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Understanding the naphtha-gasoline mix
to improve octane levels and fuel quality
Neil	Watt	
Crude	and	Refined	Products,	BB	Energy	
Argus	Gasoline	Conference		
April	2019
Overview
1.	Exploring	current	naphtha	supply	and	demand	dynamics	
2.	Looking	at	the	difference	between	naphtha	and	ethanol	in	supplying	incremental	octanes	
3.	U.S	gasoline	background	
4.	What	blends	can	be	made	to	improve	octane	levels	and	fuel	quality	
5.	Assessing	product	flows	
April	2019	2
1. Exploring current naphtha supply and demand
dynamics
April	2019	3
Cuts to Medium/Heavy grades, increasing light
production globally (Part I)
April	2019	4	
•Increasing	U.S	light	crude	production2,5	
•Cuts	concentrated	in	medium/heavy	
grades3		
•Russia	potentially	reaches	quota	in	April/
May4		
•Mandated	Canadian	production	cuts	and	
investment	uncertainty		
-1	
-1	
0	
1	
1	
2	
U.S	 Russia	 Iraq	 Canadian	Heavy	 Saudi	Arabia	 Venezuela	 Iran	(ex	
condensate)	
Key	Changes	in	Crude	Production	by	Country	from	2018	to	2019	YTD	(Mbd)	
(Canadian	National	Energy	Board1,	EIA2,	Refinitiv3)
Cuts to Medium/Heavy grades, increasing light
production globally (Part II)
April	2019	5
Trend towards increasing production of light crude
in U.S (Part I)
April	2019	6	
•Productivity	in	Permian,	Eagle	Ford	stable	while	
Bakken	improving5	
•With	increasing	rig	additions	should	continue	
to	see	production	increases	through	to	year	end	
500	
1,000	
1,500	
2,000	
2,500	
3,000	
3,500	
4,000	
4,500	
Jan-16	
Mar-16	
May-16	
Jul-16	
Sep-16	
Nov-16	
Jan-17	
Mar-17	
May-17	
Jul-17	
Sep-17	
Nov-17	
Jan-18	
Mar-18	
May-18	
Jul-18	
Sep-18	
Nov-18	
Jan-19	
Mar-19	
U.S	Production	Key	Basins	(kbd)		
(EIA5)	
Bakken	Region	Total	
production	
Eagle	Ford	Region	Total	
production	
Permian	Region	Total	
production	
Lower	48	States	Crude	Production	(kbd)	(EIA2)	 		
		 Dec-17	 Dec-18	 Δ	YoY	
API	40+		 5,301	 6,581	 1,280	
API	50+	 925	 1,020	 95
Trend towards increasing production of light crude
in U.S (Part II)
April	2019	7	
0	
500	
1,000	
1,500	
2,000	
2,500	
3,000	
3,500	
4,000	
4,500	
Jan-19	 Apr-19	 Jul-19	 Oct-19	 Jan-20	 Apr-20	 Jul-20	 Oct-20	 Jan-21	
Key	Permian-USGC	Pipeline	Capacity	Additions	(kbd)	
	(Company	Reports7-22)	
Jupiter	
Permian	Gulf	Coast	Pipeline	(ETP)	
EPIC	Crude	pipeline	(Texstar)	
Gray	Oak	(P66/Enbridge)	
EPIC	-	temporary	NGL	conversion	(Texstar)	
Cactus	2	(PAA)	
Seminole	NGL	to	Crude	Conversion	(ETP)
Increasing acceptance of light U.S grades (Part I)
April	2019	8
Increasing acceptance of light U.S grades (Part II)
April	2019	9	
•Increasingly	wide	acceptance	of	U.S	grades;	
market	increasingly	resilient	and	responsive	
•IMO	2020	Sulphur	challenges	
•WTI	FOB	premiums	to	screen	to	narrow	with	
logistics	and	WTI/Brent	with	it
Naphtha petchem economics (Part I)
April	2019	10
Naphtha petchem economics (Part II)
April	2019	11	
New	LPG	Export	Facilities	Canada	and	U.S	(Company	Reports,	Reporting23-27)	
Name	 Company	 Country	 Capacity	(kbd)	 Startup	
Mariner	East	(Marcus	Hook)	 ETP	(SXL)	 U.S	 275	 Q1,	19	
RIPET	 AltaGas	 Canada	 35	 Q2,	19	
Enterprise	Houston	Ship	Channel	 EPD	 U.S	 175	 Q3,	19	
Galena	Park	Train	6	 Targa	 U.S	 100	 Q3,Q9	
Galena	Park	Train	7	 Targa	 U.S	 110	 Q1,	20	
Prince	Rupert	 Pembina	 Canada	 25	 Q2,	20	
Galena	Park	Train	8	 Targa	 U.S	 110	 Q2,	20
Chinese Petrochemical Integration and PDH
Expansions
April	2019	12	
•Increasingly	integrated	Chinese	petchem	
complex	competing	with	less	advantaged	North	
Asian	crackers28	
•5.7	Mtpa	additional	integrated	ethylene	
capacity29-33	
•Over	2	Mtpa	PDH	capacity	expansions	this	
year34-35
Plastic demand destruction: Some Drivers…
April	2019	13	
Packaging	represents	~	30	vol%	of	plastics	in	use	and	~40%	of	European	plastics	conversion	demand36…	
	
•Environmental	activism	goes	mainstream	(	e.g	”Blue	Planet”37	and	“Schools	Climate	Strike”38)	
•Increasingly	sustainability	conscious	consumers	(e.g	millennials39)	
	•UN:	Plastic	Ocean	Waste	resolution40	
•China:	pollution	(“one	of	three	major	threats”)	to	be	tackled	by	new	agencies41	
•EU:	100%	recyclable	and	25%	recycled	plastics	by	202542	
•California:	First	state	to	enact	ban	on	single-use	plastic	bags	at	large	retail	stores43	
•Scotland:	5	pence	charge	on	carrier	bags	led	to	80%	reduction	in	bags	used	within	a	year.44	Similar	policy	
now	in	England
Plastic demand destruction: Business Response
April	2019	14	
•Major	companies	adopting	increasingly	
ambitious	sustainability	targets45-53…including	
biggest	plastic	polluters		
•World’s	largest	plastic	straw	producer	
investing	in	bioplastics	production54
Naphtha Demand Trends of Major Consumers
April	2019	15	
•Rising	demand	in	China	(increasingly	not	
marketable	naphtha)	
•Stagnant	demand	growth	or	decline	in	other	
major	demand	centers	recently55,	56
2. Looking at the difference between naphtha and
ethanol on supplying incremental octanes
April	2019	16
Comparison of naphtha and ethanol specifications
April	2019	17	
		 Density	(SG)	 Sulphur	(ppm)	 Aromatics	(vol	%)	 Olefins	(vol	%)	 IBP	(deg	C	)	 T10	deg	C	(deg	C	)	 T50	deg	C	(deg	C	)	 T90	deg	C	(deg	C	)	 FBP	(deg	C	)	 RON	 RVP	(kpa)	
Ethanol	 0.791	 0	 0	 0	 80.0	 78.5	 78.5	 78.5	 78.5	 113	 180	
Amuay	Heavy	Naphtha	 0.749	 176	 11.5	 1.07	 85.0	 99.7	 119.2	 147.2	 171.1	 56	 16	
Arzew	Naphtha	 0.725	 4	 12.75	 1.3	 33.7	 48.5	 107.6	 166.8	 181.6	 51	 37	
Bonny	Condensate	 0.692	 15	 5	 0.1	 30.4	 43.7	 64.0	 121.3	 199.6	 74	 85	
Huelva	 0.732	 190	 11.2	 0.4	 41.2	 68.9	 103.6	 132.5	 156.4	 66	 37	
Jose	NGL	 0.662	 10	 2.85	 0.6	 33.3	 41.0	 49.1	 85.9	 120.4	 72	 88	
La	Pampilla	 0.718	 130	 5	 1.06	 41.9	 67.9	 94.7	 123.9	 162.4	 66	 41	
Mamonal	 0.727	 198	 8.4	 4.9	 45.8	 69.3	 106.4	 148.2	 173.8	 65	 35	
Milazzo	LCN	 0.726	 11	 18.5	 23.1	 37.0	 52.4	 92.0	 154.7	 184.0	 88	 54	
Open	Spec	Naphtha		 0.672	 67	 0.046	 0.008	 34.2	 55.5	 68.0	 82.0	 153.0	 69	 78	
Punta	Cardon	 0.678	 14.4	 0.21	 0.5	 33.9	 48.3	 62.5	 88.6	 128.4	 66	 71	
Skikda	Splitter	 0.687	 5	 3.9	 0.5	 35.0	 47.8	 73.3	 128.3	 157.8	 62	 70
Naphtha Reforming
April	2019	18	
65%	
70%	
75%	
80%	
85%	
90%	
95%	
Jan-13	
Aug-13	
Mar-14	
Oct-14	
May-15	
Dec-15	
Jul-16	
Feb-17	
Sep-17	
Apr-18	
Nov-18	
Utilisation	of	Available	Reforming	Capacity,	U.S	and	PADD	III		
(EIA57,	BB	Energy	proprietary	data	and	estimates28)	
US	
PADD	III	
14.80%	
14.90%	
15.00%	
15.10%	
15.20%	
15.30%	
15.40%	
15.50%	
0	
500	
1,000	
1,500	
2,000	
2,500	
3,000	
2018	 2019	 2020	
CDU	and	Reforming	Capacity	Additions	in	U.S,	Euro,	Asia		
(BB	Energy	proprietary	data28)		
Reforming	(kbd)	 CDU	(kbd)	 Reforming/CDU	Installed	Capacity	(%)
Ethanol Blends: Octane Gain (Part I)
April	2019	19	
80	
85	
90	
95	
100	
105	
110	
0	 10	 20	 30	 40	 50	 60	 70	 80	
RON	
Ethanol	Blend	(vol%)	
Ethanol	Blends	and	Octane		
(Stein58)		
98	Ron	Blendstock	
95	Ron	Blendstock	
92	Ron	Blendstock	
88	Ron	Blendstock	
82	Ron	Blendstock	
0	
0.1	
0.2	
0.3	
0.4	
0.5	
0.6	
0.7	
0	 10	 20	 30	 40	 50	 60	 70	 80	
Octane	Blend	Gain	
Ethanol	Blend	(vol%)	
Octane	Blend	Gain/Ethanol	(vol%)		
(Derived	from	Stein58)	
95	Ron	Blendstock	
92	Ron	Blendstock	
88	Ron	Blendstock	
82	Ron	Blendstock
Ethanol Blends: Octane Gain (Part II)
April	2019	20	
•Olefins/aromatics	composition	significantly	
influences	ethanol	octane	blend	gain60	
•Ethanol	octane	blend	gain	differential	1.7	
between	high/low	aromatics	with	identical	
starting	neat	Octane60	
80	
85	
90	
95	
100	
105	
0	 10	 15	 30	
RON	
Ethanol	(vol%)	
Ron	and	Ethanol	by	Ratio	Aromatics/Olefins		
(Derived	from	CRC59)	
2	Aromatics/Olefins	
3	Aromatics/Olefins	
5	Aromatics/Olefins
Ethanol Blends: RVP
April	2019	21	
•Significant	decreases	in	RVP	occur	beyond	
20%61	
•Very	small	decrease	from	E10	to	E15
3. U.S Gasoline Background
April	2019	22
U.S Gasoline Background: Tier III (Part I)
April	2019	23	
•EPA	estimated	only	15%	of	the	pool	would	have	
a	compliance	cost	of	around	1-2	cpg67	
•But	in	December	2017,	average	sulfur	of	the	U.S	
gasoline	pool	was	22.4	ppm	vs	10	ppm	limit68		
•Small	refinery	exemption	expires	this	year69	
0	
0.5	
1	
1.5	
2	
2.5	
3	
0	 1	 2	 3	 4	 5	 6	 7	 8	 9	 10	 11	 12	 13	 14	 15	
Compliance	Cost	(cpg)	
Sulfur	over	10	ppm	Tier	3	Threshold	(ppm)	
Tier	3	Estimated	Compliance	Costs	by	Sulfur	Excess	vs	EPA	Estimates		
	(EPA67,	BB	Energy	estimates)	
Compliance	Cost	(Standard	Tier	3)	
Compliance	Cost	(Early	Tier	3)	
10%	Production	(EPA	Estimate)	
55%	Production	(EPA	Estimate)	
15%	Production	(EPA	Estimate)
U.S Gasoline Background: Tier III (Part IIa)
April	2019	24	
•Decrease	in	sulfur	along	with	olefins	=>	less	
octane	+	ethanol	octane	blend	gain	less	
•More	hydrotreatment	capacity	planned,	
tendency	to	increase	severity	of	hydrotreatment	
likely	to	continue28	
•Winter	RFG	3	ppm	higher	than	summer	grade69	
0	
10	
20	
30	
40	
50	
60	
70	
80	
90	
100	
8.5	
9.0	
9.5	
10.0	
10.5	
11.0	
11.5	
12.0	
2005	 2006	 2007	 2008	 2009	 2010	 2011	 2012	 2013	 2014	 2015	 2016	 2017	
Sulfur	VWA	(ppm)	
Olefins	VWA	(vol%)	
U.S	Gasoline	Pool	Characteristics	Tier	3		
(EPA69)	
Olefins	VWA	(vol%)	
Sulfur	VWA	(ppm)
U.S Gasoline Background: Tier III (Part IIb)
April	2019	25	
•Decrease	in	sulfur	along	with	olefins	=>	less	
octane	+	ethanol	octane	blend	gain	less	
•More	hydrotreatment	capacity	planned,	
tendency	to	increase	severity	of	hydrotreatment	
likely	to	continue28	
•Winter	RFG	3	ppm	higher	than	summer	grade69	
0	
5	
10	
15	
20	
25	
30	
35	
5	
7	
9	
11	
13	
15	
17	
19	
21	
2013	 2014	 2015	 2016	 2017	
Sulfur	VWA	(ppm)	
Olefins	and	Aromatics	VWA	(vol%)	
U.S	Gasoline	Pool	Characteristics	2013-2017		
(EPA69)	
Aromatics	VWA	(vol%)	
Olefins	VWA	(vol%)	
Sulfur	VWA	(ppm)
U.S Gasoline Background: Octane Supply
April	2019	26	
•Tighter	sulfur	standards	=>	degrades	octane	in	
catcracker	stream	
•Insignificant	octane	related	capacity	additions	
and	available	reforming	capacity	
•Imbalance	of	light	crude/condensate	with	lower	
octane	gasoline	fraction	
0	
50	
100	
150	
200	
250	
300	
350	
400	
450	
2016	 2017	 2018	 2019	 2020	 2021	
U.S	Cumulative	Alky	and	Hydro	Capacity	Additions	2016	to	2021	(kbd)	
	(BB	Energy	proprietary	data23)	
Gasoline/Naphtha	
Hydrotreaters	
Alkylation	Units
U.S Gasoline Background: Octane Demand (Part I)
April	2019	27	
•Efficiency	standards	+	trend	for	higher	horsepower	
•Uncertainty	over	2021/25	efficiency	standards63	
(legal	cases	probably	not	settled	until	2021)	
•Lobbying	activity	for	95	Ron	standard64	
•Increased	export	demand	for	octane	out	of	USG,	
i.e	Mexico	
	
200	
210	
220	
230	
240	
20	
21	
22	
23	
24	
25	
26	
2007	 2008	 2009	 2010	 2011	 2012	 2013	 2014	 2015	 2016	 2017	 2018	
Horsepower	(HP)	
Real	World	Fuel	Efficiency	(mpg)	
Horsepower	and	Efficiency	by	Model	Year	
	(EPA62)	
Real-World	FE	(mpg)	
Horsepower	(HP)
U.S Gasoline Background: Octane Demand (Part II)
April	2019	28	
Significant	emissions	reduction	impact	from	
higher	efficiency	(with	political	dimensions)	
	
340	
350	
360	
370	
380	
390	
400	
410	
420	
430	
440	
20	
21	
22	
23	
24	
25	
26	
2007	 2008	 2009	 2010	 2011	 2012	 2013	 2014	 2015	 2016	 2017	 2018	
Real	World	CO2	(g/mil)	
Real	World	Fuel	Efficiency	(mpg)	
CO2	Emissions	per	mile	and	Efficiency	by	Model	Year		
(EPA62)	
Real-World	FE	(mpg)	
Real-World	CO2	(g/
mi)
U.S Gasoline Background: Octane Demand (Part III)
April	2019	29	
0	
10	
20	
30	
40	
50	
60	
70	
Jan-00	 Jan-02	 Jan-04	 Jan-06	 Jan-08	 Jan-10	 Jan-12	 Jan-14	 Jan-16	 Jan-18	
Premium	differentials	to	Regular	and	Midgrade		
(EIA66)	
Premium-Regular	(cpg)	 Premium-Midgrade	(cpg)	
8.50%	
9.00%	
9.50%	
10.00%	
10.50%	
11.00%	
11.50%	
12.00%	
12.50%	
700	
750	
800	
850	
900	
950	
1,000	
1,050	
1,100	
1,150	
Jan-12	 Aug-12	 Mar-13	 Oct-13	May-14	Dec-14	 Jul-15	 Feb-16	 Sep-16	 Apr-17	 Nov-17	 Jun-18	
Evolution	of	U.S	Premium	Grade	Sales		
(EIA65)	
Premium	Gasoline	Sales	(kbd)	 Premium	Portion	of	Pool	(%)
4. What Blends can be made to improve octane
levels and fuel quality
April	2019	30
E15 (U.S): Blend Benefits
April	2019	31	
Ethanol	superior	octane	booster:		
•high	RON	
•	economic	benefit		
•benign	environmental	effects	
•decreases	sulfur	in	gasoline	pool	
•slightly	lower	RVP	than	E1061	
0	
0.5	
1	
1.5	
2	
2.5	
3	
3.5	
0	
20	
40	
60	
80	
100	
120	
140	
Ethanol	 Toluene	 MTBE	 Methanol	 Reformate	 C4		 Alkylate	
Sulfur	(ppm)	
RON	
Gasoline	Blend	Components	Sulfur	and	RON		
RON	
Sulfur	(ppm)	
Specification	 Density	(SG)	 Sulphur	(ppm)	 Aromatics	(vol	%)	 Olefins	(vol	%)	 Benzene	(vol	%)	 RON	 RVP	(kpa)	
Ethanol	 0.791	 0	 0	 0.0%	 0.0%	 113	 180	
Toluene	 0.82	 1	 0.98	 1.0%	 0.0%	 120	 20	
MTBE	 0.746	 1	 0.01	 1.0%	 0.0%	 117	 60	
Methanol	 0.78	 1	 0	 0.0%	 0.0%	 113	 475	
Reformate	 0.8301	 3	 0.681	 1.0%	 2.0%	 102	 24	
C4		 0.575	 2	 0.01	 1.0%	 0.2%	 95	 380	
Alkylate	 0.6979	 2	 0.021	 1.0%	 0.2%	 94	 50
E15 (U.S): Practical Considerations (Part I)
April	2019	32	
•  Benefits	to	the	consumer	relatively	small	
compared	to	total	outlay	on	fuel	costs	
•  Lack	of	availability	and	price	visibility	
	
0.0	
0.1	
0.2	
0.3	
0.4	
0.5	
0.6	
0.7	
0.8	
0	
50	
100	
150	
200	
250	
300	
350	
Estimated	E15	Savings	(cent/mile)	
Ethanol	and	RBOB	flat	price	(cent/gal)	
E15	Savings	and	flat	price		
(EIA66,	E85Prices70,	BB	Energy	estimates)	
Ethanol	(cent/gal)	
RBOB	(cent/gal)	
E15	Saving	cent/mile
E15 (U.S): Practical Considerations (Part II)
April	2019	33	
•Small	portion	of	the	fleet	estimated	to	be	
E15	approved	by	manufacturer		
•High	cost	of	adoption	and	opportunity	cost	
to	retail	stations74,	75		
	
0%	
10%	
20%	
30%	
40%	
50%	
60%	
70%	
80%	
90%	
100%	
2012	 2013	 2014	 2015	 2016	 2017	 2018	 2019	 2020	 2021	 2022	 2023	 2024	 2025	 2026	
%	New	sales	and	Estimated	proportion	of	fleet	E15	approved	by	manufacturer	
	(Bureau	of	Transportation	Statistics71,	NADA72,	OICA73,	BB	Energy	estimates)	
%	E15	Approved	
Vehicles/Total	Fleet	
%	New	Sales	E15	
Approved	by	
Manufacturer
E10 (China): Implementation Practicalities
April	2019	34	
•In	2018	2.9	MTpa	ethanol	was	blended	at	a	rate	
of	2.1	%77		
•~	15	MTpa	required	
•Lack	of	production	capacity	
•Trade	war	uncertainty78	
•Possibility	of	significant	imports	and/or	scaling	
back	of	program	
	
-10	
-5	
0	
5	
10	
15	
20	
Ethanol	Needed		 2018	Capacity	 Planned	Capacity	 Gap	
2020	E10	China	Ethanol	Supply	and	Demand	MTpa		
(Kejun76,	USDA77)
E10 (China): Potential Impacts of E10
April	2019	35	
•	200-300	kbd	of	MTBE	eventually	displaced	
•Reduced	environmental	impact	from	MTBE	
•U.S	ethanol	to	make	up	for	shortfalls	=>	higher	U.S	
pump	prices/RINs/ethanol	and	poorer	distribution	
economics	harming	demand	growth	
•Reduced	demand	from	MTBE	=>bearish	MTBE	
precursors	and	LPG/naphtha	
	
		 Ethanol	 MTBE	
Density	(SG)	 0.791	 0.746	
Sulphur	(ppm)	 0	 1	
Aromatics	(vol	%)	 0	 0.01	
Olefins	(vol	%)	 0.0%	 1.0%	
IBP	(deg	C	)	 80	 55	
RON	 113	 117	
RVP	(kpa)	 180	 60
5. Assessing product flows
April	2019	36	
•	Substantial	additional	production	capacity	
in	Asia	
•	Improved	blending	economics	for	gasoline	
exports	to	Latin	America	out	of	China	with	
E10	
•Tier	3	issues	shifts	USGC	production	
•Move	to	IMO	2020,	rising	bunker	costs
Conclusion: Key Points
•Crude	slate	lighter;	a	trend	towards	more	naphtha	supply	
•Naphtha	demand	outlook	challenged-	feedstock	competition,	plastics	demand	destruction,	China	petchem	
integration	
•Lack	of	reforming	capacity	and	spare	utilization	to	convert	naphtha	to	reformate	
•Regulatory	changes	creating	challenges	in	octane	supply	
•Ethanol	blends	at	higher	than	10	%	present	some	attractive	possibilities	for	meeting	octane	demands	
•Ultimately	E15	is	logistically,	structurally	challenged;	likely	to	require	time	and	support	to	uptake	significantly	
under	current	conditions	
•Short	term	feasibility	of	full	E10	implementation	in	China	questionable	given	domestic	production	gap	
•Shift	to	E10	in	China	likely	to	lead	to	higher	exports	to	Latam,	impacting	USGC	competitiveness,	pull	on	
ethanol	
April	2019	37
Sources (Part I)
1.	National	Energy	Board.	(2019,	March	5).	Estimated	Production	of	Canadian	Crude	Oil	and	Equivalent.	Retrieved	from	www.neb-one.gc.ca:	https://www.neb-one.gc.ca/
nrg/sttstc/crdlndptrlmprdct/stt/stmtdprdctn-eng.html	
2.	EIA.	(2019,	February).	
3.	Refinitiv.	(2019,	March	10).	Reuters	OPEC	Crude	Production	Survey.	
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asias-ethanol-market-faces-uncertainty	
April	2019	42

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