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Zeolite effects on soil organic carbon and
structure against erosion in vineyards
M. Gispert1, G. Masciandaro2, E. Peruzzi2, C. Macci2, C.M.
Masini3, D. Manzi4, G. Mattii5, S. Doni2
1University of Girona,
2CNR-IRET,
3Tenuta di Poggio S. S. società agricola,
4DN360
5University of Florence
1
2
7,5 mha global area under vines in 2015
Rest of the
world 50%
Spain
14%
China
11%
France
10%
Italy
9%
Turkey
7%
Share of countries in world area
surface
5 countries
represent
50% of
world
vineyard
AGRONOMIC PRACTICES THAT AFFECT SOIL QUALITY
IN VINEYARD SOILS
continuous working practices using heavy machinery
inappropriate tillage for eliminating competition between vines and other
plants for water and nutrients
excessive inputs of fertilizer and phytopharmaceutical products
The loss of soil determines the decline of soil fertility and sustainability in
terms of erosion, contamination, compaction and loss of biodiversity
EFFECT OF ZEOLITE ON SOIL FERTILITY
Zeolites have been proposed to improve
physical and chemical properties of agricultural
soils such as:
 water holding capacity,
 infiltration rate,
 saturated hydraulic conductivity,
 cation exchange capacity (high
absorption/desorption capacity for several
cations)
They are able to release nutrients
gradually for extended period of
time, making the efficiency of
fertilizers greater and the
leaching losses lower
Features of zeolites:
high surface area,
large pores or channels,
negative charges in the
structural framework,
high cation exchange
capacity.
OBJECTIVES
Potential of zeolite for improving vine
nutrition management in order to
reduce dependence from mineral
fertilizers in vineyard systems and
increase their fertility.
Vineyard variety: Trebbiano
The vineyard was divided into three plots with
zeolite at the dose:
0 t ha-1 (control),
5 t ha-1,
10 t ha-1
EXPERIMENTAL LAYOUT
Cosimo Maria Masini
Tenuta di Poggio S.S.,
San Miniato, Tuscany,
Italy.
CONTROL
5 t ha-1
10 t ha-1
Trebbiano variety one year old, not in
production yet
Zeolite application and integration in soil by ploughing to a depth of 30 cm
control 5 t ha-1 10 t ha-1
10 t ha-1
5 t ha-1
CONTROL
Sandy clay loam texture,
organic matter (OM)
content of 1.8%,
high carbonate amount
(bivalve shells were very
common), slightly
alkaline pH.
RESULTS
SOIL QUALITY INDICATORS
Chemical
Total and available
nutrients (Nitrogen,
Phosphorus,
Potassium)
CEC
Chemical-structural
composition of
organic matter
Physical
Texture
Aggregate stability
Soil shrinkage
Biological and
Biochemical
Soil respiration
Biological activity
Glomalin related
soil protein
10
b b
a
0.0
0.2
0.4
0.6
0.8
1.0
%K
Total Potassium
Total nutrients
a a a
0.0
0.2
0.4
0.6
0.8
1.0
1.2%
Total Organic Carbon
control
5 t ha-1
10 t ha-1
b
b a
0.00
0.05
0.10
0.15
%N Total N
11
c
b
a
0
5
10
15
20
25cmolckg-1
C.E.C.
control
5 t ha-1
10 t ha-1
Nutrient availability
b
a a
0.00
0.01
0.01
0.02
0.02
0.03
0.03
0.04
%K
Available K
b
a
a
0.0
0.2
0.4
0.6
0.8
mgNH4
+kg-1
Ammonia
b
a
a
0
10
20
30
40
mgNO3
-kg-1
Nitrate
12
b
ab
a
0.0
0.2
0.4
0.6
0.8
1.0
1.2
mgINTFkg-1h-1
Dehydrogenase activity
control
5 t ha-1
10 t ha-1
Microorganism
metabolic activity
Benzene (B) / Toluene (E3)
Benzene is derived
from condensed
aromatic structures;
toluene comes from
aromatic
uncondensed rings
with aliphatic
chains.
a
b
b
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
Humification Index
b
a a
0.0
0.2
0.4
0.6
0.8
1.0
Mineralization Index
Aliphatic (AL) / Aromatic (AR) compounds
Chemical
Chemical-structural
composition of organic
matter
13
Physical
Aggregate stability
Soil shrinkage
a a a
0
20
40
60
80
100
%
WSA(0.25-2)
a a a
0.0
0.2
0.4
0.6
0.8
gGRSPkg-1
Glomalin related soil protein - GRSP
b
a
b
0
20
40
60
80
100
%
WSA(2-5.6)
5 t ha-1
CONTROL
a
b b
0
5
10
15
20
25
Area%ofsurfaceshikage
Total craks
CONCLUSIONS
The application of zeolite to the vineyard soils, especially at the
highest dose (10 t ha-1) improved their cations exchange capacity and
thus their ability to retain nutrients.
The increase of available N and K significantly promoted microbial
metabolic activity and utilization of soil organic matter, with the
consequent change in soil organic matter evolution.
The dose 5 t ha-1 seems to be effective in improving soil structure and
stability, thus mitigating erosion processes in vineyard soils.
Other studies about zeolite application in combination with a source
of organic matter are carrying out in the framework of the LIFE
ZEOWINE project.
Starting from the proven efficacy features for both compost and zeolite, the LIFE
ZEOWINE project will demonstrate the improvement of:
 soil protection and sustainability,
grape quality,
yield stability
through the development and application of an innovative by-product (ZEOWINE)
derived from composting of winery wastes and natural zeolites
LIFE17 ENV/IT/000427
Policy implications
to protect the soil and preserve its capacity to perform its ecological,
economic, social and cultural functions COM (2006) 231 Thematic
Strategy for Soil Protection
develop further actions, aimed at transferring the results achieved by
this study in other agricultural productive chains
Zeolite effects on soil organic carbon and structure against erosion in vineyards

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Zeolite effects on soil organic carbon and structure against erosion in vineyards

  • 1. Zeolite effects on soil organic carbon and structure against erosion in vineyards M. Gispert1, G. Masciandaro2, E. Peruzzi2, C. Macci2, C.M. Masini3, D. Manzi4, G. Mattii5, S. Doni2 1University of Girona, 2CNR-IRET, 3Tenuta di Poggio S. S. società agricola, 4DN360 5University of Florence 1
  • 2. 2 7,5 mha global area under vines in 2015 Rest of the world 50% Spain 14% China 11% France 10% Italy 9% Turkey 7% Share of countries in world area surface 5 countries represent 50% of world vineyard
  • 3. AGRONOMIC PRACTICES THAT AFFECT SOIL QUALITY IN VINEYARD SOILS continuous working practices using heavy machinery inappropriate tillage for eliminating competition between vines and other plants for water and nutrients excessive inputs of fertilizer and phytopharmaceutical products The loss of soil determines the decline of soil fertility and sustainability in terms of erosion, contamination, compaction and loss of biodiversity
  • 4. EFFECT OF ZEOLITE ON SOIL FERTILITY Zeolites have been proposed to improve physical and chemical properties of agricultural soils such as:  water holding capacity,  infiltration rate,  saturated hydraulic conductivity,  cation exchange capacity (high absorption/desorption capacity for several cations) They are able to release nutrients gradually for extended period of time, making the efficiency of fertilizers greater and the leaching losses lower Features of zeolites: high surface area, large pores or channels, negative charges in the structural framework, high cation exchange capacity.
  • 5. OBJECTIVES Potential of zeolite for improving vine nutrition management in order to reduce dependence from mineral fertilizers in vineyard systems and increase their fertility.
  • 6. Vineyard variety: Trebbiano The vineyard was divided into three plots with zeolite at the dose: 0 t ha-1 (control), 5 t ha-1, 10 t ha-1 EXPERIMENTAL LAYOUT Cosimo Maria Masini Tenuta di Poggio S.S., San Miniato, Tuscany, Italy. CONTROL 5 t ha-1 10 t ha-1 Trebbiano variety one year old, not in production yet
  • 7. Zeolite application and integration in soil by ploughing to a depth of 30 cm
  • 8. control 5 t ha-1 10 t ha-1 10 t ha-1 5 t ha-1 CONTROL Sandy clay loam texture, organic matter (OM) content of 1.8%, high carbonate amount (bivalve shells were very common), slightly alkaline pH.
  • 9. RESULTS SOIL QUALITY INDICATORS Chemical Total and available nutrients (Nitrogen, Phosphorus, Potassium) CEC Chemical-structural composition of organic matter Physical Texture Aggregate stability Soil shrinkage Biological and Biochemical Soil respiration Biological activity Glomalin related soil protein
  • 10. 10 b b a 0.0 0.2 0.4 0.6 0.8 1.0 %K Total Potassium Total nutrients a a a 0.0 0.2 0.4 0.6 0.8 1.0 1.2% Total Organic Carbon control 5 t ha-1 10 t ha-1 b b a 0.00 0.05 0.10 0.15 %N Total N
  • 11. 11 c b a 0 5 10 15 20 25cmolckg-1 C.E.C. control 5 t ha-1 10 t ha-1 Nutrient availability b a a 0.00 0.01 0.01 0.02 0.02 0.03 0.03 0.04 %K Available K b a a 0.0 0.2 0.4 0.6 0.8 mgNH4 +kg-1 Ammonia b a a 0 10 20 30 40 mgNO3 -kg-1 Nitrate
  • 12. 12 b ab a 0.0 0.2 0.4 0.6 0.8 1.0 1.2 mgINTFkg-1h-1 Dehydrogenase activity control 5 t ha-1 10 t ha-1 Microorganism metabolic activity Benzene (B) / Toluene (E3) Benzene is derived from condensed aromatic structures; toluene comes from aromatic uncondensed rings with aliphatic chains. a b b 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 Humification Index b a a 0.0 0.2 0.4 0.6 0.8 1.0 Mineralization Index Aliphatic (AL) / Aromatic (AR) compounds Chemical Chemical-structural composition of organic matter
  • 13. 13 Physical Aggregate stability Soil shrinkage a a a 0 20 40 60 80 100 % WSA(0.25-2) a a a 0.0 0.2 0.4 0.6 0.8 gGRSPkg-1 Glomalin related soil protein - GRSP b a b 0 20 40 60 80 100 % WSA(2-5.6) 5 t ha-1 CONTROL a b b 0 5 10 15 20 25 Area%ofsurfaceshikage Total craks
  • 14. CONCLUSIONS The application of zeolite to the vineyard soils, especially at the highest dose (10 t ha-1) improved their cations exchange capacity and thus their ability to retain nutrients. The increase of available N and K significantly promoted microbial metabolic activity and utilization of soil organic matter, with the consequent change in soil organic matter evolution. The dose 5 t ha-1 seems to be effective in improving soil structure and stability, thus mitigating erosion processes in vineyard soils. Other studies about zeolite application in combination with a source of organic matter are carrying out in the framework of the LIFE ZEOWINE project.
  • 15. Starting from the proven efficacy features for both compost and zeolite, the LIFE ZEOWINE project will demonstrate the improvement of:  soil protection and sustainability, grape quality, yield stability through the development and application of an innovative by-product (ZEOWINE) derived from composting of winery wastes and natural zeolites LIFE17 ENV/IT/000427 Policy implications to protect the soil and preserve its capacity to perform its ecological, economic, social and cultural functions COM (2006) 231 Thematic Strategy for Soil Protection develop further actions, aimed at transferring the results achieved by this study in other agricultural productive chains

Editor's Notes

  1. The GRSP is a glycoprotein produced by endomycorrhizal fungi and it is defined as a major carbon pool in soil, contributing to the physical stability of soil because of its hydrophobic properties. Recent results have described glomalin as a primary soil component in the formation and maintenance of soil structure. Values of GRSP resulted very low with respect to SOC and they were no significantly different in zeolite treatments with respect to control soil. GRSP is part of soil recalcitrant organic compounds. The vineyard soils showed an unusual high aggregate stability in the 0.25–2.00 mm aggregate fraction. While lower WSA values were found in the 2.00–5.60 mm aggregate fraction probably more susceptible to water action for their larger volume but lower mineral-organic colloid strengths. These results may suggest that a larger aggregate stability is maintained in the lower aggregate fraction which seems reasonable considering that smaller aggregate may better conserve architectural frame The increase in small size cracks (< 500 μm) corresponding to micro-porosity, was considered important for maintaining optimum conditions of humidity for plant and microorganisms, whereas the increase in small-medium size cracks (500–1000 μm), representing the micro-habitat for soil microorganisms, was very important for microbiological and biochemical processes The improvement of the soil structure is of great agronomic relevance because good physical properties favour water retention, oxygen diffusion, and nutrient availability, which can all improve soil quality and fertility