Edward Thorndike was an American psychologist who developed Connectionism, which theorized that learning is based on forming associations between stimuli and responses through trial and error. Some of his key contributions included establishing laws of learning like the Law of Effect, which stated that responses connected to satisfying outcomes are strengthened, while those connected to annoying outcomes are weakened. Thorndike conducted experiments with animals like chicks and cats to understand learning through their trial-and-error behaviors. He published over 500 works and helped establish psychology as a science through his emphasis on experimental methods.