area S in mm2
was estimated by the relationship given by Asoiro and Anthony
(2011) as described by Ajav and Ogunlade (2014):
(4)
2.3 Determination of Sphericity
The sphericity is defined as the ratio of the surface area of a sphere with the same volume as
the seed to the surface area of the seed (Mohsenin, 1986). The degree of sphericity of the
seeds was calculated using equation 5 below as described by Adejumo and Abayomi, (2012).
⁄
(5)
where: Φ is the Sphericity in decimal and other parameters remain as defined above.
2.4 Determination of Densities
The true density of a seed is defined as a ratio of the mass of a sample of a seed to solid
volume occupied by the sample (Mohsenin, 1986). The true density of the fruit was
determined by weighing the mass of the fruit using a digital weighing balance reading (AND
Ek-6100i) to 0.01 g, while its volume was determined by water displacement method (Aremu
and Fadele, 2011). The water displacement method was used having ascertained that it takes
longer period of time for water to penetrate through the seeds (Obasi et al., 2012). The true
density was evaluated by finding the ratio of the true mass to that of the volume.
The bulk density (kg/m3
) is the ratio of mass of a sample of the seeds to its total volume
(Mohsenin, 1986). It was determined by filling an empty 250 ml graduated glass cylinder
with seeds from a height of about 18 cm, striking the top level and then weighing the
contents. The weight of the seeds was obtained by subtracting the weight of the cylinder from
the weight of the cylinder with seeds. The volume occupied was then noted (Theertha et al.,
2014). The process is replicated five times and the average bulk density for each replication
was calculated.
2.5 Determination of Porosity
The porosity of the Àbèèrè seeds was estimated from its bulk and true densities using the
relationship in equation (6) according to Mohsenin (1986).
⁄ (6)
where: ρb and ρt are bulk and true densities (all in kgm-3
) respectively
2.6 Determination of Static Coefficient of Friction
The static coefficient of friction was determined with the following three structural materials
on the tilting table: stainless steel, plywood and glass. The Picralima nitida seeds were placed
Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11:
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28
parallel to the direction of motion and the table is raised gently by a screw device (Olaoye,
2000). The angle at which the seeds begin to slide (i.e. angle of inclination) was read from a
graduated scale on the tilting table for the three structural materials. The coefficient of
friction was calculated as the tangent of this angle as shown in equation 7 below as reported
by Ajav and Ogunlade (2014).
(7)
where: μ is the static coefficient of friction (decimal), is the angle of Inclination (degrees).
2.7 Determination of Angle of Repose
The filling angle of repose of the seeds , , which is the angle with the horizontal at which
the seeds will stand when piled was determined using a topless and bottomless paper cylinder
of 15cm diameter and 25cm height as described by Obi et al. (2014). The cylinder was placed
at the center of a raised circular plate having a diameter of 35cm and filled with the seeds.
The cylinder was raised slowly until the seeds formed a cone on the circular plate. The angle
of repose was calculated from the measurements of the height (H) of the cone formed by the
seeds and the Diameter (D) of the cone using the relationship below:
(8)
where: f is the angle of repose (degrees), H is the Height of the cone formed by the seeds
and D is the diameter of the cone.
2.8 Statistical Analysis
Descriptive statistics were used to analyze the data obtained for each of the properties studied
at different moisture content level using Microsoft Excel 2010. Predictive models were
developed to establish relationship between the physical properties and moisture content
using regression analysis. Analysis of Variance (ANOVA) was used to evaluate the
significant effect of moisture content on the properties of the seed.
3. RESULTS AND DISCUSSION
The mean axial dimensions, arithmetic and geometric mean diameters, sphericity, surface
area, volume, densities, porosity and angles of repose of Àbèèrè seeds samples at five
different moisture content levels of 7.98, 17.98, 25.11, 37.77 and 47.77% (wb) are presented
in Tables 1a and 1b while the coefficient of static friction of on three different surfaces are
shown in Table 1c. Generally, it was observed that the values recorded for most of the
physical properties studied increased with increasing moisture content from 7.98 – 47.77%
(wb).
3.1 Àbèèrè Seeds Dimensions
Average values of the three principal dimensions of the seeds, namely length, width and
thickness, determined in this study at different moisture contents are presented in Table 1a.
Each principal dimension increased as the moisture content increased. This could be due to
the fact that upon moisture absorption, the grains expanded in length, width and thickness. It
was observed that within the moisture content range 7.98% wet basis to 47.77% wet basis,
the average length of Àbèèrè seeds increased from (28.76±1.82) mm to (30.75±2.71)mm (7%
increase in length), the width increased from (16.18±2.30)mm to (19.62±1.62)mm (21%
Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36
29
increase in width), the thickness increased from (5.75±0.75)mm to (7.15±0.73)mm (24%
increase in thickness). Similar trends were reported by Altuntas and Erkol, (2010) for shelled
and kernel walnuts and Altuntas (2014) for Juniper berries. However, the relationship
between the axial dimensions of Àbèèrè seeds and the moisture content in wet basis are given
by equations 9, 10 and 11:
L = 5.017Mc + 28.335 (R2
= 0.998) (9)
W = 8.859Mc + 15.126 (R2
= 0.918) (10)
T = 3.457Mc + 5.575 (R2
= 0.953) (11)
Table 1a: Some geometric properties of Àbèèrè seeds at five moisture contents
M. C.
(%wb)
Length
(mm)
Width
(mm)
Thickness
(mm)
Arithmetic
Mean
Diameter
(mm)
Geometric
Mean
Diameter
(mm)
Sphericity
7.98 28.76
(1.82)
16.18
(2.30)
5.75
(0.76) 16.90 (0.81) 13.81 (0.81)
0.46
(0.04)
17.98 29.24
(2.19)
16.72
(1.97)
6.20
(0.75) 17.38 (0.85) 14.09 (0.93)
0.47
(0.05)
25.11 29.55
(2.21)
16.74
(1.40)
6.62
(0.67) 17.63 (0.96) 13.95 (0.95)
0.48
(0.04)
37.77 30.23
(2.54)
18.47
(2.12)
6.88
(0.69) 18.52 (0.96) 15.27 (0.86)
0.51
(0.03)
47.77 30.75
(2.71)
19.62
(1.62)
7.15
(0.73) 19.17 (0.94) 16.11 (0.81)
0.53
(0.05)
Standard deviation values are in parentheses.
Table 1b: Some gravimetric properties of Àbèèrè seeds at five moisture contents
M. C.
(%wb)
Surface Area
(mm2
)
Volume
(mm3
)
True
Density
(x10-
3
g/mm3
)
Bulk
Density
(x10-
3
g/mm3
)
Porosity Angle
of
Repose
7.98 600.94
(69.19)
443.00
(75.20)
2.49 (0.88) 1.14
0.54
(0.14)
27.97
17.98 623.48
(59.98)
506.86
(73.12) 2.53 (0.65) 1.27
0.50
(0.13)
28.40
25.11 614.30
(83.86)
546.58
(87.39)
2.59 (0.53) 1.48
0.43
(0.11)
28.54
37.77 732.58
(79.85)
644.28
(98.78) 2.63 (0.40) 1.48
0.44
(0.12)
29.56
47.77 817.83
(80.56)
717.92
(102.06)
2.60 (0.47) 1.50
0.42
(0.10)
30.26
Standard deviation values are in parentheses.
Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11:
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30
Table 1c: Coefficient of friction of Àbèèrè seeds at five moisture contents
M. C. (%wb) Coefficient of Friction
Stainless Steel Glass Wood
7.98 0.286 (0.024) 0.357 (0.022) 0.445 (0.021)
17.98 0.320 (0.021) 0.365 (0.026) 0.435 (0.032)
25.11 0.370 (0.070) 0.374 (0.026) 0.440 (0.043)
37.77 0.376 (0.067) 0.376 (0.029) 0.452 (0.039)
47.77 0.384 (0.058) 0.389 (0.031) 0.468 (0.034)
Standard deviation values are in parentheses
The ANOVA results presented in Table 2 showed that there were no significant differences
(p<0.05) in the means of length, width, Geometric Mean Diameters and Sphericity of the
seeds across the different moisture contents studied. However, it was revealed that moisture
content had significant effect (p<0.05) on the thickness and arithmetic mean diameter. This
may be due to the fact that the seeds have absorbed enough moisture to cause significant
difference in the thickness of the seeds. Thus, the change in moisture content of the seeds will
invariably have effect on the thickness of the seeds.
Table 2: ANOVA results or the axial dimensions of Àbèèrè seeds at five different moisture
contents
M.C. Length
(mm)
Width
(mm)
Thickness
(mm)
AMD
(mm)
GMD
(mm)
Sphericity
7.98 28.76a
16.18a
5.75a
16.90a
13.81a
0.48a
17.98 29.24a
16.72a
6.20b
17.38b
14.09a
0.47a
25.11 29.55a
16.74a
6.62b
17.63b
13.95a
0.47a
37.77 30.23b
18.47b
6.88c
18.52c
15.27b
0.51b
47.77 30.75b
19.62b
7.15c
19.17c
16.11b
0.53b
*Means with same letter(s) across columns are not significantly different at p<0.05
3.2 Mean Diameters
The average arithmetic and geometric mean diameters are presented in Table 1a. The mean
values recorded increased from 16.90 to 19.17 mm and 13.81 to 16.11 mm for the arithmetic
and geometric mean diameters respectively as the moisture content increased from 7.98 –
47.77% (wb). It was observed that within the moisture content range, the average arithmetic
and geometric increase was 13.41% and 16.65% respectively. This may due to the fact that
the Abeere seed expanded more in thickness (24% increase) and width (21% increase) in
comparison with the length (7% increase). Such behavior was observed by Sacilik et al.
(2003) for hemp seed and Shafiee et al. (2009) for Dragon’s head seeds.
These properties are particularly important in the design of harvesting, threshing and
separating machines (Milani et al., 2007 and Gharibzahedi et al., 2011). However, the
relationship between the Arithmetic (Da) and Geometric (Dg) Mean Diameters with the
Moisture Content (Mc) appeared linear as shown in equations 12 and 13:
Da = 5.762Mc + 16.347 (R2
= 0.985) (12)
Dg = 5.977Mc + 13.012 (R2
= 0.856) (13)
Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36
31
3.3 Sphericity
The average values of the sphericity at the five moisture levels are as presented in Table 1a.
The sphericity of the seeds initially decreased from 0.48 to 0.47 as the moisture content
increased from 7.98% to 17.98%. However, the sphericity of the seeds increased from 0.47 to
0.53 as the moisture content increased from 25.11% to 47.77% (wb). This is due to the
differential dimensional changes in the three axial dimensions. The sphericity of Picralima
nitida seeds were observed to be lower than that of Garcinia kola seed (Igbozulike and
Aremu, 2009).
Aremu and Fadele, (2011) reported that the closer the sphericity to 1.0, the higher the
tendency of the fruit to roll about any of the three axes and the closer the ratio of thickness to
width to 1.0, the higher the tendency to rotate about the major axis. Thus, the values obtained
for the sphericity indicates the possibility of the Àbèèrè seeds not to roll relatively well but
slide where necessary. The sphericity of the seeds has a linear relationship with the moisture
content as shown in equation 14.
Φ = 0.0018Mc + 0.4401 (R² = 0.9709) (14)
Where: Φ= Sphericity; Mc = Moisture Content
Similar trends have been reported by Ndukwu (2009) for Brachystegia eurycoma seeds,
Aydin et al. (2002) for Turkish mahaleb, Sahoo and Srivastava (2002) for okra seed, Sacilik
et al., (2003) for hemp seed, (Coskuner and Karababa, 2007) for flaxseed and Altuntas et al.
(2005) for fenugreek seed.
3.4 Surface Area and Volume
Surface area of the seed has increased with increase in moisture content as shown in Table1b.
The surface area increased from (600.94±69.19) mm2
to (817.83±80.56) mm2
as moisture
content increases from 7.98% to 47.77%. Similar results were presented by Adejumo and
Abayomi, (2012) for unshelled Moringa oleifera seed, Obi et al. (2014) for Pigeon Pea
grown in Nigeria and in reports by Sacilik et al. (2003) and Baryeh (2002) for hemp seed and
millet, respectively. The surface area affects the rate of moisture loss during drying of seeds,
grains and other particulate materials.
The volume also increased from (443±75.20) mm3
to (717.92±102.06) mm3
as moisture
content increases from 7.98% to 47.77% indicating that the volume-moisture relationship was
linear as shown in Table 1b. The volumetric expansion observed may be adduced to moisture
absorption which increases the axial dimensions of the grain. The values of the surface area
(SA) and volume (V) bear the following relationship with the Moisture Content (Mc) as
described by the regression equations 15 and 16.
SA = 5.606Mc + 524.65 (R² = 0.878) (15)
V = 694.35Mc + 382.02 (R2
= 0.997) (16)
3.5 True and Bulk Density
The relationship between the true density and moisture content was almost completely linear.
The average true density of Àbèèrè seeds increased from 2.49x10-3
g/mm3
to 2.60x10-3
g/mm3
Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11:
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32
as moisture content increased from 7.98% to 47.77% wet basis as shown in Table 1b. A
decrease in true density was observed as moisture content increased from 37.77% to 47.77%.
This decrease was mainly due to the larger increase in the volume of the grain compared to
the lesser increase in the grain mass. A similar trend was reported by Bande et al. (2012) for
Melon (Citrullus colocynthis) seeds. The result of the true density shows that the seed is
heavier than water and as such will sink in water. This is useful in the design of cleaning and
separation machines to remove chaffs and other materials that can float in water. The true
density of Àbèèrè seeds is higher than that of Melon seeds (Bande et al., 2012) and higher
than that reported for Moringa oleifera seed (Adejumo and Abayomi, 2012).
As observed from Table 1b, the bulk density of Àbèèrè seeds increased with the moisture
content from 1.14x10-3
g/mm3
at 7.98% to 1.50x10-3
g/mm3
at 47.77%. This pattern was
similarly reported by Bande et al. (2012) for melon seeds and kernels. The knowledge of bulk
density is important in the handling of the seeds in terms of determining the amount and
strength of packaging for the seeds.
However, the relationship observed between values of True Density (TD) and Bulk Density
(BD) and the percent moisture content (Mc) of Àbèèrè seeds in wet basis are given by
equations 17 and 18:
TD×10-3
= 0.0031Mc + 2.4809 (R² = 0.767) (17)
BD×10-3
= 0.009Mc + 1.128 (R² = 0.775) (18)
3.6 Porosity
The porosity of the seeds calculated from the relevant experimental data decreased as shown
in Table 1b. The decrease in porosity with increase in moisture content is because an increase
in moisture content results in a more significant increase/swelling of the linear dimensions
thus reducing the airspaces and giving a more compact arrangement of the seeds invariably
reducing the porosity of the seed bulk. Altuntas and Erkol (2010) reported the same trend for
shelled and kernel walnuts and Adejumo and Abayomi, (2012) reported the same trend for
Moringa oleifera seed. However, the values of porosity for Àbèèrè seeds fall within the same
range of values obtained for Melon (Bande et al., 2012).
The porosity is the most important factor for packing and it affects the resistance to airflow
through bulk seeds. The linear relationship between porosity (P) and moisture content is
revealed below.
P = -0.0029Mc + 0.5444 (R2
= 0.760) (19)
3.7 Angle of Repose
The filling angle of repose increased with increase in moisture content of the abeere seeds.
The mean values of the filling angle of repose was found to increase from 27.97o
to 30.26o
as
the moisture content increases from 7.98% to 47.77% w.b (Table 1b). This increasing trend
of the filling angle of repose could be attributed to the surface tension caused by the layer of
Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36
33
moisture surrounding the seeds. This trend was similarly reported by Ahmadi et al., (2009)
for Fennel Seed (Foeniculum vulgare)
The values of the angle of repose (AOR) bear the following relationship with the Moisture
Content (Mc) as described by the regression equation below.
AOR = 5.851Mc + 27.346 (R² = 0.960) (20)
Singh and Goswami (1996), Nimkar and Chattopadhyay (2001), Baryeh (2002), Amin et al.
(2004) and Altuntas et al. (2005) also reported a linear increase in angle of repose with
increase in the moisture content for cumin seed, green gram, millet, lentil and fenugreek,
respectively.
3.8 Coefficient of Friction
It was observed that the coefficient of friction of the abeere seeds increased with an increase
in moisture content on all the three surfaces studied - plywood, Stainless Steel and glass. The
increase in coefficient of friction with an increase in moisture content on all surfaces could be
attributed to the increased adhesion between the seed and all the material surfaces at higher
moisture content as well as due to the increase in the size of the seed as reported by Obi et al.
(2014). The coefficient of friction increased from 0.286 to 0.384, 0.357 to 0.389 and 0.445 to
0.468 for stainless steel, glass and plywood respectively as shown in Table 1c. It was
however observed that the highest coefficient of friction of the abeere seeds was obtained on
plywood and least on glass and stainless steel. Ajav and Ogunlade, (2014) reported that the
least static coefficient of friction may be owing to smoother and more polished surface of the
glass and stainless steel than the other material used. Altuntas and Erkol, (2010) and Ajav and
Ogunlade, (2014) reported the same trend that coefficient of friction increases as the moisture
content increase for shelled and kernel walnuts and Ginger (Zingiber officinale) respectively.
However, the values of the Coefficient of Friction (COF) on all the three surfaces bear the
following relationship with the Moisture Content (Mc) as described by the regression
equations 21, 22 and 23.
COFwood = 0.0007Mc + 0.4303 (R² = 0.643) (21)
COFglass = 0.0007Mc + 0.3518 (R2
= 0.947) (22)
COFsteel = 0.0025Mc + 0.2801 (R² = 0.834) (23)
4. Conclusion
The results showed that the principal dimensions of the seeds increased with respect to
moisture content. However, the true density of the seeds does not have a linear relationship
with moisture content. The bulk density and filling angle of repose of the seeds however
increased with increased in moisture content. The porosity of the seeds decreased with
increase in moisture content. Although, the coefficient of friction of the Àbèèrè seeds
increased with an increase in moisture content on all the three surfaces studied, it was
however observed that the highest coefficient of friction of the Àbèèrè seeds was obtained on
Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11:
24-36
34
wood and least on glass and stainless steel. The physical properties of Abeere seeds have
been determined, providing the baseline data needed for its machine design.
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3. article azojete vol 11 24 36 aremu

  • 1. Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36 Copyright© Faculty of Engineering, University of Maiduguri, Nigeria. Print ISSN: 1596-2490, Electronic ISSN: 2545-5818 www.azojete.com.ng MOISTURE-DEPENDENT PHYSICAL PROPERTIES OF ÀBÈÈRÈ (PICRALIMA NITIDA) SEEDS Aremu, A. K*. and Duduyemi, A. S. (Department of Agricultural and Environmental Engineering, University of Ibadan, Ibadan, Nigeria) *Corresponding author’s email and phone no: ademolaomooroye@gmail.com, +2348023843272 Abstract Some relevant engineering properties of Àbèèrè (Picralima nitida) seeds are needed for the design of its processing equipments. The geometric, gravimetric and frictional properties of Àbèèrè seed in the moisture content ranges of 7.98% - 47.77% (wb) were investigated. The average length, width, thickness, arithmetic and geometric mean diameters, sphericity, surface area, volume, true and bulk densities and angles of repose increased from 28.76 – 30.75mm, 16.18 – 19.62mm, 5.75 – 7.15mm, 16.90 – 19.17mm, 13.81 – 16.11mm,0.48 – 0.53, 600.94 – 817.83mm2 , 443.00 – 717.92mm3 , 2.49×10-3 – 2.60×10-3 g/mm3 , 1.14×10-3 – 1.50×10- 3 g/mm3 and 27.97o – 30.26o respectively as the moisture content increased from 7.98% to 47.77%. However, values for porosity decreased from 0.54 – 0.42. The static coefficient of friction of Àbèèrè increased linearly over the three material surfaces – plywood, stainless steel and glass – with increasing moisture content from 0.445 – 0.468, 0.286 – 0.384 and 0.357 – 0.389 respectively. The steel surface had the lowest static coefficient of friction whereas the plywood gave the highest value at all moisture content levels. The regression models developed for all the physical properties of the seeds had high coefficient of determination, R2 . Key words: Àbèèrè, physical properties, moisture content, angle of repose, coefficient of friction, porosity. 1. Introduction Picralima nitida, family Apocynaceae, (Common name: Akuamma plant; Igbo: Osi-Igwe; Yoruba: Àbèèrè) grows as either a shrub or small tree up to 22 m tall, with a trunk diameter of up to 16 inches. The tree of this plant grows for about 3 to 4 years before it starts bearing fruits. Its flowers feature a white, creamy or pale yellow corolla. Its fruit is yellow and smooth. Its numerous local medicinal uses include for fever, leprosy sores, stomach, and liver problems and as an anthelmintic, especially against internal worms (Schmelzer and Wageningen, 2008). It has Berries which have an ellipsoid form, with large size and green in color. When the fruits (berries) mature on the tree, they often fall on the ground and the green pigment on the fruit turns to yellow which will initiate the germination of the seeds in the fruit. Although the berries drop to the ground after maturity, some berries can also ripen on the tree. These berries are also used in traditional medicines for treating typhoid and fight against muscular pain (Oyebadejo et al., 2014). Inside the berries are seeds (Figure 1). The seed is an object of commerce in the local market, and it is collected from the wild thus its availability has been severely threatened. Dry seeds of the plant, Picralima nitida K. Schum, are highly valued in African traditional medicine in the treatment of various human diseases, including diabetes mellitus and obesity (Adeneye and Adeyemi, 2009a; 2009b). The phytochemical analysis of the “Àbèèrè” seed revealed the presence of saponins, steroids, tannins, volatile oils, phenols and copious amount of alkaloids (Falodun et al., 2006).
  • 2. Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36 25 The proximate composition of the Picralima nitida seed revealed that the seed contains crude fat content (5.02%), crude protein content (10.20%), ash content (0.88%), crude fibre (5.64%) and moisture content (3.73%) respectively. The seed is a rich source of carbohydrate which was 74.53%. The physicochemical properties of the oil of Picralima nitida seed revealed that the oil is brownish in colour and liquid at room temperature. The free fatty acid content was 1.41%. The iodine value which indicates the degree of unsaturation was found to be 136.40 while the refractive index was 1.45. The saponification value was 198.25mg KOH/g. The peroxide value and Unsaponifiable matter were 4.59meqO2/kg Oil and 1.90%, respectively (Adebowale et al., 2012). Figure 1: Fresh Àbèèrè Seeds Despite the widespread abundance and traditional use of Picralima nitida seeds and with the several research works that have been done on the chemical, phytochemical and toxicological composition of “Àbèèrè” seed (Picralima nitida) as reported by Falodun et al. (2014), review of literatures showed that there is no information relating to the effect of moisture on the engineering properties of the seed. Presently, the post-harvest handling processes include unit operations such as manual sorting of seeds, manual decorticating of seeds and manual grounding of the dried seeds. The seeds are extracted manually by breaking/cutting the fresh fruit with cutlass and allowing the pulp- covered seed to macerate and washing off in water. Alternatively, the fruits are allowed to decay and then washed off in water using basket, to extract the seeds. The seeds are ground with stone or by pounding in a mortar using wooden pestle. Also, the seeds are being stored using locally woven baskets. These methods of handling and processing seeds are not only time and energy consuming, but also inefficient as the usage of manual labour throughout the processing chain decreases the production efficiency on the farm and sometimes results into wastage of product. This present study is focused on investigating the physical properties of “Àbèèrè” (Picralima nitida) seeds (axial dimensions, mean diameters, sphericity, surface area, seed mass, bulk density, true density, porosity, angle of repose, and static coefficient of friction) at different moisture levels for design and improvement of relevant machines and
  • 3. Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11: 24-36 26 facilities for harvesting, storing, handling, processing and packaging. These parameters are important for the design and fabrication of the equipment involved in processes such as seed decorticating and seed oil extraction. 2. Materials and Methods A bulk quantity of Picralima nitida seeds were purchased from a farm in Ile-Ife, Osun State, Nigeria and stored in a laboratory at room temperature before carrying out the experiment. The seeds were cleaned to remove all foreign materials such as dirt, dust, stone and chaff as well as immature and damaged seeds while they were identified at the Department of Botany’s Herbarium, University of Ibadan, Ibadan, Oyo State, Nigeria. The following methods were used in the determination of some physical properties of Àbèèrè seeds (Picralima nitida). The moisture content of the Picralima nitida seeds were obtained according to ASAE Standard S352.3 (1994) by drying the seeds in an electric oven at a temperature of 105(±2)°C for 24 hours until there was no change in the seeds’ mass at the Department of Animal Science, University of Ibadan, Ibadan, Oyo State and weighing the samples using a digital weighing balance (AND Ek-6100i) reading to 0.01 g. The moisture content of the seeds was varied at five major levels. The moisture content of the sample in percentage wet basis was calculated using the equation shown below. (1) where: Ms is the Moisture content of the seeds (%wb), Wi is the Initial Mass (in grams) and Wf is the Final Mass after oven drying (in grams). A method for adjusting the seed’s moisture content without damaging its morphology was developed to prepare samples for subsequent tests. After it was soaked in water for 2, 3, 5, 7 and 10 hours, the samples were wrapped in a foil paper and kept in a refrigerator at 5 ˚C (±2 ˚C) for 5 days for the moisture to distribute uniformly throughout the seed (Obi et al., 2014). The moisture content of samples after equilibration was determined before each test was conducted. Accordingly, moisture levels of 7.98, 17.98, 25.11, 37.77 and 47.77% w.b. were obtained. For each test the required quantity of seeds were taken out and allowed to equilibrate with the room temperature. Every test was repeated five times to determine the mean values. 2.1 Determination of size and shape Fifty Àbèèrè (Picralima nitida) seeds were randomly selected for each of the moisture content considered and labelled for easy identification. The linear dimensions of the Àbèèrè seeds were determined by using a digital Vernier caliper (Carrera Precision Instrument, reading to 0.01 mm) to measure the length, thickness and width of the fruit denoted as L, T and W (all in mm) respectively.
  • 4. Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36 27 2.2 Determination of Mean Diameters The Arithmetic Mean Diameter (mm), Da, and Geometric Mean diameter (mm), Dm, were calculated using equations 2 and 3 respectively.. (2) √ (3) The surface area S in mm2 was estimated by the relationship given by Asoiro and Anthony (2011) as described by Ajav and Ogunlade (2014): (4) 2.3 Determination of Sphericity The sphericity is defined as the ratio of the surface area of a sphere with the same volume as the seed to the surface area of the seed (Mohsenin, 1986). The degree of sphericity of the seeds was calculated using equation 5 below as described by Adejumo and Abayomi, (2012). ⁄ (5) where: Φ is the Sphericity in decimal and other parameters remain as defined above. 2.4 Determination of Densities The true density of a seed is defined as a ratio of the mass of a sample of a seed to solid volume occupied by the sample (Mohsenin, 1986). The true density of the fruit was determined by weighing the mass of the fruit using a digital weighing balance reading (AND Ek-6100i) to 0.01 g, while its volume was determined by water displacement method (Aremu and Fadele, 2011). The water displacement method was used having ascertained that it takes longer period of time for water to penetrate through the seeds (Obasi et al., 2012). The true density was evaluated by finding the ratio of the true mass to that of the volume. The bulk density (kg/m3 ) is the ratio of mass of a sample of the seeds to its total volume (Mohsenin, 1986). It was determined by filling an empty 250 ml graduated glass cylinder with seeds from a height of about 18 cm, striking the top level and then weighing the contents. The weight of the seeds was obtained by subtracting the weight of the cylinder from the weight of the cylinder with seeds. The volume occupied was then noted (Theertha et al., 2014). The process is replicated five times and the average bulk density for each replication was calculated. 2.5 Determination of Porosity The porosity of the Àbèèrè seeds was estimated from its bulk and true densities using the relationship in equation (6) according to Mohsenin (1986). ⁄ (6) where: ρb and ρt are bulk and true densities (all in kgm-3 ) respectively 2.6 Determination of Static Coefficient of Friction The static coefficient of friction was determined with the following three structural materials on the tilting table: stainless steel, plywood and glass. The Picralima nitida seeds were placed
  • 5. Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11: 24-36 28 parallel to the direction of motion and the table is raised gently by a screw device (Olaoye, 2000). The angle at which the seeds begin to slide (i.e. angle of inclination) was read from a graduated scale on the tilting table for the three structural materials. The coefficient of friction was calculated as the tangent of this angle as shown in equation 7 below as reported by Ajav and Ogunlade (2014). (7) where: μ is the static coefficient of friction (decimal), is the angle of Inclination (degrees). 2.7 Determination of Angle of Repose The filling angle of repose of the seeds , , which is the angle with the horizontal at which the seeds will stand when piled was determined using a topless and bottomless paper cylinder of 15cm diameter and 25cm height as described by Obi et al. (2014). The cylinder was placed at the center of a raised circular plate having a diameter of 35cm and filled with the seeds. The cylinder was raised slowly until the seeds formed a cone on the circular plate. The angle of repose was calculated from the measurements of the height (H) of the cone formed by the seeds and the Diameter (D) of the cone using the relationship below: (8) where: f is the angle of repose (degrees), H is the Height of the cone formed by the seeds and D is the diameter of the cone. 2.8 Statistical Analysis Descriptive statistics were used to analyze the data obtained for each of the properties studied at different moisture content level using Microsoft Excel 2010. Predictive models were developed to establish relationship between the physical properties and moisture content using regression analysis. Analysis of Variance (ANOVA) was used to evaluate the significant effect of moisture content on the properties of the seed. 3. RESULTS AND DISCUSSION The mean axial dimensions, arithmetic and geometric mean diameters, sphericity, surface area, volume, densities, porosity and angles of repose of Àbèèrè seeds samples at five different moisture content levels of 7.98, 17.98, 25.11, 37.77 and 47.77% (wb) are presented in Tables 1a and 1b while the coefficient of static friction of on three different surfaces are shown in Table 1c. Generally, it was observed that the values recorded for most of the physical properties studied increased with increasing moisture content from 7.98 – 47.77% (wb). 3.1 Àbèèrè Seeds Dimensions Average values of the three principal dimensions of the seeds, namely length, width and thickness, determined in this study at different moisture contents are presented in Table 1a. Each principal dimension increased as the moisture content increased. This could be due to the fact that upon moisture absorption, the grains expanded in length, width and thickness. It was observed that within the moisture content range 7.98% wet basis to 47.77% wet basis, the average length of Àbèèrè seeds increased from (28.76±1.82) mm to (30.75±2.71)mm (7% increase in length), the width increased from (16.18±2.30)mm to (19.62±1.62)mm (21%
  • 6. Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36 29 increase in width), the thickness increased from (5.75±0.75)mm to (7.15±0.73)mm (24% increase in thickness). Similar trends were reported by Altuntas and Erkol, (2010) for shelled and kernel walnuts and Altuntas (2014) for Juniper berries. However, the relationship between the axial dimensions of Àbèèrè seeds and the moisture content in wet basis are given by equations 9, 10 and 11: L = 5.017Mc + 28.335 (R2 = 0.998) (9) W = 8.859Mc + 15.126 (R2 = 0.918) (10) T = 3.457Mc + 5.575 (R2 = 0.953) (11) Table 1a: Some geometric properties of Àbèèrè seeds at five moisture contents M. C. (%wb) Length (mm) Width (mm) Thickness (mm) Arithmetic Mean Diameter (mm) Geometric Mean Diameter (mm) Sphericity 7.98 28.76 (1.82) 16.18 (2.30) 5.75 (0.76) 16.90 (0.81) 13.81 (0.81) 0.46 (0.04) 17.98 29.24 (2.19) 16.72 (1.97) 6.20 (0.75) 17.38 (0.85) 14.09 (0.93) 0.47 (0.05) 25.11 29.55 (2.21) 16.74 (1.40) 6.62 (0.67) 17.63 (0.96) 13.95 (0.95) 0.48 (0.04) 37.77 30.23 (2.54) 18.47 (2.12) 6.88 (0.69) 18.52 (0.96) 15.27 (0.86) 0.51 (0.03) 47.77 30.75 (2.71) 19.62 (1.62) 7.15 (0.73) 19.17 (0.94) 16.11 (0.81) 0.53 (0.05) Standard deviation values are in parentheses. Table 1b: Some gravimetric properties of Àbèèrè seeds at five moisture contents M. C. (%wb) Surface Area (mm2 ) Volume (mm3 ) True Density (x10- 3 g/mm3 ) Bulk Density (x10- 3 g/mm3 ) Porosity Angle of Repose 7.98 600.94 (69.19) 443.00 (75.20) 2.49 (0.88) 1.14 0.54 (0.14) 27.97 17.98 623.48 (59.98) 506.86 (73.12) 2.53 (0.65) 1.27 0.50 (0.13) 28.40 25.11 614.30 (83.86) 546.58 (87.39) 2.59 (0.53) 1.48 0.43 (0.11) 28.54 37.77 732.58 (79.85) 644.28 (98.78) 2.63 (0.40) 1.48 0.44 (0.12) 29.56 47.77 817.83 (80.56) 717.92 (102.06) 2.60 (0.47) 1.50 0.42 (0.10) 30.26 Standard deviation values are in parentheses.
  • 7. Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11: 24-36 30 Table 1c: Coefficient of friction of Àbèèrè seeds at five moisture contents M. C. (%wb) Coefficient of Friction Stainless Steel Glass Wood 7.98 0.286 (0.024) 0.357 (0.022) 0.445 (0.021) 17.98 0.320 (0.021) 0.365 (0.026) 0.435 (0.032) 25.11 0.370 (0.070) 0.374 (0.026) 0.440 (0.043) 37.77 0.376 (0.067) 0.376 (0.029) 0.452 (0.039) 47.77 0.384 (0.058) 0.389 (0.031) 0.468 (0.034) Standard deviation values are in parentheses The ANOVA results presented in Table 2 showed that there were no significant differences (p<0.05) in the means of length, width, Geometric Mean Diameters and Sphericity of the seeds across the different moisture contents studied. However, it was revealed that moisture content had significant effect (p<0.05) on the thickness and arithmetic mean diameter. This may be due to the fact that the seeds have absorbed enough moisture to cause significant difference in the thickness of the seeds. Thus, the change in moisture content of the seeds will invariably have effect on the thickness of the seeds. Table 2: ANOVA results or the axial dimensions of Àbèèrè seeds at five different moisture contents M.C. Length (mm) Width (mm) Thickness (mm) AMD (mm) GMD (mm) Sphericity 7.98 28.76a 16.18a 5.75a 16.90a 13.81a 0.48a 17.98 29.24a 16.72a 6.20b 17.38b 14.09a 0.47a 25.11 29.55a 16.74a 6.62b 17.63b 13.95a 0.47a 37.77 30.23b 18.47b 6.88c 18.52c 15.27b 0.51b 47.77 30.75b 19.62b 7.15c 19.17c 16.11b 0.53b *Means with same letter(s) across columns are not significantly different at p<0.05 3.2 Mean Diameters The average arithmetic and geometric mean diameters are presented in Table 1a. The mean values recorded increased from 16.90 to 19.17 mm and 13.81 to 16.11 mm for the arithmetic and geometric mean diameters respectively as the moisture content increased from 7.98 – 47.77% (wb). It was observed that within the moisture content range, the average arithmetic and geometric increase was 13.41% and 16.65% respectively. This may due to the fact that the Abeere seed expanded more in thickness (24% increase) and width (21% increase) in comparison with the length (7% increase). Such behavior was observed by Sacilik et al. (2003) for hemp seed and Shafiee et al. (2009) for Dragon’s head seeds. These properties are particularly important in the design of harvesting, threshing and separating machines (Milani et al., 2007 and Gharibzahedi et al., 2011). However, the relationship between the Arithmetic (Da) and Geometric (Dg) Mean Diameters with the Moisture Content (Mc) appeared linear as shown in equations 12 and 13: Da = 5.762Mc + 16.347 (R2 = 0.985) (12) Dg = 5.977Mc + 13.012 (R2 = 0.856) (13)
  • 8. Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36 31 3.3 Sphericity The average values of the sphericity at the five moisture levels are as presented in Table 1a. The sphericity of the seeds initially decreased from 0.48 to 0.47 as the moisture content increased from 7.98% to 17.98%. However, the sphericity of the seeds increased from 0.47 to 0.53 as the moisture content increased from 25.11% to 47.77% (wb). This is due to the differential dimensional changes in the three axial dimensions. The sphericity of Picralima nitida seeds were observed to be lower than that of Garcinia kola seed (Igbozulike and Aremu, 2009). Aremu and Fadele, (2011) reported that the closer the sphericity to 1.0, the higher the tendency of the fruit to roll about any of the three axes and the closer the ratio of thickness to width to 1.0, the higher the tendency to rotate about the major axis. Thus, the values obtained for the sphericity indicates the possibility of the Àbèèrè seeds not to roll relatively well but slide where necessary. The sphericity of the seeds has a linear relationship with the moisture content as shown in equation 14. Φ = 0.0018Mc + 0.4401 (R² = 0.9709) (14) Where: Φ= Sphericity; Mc = Moisture Content Similar trends have been reported by Ndukwu (2009) for Brachystegia eurycoma seeds, Aydin et al. (2002) for Turkish mahaleb, Sahoo and Srivastava (2002) for okra seed, Sacilik et al., (2003) for hemp seed, (Coskuner and Karababa, 2007) for flaxseed and Altuntas et al. (2005) for fenugreek seed. 3.4 Surface Area and Volume Surface area of the seed has increased with increase in moisture content as shown in Table1b. The surface area increased from (600.94±69.19) mm2 to (817.83±80.56) mm2 as moisture content increases from 7.98% to 47.77%. Similar results were presented by Adejumo and Abayomi, (2012) for unshelled Moringa oleifera seed, Obi et al. (2014) for Pigeon Pea grown in Nigeria and in reports by Sacilik et al. (2003) and Baryeh (2002) for hemp seed and millet, respectively. The surface area affects the rate of moisture loss during drying of seeds, grains and other particulate materials. The volume also increased from (443±75.20) mm3 to (717.92±102.06) mm3 as moisture content increases from 7.98% to 47.77% indicating that the volume-moisture relationship was linear as shown in Table 1b. The volumetric expansion observed may be adduced to moisture absorption which increases the axial dimensions of the grain. The values of the surface area (SA) and volume (V) bear the following relationship with the Moisture Content (Mc) as described by the regression equations 15 and 16. SA = 5.606Mc + 524.65 (R² = 0.878) (15) V = 694.35Mc + 382.02 (R2 = 0.997) (16) 3.5 True and Bulk Density The relationship between the true density and moisture content was almost completely linear. The average true density of Àbèèrè seeds increased from 2.49x10-3 g/mm3 to 2.60x10-3 g/mm3
  • 9. Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11: 24-36 32 as moisture content increased from 7.98% to 47.77% wet basis as shown in Table 1b. A decrease in true density was observed as moisture content increased from 37.77% to 47.77%. This decrease was mainly due to the larger increase in the volume of the grain compared to the lesser increase in the grain mass. A similar trend was reported by Bande et al. (2012) for Melon (Citrullus colocynthis) seeds. The result of the true density shows that the seed is heavier than water and as such will sink in water. This is useful in the design of cleaning and separation machines to remove chaffs and other materials that can float in water. The true density of Àbèèrè seeds is higher than that of Melon seeds (Bande et al., 2012) and higher than that reported for Moringa oleifera seed (Adejumo and Abayomi, 2012). As observed from Table 1b, the bulk density of Àbèèrè seeds increased with the moisture content from 1.14x10-3 g/mm3 at 7.98% to 1.50x10-3 g/mm3 at 47.77%. This pattern was similarly reported by Bande et al. (2012) for melon seeds and kernels. The knowledge of bulk density is important in the handling of the seeds in terms of determining the amount and strength of packaging for the seeds. However, the relationship observed between values of True Density (TD) and Bulk Density (BD) and the percent moisture content (Mc) of Àbèèrè seeds in wet basis are given by equations 17 and 18: TD×10-3 = 0.0031Mc + 2.4809 (R² = 0.767) (17) BD×10-3 = 0.009Mc + 1.128 (R² = 0.775) (18) 3.6 Porosity The porosity of the seeds calculated from the relevant experimental data decreased as shown in Table 1b. The decrease in porosity with increase in moisture content is because an increase in moisture content results in a more significant increase/swelling of the linear dimensions thus reducing the airspaces and giving a more compact arrangement of the seeds invariably reducing the porosity of the seed bulk. Altuntas and Erkol (2010) reported the same trend for shelled and kernel walnuts and Adejumo and Abayomi, (2012) reported the same trend for Moringa oleifera seed. However, the values of porosity for Àbèèrè seeds fall within the same range of values obtained for Melon (Bande et al., 2012). The porosity is the most important factor for packing and it affects the resistance to airflow through bulk seeds. The linear relationship between porosity (P) and moisture content is revealed below. P = -0.0029Mc + 0.5444 (R2 = 0.760) (19) 3.7 Angle of Repose The filling angle of repose increased with increase in moisture content of the abeere seeds. The mean values of the filling angle of repose was found to increase from 27.97o to 30.26o as the moisture content increases from 7.98% to 47.77% w.b (Table 1b). This increasing trend of the filling angle of repose could be attributed to the surface tension caused by the layer of
  • 10. Arid Zone Journal of Engineering, Technology and Environment. August, 2015; Vol. 11: 24-36 33 moisture surrounding the seeds. This trend was similarly reported by Ahmadi et al., (2009) for Fennel Seed (Foeniculum vulgare) The values of the angle of repose (AOR) bear the following relationship with the Moisture Content (Mc) as described by the regression equation below. AOR = 5.851Mc + 27.346 (R² = 0.960) (20) Singh and Goswami (1996), Nimkar and Chattopadhyay (2001), Baryeh (2002), Amin et al. (2004) and Altuntas et al. (2005) also reported a linear increase in angle of repose with increase in the moisture content for cumin seed, green gram, millet, lentil and fenugreek, respectively. 3.8 Coefficient of Friction It was observed that the coefficient of friction of the abeere seeds increased with an increase in moisture content on all the three surfaces studied - plywood, Stainless Steel and glass. The increase in coefficient of friction with an increase in moisture content on all surfaces could be attributed to the increased adhesion between the seed and all the material surfaces at higher moisture content as well as due to the increase in the size of the seed as reported by Obi et al. (2014). The coefficient of friction increased from 0.286 to 0.384, 0.357 to 0.389 and 0.445 to 0.468 for stainless steel, glass and plywood respectively as shown in Table 1c. It was however observed that the highest coefficient of friction of the abeere seeds was obtained on plywood and least on glass and stainless steel. Ajav and Ogunlade, (2014) reported that the least static coefficient of friction may be owing to smoother and more polished surface of the glass and stainless steel than the other material used. Altuntas and Erkol, (2010) and Ajav and Ogunlade, (2014) reported the same trend that coefficient of friction increases as the moisture content increase for shelled and kernel walnuts and Ginger (Zingiber officinale) respectively. However, the values of the Coefficient of Friction (COF) on all the three surfaces bear the following relationship with the Moisture Content (Mc) as described by the regression equations 21, 22 and 23. COFwood = 0.0007Mc + 0.4303 (R² = 0.643) (21) COFglass = 0.0007Mc + 0.3518 (R2 = 0.947) (22) COFsteel = 0.0025Mc + 0.2801 (R² = 0.834) (23) 4. Conclusion The results showed that the principal dimensions of the seeds increased with respect to moisture content. However, the true density of the seeds does not have a linear relationship with moisture content. The bulk density and filling angle of repose of the seeds however increased with increased in moisture content. The porosity of the seeds decreased with increase in moisture content. Although, the coefficient of friction of the Àbèèrè seeds increased with an increase in moisture content on all the three surfaces studied, it was however observed that the highest coefficient of friction of the Àbèèrè seeds was obtained on
  • 11. Aremu and Duduyemi Moisture-Dependent Physical Properties of Àbèèrè (Picralima Nitida) Seeds AZOJETE, 11: 24-36 34 wood and least on glass and stainless steel. The physical properties of Abeere seeds have been determined, providing the baseline data needed for its machine design. References Adebowale, AY., Adewuyi, A. and Adebowale, KO. 2012. Lipid composition and molecular speciation of The Triacylglycerol of the oil of Picralima nitida. GIDA, 37 (1): 1-7. Adejumo, BA. and Abayomi, DA. 2012. Effect of moisture content on some physical properties of Moringa Oleifera seed. IOSR Journal of Agriculture and Veterinary Science, 1(5): 12-21. Adeneye, AA. and Adeyemi, OO. 2009a. Hypoglycaemic effects of the aqueous seed extract of Hunteria umbellata in normal and glucose- and nicotine-induced hypoglycaemic rats. International Journal of Applied Research in Natural Products, 2(1): 9-18. Adeneye, AA. and Adeyemi, OO. 2009b. Further evaluation of antihyperglycaemic activity of Hunteria umbellata (K. Schum) Hallier f. seed extract in experimental diabetes. Journal of Ethnopharmacology, 126(2): 238-243. Ahmadi, H., Mollazade, K., Khorshidi, J. and Mohtasebi, SS. 2009. Some physical and mechanical properties of Fennel seed (Foeniculum vulgare). Journal of Agricultural Science, 1(1): 66-85. Ajav, EA. and Ogunlade, CA. 2014. Physical properties of Ginger (Zingiber Officinale). Global Journal of Science Frontier Research: D Agriculture and Veterinary, 18(8): 1-8. Altuntas, E., Ozgoz, E. and Taser, OF. 2005. Some physical properties of fenugreek (Trigonella foenum-graceum L.) seeds. Journal of Food Engineering, 71: 37–43. Altuntas, E. and Erkol, M. 2010. Physical properties of shelled and kernel walnuts as affected by the moisture content. Czech Journal of Food Science, 28: 547–556. Altuntas, E, 2014. The geometric, volumetric and frictional properties of Juniper berries. American Journal of Food Science and Nutrition Research, 2(1): 1-4. Amin, MN., Hossain, MA. and Roy KC. 2004 Effect of moisture content on some physical properties of lentil seeds. Journal of Food Engineering, 65: 83–87. Aremu, AK. and Fadele, OK. 2011. Some physical properties of Doum Palm fruit (Hyphaene thebaica). African Journal of Agricultural Research, 6(15): 3597-3602. ASAE. 1994. Moisture measurement-ungrounded grains and seeds. In: ASAE Standards 1994, 469 St. Joseph, MI. Asoiro, FU. and Anthony, OA. 2011. Determination of some physical properties of African Yam Beans. The Pacific Journal of Science and Technology, 12(1): 374-380. Aydin, C., Ogut, H. and Konak, M. 2002. Some physical properties of Turkish Mahaleb. Biosystems Engineering, 82: 231–234.
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