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Bonding and Molecules
Why atoms form chemical bonds
 Electrons are in energy levels around the
  nucleus (electron cloud).
 The higher the energy level, the more
  energy is required for an electron to
  occupy that part of the cloud.
 The outermost part of the electron cloud
  contains the valence electrons – that is
  the valence shell.
 Maximum number of valence electrons in
  an atom is 8.
 Atoms are stable
  when they have 8
  valence electrons.
 When the atoms
  have 8 electrons, it is
  called an octet .
 Atoms must lose,
  gain or share
  electrons to attain
  the octet.
 Atoms that form bonds with other atoms by
   sharing them or transferring them is known as
   the Octet Rule .
There is always an exception!
             Hydrogen and Helium
             Hydrogen needs only
              one more to fill its
              valence shell.
             Helium has a full
              valence shell – it is
              stable and does not
              bond with other
              atoms.
So what about Lithium?


 Is it easier for
 Lithium to gain 7
electrons or lose 1
     electron?
Bond…. Chemical Bonds
  Ionic Bonds
  They are formed when atoms
   gain or lose electrons.
  If the compound has a metal,
   then it is an ionic bond.
  Ex.

                     xx

          Na Cl  x        x
                          x
             xx
 When it loses 1
   Ionization              electron to become
                           more stable, it has
                           11 protons (+) and
 When atoms gain          10 electrons (-) and
  or lose an electron,     has a +1 charge.
                          Cl has 17 protons.
  they become an
                          When Cl gains 1
  ion.
                           electron to complete
 A Na atom has 11         the octet, it has 17
  positively charged       protons (+) and 18
  protons and 11           electrons (-).
  negatively charged      It is now an ion with
  electrons.               a –1 charge.
Opposites Attract
 Since the Na has a + charge and the
 Cl has a – charge, the two atoms are
 attracted together and form an ionic
 bond.
 They have a 1:1 ratio when they
 combine…..
Covalent Bonds
 Atoms that share electrons form
  covalent bonds.
 If the atoms have a covalent bond
  and are the same type of atom….
  They are diatomic molecules.
 Ex.      xx    xx
       x
       x   Cl Cl
           xx
              x
              x
                   x
                   x
              xx
Element    Bonding   Formula

Hydrogen    H-H        H2
Oxygen      O-O        O2
Nitrogen    N-N        N2
Fluorine    F-F        F2
Chlorine   Cl-Cl       Cl2
Bromine    Br-Br      Br2
 Iodine     I-I        I2
Metallic Bonding
 Metallic bonds - electrons are distributed
  equally through a metallic crystal.
 The electrons in metals can be thought of
  as being property of all the atoms.
 The positive nuclei are surrounded by a
  "sea of electrons" that are all attracted by
  the nuclei at the same time.
So you ask…. “How do I know
  if it is covalent or ionic?”
 Ionic bonds are formed by the attraction of
  two oppositely charged particles.
 Covalent bonds are formed when atoms
  share electrons.
 Typically bonds between metals and
  nonmetals form ionic bonds.
 Bonds between two nonmetals form
  covalent bonds.
Isn’t it ionic, don’t you think
 Electron pairs sometimes share
  unequally in covalent bonds.
 The attraction an atom has for the
  shared pair of electrons in a covalent
  bond is called electronegativity .
 High Electronegativity
                          (need to gain
                          electrons)
 Low Electronegativity  Atoms in Column 17
  (need to lose           have high
  electrons)              electronegativity.
 Atoms in Columns 1
  and 2 have low
  electronegativity.    Cl       F      Br
 H       K       Li

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Chemical bonds.ppt

  • 2. Why atoms form chemical bonds  Electrons are in energy levels around the nucleus (electron cloud).  The higher the energy level, the more energy is required for an electron to occupy that part of the cloud.  The outermost part of the electron cloud contains the valence electrons – that is the valence shell.  Maximum number of valence electrons in an atom is 8.
  • 3.  Atoms are stable when they have 8 valence electrons.  When the atoms have 8 electrons, it is called an octet .  Atoms must lose, gain or share electrons to attain the octet.  Atoms that form bonds with other atoms by sharing them or transferring them is known as the Octet Rule .
  • 4. There is always an exception!  Hydrogen and Helium  Hydrogen needs only one more to fill its valence shell.  Helium has a full valence shell – it is stable and does not bond with other atoms.
  • 5. So what about Lithium?  Is it easier for Lithium to gain 7 electrons or lose 1 electron?
  • 6. Bond…. Chemical Bonds  Ionic Bonds  They are formed when atoms gain or lose electrons.  If the compound has a metal, then it is an ionic bond.  Ex. xx Na Cl x x x xx
  • 7.  When it loses 1 Ionization electron to become more stable, it has 11 protons (+) and  When atoms gain 10 electrons (-) and or lose an electron, has a +1 charge.  Cl has 17 protons. they become an  When Cl gains 1 ion. electron to complete  A Na atom has 11 the octet, it has 17 positively charged protons (+) and 18 protons and 11 electrons (-). negatively charged  It is now an ion with electrons. a –1 charge.
  • 8. Opposites Attract  Since the Na has a + charge and the Cl has a – charge, the two atoms are attracted together and form an ionic bond.  They have a 1:1 ratio when they combine…..
  • 9. Covalent Bonds  Atoms that share electrons form covalent bonds.  If the atoms have a covalent bond and are the same type of atom…. They are diatomic molecules.  Ex. xx xx x x Cl Cl xx x x x x xx
  • 10. Element Bonding Formula Hydrogen H-H H2 Oxygen O-O O2 Nitrogen N-N N2 Fluorine F-F F2 Chlorine Cl-Cl Cl2 Bromine Br-Br Br2 Iodine I-I I2
  • 11. Metallic Bonding  Metallic bonds - electrons are distributed equally through a metallic crystal.  The electrons in metals can be thought of as being property of all the atoms.  The positive nuclei are surrounded by a "sea of electrons" that are all attracted by the nuclei at the same time.
  • 12. So you ask…. “How do I know if it is covalent or ionic?”  Ionic bonds are formed by the attraction of two oppositely charged particles.  Covalent bonds are formed when atoms share electrons.  Typically bonds between metals and nonmetals form ionic bonds.  Bonds between two nonmetals form covalent bonds.
  • 13. Isn’t it ionic, don’t you think  Electron pairs sometimes share unequally in covalent bonds.  The attraction an atom has for the shared pair of electrons in a covalent bond is called electronegativity .
  • 14.  High Electronegativity (need to gain electrons)  Low Electronegativity  Atoms in Column 17 (need to lose have high electrons) electronegativity.  Atoms in Columns 1 and 2 have low electronegativity. Cl F Br H K Li