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Reflectance	
  Spectra	
  of	
  the	
  Juneau	
  Icefield
Adrian	
  Peter,	
  University	
  of	
  Zurich,	
  ZH,	
  Switzerland
Elizabeth	
  Perera,	
  DePaul	
  University,	
  IL,	
  USA
4.2	
  Analysis	
  of	
  Snow	
  Impurities	
  in	
  Suncups
4.3	
  Organic	
  Matter	
  Analysis
• Percent	
  organic	
  matter	
  within	
  each	
  sample	
  correlated	
  with	
  
reflectance	
  readings	
  taken	
  on	
  the	
  Icefield.	
  
• Dirty	
  snow	
  largely	
  showed	
  the	
  most	
  organic	
  matter,	
  followed	
  by	
  red	
  
algae	
  and	
  finally,	
  clean	
  snow.
• Both	
  organic	
  and	
  inorganic	
  matter	
  contribute	
  to	
  darkening.
• Outliers	
  may	
  be	
  due	
  to	
  changing	
  cloud	
  conditions.
4.	
  Results
4.1	
  Clean	
  Snow	
  Grain	
  Size	
  Analysis	
  
• High	
  JIF	
  reflectances match	
  published	
  spectra	
  (Nolin	
  &	
  Dozier	
  2000).	
  
• Grain	
  size	
  estimated	
  using	
  size	
  of	
  certain	
  absorption	
  features.
• Snow	
  on	
  the	
  JIF	
  is	
  both	
  very	
  wet,	
  with	
  large	
  grains.	
  
• No	
  discernable	
  difference	
  in	
  reflectance	
  of	
  small	
  grain	
  sizes	
  versus	
  
large	
  grain	
  sizes,	
  but	
  more	
  variability	
  seen	
  in	
  spectral	
  grain	
  size	
  
measurements	
  than	
  in	
  field	
  observations.
3.	
  Data	
  Collection
• Hemispherical-­‐directional	
  reflectance	
  (HDR)	
  spectra	
  were	
  collected	
  
during	
  the	
  summer	
  of	
  2015.	
  
• An	
  18	
  degree	
  foreoptic was	
  used,	
  yielding	
  a	
  viewing	
  footprint	
  
approximately	
  40	
  cm	
  in	
  diameter.
• Sample	
  locations	
  were	
  distributed	
  throughout	
  the	
  accumulation	
  and	
  
ablation	
  zone	
  of	
  the	
  Juneau	
  Icefield	
  (JIF).
Figure	
  2.	
  Schematic	
  of	
  HDR	
  data	
  collection	
  method.
• Biomass	
  was	
  analyzed	
  using	
  a	
  chemical	
  digestion.	
  Material	
  taken	
  
from	
  water	
  samples	
  was	
  dried,	
  hydrogen	
  peroxide	
  added,	
  and	
  the	
  
sample	
  heated.	
  After	
  24	
  hours	
  in	
  the	
  oven,	
  percent	
  organic	
  matter	
  
was	
  determined	
  from	
  the	
  difference	
  in	
  weight.	
  
1.	
  Introduction
The	
  reflectance	
  of	
  snow	
  and	
  its	
  associated	
  albedo	
  effect	
  the	
  
snowpack’s	
  energy	
  balance	
  (Dozier	
  et	
  al.	
  2009).	
  Several	
  different	
  
properties	
  affect	
  the	
  reflectance	
  of	
  snow	
  including:	
  water	
  content,	
  
grain	
  size,	
  and	
  the	
  presence	
  of	
  dust	
  and	
  organic	
  matter	
  on	
  the	
  snow	
  
surface.	
  Variations	
  in	
  these	
  conditions	
  effects	
  the	
  amount	
  solar	
  
radiation	
  that	
  is	
  reflected	
  off	
  the	
  surface	
  and	
  back	
  into	
  the	
  atmosphere	
  
(Bøggild et	
  al.	
  2010),	
  and	
  each	
  effect	
  has	
  a	
  different	
  spectra	
  response.
Figure	
  1.	
  How	
  variations	
  in	
  grain	
  size	
  and	
  the	
  presence	
  of	
  impurities	
  
affects	
  reflectance.
Changes	
  in	
  the	
  amount	
  of	
  solar	
  radiation	
  that	
  is	
  reflected	
  off	
  the	
  snow	
  
in	
  turn	
  effects	
  the	
  amount	
  and	
  rate	
  of	
  surface	
  melting	
  that	
  occurs	
  
across	
  the	
  glacier	
  during	
  the	
  ablation	
  season	
  (Painter	
  et	
  al.	
  2013).
References	
  Cited:
Bøggild et	
  al.	
  2010.	
  J.	
  of	
  Glac.,	
  56	
  (195),	
  101-­‐113.
Dozier	
  et	
  al.	
  2009.	
  Remote	
  Sens.	
  Environ.,	
  113,	
  S25-­‐S37.
Nolin	
  and	
  Dozier	
  2000.	
  Remote	
  Sens.	
  Environ.,	
  74,	
  207-­‐216.
Painter	
  et	
  al.	
  2013.	
  J.	
  of	
  Geophys.	
  Res,	
  118,	
  9511-­‐9523.
2.	
  Research	
  Questions
Impurities,	
  algae,	
  and	
  large	
  snow	
  grains	
  all	
  reduce	
  the	
  reflectance	
  of	
  
shortwave	
  radiation	
  but	
  with	
  unique	
  spectral	
  signatures	
  (e.g., Dozier	
  et	
  
al.	
  2009).	
  
1. Spectral	
  reflectance	
  was	
  measured	
  for	
  a	
  range	
  of	
  targets,	
  creating	
  a	
  
spectral	
  catalogue	
  of	
  the	
  Taku	
  glacier	
  system.
2. Using	
  this	
  spectral	
  library:
• Red	
  algae	
  biomass	
  was	
  linked	
  to	
  spectral	
  reflectance
• Effect	
  of	
  impurities	
  in	
  suncups was	
  quantified
• Snow	
  grain	
  size	
  retrieval	
  algorithm	
  was	
  tested.
Small	Grain	Size	 Large	Grain	Size	
Impuri1es		
(dust	and	organic	ma8er)	
5.79
8
0.54
2.7
1.07
3.83
0.23 0.32 0.080
1
2
3
4
5
6
7
8
9
0.5 1 1.5 2 2.5 3 3.5
Percentages	
  (%)
Sample	
  number	
  
Percent	
  Organic	
  Matter	
  
Dirty	
  Snow	
  
Red	
  Algae	
  
Clean	
  Snow	
  
Figure	
  3. Grain	
  size	
  algorithm	
  versus	
  
ground-­‐truth	
  data.
a)
b)
Katherine	
  Popyack,	
  Hartwick College,	
  NY,	
  USA
Lara	
  Hughes-­‐Allen,	
  University	
  of	
  Southern	
  California,	
  USA
Allen	
  Pope,	
  National	
  Snow	
  and	
  Ice	
  Data	
  Center,	
  CIRES,	
  University	
  
of	
  Colorado	
  Boulder,	
  CO,	
  USA	
  – allen.pope@nsidc.org
a)	
  Qualitative	
  snow	
  categories	
  mean	
  with	
  
standard	
  deviation	
  show	
  as	
  dashed	
  lines.	
  
b)	
  Impurity	
  reflectance	
  ratio	
  (RR)	
  at	
  588	
  nm	
  
absorption	
  shoulder	
  calculated	
  by	
  using	
  the	
  
concept	
  of	
  continuum	
  removal.

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PRESENTATION XU - Copy
 

Reflectance Spectra of the Juneau Icefield

  • 1. Reflectance  Spectra  of  the  Juneau  Icefield Adrian  Peter,  University  of  Zurich,  ZH,  Switzerland Elizabeth  Perera,  DePaul  University,  IL,  USA 4.2  Analysis  of  Snow  Impurities  in  Suncups 4.3  Organic  Matter  Analysis • Percent  organic  matter  within  each  sample  correlated  with   reflectance  readings  taken  on  the  Icefield.   • Dirty  snow  largely  showed  the  most  organic  matter,  followed  by  red   algae  and  finally,  clean  snow. • Both  organic  and  inorganic  matter  contribute  to  darkening. • Outliers  may  be  due  to  changing  cloud  conditions. 4.  Results 4.1  Clean  Snow  Grain  Size  Analysis   • High  JIF  reflectances match  published  spectra  (Nolin  &  Dozier  2000).   • Grain  size  estimated  using  size  of  certain  absorption  features. • Snow  on  the  JIF  is  both  very  wet,  with  large  grains.   • No  discernable  difference  in  reflectance  of  small  grain  sizes  versus   large  grain  sizes,  but  more  variability  seen  in  spectral  grain  size   measurements  than  in  field  observations. 3.  Data  Collection • Hemispherical-­‐directional  reflectance  (HDR)  spectra  were  collected   during  the  summer  of  2015.   • An  18  degree  foreoptic was  used,  yielding  a  viewing  footprint   approximately  40  cm  in  diameter. • Sample  locations  were  distributed  throughout  the  accumulation  and   ablation  zone  of  the  Juneau  Icefield  (JIF). Figure  2.  Schematic  of  HDR  data  collection  method. • Biomass  was  analyzed  using  a  chemical  digestion.  Material  taken   from  water  samples  was  dried,  hydrogen  peroxide  added,  and  the   sample  heated.  After  24  hours  in  the  oven,  percent  organic  matter   was  determined  from  the  difference  in  weight.   1.  Introduction The  reflectance  of  snow  and  its  associated  albedo  effect  the   snowpack’s  energy  balance  (Dozier  et  al.  2009).  Several  different   properties  affect  the  reflectance  of  snow  including:  water  content,   grain  size,  and  the  presence  of  dust  and  organic  matter  on  the  snow   surface.  Variations  in  these  conditions  effects  the  amount  solar   radiation  that  is  reflected  off  the  surface  and  back  into  the  atmosphere   (Bøggild et  al.  2010),  and  each  effect  has  a  different  spectra  response. Figure  1.  How  variations  in  grain  size  and  the  presence  of  impurities   affects  reflectance. Changes  in  the  amount  of  solar  radiation  that  is  reflected  off  the  snow   in  turn  effects  the  amount  and  rate  of  surface  melting  that  occurs   across  the  glacier  during  the  ablation  season  (Painter  et  al.  2013). References  Cited: Bøggild et  al.  2010.  J.  of  Glac.,  56  (195),  101-­‐113. Dozier  et  al.  2009.  Remote  Sens.  Environ.,  113,  S25-­‐S37. Nolin  and  Dozier  2000.  Remote  Sens.  Environ.,  74,  207-­‐216. Painter  et  al.  2013.  J.  of  Geophys.  Res,  118,  9511-­‐9523. 2.  Research  Questions Impurities,  algae,  and  large  snow  grains  all  reduce  the  reflectance  of   shortwave  radiation  but  with  unique  spectral  signatures  (e.g., Dozier  et   al.  2009).   1. Spectral  reflectance  was  measured  for  a  range  of  targets,  creating  a   spectral  catalogue  of  the  Taku  glacier  system. 2. Using  this  spectral  library: • Red  algae  biomass  was  linked  to  spectral  reflectance • Effect  of  impurities  in  suncups was  quantified • Snow  grain  size  retrieval  algorithm  was  tested. Small Grain Size Large Grain Size Impuri1es (dust and organic ma8er) 5.79 8 0.54 2.7 1.07 3.83 0.23 0.32 0.080 1 2 3 4 5 6 7 8 9 0.5 1 1.5 2 2.5 3 3.5 Percentages  (%) Sample  number   Percent  Organic  Matter   Dirty  Snow   Red  Algae   Clean  Snow   Figure  3. Grain  size  algorithm  versus   ground-­‐truth  data. a) b) Katherine  Popyack,  Hartwick College,  NY,  USA Lara  Hughes-­‐Allen,  University  of  Southern  California,  USA Allen  Pope,  National  Snow  and  Ice  Data  Center,  CIRES,  University   of  Colorado  Boulder,  CO,  USA  – allen.pope@nsidc.org a)  Qualitative  snow  categories  mean  with   standard  deviation  show  as  dashed  lines.   b)  Impurity  reflectance  ratio  (RR)  at  588  nm   absorption  shoulder  calculated  by  using  the   concept  of  continuum  removal.